GB809279A - Improvements in or relating to copper-containing polyazo dyestuffs - Google Patents
Improvements in or relating to copper-containing polyazo dyestuffsInfo
- Publication number
- GB809279A GB809279A GB6607/57A GB660757A GB809279A GB 809279 A GB809279 A GB 809279A GB 6607/57 A GB6607/57 A GB 6607/57A GB 660757 A GB660757 A GB 660757A GB 809279 A GB809279 A GB 809279A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sulphonic
- mono
- sulphonic acid
- acid
- pyrazolone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/24—Disazo or polyazo compounds
- C09B45/28—Disazo or polyazo compounds containing copper
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
- C09B35/36—Trisazo dyes of the type
- C09B35/366—D is diphenyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention comprises the partially or entirely coppered complexes of dyestuffs of formula <FORM:0809279/IV (c)/1> where R1 is the radicle of a 1,8-dihydroxynaphthalene mono- or di-sulphonic acid coupled o to OH, R2 is as Z or is the residue of any other azo compound coupled o to OH and R1 and R2 must together contain at least 2 SO3H groups. They are made by coupling in an alkaline medium 1 mol. of tetrazotized 4,41-diamino-3,31 - dimethoxy - 1,11 - diphenyl in either order with 1 mol. of the dyestuff corresponding to Z or preferably its copper complex and 1 mol. of the component corresponding to R2 with subsequent coppering in substance or on the fibre. R2 is preferably Z or its copper complex or a residue of a phenol, naphthol-mono-, -di- or tri-sulphonic acid, a dihydroxy-naphthalene-mono-or di-sulphonic acid, an acylaminonaphthol sulphonic acid, a 1-aryl-5-pyrazolone which may be sulphonated or an acetoacetylamino compound. The dyestuffs dye cotton and regenerated cellulose in blue-grey to green-grey shades. In examples which illustrate the preparation of the dyestuffs and their use in dyeing processes R2 is derived from 1-naphthol-3,6- and -3,8-di- and -3,6,8-tri-sulphonic acids, 2-naphthol-4-mono- and -3,6-di-sulphonic acids, 2-benzoylamino-5-naphthol-7-sulphonic acid, 4-methyl- and 4-methyl - 2 - acetyl - and sulphoacetyl - amino - phenols, acetylacetone, acetoacetylaminobenzene and its 4-sulphonic acid, 2-acetoacetylaminonaphthalene-7-sulphonic acid, barbituric acid, 1-phenyl-3-methyl-5-pyrazolone-21, -31- and -41-mono- and -21,41-di-sulphonic and -31-carboxylic acids, 1-naphthyl (21)-3-methyl-5-pyrazolone - 61 - sulphonic acid, 1 - phenyl - 5 - pyrazolone - 3 - carboxylic acid and 1,5-dihydroxy - 2 - (11,81 - dihydroxy) - naphthyl (21)-azonaphthalene - 7,31 - and - 7,41 - di - and -7,31,61-tri-sulphonic acids, R1 being derived from 1,8-dihydroxynaphthalene-3- and -4-mono-and -3,6-di-sulphonic acids. Reference has been directed by the Comptroller to Specification 644,883.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH809279X | 1956-03-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB809279A true GB809279A (en) | 1959-02-18 |
Family
ID=4538352
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB6607/57A Expired GB809279A (en) | 1956-03-13 | 1957-02-27 | Improvements in or relating to copper-containing polyazo dyestuffs |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB809279A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004046252A1 (en) | 2002-11-15 | 2004-06-03 | Avecia Inkjet Limited | Trisazo dyes for inks for ink jet printing |
-
1957
- 1957-02-27 GB GB6607/57A patent/GB809279A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004046252A1 (en) | 2002-11-15 | 2004-06-03 | Avecia Inkjet Limited | Trisazo dyes for inks for ink jet printing |
JP2006506499A (en) * | 2002-11-15 | 2006-02-23 | アベシア・インクジェット・リミテッド | Trisazo dye for inkjet printing ink |
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