FR2394552A1 - Cyclopentadienyl-metal-carbonyles lies a des polymeres ainsi que leurs derives, leur procede de preparation - Google Patents
Cyclopentadienyl-metal-carbonyles lies a des polymeres ainsi que leurs derives, leur procede de preparationInfo
- Publication number
- FR2394552A1 FR2394552A1 FR7818062A FR7818062A FR2394552A1 FR 2394552 A1 FR2394552 A1 FR 2394552A1 FR 7818062 A FR7818062 A FR 7818062A FR 7818062 A FR7818062 A FR 7818062A FR 2394552 A1 FR2394552 A1 FR 2394552A1
- Authority
- FR
- France
- Prior art keywords
- metal
- cyclopentadienyl
- polymers
- derivatives
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
- B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2291—Olefins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
- C08F4/80—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/52—Isomerisation reactions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0202—Polynuclearity
- B01J2531/0208—Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/42—Tin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
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- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
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- B01J2531/62—Chromium
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- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
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- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
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- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
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- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
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- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La présente invention a pour objet des composés cyclopentadiényl-métal-carbonyles liés à des polymères et leurs dérivés avec d'autres ligands. Ils sont caractérisés en ce qu'ils contiennent des groupes de formules : | - (C5 R11 )Me(CO)x Ly |z dans laquelle R est un atome d'hydrogène, un radical alkyle comprenant 1 à 4 atomes de carbone, un radical benzyle, ou un radical diphénylméthyle; Me est un métal de transition des groupes 6, 7 ou 8 de la Classification Périodique; x est égal à 1, 2 ou 3 et, dans le cas où Me est un métal du groupe 8 de la Classification Périodique, x peut être égal à 0; L est un groupe tri(alkyl comprenant 1 à 3 atomes de carbone)-phosphine, triphénylphosphine, tri(alkyl comprenant 1 à 3 atomes de carbone)-phosphite, nitrosyle, allyle, SnCl 3 , ou un atome d'halogène ou d'hydrogène; y est égal à 0, 1 ou 2; z est égal à 1, 2, 3 ou 4 ; Application en tant que catalyseurs pour les réactions d'hydroformylation, carbonylation, carboxyméthylation, hydrogénation, isomérisation, oligomérisation, polymérisation, dismutations métathétiques.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2727245A DE2727245C3 (de) | 1977-06-16 | 1977-06-16 | Polymergebundene CyclopentadienylÜbergangsmetall-Verbindungen und ihre Ligand-Substitutions-Derivate, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2394552A1 true FR2394552A1 (fr) | 1979-01-12 |
FR2394552B1 FR2394552B1 (fr) | 1980-12-05 |
Family
ID=6011668
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7818062A Granted FR2394552A1 (fr) | 1977-06-16 | 1978-06-16 | Cyclopentadienyl-metal-carbonyles lies a des polymeres ainsi que leurs derives, leur procede de preparation |
Country Status (8)
Country | Link |
---|---|
US (1) | US4361497A (fr) |
JP (1) | JPS546093A (fr) |
CA (1) | CA1126284A (fr) |
DE (1) | DE2727245C3 (fr) |
FR (1) | FR2394552A1 (fr) |
GB (1) | GB2000153B (fr) |
IT (1) | IT1096736B (fr) |
NL (1) | NL7806513A (fr) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2456549A1 (fr) * | 1979-05-17 | 1980-12-12 | Us Energy | Nouveaux catalyseurs de fischer-tropsch, procede de leur preparation et procede de fischer-tropsch les utilisant |
FR2459075A1 (fr) * | 1979-06-15 | 1981-01-09 | Ugine Kuhlmann | Catalyseurs de telomerisation des dienes 1-3 |
EP0041587A1 (fr) * | 1980-06-06 | 1981-12-16 | The Standard Oil Company | Compositions catalytiques, leur préparation et leur utilisation pour la préparation de composés organiques oxygénés |
EP0705810A3 (fr) * | 1994-09-22 | 1997-04-09 | Shell Int Research | Procédé de purification de produits de départ pour réactions catalysées par des métaux et agent de purification à cet effet |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4331612A (en) | 1978-12-26 | 1982-05-25 | Standard Oil Company | Carbonylation of olefinically unsaturated compounds |
US4313893A (en) | 1978-12-26 | 1982-02-02 | Standard Oil Company | Carbonylation of olefinically unsaturated compounds |
EP0014225A1 (fr) * | 1979-02-13 | 1980-08-20 | The Dow Chemical Company | Agrégat bimétallique de rhodium-cobalt sur support de résines polyamines comme catalyseur pour l'hydroformylation, préparation de ce catalyseur et procédé oxo utilisant celui-ci |
US4451407A (en) * | 1980-07-16 | 1984-05-29 | The Standard Oil Company | Carbonylation of olefinically unsaturated compounds |
US4510214A (en) * | 1980-10-03 | 1985-04-09 | Tracer Technologies, Inc. | Electrode with electron transfer catalyst |
US4439302A (en) * | 1981-11-24 | 1984-03-27 | Massachusetts Institute Of Technology | Redox mediation and hydrogen-generation with bipyridinium reagents |
DE3150985A1 (de) * | 1981-12-23 | 1983-06-30 | Bayer Ag, 5090 Leverkusen | Verfahren zur aktivierung von substratoberflaechen fuer die stromlose metallisierung |
US4503140A (en) * | 1982-05-18 | 1985-03-05 | Minnesota Mining And Manufacturing Company | Radiation-sensitive compositions of polymers containing a π-metal carbonyl complex of conjugated polyolefin |
EP0110177B1 (fr) * | 1982-11-06 | 1989-03-22 | Denki Kagaku Kogyo Kabushiki Kaisha | Complexes de cyclopentadiénylcobalt substitués et synthèse d'homologues de pyridine à l'aide de ces complexes |
GB8320904D0 (en) * | 1983-08-03 | 1983-09-07 | Rubber & Plastic Res Ass | Transformations within polymers |
US4506030A (en) * | 1984-02-17 | 1985-03-19 | The Board Of Regents, University Of Texas System | Catalysts for hydrogenation of aromatic compounds |
US4670621A (en) * | 1986-05-05 | 1987-06-02 | Ethyl Corporation | Catalytic synthesis of olefins from paraffins |
US4751344A (en) * | 1986-05-05 | 1988-06-14 | Ethyl Corporation | Catalytic synthesis of olefins from paraffins |
US4792629A (en) * | 1987-02-24 | 1988-12-20 | Shell Oil Company | Alkylation of amine compounds |
GB8729069D0 (en) * | 1987-12-12 | 1988-01-27 | Rapra Techn Ltd | Temperature activated catalysts for liquid polymer cures |
US4880670A (en) * | 1988-06-22 | 1989-11-14 | Georgia Tech Research Corporation | Chemical vapor deposition of Group IB metals |
ATE113865T1 (de) * | 1989-12-26 | 1994-11-15 | Sagami Chem Res | Katalysator zur hydrierung, dehydrosilylierung oder hydrosilylierung und dessen verwendung. |
US5457564A (en) * | 1990-02-26 | 1995-10-10 | Molecular Displays, Inc. | Complementary surface confined polymer electrochromic materials, systems, and methods of fabrication therefor |
US5818636A (en) * | 1990-02-26 | 1998-10-06 | Molecular Displays, Inc. | Complementary surface confined polmer electrochromic materials, systems, and methods of fabrication therefor |
US5286878A (en) * | 1990-11-21 | 1994-02-15 | Massachusetts Institute Of Technology | Catalytic reduction of organic carbonyls |
US5906892A (en) * | 1993-08-09 | 1999-05-25 | The Trustees Of Princeton University | Electron acceptor compositions on polymer templates |
JP4293632B2 (ja) * | 1993-11-16 | 2009-07-08 | ブラッコ インターナショナル ベースローテン フェンノートシャップ | 固定化標識方法 |
KR19980072719A (ko) * | 1997-03-07 | 1998-11-05 | 박홍기 | 스티렌 중합용 탄소 및/또는 규소 다리화 두금속 메탈로센 촉매, 및 이를 이용한 스티렌 중합방법 |
US5962364A (en) * | 1997-07-30 | 1999-10-05 | Bp Amoco Corporation | Process for synthesis of molybdenum sulfide dimers |
EP1165629A1 (fr) * | 1999-03-05 | 2002-01-02 | Dow Corning Corporation | Composition catalytique et procede de fabrication d'un polymere ou d'un copolymere |
FR2824066B1 (fr) * | 2001-04-30 | 2004-02-06 | Atofina | Composante catalytique solide de type metallocene et son procede d'obtention |
DE102004039877A1 (de) * | 2004-08-17 | 2006-02-23 | Basell Polyolefine Gmbh | Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6 |
KR102193925B1 (ko) | 2012-09-25 | 2020-12-22 | 엔테그리스, 아이엔씨. | 코발트계 박막의 저온 ald 또는 cvd를 위한 코발트 전구체 |
US11761086B2 (en) | 2014-02-23 | 2023-09-19 | Entegris, Inc. | Cobalt precursors |
CN116395647B (zh) * | 2023-04-07 | 2023-12-29 | 贵州省畜牧兽医研究所 | 一种高分散的铁原子锚定的石墨相氮化碳及其制备方法和广谱灭菌的应用 |
Family Cites Families (16)
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US3361779A (en) * | 1959-08-20 | 1968-01-02 | Ethyl Corp | Organometallic compounds |
US3290337A (en) * | 1960-12-28 | 1966-12-06 | Ethyl Corp | Azidocarbonylcyclopentadienyl manganese tricarbonyl and process for preparing same |
US3329695A (en) * | 1963-05-27 | 1967-07-04 | Gen Electric | Silylorganocyclopentadienylmetalcarbonyls and process therefor |
US3324157A (en) * | 1963-05-27 | 1967-06-06 | Gen Electric | Metallocenyl substituted organopolysiloxanes |
NL135027C (fr) * | 1967-05-03 | |||
NL135286C (fr) * | 1967-05-03 | |||
GB1348655A (en) * | 1970-05-22 | 1974-03-20 | Montedison Spa | Catalysts for the polymerization of olefins |
US4098727A (en) * | 1970-07-23 | 1978-07-04 | Mobil Oil Corporation | Insoluble polymers having functional groups containing chemically bonded Group VIII metal |
US3709861A (en) * | 1970-12-14 | 1973-01-09 | Shell Oil Co | Process for light-induced curing of epoxy resins in presence of cyclopentadienylmanganese tricarbonyl compounds |
US3907852A (en) * | 1972-06-23 | 1975-09-23 | Exxon Research Engineering Co | Silylhydrocarbyl phosphines and related compounds |
CA978926A (en) * | 1972-07-19 | 1975-12-02 | Graeme G. Strathdee | Anchored homogeneous-type catalysts for h-d exchange |
US3844975A (en) * | 1972-11-10 | 1974-10-29 | Union Carbide Corp | Thermally aged hydride based polymerization catalyst |
SU492298A1 (ru) * | 1973-07-24 | 1975-11-25 | Институт нефтехимического синтеза им.А.В.Топчиева АН СССР | Катализатор дл полимеризации и сополимеризации этилена, -олефинов и сопр женных и несопр женных диенов |
US3998864A (en) * | 1975-02-03 | 1976-12-21 | Standard Oil Company (Indiana) | Heterogeneous catalyst for the hydroformylation of olegins |
US4062883A (en) * | 1976-08-06 | 1977-12-13 | The United States Of America As Represented By The Secretary Of The Navy | Polymer-bound metallocarborane catalyst product and process |
US4173575A (en) * | 1978-02-13 | 1979-11-06 | Continental Oil Company | Polymer bound (pentahaptocyclopentadienyl) bis carbonyl rhodium hydroformylation catalyst |
-
1977
- 1977-06-16 DE DE2727245A patent/DE2727245C3/de not_active Expired
-
1978
- 1978-06-14 IT IT24548/78A patent/IT1096736B/it active
- 1978-06-15 US US05/915,750 patent/US4361497A/en not_active Expired - Lifetime
- 1978-06-15 JP JP7158578A patent/JPS546093A/ja active Pending
- 1978-06-15 CA CA305,512A patent/CA1126284A/fr not_active Expired
- 1978-06-16 FR FR7818062A patent/FR2394552A1/fr active Granted
- 1978-06-16 NL NL7806513A patent/NL7806513A/xx not_active Application Discontinuation
- 1978-06-16 GB GB7827108A patent/GB2000153B/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2456549A1 (fr) * | 1979-05-17 | 1980-12-12 | Us Energy | Nouveaux catalyseurs de fischer-tropsch, procede de leur preparation et procede de fischer-tropsch les utilisant |
FR2459075A1 (fr) * | 1979-06-15 | 1981-01-09 | Ugine Kuhlmann | Catalyseurs de telomerisation des dienes 1-3 |
EP0041587A1 (fr) * | 1980-06-06 | 1981-12-16 | The Standard Oil Company | Compositions catalytiques, leur préparation et leur utilisation pour la préparation de composés organiques oxygénés |
EP0705810A3 (fr) * | 1994-09-22 | 1997-04-09 | Shell Int Research | Procédé de purification de produits de départ pour réactions catalysées par des métaux et agent de purification à cet effet |
Also Published As
Publication number | Publication date |
---|---|
IT7824548A0 (it) | 1978-06-14 |
CA1126284A (fr) | 1982-06-22 |
JPS546093A (en) | 1979-01-17 |
US4361497A (en) | 1982-11-30 |
DE2727245C3 (de) | 1980-06-26 |
GB2000153A (en) | 1979-01-04 |
IT1096736B (it) | 1985-08-26 |
DE2727245B2 (de) | 1979-10-04 |
FR2394552B1 (fr) | 1980-12-05 |
DE2727245A1 (de) | 1978-12-21 |
NL7806513A (nl) | 1978-12-19 |
GB2000153B (en) | 1982-11-24 |
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