GB665993A - Process and composition for producing a dyeable corrosion-resistant coating on zinc and zinc alloys - Google Patents

Process and composition for producing a dyeable corrosion-resistant coating on zinc and zinc alloys

Info

Publication number
GB665993A
GB665993A GB16204/48A GB1620448A GB665993A GB 665993 A GB665993 A GB 665993A GB 16204/48 A GB16204/48 A GB 16204/48A GB 1620448 A GB1620448 A GB 1620448A GB 665993 A GB665993 A GB 665993A
Authority
GB
United Kingdom
Prior art keywords
acid
zinc
composition
per cent
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16204/48A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Plasco Ltd
Original Assignee
Plasco Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Plasco Ltd filed Critical Plasco Ltd
Publication of GB665993A publication Critical patent/GB665993A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/82After-treatment
    • C23C22/84Dyeing
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/24Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing hexavalent chromium compounds
    • C23C22/26Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing hexavalent chromium compounds containing also organic compounds
    • C23C22/27Acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Chemically Coating (AREA)

Abstract

A composition for producing a corrosion-resistant coating having good dye affinity on the surface of zinc and zinc-rich alloys comprises chromic acid or a water-soluble salt thereof in an amount equivalent to 145-155 grams per litre of chromium trioxide, lactic acid or a water-soluble lactate in an amount equivalent to 0.1-9 grams per litre of lactic acid, a strong mineral acid, e.g. sulphuric, nitric, hydrochloric or phosphoric, in an amount sufficient to impart a pH of 0.65-1.5 to the composition, and the balance water. After treatment and rinsing, the surface be dyed; and after further rinsing, dried at 140-150 DEG F, and cured at 150-250 DEG F for about 15 minutes.ALSO:A composition for producing a corrosion-resistant coating having good dye affinity on the surface of zinc and zinc-rich alloys comprises chromic acid or a water-soluble salt thereof in an amount equivalent to 145-155 grams per litre of chromium trioxide, lactic acid or a water-soluble lactate in an amount equivalent to 0.1-9 grams per litre of lactic acid, a strong mineral acid, e.g. sulphuric, nitric, hydrochloric or phosphoric, in amount sufficient to impart a pH of 0.65-1.5 to the composition, and the balance water. After treatment and rinsing, the surface may be dyed. Prior to treatment the surface may be cleaned with 1 per cent caustic soda solution at 200 DEG F, 0.5 per cent of sodium hexametaphosphate or sodium oleyl alcohol sulphonate or both being added, if desired. The alkali may be neutralized by washing with 1-2 per cent sulphuric acid which may contain naphthaline sulphonic acid. After dyeing and rinsing, the articles may be dried at 140-150 DEG F and cured at 150-250 DEG F for about 15 minutes. In one example, the cleaning stage is preceded by precleaning in a solution containing 0.5 per cent sodium lauryl sulphonate and 0.25 per cent sodium hexametaphosphate at 200-210 DEG F and pretreated with 3 per cent nitric acid at 75 DEG F.
GB16204/48A 1947-07-23 1948-06-16 Process and composition for producing a dyeable corrosion-resistant coating on zinc and zinc alloys Expired GB665993A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US665993XA 1947-07-23 1947-07-23

Publications (1)

Publication Number Publication Date
GB665993A true GB665993A (en) 1952-02-06

Family

ID=22070523

Family Applications (1)

Application Number Title Priority Date Filing Date
GB16204/48A Expired GB665993A (en) 1947-07-23 1948-06-16 Process and composition for producing a dyeable corrosion-resistant coating on zinc and zinc alloys

Country Status (1)

Country Link
GB (1) GB665993A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000018983A1 (en) * 1998-09-28 2000-04-06 Chemetall Gmbh Preparation of workpieces for cold forming

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000018983A1 (en) * 1998-09-28 2000-04-06 Chemetall Gmbh Preparation of workpieces for cold forming
US6482273B1 (en) 1998-09-28 2002-11-19 Chemetall Gmbh Preparation of workpieces for cold forming

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