ES2128475T3 - Procedimiento para la obtencion de homo- o copolimeros de varias fases de alqu-1-enos con 2 a 10 atomos de carbono en una zona de reaccion. - Google Patents

Procedimiento para la obtencion de homo- o copolimeros de varias fases de alqu-1-enos con 2 a 10 atomos de carbono en una zona de reaccion.

Info

Publication number
ES2128475T3
ES2128475T3 ES94113846T ES94113846T ES2128475T3 ES 2128475 T3 ES2128475 T3 ES 2128475T3 ES 94113846 T ES94113846 T ES 94113846T ES 94113846 T ES94113846 T ES 94113846T ES 2128475 T3 ES2128475 T3 ES 2128475T3
Authority
ES
Spain
Prior art keywords
group
alqu
enso
homo
copolymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94113846T
Other languages
English (en)
Inventor
Stefan Dr Seelert
Franz Dr Langhauser
Jurgen Dr Kerth
Patrik Dr Muller
David Dr Fischer
Gunther Dr Schweier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2128475T3 publication Critical patent/ES2128475T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63904—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with another component of C08F4/62
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)

Abstract

PROCESO PARA LA ELABORACION DE HOMOPOLIMERIZADOS O COPOLIMERIZADOS DE MULTIPLES FASES DE C2 ACTERIZADO PORQUE, EN PRESENCIA DE DOS SISTEMAS DE CATALIZADOR DIFERENTE SE POLIMERIZAN EN UNA ZONA DE REACCION, CON LO CUAL SE UTILIZA UNO DE LOS SISTEMAS DE CATALIZADOR COMO COMPONENTE ACTIVO CON UN COMPLEJO METALOCENO DE LA FORMULA GENERAL (I) O (II) DONDE M1 ES UN METAL DEL GRUPO IVB, VB O VIB DEL SISTEMA PERIODICO, R1 Y R2 SON IGUALES O DIFERENTES Y SIGNIFICAN UN ATOMO DE HIDROGENO, UN GRUPO C1 ALCOXI, UN GRUPO C6 UN GRUPO C7 IL O UN ATOMO DE HALOGENO, R3 Y R4 SON IGUALES O DIFERENTES Y SIGNIFICAN UN ATOMO DE HIDROGENO, UN ATOMO DE HALOGENO, UN GRUPO C1 C10 RENTES Y TIENEN EL SIGNIFICADO CONOCIDO PARA R3 Y R4, CON LA CONDICION DE QUE R5 Y R6 NO SON HIDROGENO.
ES94113846T 1993-09-10 1994-09-03 Procedimiento para la obtencion de homo- o copolimeros de varias fases de alqu-1-enos con 2 a 10 atomos de carbono en una zona de reaccion. Expired - Lifetime ES2128475T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4330667A DE4330667A1 (de) 1993-09-10 1993-09-10 Verfahren zur Herstellung von mehrphasigen Homo- oder Copolymerisaten von C¶2¶-C¶1¶¶0¶-Alk-1-enen in einer Reaktionszone

Publications (1)

Publication Number Publication Date
ES2128475T3 true ES2128475T3 (es) 1999-05-16

Family

ID=6497334

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94113846T Expired - Lifetime ES2128475T3 (es) 1993-09-10 1994-09-03 Procedimiento para la obtencion de homo- o copolimeros de varias fases de alqu-1-enos con 2 a 10 atomos de carbono en una zona de reaccion.

Country Status (5)

Country Link
US (1) US6197900B1 (es)
EP (1) EP0643084B1 (es)
JP (1) JP3484461B2 (es)
DE (2) DE4330667A1 (es)
ES (1) ES2128475T3 (es)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19516801A1 (de) * 1995-05-08 1996-11-14 Hoechst Ag Organometallverbindung
US5786291A (en) * 1996-02-23 1998-07-28 Exxon Chemical Patents, Inc. Engineered catalyst systems and methods for their production and use
US6417130B1 (en) * 1996-03-25 2002-07-09 Exxonmobil Oil Corporation One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization
DE19623707A1 (de) * 1996-06-14 1997-12-18 Hoechst Ag Übergangsmetallverbindung
US6583227B2 (en) * 1996-09-04 2003-06-24 Exxonmobil Chemical Patents Inc. Propylene polymers for films
WO1998010016A1 (en) 1996-09-04 1998-03-12 Exxon Chemical Patents Inc. Improved propylene polymers for oriented films
DE19812229A1 (de) 1998-03-20 1999-09-23 Basf Ag Polymere des Propens
ES2226362T3 (es) * 1998-05-06 2005-03-16 Huntsman Polymers Corporation Polimerizaciones usando catalizador adyuvante.
US6207606B1 (en) * 1998-05-15 2001-03-27 Univation Technologies, Llc Mixed catalysts and their use in a polymerization process
US7041617B2 (en) 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US7132486B2 (en) * 2000-10-06 2006-11-07 Univation Technologies, Llc Linear low density polyethylenes with high melt strength and high melt index ratio
US6884747B2 (en) * 2000-10-06 2005-04-26 Univation Technologies, Llc Linear low density polyethylenes with high melt strength and high melt index ratio
EP1298148A1 (en) * 2001-09-27 2003-04-02 Atofina Research S.A. Catalyst component comprising a metallocene with two tetrahydroindenyl ligands for producing a polyolefin
CN1275985C (zh) * 2001-11-30 2006-09-20 埃克森美孚化学专利公司 用非单中心/单中心催化剂结合物制备的乙烯/α－烯烃共聚物及其制备方法和用途
WO2003106553A1 (en) * 2002-06-01 2003-12-24 Basell Polyolefine Gmbh Propylene copolymer compositions having a good low-temperature impact toughness and a high transparency
CA2483204A1 (en) * 2002-06-12 2003-12-24 Basell Polyolefine Gmbh Flexible propylene copolymer compositions having a high transparency
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
US8529663B2 (en) * 2007-05-18 2013-09-10 Exxonmobil Research And Engineering Company Process for removing a target gas from a mixture of gases by swing adsorption
CN102234337B (zh) * 2010-04-22 2013-08-14 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分及其催化剂

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4935474A (en) * 1983-06-06 1990-06-19 Exxon Research & Engineering Company Process and catalyst for producing polyethylene having a broad molecular weight distribution
US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US5124418A (en) * 1985-11-15 1992-06-23 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4939217A (en) * 1987-04-03 1990-07-03 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
DE3730022A1 (de) * 1987-09-08 1989-03-16 Basf Ag Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems
KR920006464B1 (ko) * 1988-09-14 1992-08-07 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 올레핀중합용 촉매성분, 올레핀중합용 촉매 및 이 올레핀중합용 촉매를 사용한 올레핀의 중합방법
US5032562A (en) * 1989-12-27 1991-07-16 Mobil Oil Corporation Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
US5145818A (en) * 1989-12-29 1992-09-08 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
US5120696A (en) * 1989-12-29 1992-06-09 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
DE4019453A1 (de) 1990-06-19 1992-01-02 Basf Ag Propylen-ethylen-copolymerisate mit vermindertem weissbruch
DE4004087A1 (de) 1990-02-10 1991-08-14 Basf Ag Copolymerisate des propylens
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CA2060019A1 (en) * 1991-03-04 1992-09-05 Phil Marvin Stricklen Process for producing polyolefins having a bimodal molecular weight distribution
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CA2077744C (en) * 1991-09-30 2003-04-15 Edwar Shoukri Shamshoum Homogeneous-heterogeneous catalyst system for polyolefins

Also Published As

Publication number Publication date
JP3484461B2 (ja) 2004-01-06
DE59407901D1 (de) 1999-04-15
EP0643084A3 (de) 1995-04-26
EP0643084A2 (de) 1995-03-15
JPH07173209A (ja) 1995-07-11
US6197900B1 (en) 2001-03-06
DE4330667A1 (de) 1995-03-16
EP0643084B1 (de) 1999-03-10

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