GB1074645A - Process for the production of polyurethanes - Google Patents

Process for the production of polyurethanes

Info

Publication number
GB1074645A
GB1074645A GB2705165A GB2705165A GB1074645A GB 1074645 A GB1074645 A GB 1074645A GB 2705165 A GB2705165 A GB 2705165A GB 2705165 A GB2705165 A GB 2705165A GB 1074645 A GB1074645 A GB 1074645A
Authority
GB
United Kingdom
Prior art keywords
hydroxyl
polymer
ended
ended polymer
diisocyanates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2705165A
Inventor
Raymond Joseph Marklow
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB2705165A priority Critical patent/GB1074645A/en
Publication of GB1074645A publication Critical patent/GB1074645A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/089Reaction retarding agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

Elastomeric polyurethanes are prepared by reacting an organic polyisocyanate with an hydroxyl-ended polymer in the presence of 0.001% to 0.1%, by weight of the hydroxylended polymer of thioglycollic acid. Aromatic diisocyanates such as tolylene-2,4 and -2,6-diisocyanates and mixtures thereof and 4,41-diisocyanato - diphenylmethan are preferred, whilst the hydroxyl-ended polymer is suitably a polyester containing a small amount of branching e.g. those derived from acids such as adipic acid with glycols such as ethylene, diethylene, propylene and butylene glycols together with small proportions of polyhydric alcohols having more than two hydroxyl groups such as glycerol, trimethylol propane, hexanetriol and pentaerythritol. The process is conveniently carried out by adding the thioglycollic acid to the dry hydroxyl-ended polymer, which mixture is then reacted with the polyisocyanate.
GB2705165A 1965-06-25 1965-06-25 Process for the production of polyurethanes Expired GB1074645A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2705165A GB1074645A (en) 1965-06-25 1965-06-25 Process for the production of polyurethanes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2705165A GB1074645A (en) 1965-06-25 1965-06-25 Process for the production of polyurethanes

Publications (1)

Publication Number Publication Date
GB1074645A true GB1074645A (en) 1967-07-05

Family

ID=10253370

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2705165A Expired GB1074645A (en) 1965-06-25 1965-06-25 Process for the production of polyurethanes

Country Status (1)

Country Link
GB (1) GB1074645A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2596292A1 (en) * 1986-03-27 1987-10-02 Ashland Oil Inc TENSILE OR TIN COMPLEX CATALYST, REACTION MIXTURE OF POLYOL / POLYISOCYANATE CATALYSIS CONTAINING THE SAME, AND PROCESS FOR CURING SUCH A MIXTURE
EP0276667A2 (en) * 1987-01-12 1988-08-03 Ashland Oil, Inc. Stabilized moisture curable polyurethane coatings

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2596292A1 (en) * 1986-03-27 1987-10-02 Ashland Oil Inc TENSILE OR TIN COMPLEX CATALYST, REACTION MIXTURE OF POLYOL / POLYISOCYANATE CATALYSIS CONTAINING THE SAME, AND PROCESS FOR CURING SUCH A MIXTURE
BE1001374A3 (en) * 1986-03-27 1989-10-17 Ashland Oil Inc Catalyst complex based or tin bismuth and their use for the initiation of coatings outlet.
EP0276667A2 (en) * 1987-01-12 1988-08-03 Ashland Oil, Inc. Stabilized moisture curable polyurethane coatings
EP0276667A3 (en) * 1987-01-12 1988-12-07 Ashland Oil, Inc. Stabilized moisture curable polyurethane coatings
JPH0730282B2 (en) 1987-01-12 1995-04-05 アツシユランド・オイル・インコーポレーテツド Method for increasing storage stability of moisture-curable polyurethane coating composition

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