FI76354C - Katalytkomponent för Ziegler-Natta katalyter och förfarande för polyme risering av alfa-olefiner - Google Patents
Katalytkomponent för Ziegler-Natta katalyter och förfarande för polyme risering av alfa-olefiner Download PDFInfo
- Publication number
- FI76354C FI76354C FI865361A FI865361A FI76354C FI 76354 C FI76354 C FI 76354C FI 865361 A FI865361 A FI 865361A FI 865361 A FI865361 A FI 865361A FI 76354 C FI76354 C FI 76354C
- Authority
- FI
- Finland
- Prior art keywords
- compound
- catalytic component
- ziegler
- catalyst
- foer
- Prior art date
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- 230000003197 catalytic effect Effects 0.000 title claims 9
- 239000011954 Ziegler–Natta catalyst Substances 0.000 title description 3
- -1 titanium halides Chemical class 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 18
- 239000010936 titanium Substances 0.000 claims description 16
- 229910052719 titanium Inorganic materials 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 10
- 150000002901 organomagnesium compounds Chemical class 0.000 claims description 10
- 229910000077 silane Inorganic materials 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 239000000460 chlorine Substances 0.000 claims description 6
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical group Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 6
- 238000011282 treatment Methods 0.000 claims description 6
- OLLFKUHHDPMQFR-UHFFFAOYSA-N dihydroxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](O)(O)C1=CC=CC=C1 OLLFKUHHDPMQFR-UHFFFAOYSA-N 0.000 claims description 5
- NLSXASIDNWDYMI-UHFFFAOYSA-N triphenylsilanol Chemical compound C=1C=CC=CC=1[Si](C=1C=CC=CC=1)(O)C1=CC=CC=C1 NLSXASIDNWDYMI-UHFFFAOYSA-N 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 150000002681 magnesium compounds Chemical class 0.000 claims description 4
- 150000004756 silanes Chemical class 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 3
- 125000005234 alkyl aluminium group Chemical group 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 3
- 229910052801 chlorine Inorganic materials 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 239000011230 binding agent Substances 0.000 claims 1
- 150000004796 dialkyl magnesium compounds Chemical class 0.000 claims 1
- 239000003054 catalyst Substances 0.000 description 63
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 32
- 238000006116 polymerization reaction Methods 0.000 description 27
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 17
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 17
- 239000011777 magnesium Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- 229910052749 magnesium Inorganic materials 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- KCIKCCHXZMLVDE-UHFFFAOYSA-N silanediol Chemical compound O[SiH2]O KCIKCCHXZMLVDE-UHFFFAOYSA-N 0.000 description 4
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 4
- 239000002879 Lewis base Substances 0.000 description 3
- 229910020175 SiOH Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 150000007527 lewis bases Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 150000003623 transition metal compounds Chemical class 0.000 description 3
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 2
- MVECFARLYQAUNR-UHFFFAOYSA-N CCCC[Mg]CC Chemical compound CCCC[Mg]CC MVECFARLYQAUNR-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 235000011147 magnesium chloride Nutrition 0.000 description 2
- KXDANLFHGCWFRQ-UHFFFAOYSA-N magnesium;butane;octane Chemical compound [Mg+2].CCC[CH2-].CCCCCCC[CH2-] KXDANLFHGCWFRQ-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- RTAQCQOZRWKSTQ-UHFFFAOYSA-N CC(C)C[Mg]CC(C)C Chemical compound CC(C)C[Mg]CC(C)C RTAQCQOZRWKSTQ-UHFFFAOYSA-N 0.000 description 1
- MIEFVQIJSAGPBZ-UHFFFAOYSA-N CCC[Mg] Chemical compound CCC[Mg] MIEFVQIJSAGPBZ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- LJWBIAMZBJWAOW-UHFFFAOYSA-N benzhydryloxysilane Chemical compound C=1C=CC=CC=1C(O[SiH3])C1=CC=CC=C1 LJWBIAMZBJWAOW-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
- DLPASUVGCQPFFO-UHFFFAOYSA-N magnesium;ethane Chemical compound [Mg+2].[CH2-]C.[CH2-]C DLPASUVGCQPFFO-UHFFFAOYSA-N 0.000 description 1
- RVOYYLUVELMWJF-UHFFFAOYSA-N magnesium;hexane Chemical compound [Mg+2].CCCCC[CH2-].CCCCC[CH2-] RVOYYLUVELMWJF-UHFFFAOYSA-N 0.000 description 1
- KMYFNYFIPIGQQZ-UHFFFAOYSA-N magnesium;octane Chemical compound [Mg+2].CCCCCCC[CH2-].CCCCCCC[CH2-] KMYFNYFIPIGQQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 150000003022 phthalic acids Chemical class 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000010076 replication Effects 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 1
- 239000005052 trichlorosilane Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Claims (7)
1. Katalytkomponent som anvMnds vid katalytkomposiotioner av Ziegler-Natta typ utan bMrare för polymerisering av o<-olefiner med minst 5. kolatomer, varvid nämnda katalytkomponent erhalllts genom att be- handla en organisk magnesiumförening som inte innehaller klor med fasta silanföreningar som innehaller en eller tva hydroxylgrupper och tltanhalider, kännetecknad därav, att nämnda behandling av organomagnesiumföreningen utförs genom att fSrst behandla med nämnda 10 silanförenlng vid en temperatur pa 60-110°C och därefter med en titanhalidförening valbart tillsammans med en elektrondonorförenlng.
1 Patentkrav
2. Katalytkomponent enllgt patentkrav 1, kännetecknad därav, att nämnda organomagnesiumforening som inte innehaller klor 15 är en dialkylmagnesiumförening, där alkylgrupperna är likadana eller olika och innehaller 2-10 kolatomer.
3. Katalytkomponent enligt patentkraven 1-2, kännetecknad därav, att silanföreningen som innehaller nämnda en eller tva hydroxyl- 20 grupper Mr vald ur gruppen difenylsilandiol och trifenylsilanol.
4. Katalytkomponent enligt nlgot av patentkraven 1-3, kännetecknad därav, att nämnda titanhalid är titantetraklorid.
5. Ziegler-Natta katalytkomposition utan bärare för polymerisering av oC-olefiner med minst 3 kolatomer, som innefattar (1) en katalytkomponent som erhalllts genom att behandla en organomagnesiumförening som inte Innehaller klor med fasta silanföreningar som Innehaller en eller tva hydroxylgrupper och tltanhalldföreningar, (2) en kokatalyt, 30 som valts ur gruppen alkyllitlum, alkylmagnesium, alkylaluminium, alkyl-aluminiumhalid eller alkylzink, och (3) valbart en yttre elektrondonor-förenlng, kännetecknad därav, att nämnda behandling av organomagnesiumföreningen har utförts genom att först behandla med nämnda silanförenlng vid en temperatur pa 60-110°C och därefter med en 35 titanhalidförening valbart tillsammans med en elektrondonor.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI865361A FI76354C (sv) | 1986-12-31 | 1986-12-31 | Katalytkomponent för Ziegler-Natta katalyter och förfarande för polyme risering av alfa-olefiner |
| IT8722761A IT1224643B (it) | 1986-12-31 | 1987-11-26 | Componente di catalizzatore per catalizzatori ziegler natta emetodo per polimerizzare alfa olefine. |
| BE8701359A BE1000160A7 (fr) | 1986-12-31 | 1987-11-30 | Composant catalytique pour catalyseurs de ziegler-natta et procede pour la polymerisation d'alpha-olefines. |
| PCT/FI1987/000167 WO1988005056A1 (en) | 1986-12-31 | 1987-12-10 | CATALYST COMPONENT FOR ZIEGLER-NATTA CATALYSTS AND METHOD FOR POLYMERIZING alpha-OLEFINS |
| FR8717402A FR2609035A1 (fr) | 1986-12-31 | 1987-12-14 | Composant catalytique pour composition de catalyseur de ziegler-natta sans support, composition contenant ce composant et procede de polymerisation d'a-olefines en presence de cette composition |
| JP62336800A JPS63175008A (ja) | 1986-12-31 | 1987-12-29 | α−オレフィン重合方法および触媒成分 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI865361A FI76354C (sv) | 1986-12-31 | 1986-12-31 | Katalytkomponent för Ziegler-Natta katalyter och förfarande för polyme risering av alfa-olefiner |
| FI865361 | 1986-12-31 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI865361A0 FI865361A0 (fi) | 1986-12-31 |
| FI76354B FI76354B (fi) | 1988-06-30 |
| FI76354C true FI76354C (sv) | 1988-10-10 |
Family
ID=8523727
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI865361A FI76354C (sv) | 1986-12-31 | 1986-12-31 | Katalytkomponent för Ziegler-Natta katalyter och förfarande för polyme risering av alfa-olefiner |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS63175008A (sv) |
| BE (1) | BE1000160A7 (sv) |
| FI (1) | FI76354C (sv) |
| FR (1) | FR2609035A1 (sv) |
| IT (1) | IT1224643B (sv) |
| WO (1) | WO1988005056A1 (sv) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5063188A (en) * | 1990-04-06 | 1991-11-05 | Texas Alkyls, Inc. | Catalyst component for ethylene polyermization and copolymerization |
| JP3943230B2 (ja) * | 1998-02-26 | 2007-07-11 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分及び触媒 |
| CN107522801B (zh) * | 2016-06-22 | 2020-07-31 | 中国石化扬子石油化工有限公司 | 一种丙烯丁烯共聚催化剂体系及其在制备丙烯丁烯共聚物的应用 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58448B2 (ja) * | 1976-09-27 | 1983-01-06 | 三井化学株式会社 | ポリオレフインの製造方法 |
| JPS53136086A (en) * | 1977-05-04 | 1978-11-28 | Mitsubishi Chem Ind Ltd | Production of olefin polymer |
| JPS5470389A (en) * | 1977-11-16 | 1979-06-06 | Mitsubishi Chem Ind Ltd | Production of olefin polymer |
| JPS57165407A (en) * | 1981-04-04 | 1982-10-12 | Mitsubishi Chem Ind Ltd | Preparation of olefinic polymer |
| US4477586A (en) * | 1982-08-27 | 1984-10-16 | Phillips Petroleum Company | Polymerization of olefins |
| US4525557A (en) * | 1984-02-27 | 1985-06-25 | Gulf Oil Corporation | Catalyst and process for the polymerization of ethylene |
| JPH062774B2 (ja) * | 1985-03-12 | 1994-01-12 | 三井東圧化学株式会社 | オレフインの重合方法 |
-
1986
- 1986-12-31 FI FI865361A patent/FI76354C/sv not_active IP Right Cessation
-
1987
- 1987-11-26 IT IT8722761A patent/IT1224643B/it active
- 1987-11-30 BE BE8701359A patent/BE1000160A7/fr not_active IP Right Cessation
- 1987-12-10 WO PCT/FI1987/000167 patent/WO1988005056A1/en unknown
- 1987-12-14 FR FR8717402A patent/FR2609035A1/fr active Pending
- 1987-12-29 JP JP62336800A patent/JPS63175008A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| IT8722761A0 (it) | 1987-11-26 |
| JPS63175008A (ja) | 1988-07-19 |
| WO1988005056A1 (en) | 1988-07-14 |
| FR2609035A1 (fr) | 1988-07-01 |
| FI865361A0 (fi) | 1986-12-31 |
| BE1000160A7 (fr) | 1988-06-28 |
| IT1224643B (it) | 1990-10-18 |
| FI76354B (fi) | 1988-06-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed |
Owner name: NESTE OY |