GB1035389A - A process for treating cellulosic fibres - Google Patents
A process for treating cellulosic fibresInfo
- Publication number
- GB1035389A GB1035389A GB45777/64A GB4577764A GB1035389A GB 1035389 A GB1035389 A GB 1035389A GB 45777/64 A GB45777/64 A GB 45777/64A GB 4577764 A GB4577764 A GB 4577764A GB 1035389 A GB1035389 A GB 1035389A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sultone
- weight
- formaldehyde resins
- materials
- formaldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 3
- -1 hydrocarbon sultone Chemical class 0.000 abstract 7
- 239000000463 material Substances 0.000 abstract 5
- 239000000243 solution Substances 0.000 abstract 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- 229920000297 Rayon Polymers 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 239000000981 basic dye Substances 0.000 abstract 2
- 239000003518 caustics Substances 0.000 abstract 2
- 239000003431 cross linking reagent Substances 0.000 abstract 2
- 238000007598 dipping method Methods 0.000 abstract 2
- 239000004744 fabric Substances 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 2
- 238000005507 spraying Methods 0.000 abstract 2
- 150000008053 sultones Chemical class 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- FSSPGSAQUIYDCN-UHFFFAOYSA-N 1,3-Propane sultone Chemical compound O=S1(=O)CCCO1 FSSPGSAQUIYDCN-UHFFFAOYSA-N 0.000 abstract 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 abstract 1
- 241000237974 Conus textile Species 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 229920001807 Urea-formaldehyde Polymers 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 240000008042 Zea mays Species 0.000 abstract 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract 1
- 229940072056 alginate Drugs 0.000 abstract 1
- 235000010443 alginic acid Nutrition 0.000 abstract 1
- 229920000615 alginic acid Polymers 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 abstract 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 229920002301 cellulose acetate Polymers 0.000 abstract 1
- 238000010276 construction Methods 0.000 abstract 1
- 235000005822 corn Nutrition 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 abstract 1
- WVJOGYWFVNTSAU-UHFFFAOYSA-N dimethylol ethylene urea Chemical compound OCN1CCN(CO)C1=O WVJOGYWFVNTSAU-UHFFFAOYSA-N 0.000 abstract 1
- XVVGGZUZOITHPH-UHFFFAOYSA-N formaldehyde;prop-2-enal Chemical compound O=C.C=CC=O XVVGGZUZOITHPH-UHFFFAOYSA-N 0.000 abstract 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- MHYFEEDKONKGEB-UHFFFAOYSA-N oxathiane 2,2-dioxide Chemical compound O=S1(=O)CCCCO1 MHYFEEDKONKGEB-UHFFFAOYSA-N 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 239000002964 rayon Substances 0.000 abstract 1
- 230000009257 reactivity Effects 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- 239000000080 wetting agent Substances 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65168—Sulfur-containing compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/228—Cyclic esters, e.g. lactones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
- D06M15/429—Amino-aldehyde resins modified by compounds containing sulfur
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Cellulosic textile materials are creaseproofed and stiffened and their reactivity towards cross-linking agents and basic dyes is improved by impregnating them with an aqueous caustic solution and then treating them with a solution containing a hydrocarbon sultone which is an intra-molecular cyclic ester of a hydroxysulphonic acid which may be an aliphatic, cyclo-aliphatic or an aromatic acid, e.g. 1, 3-propane sultone, 1, 4-butane sultone, 1, 3-hexane sultone, benzlyl sultone, tolyl sultone and mixtures thereof. The materials may be impregnated with an aqueous solution containing 1-30% by weight of an alkali or alkaline earth metal hydroxide, preferably sodium or potassium hydroxide, by dipping, spraying or padding at 10 DEG -40 DEG C. Standard mercerizing procedures using 16-18% caustic solutions are suitable and the process may follow the mercerizing step directly. The sultone may be applied as a 1-25% by weight solution in water, acetone or alcohol at a temperature of 15 DEG -90 DEG C. by dipping spraying or padding. The solutions of the hydrocarbon sultones may contain 0.1-5% by weight of a cationic, anionic or non-ionic wetting agent. The treated materials may be washed with water which may contain a detergent and dried at a temperature of from ambient temperature to 125 DEG C. They may subsequently be dyed with basic dyes or padded with an aqueous solution containing 5-25% by weight of a cross-linking agent, e.g. formaldehyde, urea-formaldehyde resins, dimethylol ethylene urea, acrolein-formaldehyde resins, dicyandiamide formaldehyde resins, melamine formaldehyde resins and polyepoxides, at 20 DEG -100 DEG C. and cured at 70 DEG -175 DEG C. Textile materials comprising cotton, linen, viscose rayon, cuprammonium rayon or cellulose acetate fibres alone or in admixture with wool, acrylonitrite, urnylidene cyanides, vinylidene chloride or vinyl chloride polymer, nylon, polyester-polyamide, corn protein-formaldehyde, polyethylene, polypropylene, polyurethane, mineral or alginate fibres may be treated. The treated materials may be used in the production of dresses, drapes, upholsteries, show fabrics, carpets, coats, skirts, uniform, shoes, cords and construction fabrics.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US32309063A | 1963-11-12 | 1963-11-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1035389A true GB1035389A (en) | 1966-07-06 |
Family
ID=23257695
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB45777/64A Expired GB1035389A (en) | 1963-11-12 | 1964-11-10 | A process for treating cellulosic fibres |
Country Status (7)
Country | Link |
---|---|
US (1) | US3506390A (en) |
BE (1) | BE655568A (en) |
CH (2) | CH422711A (en) |
DE (1) | DE1469473A1 (en) |
FR (1) | FR1421620A (en) |
GB (1) | GB1035389A (en) |
NL (1) | NL6413072A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2186298A (en) * | 1986-01-13 | 1987-08-12 | Sandoz Ltd | Alkaline treatment of cellulose/polyacrylonitrile fibre blends |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3854868A (en) * | 1972-11-15 | 1974-12-17 | Us Agriculture | Non-aqueous process for reacting sultones with cellulosic materials and the product produced |
US3854867A (en) * | 1972-11-15 | 1974-12-17 | Us Agriculture | Process for reacting sultones with cellulosic materials to produce cellulosic materials having both basic and acidic groups and product produced |
CN102251407B (en) * | 2011-06-09 | 2013-01-30 | 泰安市金飞虹织造有限公司 | Treatment method for alginate fiber fabric |
CN104988766A (en) * | 2015-06-24 | 2015-10-21 | 张家港市华阳针纺织品有限公司 | Processing technology of color-changing environment-friendly clothing fabric |
CN110080010B (en) * | 2019-02-26 | 2020-06-12 | 东华大学 | Preparation method of colored cellulose fibers |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE570888A (en) * | ||||
DE1028527B (en) * | 1956-08-16 | 1958-04-24 | Boehme Fettchemie Gmbh | Process for the improvement of synthetically obtained molded articles containing carbonamide groups |
DE1146870B (en) * | 1961-07-24 | 1963-04-11 | Boehme Fettchemie Gmbh | Process for the production of propensultone |
-
1963
- 1963-11-12 US US323090A patent/US3506390A/en not_active Expired - Lifetime
-
1964
- 1964-11-10 DE DE19641469473 patent/DE1469473A1/en active Pending
- 1964-11-10 GB GB45777/64A patent/GB1035389A/en not_active Expired
- 1964-11-10 BE BE655568D patent/BE655568A/xx unknown
- 1964-11-10 FR FR994464A patent/FR1421620A/en not_active Expired
- 1964-11-10 NL NL6413072A patent/NL6413072A/xx unknown
- 1964-11-10 CH CH1450164A patent/CH422711A/en unknown
- 1964-11-10 CH CH50566A patent/CH441215A/en unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2186298A (en) * | 1986-01-13 | 1987-08-12 | Sandoz Ltd | Alkaline treatment of cellulose/polyacrylonitrile fibre blends |
GB2186298B (en) * | 1986-01-13 | 1989-11-01 | Sandoz Ltd | Improvements in or relating to organic compounds |
Also Published As
Publication number | Publication date |
---|---|
CH50566A4 (en) | 1967-01-31 |
FR1421620A (en) | 1965-12-17 |
BE655568A (en) | 1965-05-10 |
DE1469473A1 (en) | 1970-03-19 |
US3506390A (en) | 1970-04-14 |
CH422711A (en) | 1967-04-29 |
NL6413072A (en) | 1965-05-13 |
CH1450164A4 (en) | 1966-05-31 |
CH441215A (en) | 1968-01-15 |
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