ES2345518T3 - Composiciones biodegradables a base de almidon nanoparticulado. - Google Patents

Composiciones biodegradables a base de almidon nanoparticulado. Download PDF

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Publication number
ES2345518T3
ES2345518T3 ES07820625T ES07820625T ES2345518T3 ES 2345518 T3 ES2345518 T3 ES 2345518T3 ES 07820625 T ES07820625 T ES 07820625T ES 07820625 T ES07820625 T ES 07820625T ES 2345518 T3 ES2345518 T3 ES 2345518T3
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ES
Spain
Prior art keywords
starch
phase
film
multiphase
compositions according
Prior art date
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Active
Application number
ES07820625T
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English (en)
Spanish (es)
Inventor
Catia Bastioli
Giovanni Floridi
Gianfranco Del Tredici
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novamont SpA
Original Assignee
Novamont SpA
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Publication of ES2345518T3 publication Critical patent/ES2345518T3/es
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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • C08L101/16Compositions of unspecified macromolecular compounds the macromolecular compounds being biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2303/00Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08J2303/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/04Polyesters derived from hydroxy carboxylic acids, e.g. lactones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/062Copolymers with monomers not covered by C08L33/06
    • C08L33/068Copolymers with monomers not covered by C08L33/06 containing glycidyl groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S220/00Receptacles
    • Y10S220/30Biodegradable
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1334Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1372Randomly noninterengaged or randomly contacting fibers, filaments, particles, or flakes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254Polymeric or resinous material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/268Monolayer with structurally defined element
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/269Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension including synthetic resin or polymer layer or component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31786Of polyester [e.g., alkyd, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31971Of carbohydrate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/681Spun-bonded nonwoven fabric

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Artificial Filaments (AREA)
  • Wrappers (AREA)
  • Laminated Bodies (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
ES07820625T 2006-09-27 2007-09-26 Composiciones biodegradables a base de almidon nanoparticulado. Active ES2345518T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT001844A ITMI20061844A1 (it) 2006-09-27 2006-09-27 Composizioni biodegradabili a base di amido nanoparticellare
ITMI06A1844 2006-09-27

Publications (1)

Publication Number Publication Date
ES2345518T3 true ES2345518T3 (es) 2010-09-24

Family

ID=37770434

Family Applications (2)

Application Number Title Priority Date Filing Date
ES07820625T Active ES2345518T3 (es) 2006-09-27 2007-09-26 Composiciones biodegradables a base de almidon nanoparticulado.
ES10158541T Active ES2382530T3 (es) 2006-09-27 2007-09-26 Composiciones biodegradables a base de almidón nanoparticulado

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES10158541T Active ES2382530T3 (es) 2006-09-27 2007-09-26 Composiciones biodegradables a base de almidón nanoparticulado

Country Status (15)

Country Link
US (1) US8043679B2 (fr)
EP (2) EP2074176B1 (fr)
JP (1) JP2010505018A (fr)
CN (1) CN101516997B (fr)
AT (2) ATE468372T1 (fr)
AU (1) AU2007302010B2 (fr)
BR (1) BRPI0715276B1 (fr)
CA (1) CA2662446C (fr)
DE (1) DE602007006679D1 (fr)
ES (2) ES2345518T3 (fr)
IT (1) ITMI20061844A1 (fr)
PL (2) PL2202274T3 (fr)
PT (1) PT2202274E (fr)
RU (1) RU2479607C2 (fr)
WO (1) WO2008037749A2 (fr)

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ITMI20061845A1 (it) 2006-09-27 2008-03-28 Novamont Spa Composizioni biodegradabili polifasiche a base di amido
AU2009311259B2 (en) * 2008-11-06 2015-02-12 Tristano Pty Ltd Biodegradable polymer composition
US8974881B2 (en) 2008-12-26 2015-03-10 Mitsubishi Chemical Corporation Resin composition, film, bag product and production process of resin composition
US20120016328A1 (en) * 2010-07-19 2012-01-19 Bo Shi Biodegradable films
IT1401318B1 (it) 2010-08-06 2013-07-18 Novamont Spa Composizioni biodegradabili polifasiche contenenti almeno un polimero di origine naturale
GB2489934B (en) * 2011-04-08 2015-11-25 Innovia Films Ltd Film
CN102321249B (zh) 2011-06-30 2013-01-16 无锡碧杰生物材料科技有限公司 一种热塑性淀粉和生物降解聚酯/淀粉复合材料及其制备
CN103906809B (zh) * 2011-11-15 2016-06-29 昭和电工株式会社 生物降解性树脂组合物和生物降解性膜
CN102516714B (zh) * 2011-11-29 2013-06-12 武汉理工大学 一种环氧树脂纳米复合材料的制备方法
CN104470986B (zh) 2012-05-31 2017-09-15 沙特基础工业公司 双轴拉伸制品
EP2784114B1 (fr) 2013-03-26 2016-01-13 Sociedad Anónima Minera Catalano-Aragonesa Polymère biodégradable et d'origine biologique
EP2984138B1 (fr) * 2013-04-10 2017-10-04 BIOTEC Biologische Naturverpackungen GmbH & Co. KG Composition polymère
WO2015071396A1 (fr) 2013-11-14 2015-05-21 Saudi Basic Industries Corporation Article étiré bi-axialement et film d'ensilage
KR101634076B1 (ko) * 2014-02-17 2016-06-28 씨제이제일제당(주) 바이오매스를 이용한 시트용 조성물, 친환경 복합시트 및 이의 제조방법
EP3129430A1 (fr) * 2014-04-09 2017-02-15 Saudi Basic Industries Corporation Inc. Film d'ensilage
CN103980548B (zh) * 2014-05-16 2016-06-15 江苏省农业科学院 一种淀粉基可降解农用地膜及其制备方法
US11879058B2 (en) 2015-06-30 2024-01-23 Biologiq, Inc Yarn materials and fibers including starch-based polymeric materials
US11046840B2 (en) 2015-06-30 2021-06-29 BiologiQ, Inc. Methods for lending biodegradability to non-biodegradable plastic materials
US11674014B2 (en) 2015-06-30 2023-06-13 BiologiQ, Inc. Blending of small particle starch powder with synthetic polymers for increased strength and other properties
US11926929B2 (en) 2015-06-30 2024-03-12 Biologiq, Inc Melt blown nonwoven materials and fibers including starch-based polymeric materials
US11674018B2 (en) 2015-06-30 2023-06-13 BiologiQ, Inc. Polymer and carbohydrate-based polymeric material blends with particular particle size characteristics
US11111363B2 (en) 2015-06-30 2021-09-07 BiologiQ, Inc. Articles formed with renewable and/or sustainable green plastic material and carbohydrate-based polymeric materials lending increased strength and/or biodegradability
US11926940B2 (en) 2015-06-30 2024-03-12 BiologiQ, Inc. Spunbond nonwoven materials and fibers including starch-based polymeric materials
CN105820524A (zh) * 2016-04-16 2016-08-03 巢湖市神龙渔具有限公司 一种环保渔网
CN105733211B (zh) * 2016-05-17 2019-06-21 江南大学 含有淀粉纳米粒子的组合物及其制备方法
JP6785944B2 (ja) 2016-08-02 2020-11-18 フィテサ ジャーマニー ゲゼルシャフト ミット ベシュレンクテル ハフツング ポリ乳酸不織布を調製するためのシステムおよび方法
US11441251B2 (en) 2016-08-16 2022-09-13 Fitesa Germany Gmbh Nonwoven fabrics comprising polylactic acid having improved strength and toughness
CN106903952B (zh) * 2017-01-20 2019-03-12 山东农业大学 一种聚乳酸/淀粉高阻隔复合膜及其制备方法
CN107237001B (zh) * 2017-06-09 2019-12-27 中国水产科学研究院东海水产研究所 一种渔用淀粉改性聚乳酸单丝及其制备方法
CN107857903A (zh) * 2017-12-06 2018-03-30 佛山君帝环保科技有限公司 一种可降解的环保型餐具
CA3104794A1 (fr) * 2018-06-29 2020-01-02 Stichting Wageningen Research Materiau d'emballage a atmosphere modifiee dynamique pour produits horticoles frais
US10975213B2 (en) 2018-08-13 2021-04-13 Erthos Inc. Composition and method of making biodegradable pellets
CN111057274A (zh) * 2019-11-29 2020-04-24 湖南工业大学 一种高填充淀粉基热塑性复合材料及其制备方法
US11820881B2 (en) * 2020-04-02 2023-11-21 Singular Solutions Inc. Plastic pro-biodegradation additives, biodegradable plastic compositions, and related methods

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GB2214918B (en) 1988-02-03 1992-10-07 Warner Lambert Co Polymeric materials made from starch and at least one synthetic thermoplastic polymeric material
IT1233599B (it) * 1989-05-30 1992-04-06 Butterfly Srl Composizioni polimeriche per la produzione di articoli di materiale plastico biodegradabile e procedimenti per la loro preparazione
ATE349476T1 (de) 1990-11-30 2007-01-15 Novamont Spa Aliphatisch-aromatische copolyester
IT1245408B (it) 1991-02-20 1994-09-20 Butterfly Srl Composizioni polimeriche biodegradabili a base di amido e di polimero termoplastico
DE4440858A1 (de) 1994-11-15 1996-05-23 Basf Ag Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper
EP2270093A3 (fr) * 1996-11-05 2013-10-30 NOVAMONT S.p.A. Compositions polymériques biodégradables contenant de l' amidon et un polymère thermoplastique
ITTO980524A1 (it) * 1998-06-17 1999-12-17 Novamont Spa Composizioni contenenti amido aventi elevata resistenza all'invecchiam ento.
CN1214078C (zh) 1998-08-28 2005-08-10 戴尔大学科技研究部 用聚酯树脂生产有优良防潮性的制品
ITMI20020864A1 (it) * 2002-04-22 2003-10-22 Novamont Spa Copolimeri a blocchi amorfo-cristallini
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ITMI20050452A1 (it) * 2005-03-18 2006-09-19 Novamont Spa Poliestere biodegradabile alifatico-aromatico

Also Published As

Publication number Publication date
US20090311455A1 (en) 2009-12-17
CN101516997A (zh) 2009-08-26
EP2202274A2 (fr) 2010-06-30
WO2008037749A3 (fr) 2008-05-15
PT2202274E (pt) 2012-05-21
PL2074176T3 (pl) 2010-10-29
BRPI0715276A2 (pt) 2013-06-04
ATE547476T1 (de) 2012-03-15
EP2202274B1 (fr) 2012-02-29
AU2007302010A1 (en) 2008-04-03
AU2007302010B2 (en) 2012-08-23
ES2382530T3 (es) 2012-06-11
EP2074176B1 (fr) 2010-05-19
CN101516997B (zh) 2012-11-28
CA2662446A1 (fr) 2008-04-03
PL2202274T3 (pl) 2012-08-31
RU2009114684A (ru) 2010-11-10
JP2010505018A (ja) 2010-02-18
EP2074176A2 (fr) 2009-07-01
US8043679B2 (en) 2011-10-25
CA2662446C (fr) 2014-07-29
BRPI0715276B1 (pt) 2018-05-02
EP2202274A3 (fr) 2010-10-27
RU2479607C2 (ru) 2013-04-20
WO2008037749A2 (fr) 2008-04-03
ATE468372T1 (de) 2010-06-15
DE602007006679D1 (de) 2010-07-01
ITMI20061844A1 (it) 2008-03-28

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