FI78679B - Nya cyklopropankarboxylsyraderivat, deras framstaellningsfoerfarande och preparat innehaollande dessa derivat foer bekaempning av parasiter. - Google Patents
Nya cyklopropankarboxylsyraderivat, deras framstaellningsfoerfarande och preparat innehaollande dessa derivat foer bekaempning av parasiter. Download PDFInfo
- Publication number
- FI78679B FI78679B FI813042A FI813042A FI78679B FI 78679 B FI78679 B FI 78679B FI 813042 A FI813042 A FI 813042A FI 813042 A FI813042 A FI 813042A FI 78679 B FI78679 B FI 78679B
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- FI
- Finland
- Prior art keywords
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- formula
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/64—One oxygen atom attached in position 2 or 6
- C07D213/647—One oxygen atom attached in position 2 or 6 and having in the molecule an acyl radical containing a saturated three-membered ring, e.g. chrysanthemumic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C69/743—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring of acids with a three-membered ring and with unsaturation outside the ring
- C07C69/747—Chrysanthemumic acid esters
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K20/00—Accessory food factors for animal feeding-stuffs
- A23K20/10—Organic substances
- A23K20/105—Aliphatic or alicyclic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K20/00—Accessory food factors for animal feeding-stuffs
- A23K20/10—Organic substances
- A23K20/111—Aromatic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/21—Esters, e.g. nitroglycerine, selenocyanates
- A61K31/215—Esters, e.g. nitroglycerine, selenocyanates of carboxylic acids
- A61K31/22—Esters, e.g. nitroglycerine, selenocyanates of carboxylic acids of acyclic acids, e.g. pravastatin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/21—Esters, e.g. nitroglycerine, selenocyanates
- A61K31/215—Esters, e.g. nitroglycerine, selenocyanates of carboxylic acids
- A61K31/22—Esters, e.g. nitroglycerine, selenocyanates of carboxylic acids of acyclic acids, e.g. pravastatin
- A61K31/225—Polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Zoology (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Food Science & Technology (AREA)
- Animal Husbandry (AREA)
- Emergency Medicine (AREA)
- Medicinal Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Indole Compounds (AREA)
- Pyridine Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Furan Compounds (AREA)
- Thiazole And Isothizaole Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Pyrane Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Plural Heterocyclic Compounds (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Claims (15)
1. Föreningar med formeln I 5 X\ yCH ,0 // I RO-C^ \X2X^C-°B i 3 10 väri R är en rakkedjad, förgrenad eller cyklisk, mättad alkylgrupp med 1-8 kolatomer, vilken kan vara substi-tuerad med en eller flera halogenatomer eller lägre alkoxigrupper, B är gruppen 15 CH, | ^^CH2-CH=CH2 20 eller gruppen O -CH »-N N-CH--CäCH V O eller gruppen F f -CH-—n A— F 30 F F eller gruppen _ Tn O-T 35 56 73679 väri R^ är en väteatom eller en metyl-, etynyl- eller cyanoradikal och R^j. är en väte- eller fluoratom, eller gruppen och X är en halogenatom, och i vilken förening I etylendubbelbindningen har konfi-gurationen E och cyklopropanstammen har strukturen 1R cis.
2. Förening enligt patentkravet 1, känne- t e c k n a d därav, att den utgörs av (2)Cfc-cyano-3-fen-oxibensyl-(1R, cis)-2,2-dimetyl-3(E)-^2-fluor-2-(etoxi-karbony1)eteny l) cyklopropan-1-karboxylat.
3. Användning av föreningarna enligt patentkravet 1 vid bekämpning av växtparasiter och husparasiter.
4. Kompositioner avsedda för bekämpning av växt-2q parasiter och husparasiter, kännetecknade därav, att de som aktiv ingrediens innehäller ätminstone en förening definierad i patentkravet 1.
5. Insekticida kompositioner, kännetecknade därav, att de som aktiv ingrediens innehäller : 25 ätminstone en förening definierad i patentkravet 1.
6. Akaricida kompositioner, kännetecknade därav, att de som aktiv ingrediens innehäller ätminstone en förening definierad i patentkravet 1.
7. Förfarande för framställning av föreningarna jq med formeln I och definierade i patentkravet 1, k ä n - netecknat därav, att en syra med formeln II X H OH ^>=<1 ^ C=0 II RO-C 1
11. H 57 78679 väri X och R har ovan angivna betydelse, eller ett funk-tionellt derivat av derma syra, omsätts med en alkohol med formeIn III
5 B-OH III väri B har ovan angivna betydelse, eller med ett funk-tionellt derivat av denna alkohol, för erhällande av mot-svarande förening med formeln I, vilken, om sA önskas, omsätts med ett medel som selektivt avspjäkar gruppen 10 CC^R, för erhAllande av en förening med formeln lv x H X / CH3v^CH3 O >< JK » / X/ \^C-OB HO-C -X
15. XH IV O väri B har ovan angivna betydelse, varefter syran med formeln IV eller ett funktionellt derivat av denna syra, omsätts med en alkohol med formeln R-OH, väri R har ovan 20 angivna betydelse, och att föreningen 1R cis E separeras fr An blandningen 1R cis (E + Z) genom kromatografering.
8. Förfarande enligt patentkravet 7, känne-t e c k n a t därav, att syran med formeln II, väri R är en alkylgrupp med 1-5 kolatomer, framställs genom 25 att man medelst Wittig-reaktion i närvaro av en stark bas, omsätter en cis-aldehyd i form av ett lakton med formeln V »o/Vo eller en trans-aldehyd med formeln VI
35 H \ / ° 0=C. /X, .C-OH VI xz—χΓ H
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8021017 | 1980-10-01 | ||
FR8021017A FR2491060A1 (fr) | 1980-10-01 | 1980-10-01 | Esters d'acides cyclopropanes carboxyliques apparentes a l'acide pyrethrique, leur procede de preparation et leur application a la lutte contre les parasites |
Publications (3)
Publication Number | Publication Date |
---|---|
FI813042L FI813042L (fi) | 1982-04-02 |
FI78679B true FI78679B (fi) | 1989-05-31 |
FI78679C FI78679C (sv) | 1989-09-11 |
Family
ID=9246463
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FI813042A FI78679C (sv) | 1980-10-01 | 1981-09-30 | Nya cyklopropankarboxylsyraderivat, deras framställningsförfarande och preparat innehållande dessa derivat för bekämpning av parasiter |
Country Status (24)
Country | Link |
---|---|
EP (1) | EP0050534B1 (sv) |
JP (2) | JPS57126447A (sv) |
KR (1) | KR880001829B1 (sv) |
AT (1) | ATE12490T1 (sv) |
AU (1) | AU548041B2 (sv) |
BR (1) | BR8106299A (sv) |
CA (2) | CA1237135A (sv) |
DD (2) | DD211473A5 (sv) |
DE (1) | DE3169688D1 (sv) |
DK (2) | DK164740C (sv) |
ES (1) | ES505887A0 (sv) |
FI (1) | FI78679C (sv) |
FR (2) | FR2491060A1 (sv) |
GR (1) | GR75021B (sv) |
HU (1) | HU195759B (sv) |
IE (1) | IE52212B1 (sv) |
IL (1) | IL63979A0 (sv) |
MA (1) | MA19293A1 (sv) |
NZ (1) | NZ198515A (sv) |
OA (1) | OA07538A (sv) |
PT (1) | PT73753B (sv) |
SU (1) | SU1473707A3 (sv) |
ZA (1) | ZA816768B (sv) |
ZW (1) | ZW24181A1 (sv) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2536392A2 (fr) * | 1982-11-22 | 1984-05-25 | Roussel Uclaf | Nouveaux derives de l'acide cyclopropane carboxylique, leur procede de preparation et leur application a la lutte contre les parasites |
FR2536389B2 (fr) * | 1982-11-22 | 1986-06-27 | Roussel Uclaf | Esters d'acides cyclopropane carboxyliques apparentes a l'acide pyretrique, leur procede de preparation et leur application a la lutte contre les parasites |
FR2491060A1 (fr) * | 1980-10-01 | 1982-04-02 | Roussel Uclaf | Esters d'acides cyclopropanes carboxyliques apparentes a l'acide pyrethrique, leur procede de preparation et leur application a la lutte contre les parasites |
FR2533416B1 (fr) * | 1982-09-29 | 1988-09-02 | Roussel Uclaf | Nouvelles compositions pesticides renfermant un photostabilisant |
FR2534252A1 (fr) * | 1982-10-12 | 1984-04-13 | Roussel Uclaf | Nouveaux derives de l'acide cyclopropane carboxylique substitues en 3 par une chaine vinylique elle-meme substituee, leur procede de preparation et leur application comme pesticides |
FR2535315A1 (fr) * | 1982-11-02 | 1984-05-04 | Roussel Uclaf | Nouveaux derives de l'acide cyclopropane carboxylique comportant un groupement alcoylthio carbonyle et un atome d'halogene, leur preparation, leur application a la lutte contre les parasites des vegetaux, des animaux et des locaux et les compositions les renfermant |
FR2536748A1 (fr) * | 1982-11-25 | 1984-06-01 | Roussel Uclaf | Nouveaux esters derives d'acides 2,2-dimethyl cyclopropane carboxyliques et d'alcools biaryliques, leur procede de preparation et leur application a la lutte contre les parasites |
FR2537973B1 (fr) * | 1982-12-15 | 1985-11-08 | Roussel Uclaf | Esters d'acides cyclopropane carboxyliques et d'alcools aliphatiques insatures, leur procede de preparation et les compositions pesticides les renfermant |
FR2547817B2 (fr) * | 1982-12-15 | 1986-02-14 | Roussel Uclaf | Esters d'acides cyclopropane carboxyliques et d'alcools aliphatiques insatures, leur procede de preparation et les compositions pesticides les renfermant |
FR2569189B1 (fr) * | 1984-08-14 | 1986-12-19 | Roussel Uclaf | Nouveaux derives du pyrrole, leur procede de preparation et leur application comme pesticides |
FR2590259B1 (fr) * | 1985-11-20 | 1989-05-12 | Roussel Uclaf | Procede de preparation de derives fluores de l'acide phosphonique, et produits obtenus par la mise en oeuvre de ce procede |
FR2608152B1 (fr) * | 1986-12-11 | 1989-03-31 | Roussel Uclaf | Le 2,2-dimethyl 3-formyl cyclopropane carboxylate de pentafluorophenylmethyle, son procede de preparation et son application a la synthese de produits pesticides |
FR2610624B1 (fr) * | 1987-02-06 | 1989-06-09 | Roussel Uclaf | Nouveaux esters d'acides cyclopropanecarboxyliques apparentes a l'acide pyrethrique, leur procede de preparation et leur application a la lutte contre les parasites |
FR2618432B1 (fr) * | 1987-07-20 | 1989-12-01 | Roussel Uclaf | Nouveaux derives pyrethrinoides comportant un heterocycle azote, leur procede de preparation et leurs applications comme pesticides |
JP2570388B2 (ja) * | 1988-06-10 | 1997-01-08 | 住友化学工業株式会社 | カルボン酸エステルおよびその殺虫剤としての用途 |
GB8902324D0 (en) * | 1989-02-02 | 1989-03-22 | Ici Plc | Insecticidal compounds |
FR2687666A1 (fr) * | 1992-02-21 | 1993-08-27 | Roussel Uclaf | Nouveaux esters pyrethrinouiques, derives de l'alcool 6-(trifluoromethyl) benzylique, leur procede de preparation et leur application comme pesticides. |
FR2693082B1 (fr) * | 1992-07-01 | 1994-08-26 | Roussel Uclaf | Nouvelles compositions insecticides renfermant comme principe actif un ester de l'acide 3-[(DELTAZ) 2-fluoro 3-oxo 3-méthoxy propényl] cyclopropane carboxylique. |
FR2703044B1 (fr) * | 1993-03-25 | 1995-06-02 | Roussel Uclaf | Nouveau procédé d'isomérisation de doubles liaisons. |
JP3694915B2 (ja) * | 1994-06-17 | 2005-09-14 | 住友化学株式会社 | エステル化合物およびそれを有効成分とする有害生物防除剤 |
US5852048A (en) * | 1995-03-01 | 1998-12-22 | Sumitomo Chemical Company, Limited | Ester compound and a pesticidal agent containing the same as an active ingredient |
JP3286598B2 (ja) * | 1998-06-11 | 2002-05-27 | 富士写真フイルム株式会社 | シートの搬送装置 |
JP4552456B2 (ja) * | 2004-02-27 | 2010-09-29 | 住友化学株式会社 | エステル化合物およびその用途 |
JP5066843B2 (ja) * | 2006-06-15 | 2012-11-07 | 住友化学株式会社 | エステル化合物及びその有害生物防除用途 |
CN106642346A (zh) * | 2016-12-28 | 2017-05-10 | 武汉海尔电器股份有限公司 | 空调器 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1446304A (en) * | 1972-05-25 | 1976-08-18 | Nat Res Dev | 3-substituted cyclopropane carboxylic acids and derivatives thereof |
DE2326077C2 (de) * | 1972-05-25 | 1985-12-12 | National Research Development Corp., London | Ungesättigte Cyclopropancarbonsäuren und deren Derivate, deren Herstellung und diese enthaltende Insektizide |
OA06786A (fr) * | 1980-04-16 | 1982-12-31 | Roussel Uclaf | Nouveaux dérivés de l'acide cyclopropane, leur préparation, leur application à la lutte contre les parasites des végétaux et des animaux, les compositions les renfermant et les nouveaux intermediaires obtenus. |
FR2482955A1 (fr) * | 1980-05-23 | 1981-11-27 | Roussel Uclaf | Nouveaux derives de l'acide cyclopropane carboxylique, leur procede de preparation et leur application a la lutte contre les parasites |
FR2491060A1 (fr) * | 1980-10-01 | 1982-04-02 | Roussel Uclaf | Esters d'acides cyclopropanes carboxyliques apparentes a l'acide pyrethrique, leur procede de preparation et leur application a la lutte contre les parasites |
-
1980
- 1980-10-01 FR FR8021017A patent/FR2491060A1/fr active Granted
-
1981
- 1981-08-28 EP EP81401360A patent/EP0050534B1/fr not_active Expired
- 1981-08-28 DE DE8181401360T patent/DE3169688D1/de not_active Expired
- 1981-08-28 AT AT81401360T patent/ATE12490T1/de active
- 1981-09-29 GR GR66153A patent/GR75021B/el unknown
- 1981-09-29 ZW ZW241/81A patent/ZW24181A1/xx unknown
- 1981-09-30 NZ NZ198515A patent/NZ198515A/en unknown
- 1981-09-30 FI FI813042A patent/FI78679C/sv not_active IP Right Cessation
- 1981-09-30 ZA ZA816768A patent/ZA816768B/xx unknown
- 1981-09-30 CA CA000386995A patent/CA1237135A/fr not_active Expired
- 1981-09-30 BR BR8106299A patent/BR8106299A/pt unknown
- 1981-09-30 MA MA19494A patent/MA19293A1/fr unknown
- 1981-09-30 DK DK432781A patent/DK164740C/da not_active IP Right Cessation
- 1981-09-30 DD DD81249256A patent/DD211473A5/de not_active IP Right Cessation
- 1981-09-30 IE IE2274/81A patent/IE52212B1/en not_active IP Right Cessation
- 1981-09-30 SU SU813372847A patent/SU1473707A3/ru active
- 1981-09-30 DD DD81233716A patent/DD202422A5/de not_active IP Right Cessation
- 1981-09-30 CA CA000386984A patent/CA1242648A/fr not_active Expired
- 1981-09-30 PT PT73753A patent/PT73753B/pt not_active IP Right Cessation
- 1981-09-30 ES ES505887A patent/ES505887A0/es active Granted
- 1981-09-30 HU HU812824A patent/HU195759B/hu not_active IP Right Cessation
- 1981-10-01 JP JP56154927A patent/JPS57126447A/ja active Granted
- 1981-10-01 IL IL63979A patent/IL63979A0/xx not_active IP Right Cessation
- 1981-10-01 AU AU75961/81A patent/AU548041B2/en not_active Ceased
- 1981-10-02 KR KR1019810003710A patent/KR880001829B1/ko active
-
1983
- 1983-09-22 OA OA58107A patent/OA07538A/xx unknown
-
1984
- 1984-02-24 FR FR8402831A patent/FR2560189B2/fr not_active Expired
- 1984-05-21 JP JP59100736A patent/JPH0643369B2/ja not_active Expired - Lifetime
-
1991
- 1991-01-29 DK DK015691A patent/DK164402C/da not_active IP Right Cessation
Also Published As
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM | Patent lapsed | ||
MM | Patent lapsed |
Owner name: ROUSSEL UCLAF SOCIETE ANONYME |