FR3018814B1 - Polymeres amphiphiles multibloc - Google Patents
Polymeres amphiphiles multiblocInfo
- Publication number
- FR3018814B1 FR3018814B1 FR1400709A FR1400709A FR3018814B1 FR 3018814 B1 FR3018814 B1 FR 3018814B1 FR 1400709 A FR1400709 A FR 1400709A FR 1400709 A FR1400709 A FR 1400709A FR 3018814 B1 FR3018814 B1 FR 3018814B1
- Authority
- FR
- France
- Prior art keywords
- aqueous medium
- radical polymerization
- present
- multiblock
- mol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920000642 polymer Polymers 0.000 title abstract 2
- 239000012736 aqueous medium Substances 0.000 abstract 3
- 239000000693 micelle Substances 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 238000010526 radical polymerization reaction Methods 0.000 abstract 2
- 239000004094 surface-active agent Substances 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 abstract 1
- 230000002209 hydrophobic effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000007870 radical polymerization initiator Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
Abstract
La présente invention concerne un procédé de préparation d'un polymère de masse Mw inférieure à 300 000g/mol (notamment entre 1 000 et 300 000g/mol), comprenant une étape (E) de polymérisation radicalaire contrôlée où on met en contact dans un milieu aqueux où sont dispersés des micelles de tensioactifs : - des monomères hydrophiles éthyléniquement insaturés, présents en majorité au sein du milieu aqueux ; - des monomères hydrophobes partiellement hydrosolubles, éthyléniquement insaturés distincts des précédents, présents au moins en partie au sein des micelles de tensioactifs, et ayant une solubilité dans le milieu aqueux au moins égale à celle de l'acrylate d'hexyle ; - au moins un amorceur de polymérisation radicalaire ; et - au moins un agent de contrôle de polymérisation radicalaire.
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1400709A FR3018814B1 (fr) | 2014-03-24 | 2014-03-24 | Polymeres amphiphiles multibloc |
US15/128,162 US10450397B2 (en) | 2014-03-24 | 2015-03-16 | Amphiphilic multiblock polymers |
EP15709711.4A EP3122793A1 (fr) | 2014-03-24 | 2015-03-16 | Polymères amphiphiles multibloc |
CN201580027593.3A CN106414528B (zh) | 2014-03-24 | 2015-03-16 | 两亲性多嵌段聚合物 |
PCT/EP2015/055436 WO2015144475A1 (fr) | 2014-03-24 | 2015-03-16 | Polymères amphiphiles multibloc |
US16/655,475 US11267923B2 (en) | 2014-03-24 | 2019-10-17 | Multiblock amphiphilic polymers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1400709A FR3018814B1 (fr) | 2014-03-24 | 2014-03-24 | Polymeres amphiphiles multibloc |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3018814A1 FR3018814A1 (fr) | 2015-09-25 |
FR3018814B1 true FR3018814B1 (fr) | 2016-03-04 |
Family
ID=50829039
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR1400709A Active FR3018814B1 (fr) | 2014-03-24 | 2014-03-24 | Polymeres amphiphiles multibloc |
Country Status (5)
Country | Link |
---|---|
US (2) | US10450397B2 (fr) |
EP (1) | EP3122793A1 (fr) |
CN (1) | CN106414528B (fr) |
FR (1) | FR3018814B1 (fr) |
WO (1) | WO2015144475A1 (fr) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3043083B1 (fr) * | 2015-10-30 | 2019-04-19 | Rhodia Operations | Polymeres sequences amphiphiles solubles en milieu fortement salin |
EP3412691A1 (fr) * | 2017-06-07 | 2018-12-12 | Rhodia Operations | Dispersions de polymères pour l'inhibition de cire |
CN108047455B (zh) * | 2018-02-09 | 2020-12-25 | 中国人民解放军陆军军医大学 | 用于抗原载体的两亲性超支化聚合物及其制备方法和应用 |
CN108329483B (zh) * | 2018-02-09 | 2020-12-29 | 中国人民解放军陆军军医大学 | 两亲性超支化聚合物及其制备方法和应用 |
WO2020073286A1 (fr) * | 2018-10-11 | 2020-04-16 | Rhodia Operations | Dispersion polymère par polymérisation radicalaire contrôlée |
WO2020088858A1 (fr) * | 2018-11-02 | 2020-05-07 | Rhodia Operations | Dispersions polymères pour l'inhibition de la cire pendant un traitement de stimulation |
MX2021008508A (es) * | 2019-02-11 | 2021-08-19 | Dow Global Technologies Llc | Metodo de polimerizacion por transferencia de yodo y composiciones a partir del mismo. |
WO2021222694A1 (fr) * | 2020-04-30 | 2021-11-04 | Dow Global Technologies Llc | Procédé de préparation de copolymères séquencés d'oléfine-acrylate par polymérisation raft |
CN116970378B (zh) * | 2023-09-25 | 2023-12-01 | 四川蜀宏悦能源科技有限公司 | 微泡修井液及其制备方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR0107548A (pt) * | 2000-01-11 | 2002-10-08 | Ciba Sc Holding Ag | Polìmeros de estrutura tipo pente de macromonÈmeros atrp |
FR2846973B1 (fr) * | 2002-11-07 | 2004-12-17 | Rhodia Chimie Sa | Composition d'antifroissage comprenant un copolymere a architecture controlee, pour articles en fibres textiles |
EP1660548B1 (fr) * | 2003-09-03 | 2008-08-27 | Rhodia Inc. | Nouveau copolymere a structure controlee et utilisation de celui-ci |
JP5375068B2 (ja) * | 2008-12-15 | 2013-12-25 | コニカミノルタ株式会社 | 静電潜像現像用トナーと画像形成方法 |
FR2965264B1 (fr) * | 2010-09-27 | 2013-11-29 | Rhodia Operations | Polymerisation radicalaire controlee de n-vinyl lactames en milieu aqueux |
RU2632886C2 (ru) | 2011-10-24 | 2017-10-11 | Родиа Операсьон | Получение амфифильных блок-сополимеров путем контролируемой радикальной мицеллярной полимеризации |
-
2014
- 2014-03-24 FR FR1400709A patent/FR3018814B1/fr active Active
-
2015
- 2015-03-16 US US15/128,162 patent/US10450397B2/en active Active
- 2015-03-16 WO PCT/EP2015/055436 patent/WO2015144475A1/fr active Application Filing
- 2015-03-16 EP EP15709711.4A patent/EP3122793A1/fr not_active Withdrawn
- 2015-03-16 CN CN201580027593.3A patent/CN106414528B/zh active Active
-
2019
- 2019-10-17 US US16/655,475 patent/US11267923B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
US20200048391A1 (en) | 2020-02-13 |
CN106414528B (zh) | 2020-04-10 |
US20170096516A1 (en) | 2017-04-06 |
FR3018814A1 (fr) | 2015-09-25 |
WO2015144475A1 (fr) | 2015-10-01 |
EP3122793A1 (fr) | 2017-02-01 |
CN106414528A (zh) | 2017-02-15 |
US11267923B2 (en) | 2022-03-08 |
US10450397B2 (en) | 2019-10-22 |
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