ES2084743T3 - Procedimiento para producir acido metacrilico. - Google Patents

Procedimiento para producir acido metacrilico.

Info

Publication number
ES2084743T3
ES2084743T3 ES91116301T ES91116301T ES2084743T3 ES 2084743 T3 ES2084743 T3 ES 2084743T3 ES 91116301 T ES91116301 T ES 91116301T ES 91116301 T ES91116301 T ES 91116301T ES 2084743 T3 ES2084743 T3 ES 2084743T3
Authority
ES
Spain
Prior art keywords
acid
alpha
stage
prustic
iii
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91116301T
Other languages
English (en)
Inventor
Yoshikazu Shima
Takafumi Abe
Hirofumi Higuchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Gas Chemical Co Inc
Original Assignee
Mitsubishi Gas Chemical Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Gas Chemical Co Inc filed Critical Mitsubishi Gas Chemical Co Inc
Application granted granted Critical
Publication of ES2084743T3 publication Critical patent/ES2084743T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/18—Preparation of carboxylic acid esters by conversion of a group containing nitrogen into an ester group
    • C07C67/20—Preparation of carboxylic acid esters by conversion of a group containing nitrogen into an ester group from amides or lactams
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

SE PRESENTA AQUI UN PROCESO PARA PRODUCIR ACIDO METACRILICO QUE COMPRENDE: (I) UNA ETAPA DE PRODUCCION DE ACETONACIANOHIDRINA DE ACIDO PRUSICO Y ACETONA; (II) UNA ETAPA DE HIDRATACION DE LA ACETONACIANOHIDRINA OBTENIDA EN LA ETAPA PRECEDENTE (I) PARA FORMAR AMIDA ACIDO (ALFA)-HIDROXISOBUTIRICO; (III) UNA ETAPA DE REACCION DE LA AMIDA ACIDO (ALFA)-HIDROXISOBUTIRICO OBTENIDA EN EL PASO PRECEDENTE (II) CON UN FORMADO DE METILO O METANOL Y MONOXIDO DE CARBONO PARA FORMAR METIL-(ALFA)-HIDROXISOBUTIRATO Y FORMANIDA; (IV) UNA ETAPA DE HIDROLIZACION DE METIL (ALFA)-HIDROXISOBUTIRATO OBTENIDO EN LA ETAPA PRECEDENTE (III) PARA FORMAR UN ACIDO (ALFA)-HIDROXISOBUTIRICO; (V) UN PASO DE DESHIDRATACION DEL ACIDO (ALFA)-HIDROXISOBUTIRICO OBTENIDO EN EL PASO ANTERIOR (IV) PARA FORMAR ACIDO METACRILICO; Y (VI) UN PASO DE DESHIDRATACION DE FORMANIDA SEPARADA DE LOS PRODUCTOS OBTENIDOS EN EL PASO (III) ANTERIORMENTE MENCIONADO PARA FORMAR ACIDO PRUSICO Y RECICLAR EL ACIDO PRUSICO PARA REUTILIZARLO COMO MATERIAL DE COMIENZO. EL PROCESO ES CAPAZ DE PRODUCIR ACIDO METACRILICO DE MATERIALES DE COMIENZO DE FACIL DISPONIBILIDAD CON UN ALTO RENDIMIENTO Y SELECTIVIDAD SIN FORMAR SUB-PRODUCTOS INDESEABLES TALES COMO SULFATO DE AMONIACO, ETC.
ES91116301T 1990-11-28 1991-09-25 Procedimiento para producir acido metacrilico. Expired - Lifetime ES2084743T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2322464A JP2959121B2 (ja) 1990-11-28 1990-11-28 メタクリル酸の製造法

Publications (1)

Publication Number Publication Date
ES2084743T3 true ES2084743T3 (es) 1996-05-16

Family

ID=18143944

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91116301T Expired - Lifetime ES2084743T3 (es) 1990-11-28 1991-09-25 Procedimiento para producir acido metacrilico.

Country Status (7)

Country Link
US (1) US5225594A (es)
EP (1) EP0487853B1 (es)
JP (1) JP2959121B2 (es)
KR (1) KR970008591B1 (es)
DE (1) DE69115862T2 (es)
ES (1) ES2084743T3 (es)
TW (1) TW307752B (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5824818A (en) * 1994-02-21 1998-10-20 Mitsubishi Gas Chemical Company, Inc. Process for preparing lactate
JP3191842B2 (ja) * 1994-02-21 2001-07-23 三菱瓦斯化学株式会社 乳酸エステルの製造法
US6582943B1 (en) 2002-02-05 2003-06-24 E. I. Du Pont De Nemours And Company Method for producing 2-hydroxyisobutyric acid and methacrylic acid from acetone cyanohydrin
JP4032033B2 (ja) * 2003-06-30 2008-01-16 ローム アンド ハース カンパニー 高純度メタクリル酸の製造法
DE102004006826A1 (de) * 2004-02-11 2005-08-25 Röhm GmbH & Co. KG Verfahren zur Herstellung von alpha-Hydroxy-carbonsäuren und deren Ester
DE102005023975A1 (de) * 2005-05-20 2006-11-23 Röhm Gmbh Verfahren zur Herstellung von Alkyl(meth)acrylaten
DE102006017760A1 (de) * 2006-03-24 2007-09-27 Ufz-Umweltforschungszentrum Leipzig-Halle Gmbh Verfahren zur enzymatischen Herstellung von 2-Hydroxy-2-methylcarbonsäuren
CN101448949B (zh) * 2006-03-24 2013-09-18 赢创罗姆有限责任公司 酶促制备2-羟基-2-甲基羧酸的方法
DE102006055427A1 (de) * 2006-11-22 2008-05-29 Evonik Röhm Gmbh Verfahren zur Herstellung von Tetramethylglycolid
DE102008002715A1 (de) 2008-06-27 2009-12-31 Evonik Röhm Gmbh 2-Hydroxyisobuttersäure produzierende rekombinante Zelle
DE102008040193A1 (de) 2008-07-04 2010-01-07 Evonik Röhm Gmbh Verfahren zur Herstellung freier Carbonsäuren
DE102008040415A1 (de) 2008-07-15 2010-01-21 Evonik Röhm Gmbh Thermisches Salzspalten von Ammoniumcarboxylaten
DE102009029651A1 (de) 2009-09-22 2011-03-24 Evonik Röhm Gmbh Verfahren zur Herstellung freier Carbonsäuren
TWI373592B (en) 2009-09-30 2012-10-01 Everlight Electronics Co Ltd Light source module
DE102011076642A1 (de) 2011-05-27 2012-11-29 Evonik Röhm Gmbh Verfahren zur Herstellung von Methacrylsäure
DE102013209821A1 (de) 2013-05-27 2014-11-27 Evonik Industries Ag Verfahren zur Dehydratisierung von alpha-substituierten Carbonsäuren
DE102014204621A1 (de) 2014-03-13 2015-09-17 Evonik Industries Ag Verfahren zur Rektifikation von hydroxycarbonsäurehaltigen Gemischen
DE102014209650A1 (de) 2014-05-21 2015-11-26 Evonik Industries Ag Verfahren zur Durchführung von Eliminierungsreaktionen an alpha-beta-substituierten Carbonsäuren unter homogener Katalyse und Katalysatorrezyklierung
DE102014213016A1 (de) 2014-07-04 2016-01-07 Evonik Röhm Gmbh Dehydratisierung von alpha-substituierten Carbonsäuren in Gegenwart von Wasser bei hohen Drücken
EP3144291A1 (de) 2015-09-16 2017-03-22 Evonik Röhm GmbH Synthese von methacrylsäure aus auf methacrolein basierenden alkylmethacrylat
DE102016210285A1 (de) 2016-06-10 2017-12-14 Evonik Röhm Gmbh Verfahren zur Herstellung von Methacrylaten und Methacrylsäure
WO2022194590A1 (de) 2021-03-15 2022-09-22 Röhm Gmbh Neues verfahren zur kontinuierlichen herstellung von methacrylsäure durch katalytische hydrolyse von methylmethacrylat
WO2023117754A1 (de) 2021-12-23 2023-06-29 Röhm Gmbh Verfahren zur herstellung von alkylmethacrylaten mit verbesserter ausbeute und verminderten emissionen flüchtiger organischer verbindungen
WO2023169810A1 (de) 2022-03-11 2023-09-14 Röhm Gmbh Verfahren zur herstellung von alpha-hydroxyisobuttersäuremethylester und dessen anwendung in der elektronik-industrie

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1215702A (fr) * 1957-10-29 1960-04-20 Escambia Chem Corp Perfectionnements à la production de l'acide méthacrylique et de ses esters
US4351955A (en) * 1980-11-05 1982-09-28 Shell Oil Company Alpha-hydroxyisobutyric acid process
JP2893730B2 (ja) * 1989-07-04 1999-05-24 三菱瓦斯化学株式会社 メタクリル酸メチルの製造法

Also Published As

Publication number Publication date
KR920009768A (ko) 1992-06-25
JP2959121B2 (ja) 1999-10-06
US5225594A (en) 1993-07-06
JPH04198152A (ja) 1992-07-17
EP0487853A3 (es) 1994-03-23
EP0487853B1 (en) 1995-12-27
KR970008591B1 (ko) 1997-05-27
EP0487853A2 (en) 1992-06-03
DE69115862T2 (de) 1996-05-30
TW307752B (es) 1997-06-11
DE69115862D1 (de) 1996-02-08

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