MX354132B - Preparacion de los polimeros en bloques anfifilicos por medio de la polimerizacion micelar por radicales controlada. - Google Patents
Preparacion de los polimeros en bloques anfifilicos por medio de la polimerizacion micelar por radicales controlada.Info
- Publication number
- MX354132B MX354132B MX2014004978A MX2014004978A MX354132B MX 354132 B MX354132 B MX 354132B MX 2014004978 A MX2014004978 A MX 2014004978A MX 2014004978 A MX2014004978 A MX 2014004978A MX 354132 B MX354132 B MX 354132B
- Authority
- MX
- Mexico
- Prior art keywords
- preparation
- polymerisation
- block polymers
- amphiphilic block
- controlled radical
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/04—Aqueous well-drilling compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/588—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/84—Compositions based on water or polar solvents
- C09K8/86—Compositions based on water or polar solvents containing organic compounds
- C09K8/88—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/882—Compositions based on water or polar solvents containing organic compounds macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/026—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising acrylic acid, methacrylic acid or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
La presente invención se relaciona con la preparación de los copolímeros en bloques, que pueden usarse particularmente como agentes reológicos, convenientes, ínter alía, para la extracción de aceite, que comprende una etapa de polimerización micelar por radicales donde los siguientes elementos se ponen en contacto en un medio acuoso: monómeros hidrofílicos, disueltos o dispersos en el medio acuoso; monómeros hidrofóbicos en forma de solución micelar, es decir que contiene, en un estado disperso, las micelas que comprenden estos monómeros hidrofóbicos; por lo menos un iniciador de polimerización por radicales; y por lo menos un agente de control de polimerización por radicales. Los polímeros obtenidos de acuerdo con la invención pueden usarse particularmente para la recuperación de aceite mejorada (EQR, por sus siglas en inglés).
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1103246 | 2011-10-24 | ||
FR1103707 | 2011-12-05 | ||
PCT/EP2012/071079 WO2013060741A1 (fr) | 2011-10-24 | 2012-10-24 | Preparation de polymeres sequences amphiphiles par polymerisation radicalaire micellaire a caractere controle |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2014004978A MX2014004978A (es) | 2014-10-24 |
MX354132B true MX354132B (es) | 2018-02-14 |
Family
ID=47049200
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014004978A MX354132B (es) | 2011-10-24 | 2012-10-24 | Preparacion de los polimeros en bloques anfifilicos por medio de la polimerizacion micelar por radicales controlada. |
Country Status (9)
Country | Link |
---|---|
US (1) | US9580535B2 (es) |
EP (1) | EP2780383B1 (es) |
CN (1) | CN104011101B (es) |
BR (1) | BR112014009835B1 (es) |
CA (1) | CA2852104C (es) |
DK (1) | DK2780383T3 (es) |
MX (1) | MX354132B (es) |
RU (1) | RU2632886C2 (es) |
WO (1) | WO2013060741A1 (es) |
Families Citing this family (29)
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FR3018814B1 (fr) | 2014-03-24 | 2016-03-04 | Rhodia Operations | Polymeres amphiphiles multibloc |
FR3025520A1 (fr) * | 2014-09-05 | 2016-03-11 | Rhodia Operations | Hydratation amelioree de polymeres associatifs |
FR3037074B1 (fr) * | 2015-06-03 | 2017-07-14 | Rhodia Operations | Agents de suspension obtenus par polymerisation micellaire |
FR3037073B1 (fr) * | 2015-06-03 | 2017-07-14 | Rhodia Operations | Polymeres amphiphiles pour le controle du filtrat |
CN104974733A (zh) * | 2015-06-10 | 2015-10-14 | 天津大港油田滨港集团博弘石油化工有限公司 | 一种聚合物驱油剂及其制备方法 |
FR3037584B1 (fr) * | 2015-06-22 | 2017-06-09 | Rhodia Operations | Stabilisation de mousses minerales |
CN106336859B (zh) | 2015-07-07 | 2019-05-24 | 中国石油化工股份有限公司 | 一种组合物及其应用和油基钻井液及提高油基钻井液切力的方法 |
FR3043083B1 (fr) | 2015-10-30 | 2019-04-19 | Rhodia Operations | Polymeres sequences amphiphiles solubles en milieu fortement salin |
IT201600086697A1 (it) * | 2016-08-23 | 2018-02-23 | Eni Spa | Metodo per inibire la permeazione di acqua in un pozzo di estrazione di un olio idrocarburico da un giacimento sotterraneo. |
RU2019115085A (ru) | 2016-11-29 | 2021-01-11 | Родиа Оперейшнс | Полимерные системы для дисперсии частиц |
EP3412691A1 (en) * | 2017-06-07 | 2018-12-12 | Rhodia Operations | Polymer dispersions for wax inhibition |
FR3070043B1 (fr) | 2017-08-09 | 2019-08-16 | Rhodia Operations | Formulation contenant un polymere associatif |
CN111566184B (zh) * | 2017-12-19 | 2023-08-01 | 罗地亚经营管理公司 | 用于辅助开采石油的表面活性剂和缔合聚合物的水性配制品 |
CN111492035B (zh) | 2017-12-20 | 2023-05-02 | 罗地亚经营管理公司 | 用于颗粒分散的聚合物体系 |
FR3079833B1 (fr) * | 2018-04-10 | 2020-10-09 | Rhodia Operations | Composition aqueuse gelifiee pour l'extraction petroliere |
FR3083238A1 (fr) * | 2018-07-02 | 2020-01-03 | Rhodia Operations | Relargage progressif de chaines polymeres en milieu liquide |
CA3115384A1 (en) | 2018-10-11 | 2020-04-16 | Rhodia Operations | Polymer dispersion by controlled radical polymerization |
CN113631682B (zh) * | 2018-11-02 | 2024-01-26 | 能源解决方案(美国)有限责任公司 | 用于在增产处理期间进行蜡抑制的聚合物分散体 |
JP7271962B2 (ja) * | 2019-01-22 | 2023-05-12 | 東亞合成株式会社 | 水溶性ポリマーの製造方法 |
WO2020190622A1 (en) | 2019-03-15 | 2020-09-24 | Rhodia Operations | Polymer compositions and use of the same |
CN115003776A (zh) | 2019-12-02 | 2022-09-02 | 索尔维美国有限公司 | 用于油田减摩的聚合物分散体 |
TW202136207A (zh) | 2020-01-29 | 2021-10-01 | 美商艾德凡斯化學公司 | 胺基酸界面活性劑 |
WO2021183565A1 (en) * | 2020-03-11 | 2021-09-16 | Advansix Resins & Chemicals Llc | Surfactants for oil and gas production |
US11603487B2 (en) * | 2020-05-29 | 2023-03-14 | Halliburton Energy Services, Inc. | Low molecular mass organic gelator wellbore stabilizers |
CN111793178B (zh) * | 2020-07-20 | 2022-07-15 | 宁波锋成先进能源材料研究院 | 一种双亲蒙脱土及其制备方法与应用 |
WO2022083963A1 (en) | 2020-10-23 | 2022-04-28 | Rhodia Operations | Polymeric systems having enhanced viscosity and proppant transport properties |
WO2022170035A1 (en) * | 2021-02-04 | 2022-08-11 | Aramco Services Company | Ultra-high molecular weight (uhmw) branched block copolymer viscosifier for water based drilling fluids |
WO2022170041A1 (en) * | 2021-02-04 | 2022-08-11 | Aramco Services Company | Development of ultra-high molecular weight (uhmw) branched block copolymer drag reducer with improved mechanical and chemical stability |
WO2022170039A1 (en) * | 2021-02-04 | 2022-08-11 | Aramco Services Company | Development of ultra-high molecular weight (uhmw) branced block copolymer shale inhibitor for water based drilling fluid |
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US4432881A (en) | 1981-02-06 | 1984-02-21 | The Dow Chemical Company | Water-dispersible hydrophobic thickening agent |
US4565647B1 (en) | 1982-04-26 | 1994-04-05 | Procter & Gamble | Foaming surfactant compositions |
US4584358A (en) | 1985-06-12 | 1986-04-22 | University Of Southern Mississippi | Calcium-tolerant N-substituted acrylamides as thickeners for aqueous systems |
US5763548A (en) | 1995-03-31 | 1998-06-09 | Carnegie-Mellon University | (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization |
MY125052A (en) * | 1996-04-08 | 2006-07-31 | Matsushita Electric Ind Co Ltd | Process of recovering copper from winding. |
KR100454757B1 (ko) * | 1996-07-02 | 2004-12-30 | 포라 가세이 고교 가부시키가이샤 | 광노화방지제및피부화장료 |
US7714075B1 (en) | 1996-07-10 | 2010-05-11 | Commonwealth Scientific And Industrial Research Organisation | Polymerization with living characteristics |
FR2764892B1 (fr) | 1997-06-23 | 2000-03-03 | Rhodia Chimie Sa | Procede de synthese de polymeres a blocs |
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CA2315914A1 (fr) | 1997-12-31 | 1999-07-15 | Xavier Franck | Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee a partir de composes dithiocarbamates |
FR2773161B1 (fr) | 1997-12-31 | 2000-01-21 | Rhodia Chimie Sa | Procede de synthese de polymeres a blocs |
US6150468A (en) * | 1998-11-12 | 2000-11-21 | National Starch And Chemical Investment Holding Corporation | Water soluble amphiphilic heteratom star polymers and their use as emulsion stabilizers in emulsion polymerization |
FR2794464B1 (fr) | 1999-06-04 | 2005-03-04 | Rhodia Chimie Sa | Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee a l'aide de thioether-thiones |
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FR2802208B1 (fr) | 1999-12-09 | 2003-02-14 | Rhodia Chimie Sa | Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates |
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AU2003211689B2 (en) | 2002-02-11 | 2007-10-04 | Rhodia Chimie | Method for controlling the stability or the droplets size of simple water-in-oil emulsions, and stabilized simple water-in-oil emulsions |
EP1660548B1 (en) | 2003-09-03 | 2008-08-27 | Rhodia Inc. | New copolymer having a controlled structure, and use thereof |
FR2889703A1 (fr) * | 2005-08-09 | 2007-02-16 | Arkema Sa | Procede de preparation d'un materiau polymerique comprenant un copolymere multibloc obtenu par polymerisation radicalaire controlee |
US20100048750A1 (en) * | 2006-10-20 | 2010-02-25 | The University Of Sydney | Vesiculated polymer particles |
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2012
- 2012-10-24 US US14/353,360 patent/US9580535B2/en active Active
- 2012-10-24 BR BR112014009835-2A patent/BR112014009835B1/pt active IP Right Grant
- 2012-10-24 CN CN201280064296.2A patent/CN104011101B/zh active Active
- 2012-10-24 EP EP12775527.0A patent/EP2780383B1/fr active Active
- 2012-10-24 DK DK12775527.0T patent/DK2780383T3/da active
- 2012-10-24 WO PCT/EP2012/071079 patent/WO2013060741A1/fr active Application Filing
- 2012-10-24 RU RU2014121011A patent/RU2632886C2/ru active
- 2012-10-24 MX MX2014004978A patent/MX354132B/es active IP Right Grant
- 2012-10-24 CA CA2852104A patent/CA2852104C/fr active Active
Also Published As
Publication number | Publication date |
---|---|
US9580535B2 (en) | 2017-02-28 |
EP2780383A1 (fr) | 2014-09-24 |
MX2014004978A (es) | 2014-10-24 |
CA2852104C (fr) | 2019-09-10 |
DK2780383T3 (da) | 2017-02-20 |
US20140378617A1 (en) | 2014-12-25 |
CN104011101A (zh) | 2014-08-27 |
RU2632886C2 (ru) | 2017-10-11 |
BR112014009835A2 (pt) | 2017-05-02 |
RU2014121011A (ru) | 2015-12-10 |
WO2013060741A1 (fr) | 2013-05-02 |
BR112014009835B1 (pt) | 2021-03-02 |
EP2780383B1 (fr) | 2016-03-16 |
CA2852104A1 (fr) | 2013-05-02 |
CN104011101B (zh) | 2018-01-05 |
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