FR2394552A1 - Cyclopentadienyl-metal-carbonyles lies a des polymeres ainsi que leurs derives, leur procede de preparation - Google Patents

Cyclopentadienyl-metal-carbonyles lies a des polymeres ainsi que leurs derives, leur procede de preparation

Info

Publication number
FR2394552A1
FR2394552A1 FR7818062A FR7818062A FR2394552A1 FR 2394552 A1 FR2394552 A1 FR 2394552A1 FR 7818062 A FR7818062 A FR 7818062A FR 7818062 A FR7818062 A FR 7818062A FR 2394552 A1 FR2394552 A1 FR 2394552A1
Authority
FR
France
Prior art keywords
metal
cyclopentadienyl
polymers
derivatives
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7818062A
Other languages
English (en)
Other versions
FR2394552B1 (fr
Inventor
Hans H Brintzinger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of FR2394552A1 publication Critical patent/FR2394552A1/fr
Application granted granted Critical
Publication of FR2394552B1 publication Critical patent/FR2394552B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2291—Olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/80—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0208—Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/42—Tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La présente invention a pour objet des composés cyclopentadiényl-métal-carbonyles liés à des polymères et leurs dérivés avec d'autres ligands. Ils sont caractérisés en ce qu'ils contiennent des groupes de formules : | - (C5 R11 )Me(CO)x Ly |z dans laquelle R est un atome d'hydrogène, un radical alkyle comprenant 1 à 4 atomes de carbone, un radical benzyle, ou un radical diphénylméthyle; Me est un métal de transition des groupes 6, 7 ou 8 de la Classification Périodique; x est égal à 1, 2 ou 3 et, dans le cas où Me est un métal du groupe 8 de la Classification Périodique, x peut être égal à 0; L est un groupe tri(alkyl comprenant 1 à 3 atomes de carbone)-phosphine, triphénylphosphine, tri(alkyl comprenant 1 à 3 atomes de carbone)-phosphite, nitrosyle, allyle, SnCl 3 , ou un atome d'halogène ou d'hydrogène; y est égal à 0, 1 ou 2; z est égal à 1, 2, 3 ou 4 ; Application en tant que catalyseurs pour les réactions d'hydroformylation, carbonylation, carboxyméthylation, hydrogénation, isomérisation, oligomérisation, polymérisation, dismutations métathétiques.
FR7818062A 1977-06-16 1978-06-16 Cyclopentadienyl-metal-carbonyles lies a des polymeres ainsi que leurs derives, leur procede de preparation Granted FR2394552A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2727245A DE2727245C3 (de) 1977-06-16 1977-06-16 Polymergebundene CyclopentadienylÜbergangsmetall-Verbindungen und ihre Ligand-Substitutions-Derivate, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren

Publications (2)

Publication Number Publication Date
FR2394552A1 true FR2394552A1 (fr) 1979-01-12
FR2394552B1 FR2394552B1 (fr) 1980-12-05

Family

ID=6011668

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7818062A Granted FR2394552A1 (fr) 1977-06-16 1978-06-16 Cyclopentadienyl-metal-carbonyles lies a des polymeres ainsi que leurs derives, leur procede de preparation

Country Status (8)

Country Link
US (1) US4361497A (fr)
JP (1) JPS546093A (fr)
CA (1) CA1126284A (fr)
DE (1) DE2727245C3 (fr)
FR (1) FR2394552A1 (fr)
GB (1) GB2000153B (fr)
IT (1) IT1096736B (fr)
NL (1) NL7806513A (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2456549A1 (fr) * 1979-05-17 1980-12-12 Us Energy Nouveaux catalyseurs de fischer-tropsch, procede de leur preparation et procede de fischer-tropsch les utilisant
FR2459075A1 (fr) * 1979-06-15 1981-01-09 Ugine Kuhlmann Catalyseurs de telomerisation des dienes 1-3
EP0041587A1 (fr) * 1980-06-06 1981-12-16 The Standard Oil Company Compositions catalytiques, leur préparation et leur utilisation pour la préparation de composés organiques oxygénés
EP0705810A3 (fr) * 1994-09-22 1997-04-09 Shell Int Research Procédé de purification de produits de départ pour réactions catalysées par des métaux et agent de purification à cet effet

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4331612A (en) 1978-12-26 1982-05-25 Standard Oil Company Carbonylation of olefinically unsaturated compounds
US4313893A (en) 1978-12-26 1982-02-02 Standard Oil Company Carbonylation of olefinically unsaturated compounds
EP0014225A1 (fr) * 1979-02-13 1980-08-20 The Dow Chemical Company Agrégat bimétallique de rhodium-cobalt sur support de résines polyamines comme catalyseur pour l'hydroformylation, préparation de ce catalyseur et procédé oxo utilisant celui-ci
US4451407A (en) * 1980-07-16 1984-05-29 The Standard Oil Company Carbonylation of olefinically unsaturated compounds
US4510214A (en) * 1980-10-03 1985-04-09 Tracer Technologies, Inc. Electrode with electron transfer catalyst
US4439302A (en) * 1981-11-24 1984-03-27 Massachusetts Institute Of Technology Redox mediation and hydrogen-generation with bipyridinium reagents
DE3150985A1 (de) * 1981-12-23 1983-06-30 Bayer Ag, 5090 Leverkusen Verfahren zur aktivierung von substratoberflaechen fuer die stromlose metallisierung
US4503140A (en) * 1982-05-18 1985-03-05 Minnesota Mining And Manufacturing Company Radiation-sensitive compositions of polymers containing a π-metal carbonyl complex of conjugated polyolefin
EP0110177B1 (fr) * 1982-11-06 1989-03-22 Denki Kagaku Kogyo Kabushiki Kaisha Complexes de cyclopentadiénylcobalt substitués et synthèse d'homologues de pyridine à l'aide de ces complexes
GB8320904D0 (en) * 1983-08-03 1983-09-07 Rubber & Plastic Res Ass Transformations within polymers
US4506030A (en) * 1984-02-17 1985-03-19 The Board Of Regents, University Of Texas System Catalysts for hydrogenation of aromatic compounds
US4670621A (en) * 1986-05-05 1987-06-02 Ethyl Corporation Catalytic synthesis of olefins from paraffins
US4751344A (en) * 1986-05-05 1988-06-14 Ethyl Corporation Catalytic synthesis of olefins from paraffins
US4792629A (en) * 1987-02-24 1988-12-20 Shell Oil Company Alkylation of amine compounds
GB8729069D0 (en) * 1987-12-12 1988-01-27 Rapra Techn Ltd Temperature activated catalysts for liquid polymer cures
US4880670A (en) * 1988-06-22 1989-11-14 Georgia Tech Research Corporation Chemical vapor deposition of Group IB metals
ATE113865T1 (de) * 1989-12-26 1994-11-15 Sagami Chem Res Katalysator zur hydrierung, dehydrosilylierung oder hydrosilylierung und dessen verwendung.
US5457564A (en) * 1990-02-26 1995-10-10 Molecular Displays, Inc. Complementary surface confined polymer electrochromic materials, systems, and methods of fabrication therefor
US5818636A (en) * 1990-02-26 1998-10-06 Molecular Displays, Inc. Complementary surface confined polmer electrochromic materials, systems, and methods of fabrication therefor
US5286878A (en) * 1990-11-21 1994-02-15 Massachusetts Institute Of Technology Catalytic reduction of organic carbonyls
US5906892A (en) * 1993-08-09 1999-05-25 The Trustees Of Princeton University Electron acceptor compositions on polymer templates
JP4293632B2 (ja) * 1993-11-16 2009-07-08 ブラッコ インターナショナル ベースローテン フェンノートシャップ 固定化標識方法
KR19980072719A (ko) * 1997-03-07 1998-11-05 박홍기 스티렌 중합용 탄소 및/또는 규소 다리화 두금속 메탈로센 촉매, 및 이를 이용한 스티렌 중합방법
US5962364A (en) * 1997-07-30 1999-10-05 Bp Amoco Corporation Process for synthesis of molybdenum sulfide dimers
EP1165629A1 (fr) * 1999-03-05 2002-01-02 Dow Corning Corporation Composition catalytique et procede de fabrication d'un polymere ou d'un copolymere
FR2824066B1 (fr) * 2001-04-30 2004-02-06 Atofina Composante catalytique solide de type metallocene et son procede d'obtention
DE102004039877A1 (de) * 2004-08-17 2006-02-23 Basell Polyolefine Gmbh Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6
KR102193925B1 (ko) 2012-09-25 2020-12-22 엔테그리스, 아이엔씨. 코발트계 박막의 저온 ａｌｄ 또는 ｃｖｄ를 위한 코발트 전구체
US11761086B2 (en) 2014-02-23 2023-09-19 Entegris, Inc. Cobalt precursors
CN116395647B (zh) * 2023-04-07 2023-12-29 贵州省畜牧兽医研究所 一种高分散的铁原子锚定的石墨相氮化碳及其制备方法和广谱灭菌的应用

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3361779A (en) * 1959-08-20 1968-01-02 Ethyl Corp Organometallic compounds
US3290337A (en) * 1960-12-28 1966-12-06 Ethyl Corp Azidocarbonylcyclopentadienyl manganese tricarbonyl and process for preparing same
US3329695A (en) * 1963-05-27 1967-07-04 Gen Electric Silylorganocyclopentadienylmetalcarbonyls and process therefor
US3324157A (en) * 1963-05-27 1967-06-06 Gen Electric Metallocenyl substituted organopolysiloxanes
NL135027C (fr) * 1967-05-03
NL135286C (fr) * 1967-05-03
GB1348655A (en) * 1970-05-22 1974-03-20 Montedison Spa Catalysts for the polymerization of olefins
US4098727A (en) * 1970-07-23 1978-07-04 Mobil Oil Corporation Insoluble polymers having functional groups containing chemically bonded Group VIII metal
US3709861A (en) * 1970-12-14 1973-01-09 Shell Oil Co Process for light-induced curing of epoxy resins in presence of cyclopentadienylmanganese tricarbonyl compounds
US3907852A (en) * 1972-06-23 1975-09-23 Exxon Research Engineering Co Silylhydrocarbyl phosphines and related compounds
CA978926A (en) * 1972-07-19 1975-12-02 Graeme G. Strathdee Anchored homogeneous-type catalysts for h-d exchange
US3844975A (en) * 1972-11-10 1974-10-29 Union Carbide Corp Thermally aged hydride based polymerization catalyst
SU492298A1 (ru) * 1973-07-24 1975-11-25 Институт нефтехимического синтеза им.А.В.Топчиева АН СССР Катализатор дл полимеризации и сополимеризации этилена, -олефинов и сопр женных и несопр женных диенов
US3998864A (en) * 1975-02-03 1976-12-21 Standard Oil Company (Indiana) Heterogeneous catalyst for the hydroformylation of olegins
US4062883A (en) * 1976-08-06 1977-12-13 The United States Of America As Represented By The Secretary Of The Navy Polymer-bound metallocarborane catalyst product and process
US4173575A (en) * 1978-02-13 1979-11-06 Continental Oil Company Polymer bound (pentahaptocyclopentadienyl) bis carbonyl rhodium hydroformylation catalyst

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2456549A1 (fr) * 1979-05-17 1980-12-12 Us Energy Nouveaux catalyseurs de fischer-tropsch, procede de leur preparation et procede de fischer-tropsch les utilisant
FR2459075A1 (fr) * 1979-06-15 1981-01-09 Ugine Kuhlmann Catalyseurs de telomerisation des dienes 1-3
EP0041587A1 (fr) * 1980-06-06 1981-12-16 The Standard Oil Company Compositions catalytiques, leur préparation et leur utilisation pour la préparation de composés organiques oxygénés
EP0705810A3 (fr) * 1994-09-22 1997-04-09 Shell Int Research Procédé de purification de produits de départ pour réactions catalysées par des métaux et agent de purification à cet effet

Also Published As

Publication number Publication date
IT7824548A0 (it) 1978-06-14
CA1126284A (fr) 1982-06-22
JPS546093A (en) 1979-01-17
US4361497A (en) 1982-11-30
DE2727245C3 (de) 1980-06-26
GB2000153A (en) 1979-01-04
IT1096736B (it) 1985-08-26
DE2727245B2 (de) 1979-10-04
FR2394552B1 (fr) 1980-12-05
DE2727245A1 (de) 1978-12-21
NL7806513A (nl) 1978-12-19
GB2000153B (en) 1982-11-24

Similar Documents

Publication Publication Date Title
FR2394552A1 (fr) Cyclopentadienyl-metal-carbonyles lies a des polymeres ainsi que leurs derives, leur procede de preparation
FR2392037A1 (fr) Catalyseurs pour la polymerisation d'olefines
DE1269618B (de) Verfahren zur Herstellung von Addukten des Tetrachlorkohlenstoffs an olefinisch ungesaettigten Verbindungen
FR2359811A1 (fr) Procede de preparation d'esters a partir d'homologues d'ethers ou d'esters inferieurs
ES450844A1 (es) Un procedimiento para la preparacion de un catalizador zie- gler sobre soporte.
Clark et al. Trans-ligand effects in the insertion reactions of ethylene and phenylmethylacetylene with neutral and cationic hydridoplatinum (II) complexes
ES432100A1 (es) Un procedimiento para la preparacion de derivados de ciclo- penteno.
Bruce et al. Reactions of copper acetylides. Structure of (π-C5H5) Ru (PPh3) 2 (C CPh) CuCl, and new syntheses of transition metal cluster compounds
FR2371463A1 (fr) Catalyseur pour polymeriser des olefines et procede pour la polymerisation d'olefines
ES312890A1 (es) Procedimiento para la polimerizacion de olefinas.
FR2455054A1 (fr) Catalyseurs pour la polymerisation d'olefines
Lau et al. Diethyl-2, 2′-bipyridyl-palladium (II), a case for the study of combination vs. disproportionation products.
US2706202A (en) Bicycloheptane derivatives and process for preparing the same
US3625996A (en) Preparation of olefinic acids and esters
FR2402670A1 (fr) Procede de polymerisation de cyclopentene et d'autres olefines et diolefiniques cycliques
US2231360A (en) Chloropropionitriles and method of preparing them
Kinstle et al. Formation of cis-substituted esters by means of phosphonate esters condensations
US2384889A (en) Alpha-chloroacrylonitrile and method of preparing the same
ES298331A1 (es) Un procedimiento para polimerizar 1,3-butadieno
US5434282A (en) Double-branched compounds and processes for their production
US2572557A (en) Mineral oil compositions containing the reaction product of polystyrene and an alkyl ester of an unsaturated acid
ES394569A1 (es) Procedimiento para elevar el peso molecular de un polimero de un dieno conjugado yno un hodrocarburo vinilaromatico.
ES399408A1 (es) Procedimiento para (co) polimerizar olefinas.
FOX Acyclic enediols. A new method of preparation
JP2893728B2 (ja) 重合開始剤および塩化ビニルの重合方法

Legal Events

Date Code Title Description
ST Notification of lapse