CA2055216A1 - Process for the preparation of a high molecular weight olefin polymer - Google Patents

Process for the preparation of a high molecular weight olefin polymer

Info

Publication number
CA2055216A1
CA2055216A1 CA002055216A CA2055216A CA2055216A1 CA 2055216 A1 CA2055216 A1 CA 2055216A1 CA 002055216 A CA002055216 A CA 002055216A CA 2055216 A CA2055216 A CA 2055216A CA 2055216 A1 CA2055216 A1 CA 2055216A1
Authority
CA
Canada
Prior art keywords
molecular weight
high molecular
preparation
olefin polymer
weight olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002055216A
Other languages
French (fr)
Other versions
CA2055216C (en
Inventor
Andreas Winter
Martin Antberg
Walter Spaleck
Jurgen Rohrmann
Volker Dolle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Andreas Winter
Martin Antberg
Walter Spaleck
Jurgen Rohrmann
Volker Dolle
Hoechst Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Andreas Winter, Martin Antberg, Walter Spaleck, Jurgen Rohrmann, Volker Dolle, Hoechst Aktiengesellschaft filed Critical Andreas Winter
Publication of CA2055216A1 publication Critical patent/CA2055216A1/en
Application granted granted Critical
Publication of CA2055216C publication Critical patent/CA2055216C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Abstract

Process for the preparation of a high molecular weight olefin polymer A very active catalyst system for olefin polymerization is composed of an aluminoxane and a metallocene of the formula I

(see formula I) wherein preferably M1 is Zr or Hf, R1 and R2 are alkyl or halogen, R3 and R4 are hydrogen, R5 and R6 are alkyl or haloalkyl, -(CR8R9)m-R7-(CR8R9)n- is a single-membered or multimembered chain in which R7 may also be a (sub-stituted) hetero atom, and m+n is zero or 1. The catal-yst system gives polymers having a high molecular weight and high stereospecificity.
CA002055216A 1990-11-12 1991-11-08 Process for the preparation of a high molecular weight olefin polymer Expired - Fee Related CA2055216C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4035886.0 1990-11-12
DE4035886 1990-11-12

Publications (2)

Publication Number Publication Date
CA2055216A1 true CA2055216A1 (en) 1992-05-13
CA2055216C CA2055216C (en) 2004-02-10

Family

ID=6418065

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002055216A Expired - Fee Related CA2055216C (en) 1990-11-12 1991-11-08 Process for the preparation of a high molecular weight olefin polymer

Country Status (7)

Country Link
EP (1) EP0485822B1 (en)
JP (1) JP3362153B2 (en)
AU (1) AU640286B2 (en)
CA (1) CA2055216C (en)
DE (1) DE59107973D1 (en)
ES (1) ES2091273T3 (en)
ZA (1) ZA918925B (en)

Cited By (4)

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US5597881A (en) * 1992-09-11 1997-01-28 Hoechst Aktiengesellschaft Polyolefin molding composition for the production of molding of high rigidity and transparency by injection molding
US5770753A (en) * 1992-06-27 1998-06-23 Targor Gmbh Metallocenes containing aryl-substituted indenyl derivatives as ligands, process for their preparation, and their use as catalysts
US6787618B1 (en) 1995-12-01 2004-09-07 Basell Polypropylen Gmbh Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms
US11447620B2 (en) 2007-05-02 2022-09-20 Dow Global Technologies Llc High-density polyethylene compositions, method of making the same, injection molded articles made therefrom, and method of making such articles

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US5786432A (en) * 1992-06-27 1998-07-28 Targor Gmbh Metallocenes containing aryl-substituted indenyl derivatives as ligands, process for their preparation, and their use as catalysts
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US6242544B1 (en) 1992-06-27 2001-06-05 Targor Gmbh Metallocenes containing aryl-substituted indenyl ligands and their use as catalysts
US6255506B1 (en) 1992-06-27 2001-07-03 Targor Gmbh Metallocenes containing aryl-substituted indenyl derivatives as ligands, process for their preparation, and their use as catalysts
US5597881A (en) * 1992-09-11 1997-01-28 Hoechst Aktiengesellschaft Polyolefin molding composition for the production of molding of high rigidity and transparency by injection molding
US6787618B1 (en) 1995-12-01 2004-09-07 Basell Polypropylen Gmbh Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms
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DE59107973D1 (en) 1996-08-08
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EP0485822A3 (en) 1992-11-25
ES2091273T3 (en) 1996-11-01
EP0485822A2 (en) 1992-05-20
ZA918925B (en) 1992-07-29
AU640286B2 (en) 1993-08-19
JP3362153B2 (en) 2003-01-07
AU8775991A (en) 1992-05-14
JPH04268307A (en) 1992-09-24

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