GB809279A - Improvements in or relating to copper-containing polyazo dyestuffs - Google Patents

Improvements in or relating to copper-containing polyazo dyestuffs

Info

Publication number
GB809279A
GB809279A GB6607/57A GB660757A GB809279A GB 809279 A GB809279 A GB 809279A GB 6607/57 A GB6607/57 A GB 6607/57A GB 660757 A GB660757 A GB 660757A GB 809279 A GB809279 A GB 809279A
Authority
GB
United Kingdom
Prior art keywords
sulphonic
mono
sulphonic acid
acid
pyrazolone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB6607/57A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sandoz AG
Original Assignee
Sandoz AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sandoz AG filed Critical Sandoz AG
Publication of GB809279A publication Critical patent/GB809279A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B45/00Complex metal compounds of azo dyes
    • C09B45/02Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
    • C09B45/24Disazo or polyazo compounds
    • C09B45/28Disazo or polyazo compounds containing copper
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B35/00Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
    • C09B35/36Trisazo dyes of the type
    • C09B35/366D is diphenyl

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Abstract

The invention comprises the partially or entirely coppered complexes of dyestuffs of formula <FORM:0809279/IV (c)/1> where R1 is the radicle of a 1,8-dihydroxynaphthalene mono- or di-sulphonic acid coupled o to OH, R2 is as Z or is the residue of any other azo compound coupled o to OH and R1 and R2 must together contain at least 2 SO3H groups. They are made by coupling in an alkaline medium 1 mol. of tetrazotized 4,41-diamino-3,31 - dimethoxy - 1,11 - diphenyl in either order with 1 mol. of the dyestuff corresponding to Z or preferably its copper complex and 1 mol. of the component corresponding to R2 with subsequent coppering in substance or on the fibre. R2 is preferably Z or its copper complex or a residue of a phenol, naphthol-mono-, -di- or tri-sulphonic acid, a dihydroxy-naphthalene-mono-or di-sulphonic acid, an acylaminonaphthol sulphonic acid, a 1-aryl-5-pyrazolone which may be sulphonated or an acetoacetylamino compound. The dyestuffs dye cotton and regenerated cellulose in blue-grey to green-grey shades. In examples which illustrate the preparation of the dyestuffs and their use in dyeing processes R2 is derived from 1-naphthol-3,6- and -3,8-di- and -3,6,8-tri-sulphonic acids, 2-naphthol-4-mono- and -3,6-di-sulphonic acids, 2-benzoylamino-5-naphthol-7-sulphonic acid, 4-methyl- and 4-methyl - 2 - acetyl - and sulphoacetyl - amino - phenols, acetylacetone, acetoacetylaminobenzene and its 4-sulphonic acid, 2-acetoacetylaminonaphthalene-7-sulphonic acid, barbituric acid, 1-phenyl-3-methyl-5-pyrazolone-21, -31- and -41-mono- and -21,41-di-sulphonic and -31-carboxylic acids, 1-naphthyl (21)-3-methyl-5-pyrazolone - 61 - sulphonic acid, 1 - phenyl - 5 - pyrazolone - 3 - carboxylic acid and 1,5-dihydroxy - 2 - (11,81 - dihydroxy) - naphthyl (21)-azonaphthalene - 7,31 - and - 7,41 - di - and -7,31,61-tri-sulphonic acids, R1 being derived from 1,8-dihydroxynaphthalene-3- and -4-mono-and -3,6-di-sulphonic acids. Reference has been directed by the Comptroller to Specification 644,883.
GB6607/57A 1956-03-13 1957-02-27 Improvements in or relating to copper-containing polyazo dyestuffs Expired GB809279A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH809279X 1956-03-13

Publications (1)

Publication Number Publication Date
GB809279A true GB809279A (en) 1959-02-18

Family

ID=4538352

Family Applications (1)

Application Number Title Priority Date Filing Date
GB6607/57A Expired GB809279A (en) 1956-03-13 1957-02-27 Improvements in or relating to copper-containing polyazo dyestuffs

Country Status (1)

Country Link
GB (1) GB809279A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004046252A1 (en) 2002-11-15 2004-06-03 Avecia Inkjet Limited Trisazo dyes for inks for ink jet printing

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004046252A1 (en) 2002-11-15 2004-06-03 Avecia Inkjet Limited Trisazo dyes for inks for ink jet printing
JP2006506499A (en) * 2002-11-15 2006-02-23 アベシア・インクジェット・リミテッド Trisazo dye for inkjet printing ink

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