GB589242A - Improvements in and relating to the preparation of salts of organic acids - Google Patents
Improvements in and relating to the preparation of salts of organic acidsInfo
- Publication number
- GB589242A GB589242A GB1824844A GB1824844A GB589242A GB 589242 A GB589242 A GB 589242A GB 1824844 A GB1824844 A GB 1824844A GB 1824844 A GB1824844 A GB 1824844A GB 589242 A GB589242 A GB 589242A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ester
- water
- oxygen
- converter
- esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
Abstract
A process for the production of metal salts of organic acids comprises heating one or more esters of an organic acid in the fluid state with lead, copper, cadmium, zinc, iron, nickel, silver or tin in the presence of water and oxygen. The process may be carried out (a) by passing oxygen or an oxygen containing gas such as air together with the ester and water (in an amount between 10 and 50 times that stoichiometrically required) into a converter having a high ratio of length to the greatest cross-sectional dimension and containing in fragmentary form the metal to be treated, or (b) by passing the gas into a suitable vessel such as the above described converter charged with the metal particles, ester and water. During both processes a portion of the fluid material may be removed from the converter and returned thereto at a point remote from where it was removed. In a modification the reaction is effected in a solvent for both the ester and metal salt. The process is executed at temperatures ranging from 50 DEG C to 200 DEG C and at normal or super atmospheric pressures. The esters specified are the methyl, ethyl, propyl, higher alkyl, glycerol and glycol esters of acetic, propionic, butyric, caproic, lauric, palmitic, stearic, ricinoleic, melissic glycollic, lactic, tartaric, oxalic, glutaric, adipic, acrylic, methacrylic, oleic, benzoic, and naphthenic acids, and the acids in coconut, corn, cottonseed, rapeseed and similar vegetable oils.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1824844A GB589242A (en) | 1944-09-25 | 1944-09-25 | Improvements in and relating to the preparation of salts of organic acids |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1824844A GB589242A (en) | 1944-09-25 | 1944-09-25 | Improvements in and relating to the preparation of salts of organic acids |
Publications (1)
Publication Number | Publication Date |
---|---|
GB589242A true GB589242A (en) | 1947-06-16 |
Family
ID=10109202
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1824844A Expired GB589242A (en) | 1944-09-25 | 1944-09-25 | Improvements in and relating to the preparation of salts of organic acids |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB589242A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2584041A (en) * | 1949-07-06 | 1952-01-29 | Nuodex Products Co Inc | Process of preparing oil-soluble metal soaps |
EP0431589A2 (en) * | 1989-12-05 | 1991-06-12 | Mitsubishi Gas Chemical Company, Inc. | Process for producing copper formate |
-
1944
- 1944-09-25 GB GB1824844A patent/GB589242A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2584041A (en) * | 1949-07-06 | 1952-01-29 | Nuodex Products Co Inc | Process of preparing oil-soluble metal soaps |
EP0431589A2 (en) * | 1989-12-05 | 1991-06-12 | Mitsubishi Gas Chemical Company, Inc. | Process for producing copper formate |
EP0431589A3 (en) * | 1989-12-05 | 1991-10-23 | Mitsubishi Gas Chemical Company, Inc. | Process for producing copper formate |
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