ES2192408T3 - Procedimiento para la fabricacion de monoariloxi-ansa-metalocenos. - Google Patents
Procedimiento para la fabricacion de monoariloxi-ansa-metalocenos.Info
- Publication number
- ES2192408T3 ES2192408T3 ES99960984T ES99960984T ES2192408T3 ES 2192408 T3 ES2192408 T3 ES 2192408T3 ES 99960984 T ES99960984 T ES 99960984T ES 99960984 T ES99960984 T ES 99960984T ES 2192408 T3 ES2192408 T3 ES 2192408T3
- Authority
- ES
- Spain
- Prior art keywords
- manufacture
- metallocenes
- ansa
- polymerization
- monoariloxi
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Procedimiento para la fabricación de monoariloxi-ansa-metalocenos. La presente invención hace referencia a un procedimiento de síntesis para la fabricación de monoariloxiansa-metalocenos así como a su utilización en la polimerización de olefinas. Los metalocenos pueden, si se diera el caso en combinación con uno o varios cocatalizadores, ser empleados como componentes del catalizador para la polimerización y copolimerización de las olefinas. En especial, se emplean los metalocenos que contienen halógenos como etapas previas del catalizador, ya que por ejemplo, pueden transformarse en un complejo del metaloceno catiónico activo en la polimerización a través de un aluminoxano.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19854350 | 1998-11-25 | ||
DE1999112576 DE19912576A1 (de) | 1999-03-19 | 1999-03-19 | Verfahren zur Herstellung von Monoaryloxy-Ansa-Metallocenen |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2192408T3 true ES2192408T3 (es) | 2003-10-01 |
Family
ID=26050368
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES99960984T Expired - Lifetime ES2192408T3 (es) | 1998-11-25 | 1999-11-18 | Procedimiento para la fabricacion de monoariloxi-ansa-metalocenos. |
Country Status (7)
Country | Link |
---|---|
US (1) | US6620953B1 (es) |
EP (1) | EP1133504B1 (es) |
JP (1) | JP2002530416A (es) |
BR (1) | BR9915708B1 (es) |
DE (1) | DE59904565D1 (es) |
ES (1) | ES2192408T3 (es) |
WO (1) | WO2000031091A1 (es) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5008794B2 (ja) * | 1998-11-25 | 2012-08-22 | バーゼル、ポリプロピレン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | メタロセンモノハロゲン化物 |
JP2002530414A (ja) | 1998-11-25 | 2002-09-17 | バーゼル、ポリプロピレン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | メタロセンの精製方法 |
EP1254075B1 (en) | 2000-01-21 | 2007-02-21 | U.S. Borax Inc. | Nonaborate compositions and their preparation |
US6376412B1 (en) * | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
US6376410B1 (en) * | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
US6376413B1 (en) * | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
US6380122B1 (en) * | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
US7122498B2 (en) * | 2000-06-30 | 2006-10-17 | Exxonmobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
DE10200422A1 (de) * | 2002-01-08 | 2003-07-17 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von Dialkyl-ansa-Metallocenen |
DE10250025A1 (de) * | 2002-10-25 | 2004-05-06 | Basell Polyolefine Gmbh | Verfahren zur Darstellung teilweise hydrierter rac-ansa-Metallocen-Komplexe |
RU2337104C9 (ru) * | 2002-10-25 | 2009-08-27 | Базелль Полиолефине Гмбх | СПОСОБ ДИАСТЕРЕОСЕЛЕКТИВНОГО СИНТЕЗА РАЦЕМИЧЕСКИХ ДИОРГАНОСИЛИЛБИС(2-МЕТИЛБЕНЗО[е]ИНДЕНИЛ)ЦИРКОНИЕВЫХ СОЕДИНЕНИЙ И РАЦЕМИЧЕСКОЕ СОЕДИНЕНИЕ ПЕРЕХОДНОГО МЕТАЛЛА |
AU2003293887A1 (en) * | 2002-12-16 | 2004-07-09 | Basell Polyolefine Gmbh | Preparation of supported catalyst systems containing reduced amounts of aluminoxanes |
WO2004056481A1 (en) * | 2002-12-20 | 2004-07-08 | Basell Polyolefine Gmbh | Monocyclopentadienyl complexes |
DE10360060A1 (de) * | 2003-12-19 | 2005-07-21 | Basell Polyolefine Gmbh | Verfahren zur meso-selektiven Synthese von anso-Metallocen |
DE102004020524A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
DE102004022861A1 (de) * | 2004-05-06 | 2005-12-01 | Basell Polyolefine Gmbh | Verfahren zur racemo-selectiven Herstellung von ansa-Metallocenen |
DE102006001959A1 (de) | 2006-01-13 | 2007-07-19 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen |
JP5462634B2 (ja) | 2007-03-06 | 2014-04-02 | バーゼル・ポリオレフィン・ゲーエムベーハー | 鉄コンプレックス及び重合プロセスにおけるそれらの使用 |
DE102007017903A1 (de) * | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
US20100093953A1 (en) * | 2007-05-04 | 2010-04-15 | Basell Polyolefine Gmbh | Polyethylene, process and catalyst composition for the preparation thereof |
US8133832B2 (en) * | 2007-07-27 | 2012-03-13 | Basell Polyolefine Gmbh | Catalyst system for polymerization of olefinic monomers, process for preparing polymers, and polymers prepared by the process |
WO2009050037A1 (en) * | 2007-10-19 | 2009-04-23 | Basell Polyolefine Gmbh | Metallocene compounds based on ethanediyl-bridged indene and cyclopentadithiophene ligands |
US8207281B2 (en) * | 2007-12-18 | 2012-06-26 | Basell Polyolefine Gmbh | Process for preparing transition metal compounds for olefins polymerization |
US8247587B2 (en) | 2007-12-19 | 2012-08-21 | Basell Polyolefine Gmbh | Mono-hydroindacenyl complexes |
EP2222722B1 (en) * | 2007-12-21 | 2011-11-30 | Basell Polyolefine GmbH | Phenantroline-comprising complexes |
US8435911B2 (en) * | 2008-10-16 | 2013-05-07 | Basell Polyolefine Gmbh | Hybrid catalyst composition for polymerization of olefins |
EP2536735B1 (en) * | 2010-02-19 | 2018-08-01 | Dow Global Technologies LLC | Metal-ligand complexes and catalysts |
US9376518B2 (en) | 2013-08-28 | 2016-06-28 | Exxonmobil Chemical Patents Inc. | Racemo selective metallation process |
CN105358562A (zh) * | 2013-08-28 | 2016-02-24 | 埃克森美孚化学专利公司 | 外消旋选择性金属化方法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
US4752597A (en) | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
DE3742934A1 (de) | 1987-12-18 | 1989-06-29 | Hoechst Ag | Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung |
US5017714A (en) | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
ES2071888T3 (es) | 1990-11-12 | 1995-07-01 | Hoechst Ag | Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas. |
EP0537686B1 (de) | 1991-10-15 | 2005-01-12 | Basell Polyolefine GmbH | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden |
US5830821A (en) | 1991-11-30 | 1998-11-03 | Targor Gmbh | Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands |
DE59206948D1 (de) | 1991-11-30 | 1996-09-26 | Hoechst Ag | Metallocene mit benzokondensierten Indenylderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
US5245623A (en) | 1991-12-02 | 1993-09-14 | Hughes Aircraft Company | Infrared-to-visible upconversion display system and method operable at room temperature |
TW294669B (es) | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
DE4406109A1 (de) | 1994-02-25 | 1995-08-31 | Witco Gmbh | Verfahren zur Herstellung von verbrückten stereorigiden Metallocenen |
US5597935A (en) | 1994-06-01 | 1997-01-28 | University Of Iowa Research Foundation | Synthesis of ansa-metallocene catalysts |
JP3143347B2 (ja) | 1994-12-30 | 2001-03-07 | ワイケイケイ株式会社 | スナップボタン |
DE19547147A1 (de) | 1995-01-14 | 1996-07-18 | Volkswagen Ag | Vorrichtung zur Lagerung einer Abtriebswelle in einem Getriebegehäuse eines Kraftfahrzeuges |
US5556997A (en) | 1995-04-24 | 1996-09-17 | Albemarle Corporation | Enhanced synthesis of racemic metallocenes |
EP0780396B1 (de) | 1995-12-18 | 2002-10-02 | Basell Polyolefine GmbH | Verfahren zur Abreicherung von Nebenprodukten in Produktgemischen |
BR9808827B1 (pt) | 1997-03-07 | 2009-12-01 | processo para a preparação de indanonas, e, uso de uma indanona. | |
JP2002530414A (ja) * | 1998-11-25 | 2002-09-17 | バーゼル、ポリプロピレン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | メタロセンの精製方法 |
JP5008794B2 (ja) * | 1998-11-25 | 2012-08-22 | バーゼル、ポリプロピレン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | メタロセンモノハロゲン化物 |
-
1999
- 1999-11-18 US US09/856,041 patent/US6620953B1/en not_active Expired - Lifetime
- 1999-11-18 ES ES99960984T patent/ES2192408T3/es not_active Expired - Lifetime
- 1999-11-18 WO PCT/EP1999/008854 patent/WO2000031091A1/de active IP Right Grant
- 1999-11-18 JP JP2000583919A patent/JP2002530416A/ja active Pending
- 1999-11-18 EP EP99960984A patent/EP1133504B1/de not_active Expired - Lifetime
- 1999-11-18 DE DE59904565T patent/DE59904565D1/de not_active Expired - Lifetime
- 1999-11-18 BR BRPI9915708-0A patent/BR9915708B1/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP1133504A1 (de) | 2001-09-19 |
EP1133504B1 (de) | 2003-03-12 |
JP2002530416A (ja) | 2002-09-17 |
US6620953B1 (en) | 2003-09-16 |
BR9915708A (pt) | 2001-08-14 |
BR9915708B1 (pt) | 2010-07-13 |
DE59904565D1 (de) | 2003-04-17 |
WO2000031091A1 (de) | 2000-06-02 |
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