FR2456549A1 - Nouveaux catalyseurs de fischer-tropsch, procede de leur preparation et procede de fischer-tropsch les utilisant - Google Patents

Nouveaux catalyseurs de fischer-tropsch, procede de leur preparation et procede de fischer-tropsch les utilisant

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Publication number
FR2456549A1
FR2456549A1 FR8011032A FR8011032A FR2456549A1 FR 2456549 A1 FR2456549 A1 FR 2456549A1 FR 8011032 A FR8011032 A FR 8011032A FR 8011032 A FR8011032 A FR 8011032A FR 2456549 A1 FR2456549 A1 FR 2456549A1
Authority
FR
France
Prior art keywords
fischer
tropsch
equal
preparation
catalyzers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8011032A
Other languages
English (en)
Other versions
FR2456549B1 (fr
Inventor
Kurt Peter Christian Vollhardt
Patrick Perkins
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
US Department of Energy
Original Assignee
US Department of Energy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by US Department of Energy filed Critical US Department of Energy
Publication of FR2456549A1 publication Critical patent/FR2456549A1/fr
Application granted granted Critical
Publication of FR2456549B1 publication Critical patent/FR2456549B1/fr
Expired legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2295Cyclic compounds, e.g. cyclopentadienyls
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/06Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
    • C07C1/063Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60Reduction reactions, e.g. hydrogenation
    • B01J2231/64Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/648Fischer-Tropsch-type reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/845Cobalt
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/20Carbonyls

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

L'INVENTION CONCERNE DE NOUVEAUX COMPLEXES METALLIQUES FIXES A UN SUPPORT DE POLYMERE DE FORMULE: (CF DESSIN DANS BOPI) OUPSREPRESENTE UN POLYSTYRENE RETICULE PAR DU DIVINYLBENZENE A RAISON DE PLUS DE 1 ET DE MOINS D'ENVIRON 18, R REPRESENTE UN RADICAL CYCLOALCADIENYLE COMPORTANT 4 A 6ATOMES DE CARBONE, ME REPRESENTE UN METAL DU GROUPE VIII, CO REPRESENTE UN RADICAL CARBONYLE, H REPRESENTE L'HYDROGENE, N EST EGAL A 0, 1, 2 OU 3, M EST EGAL A 0, 1 OU 2 INCLUSIVEMENT, SOUS RESERVE QUE LA SOMME DE 2NM AJOUTEE AU NOMBRE D'ELECTRONS DE R ET ME FASSE 18 OU QUE NM SOIT EGAL A 0; UN PROCEDE DE PREPARATION DE CES COMPLEXES ET LEUR EMPLOI COMME CATALYSEURS AMELIORES DE FISCHER-TROPSCH CONVENANT PARTICULIEREMENT BIEN A LA CONVERSION DE COH EN HYDROCARBURES GAZEUX OU LIQUIDES DANS DES CONDITIONS PLUS MODEREES QU'AVEC LES CATALYSEURS CONNUS SONT EGALEMENT DECRITS.
FR8011032A 1979-05-17 1980-05-16 Nouveaux catalyseurs de fischer-tropsch, procede de leur preparation et procede de fischer-tropsch les utilisant Expired FR2456549B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/039,986 US4230633A (en) 1979-05-17 1979-05-17 Novel Fischer-Tropsch catalysts

Publications (2)

Publication Number Publication Date
FR2456549A1 true FR2456549A1 (fr) 1980-12-12
FR2456549B1 FR2456549B1 (fr) 1986-02-28

Family

ID=21908454

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8011032A Expired FR2456549B1 (fr) 1979-05-17 1980-05-16 Nouveaux catalyseurs de fischer-tropsch, procede de leur preparation et procede de fischer-tropsch les utilisant

Country Status (8)

Country Link
US (1) US4230633A (fr)
JP (1) JPS55152550A (fr)
AU (1) AU534881B2 (fr)
CA (1) CA1136602A (fr)
DE (1) DE3018976A1 (fr)
FR (1) FR2456549B1 (fr)
GB (1) GB2051082B (fr)
IT (1) IT1140953B (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4276395A (en) * 1979-05-17 1981-06-30 The United States Of America As Represented By The United States Department Of Energy Novel Fischer-Tropsch catalysts
US4292415A (en) * 1979-05-17 1981-09-29 The United State Of America As Represented By The United States Department Of Energy Novel Fischer-Tropsch catalysts
US4383087A (en) * 1982-02-04 1983-05-10 Combustion Engineering, Inc. Organic polymer layered trichalcogenides
US4383088A (en) * 1982-02-04 1983-05-10 Combustion Engineering, Inc. Organic polymer layered dichalcogenides
US4725568A (en) * 1984-07-17 1988-02-16 The Goodyear Tire & Rubber Company Polymer bound fischer-tropsch catalysts
US4596831A (en) * 1984-07-17 1986-06-24 The Goodyear Tire & Rubber Company Polymer bound fischer-tropsch catalysts
US4935395A (en) * 1986-12-19 1990-06-19 Associated Universities, Inc. Homogeneous catalyst formulations for methanol production
GB8729069D0 (en) * 1987-12-12 1988-01-27 Rapra Techn Ltd Temperature activated catalysts for liquid polymer cures
US6613808B2 (en) 2000-06-12 2003-09-02 Conoco Inc. Fischer-Tropsch processes and catalysts using polyacrylate matrix structures
RU2537850C1 (ru) * 2013-09-12 2015-01-10 Общество с ограниченной ответственностью "АНИКО" Катализатор и способ получения синтетических углеводородов алифатического ряда из оксида углерода и водорода в его присутствии
RU2745214C1 (ru) * 2020-08-11 2021-03-22 Федеральное государственное бюджетное образовательное учреждение высшего образования "Тверской государственный технический университет" Катализатор синтеза фишера-тропша и способ его получения

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4022810A (en) * 1976-02-02 1977-05-10 Gulf Research & Development Company Metal chrysotile methane synthesis catalyst
US4132672A (en) * 1976-03-15 1979-01-02 American Gas Association Methanation catalyst
FR2394552A1 (fr) * 1977-06-16 1979-01-12 Brintzinger Hans Cyclopentadienyl-metal-carbonyles lies a des polymeres ainsi que leurs derives, leur procede de preparation
US4144191A (en) * 1977-06-06 1979-03-13 The Dow Chemical Company Amine-resin supported rhodium-cobalt carbonyl bimetallic clusters as novel hydroformylation catalysts

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4032556A (en) * 1971-11-23 1977-06-28 The Gas Council Methanation of gases
US4096163A (en) * 1975-04-08 1978-06-20 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4022810A (en) * 1976-02-02 1977-05-10 Gulf Research & Development Company Metal chrysotile methane synthesis catalyst
US4132672A (en) * 1976-03-15 1979-01-02 American Gas Association Methanation catalyst
US4144191A (en) * 1977-06-06 1979-03-13 The Dow Chemical Company Amine-resin supported rhodium-cobalt carbonyl bimetallic clusters as novel hydroformylation catalysts
FR2394552A1 (fr) * 1977-06-16 1979-01-12 Brintzinger Hans Cyclopentadienyl-metal-carbonyles lies a des polymeres ainsi que leurs derives, leur procede de preparation

Also Published As

Publication number Publication date
DE3018976A1 (de) 1980-11-20
GB2051082B (en) 1983-04-07
US4230633A (en) 1980-10-28
JPS55152550A (en) 1980-11-27
FR2456549B1 (fr) 1986-02-28
AU5849380A (en) 1980-11-20
IT8022147A0 (it) 1980-05-16
CA1136602A (fr) 1982-11-30
GB2051082A (en) 1981-01-14
IT1140953B (it) 1986-10-10
AU534881B2 (en) 1984-02-16

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