GB1074645A - Process for the production of polyurethanes - Google Patents
Process for the production of polyurethanesInfo
- Publication number
- GB1074645A GB1074645A GB2705165A GB2705165A GB1074645A GB 1074645 A GB1074645 A GB 1074645A GB 2705165 A GB2705165 A GB 2705165A GB 2705165 A GB2705165 A GB 2705165A GB 1074645 A GB1074645 A GB 1074645A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydroxyl
- polymer
- ended
- ended polymer
- diisocyanates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/089—Reaction retarding agents
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Elastomeric polyurethanes are prepared by reacting an organic polyisocyanate with an hydroxyl-ended polymer in the presence of 0.001% to 0.1%, by weight of the hydroxylended polymer of thioglycollic acid. Aromatic diisocyanates such as tolylene-2,4 and -2,6-diisocyanates and mixtures thereof and 4,41-diisocyanato - diphenylmethan are preferred, whilst the hydroxyl-ended polymer is suitably a polyester containing a small amount of branching e.g. those derived from acids such as adipic acid with glycols such as ethylene, diethylene, propylene and butylene glycols together with small proportions of polyhydric alcohols having more than two hydroxyl groups such as glycerol, trimethylol propane, hexanetriol and pentaerythritol. The process is conveniently carried out by adding the thioglycollic acid to the dry hydroxyl-ended polymer, which mixture is then reacted with the polyisocyanate.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2705165A GB1074645A (en) | 1965-06-25 | 1965-06-25 | Process for the production of polyurethanes |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2705165A GB1074645A (en) | 1965-06-25 | 1965-06-25 | Process for the production of polyurethanes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1074645A true GB1074645A (en) | 1967-07-05 |
Family
ID=10253370
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2705165A Expired GB1074645A (en) | 1965-06-25 | 1965-06-25 | Process for the production of polyurethanes |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1074645A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2596292A1 (en) * | 1986-03-27 | 1987-10-02 | Ashland Oil Inc | TENSILE OR TIN COMPLEX CATALYST, REACTION MIXTURE OF POLYOL / POLYISOCYANATE CATALYSIS CONTAINING THE SAME, AND PROCESS FOR CURING SUCH A MIXTURE |
EP0276667A2 (en) * | 1987-01-12 | 1988-08-03 | Ashland Oil, Inc. | Stabilized moisture curable polyurethane coatings |
-
1965
- 1965-06-25 GB GB2705165A patent/GB1074645A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2596292A1 (en) * | 1986-03-27 | 1987-10-02 | Ashland Oil Inc | TENSILE OR TIN COMPLEX CATALYST, REACTION MIXTURE OF POLYOL / POLYISOCYANATE CATALYSIS CONTAINING THE SAME, AND PROCESS FOR CURING SUCH A MIXTURE |
BE1001374A3 (en) * | 1986-03-27 | 1989-10-17 | Ashland Oil Inc | Catalyst complex based or tin bismuth and their use for the initiation of coatings outlet. |
EP0276667A2 (en) * | 1987-01-12 | 1988-08-03 | Ashland Oil, Inc. | Stabilized moisture curable polyurethane coatings |
EP0276667A3 (en) * | 1987-01-12 | 1988-12-07 | Ashland Oil, Inc. | Stabilized moisture curable polyurethane coatings |
JPH0730282B2 (en) | 1987-01-12 | 1995-04-05 | アツシユランド・オイル・インコーポレーテツド | Method for increasing storage stability of moisture-curable polyurethane coating composition |
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