ES2080888T3 - Preparacion de particulas polimeras. - Google Patents
Preparacion de particulas polimeras.Info
- Publication number
- ES2080888T3 ES2080888T3 ES91301563T ES91301563T ES2080888T3 ES 2080888 T3 ES2080888 T3 ES 2080888T3 ES 91301563 T ES91301563 T ES 91301563T ES 91301563 T ES91301563 T ES 91301563T ES 2080888 T3 ES2080888 T3 ES 2080888T3
- Authority
- ES
- Spain
- Prior art keywords
- nero
- copolymer
- cover
- weight
- polymer particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B1/00—Nanostructures formed by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/902—Core-shell
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2998—Coated including synthetic resin or polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Graft Or Block Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
UN PROCESO PARA LA FABRICACION DE PARTICULAS DE POLIMEROS NUCLEO/CUBIERTA CONSISTE EN FORMAR UNA PARTICULA NUCLEO QUE CONTIENE UNA FUNCIONALIDAD ACIDA, UNA PRIMERA CUBIERTA ALREDEDOR DE DICHO NUCLEO DE UN COPOLIMERO DE UN MONOMERO AROMATICO NO SATURADO MONOETILENICAMENTE NO IONICO Y UN MONOMERO POLAR COPOLIMERIZABLE EN UNA CANTIDAD DE POR LO MENOS UN 15% POR PESO DEL COPOLIMERO Y QUE TIENE UNA SOLUBILIDAD EN AGUA A 20 C DE POR LO MENOS UN 1% POR PESO Y UNA SEGUNDA CUBIERTA ALREDEDOR DE DICHA PRIMERA CUBIERTA DE UN POLIMERO O COPOLIMERO DE UN MONOMERO NO IONICO QUE TIENE UNA SOLUBILIDAD EN AGUA A 20 C DE MENOS DEL 1% POR PESO Y AGRANDAR LA PARTICULA EN UN ALCALI NO VOLATIL PARA GENERAR UNA O MAS VESICULAS. PREFERIBLEMENTE CADA CUBIERTA CONTIENE UN POLIMERO O COPOLIMERO DE ESTIRENO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB909007199A GB9007199D0 (en) | 1990-03-30 | 1990-03-30 | Preparation of polymeric particles |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2080888T3 true ES2080888T3 (es) | 1996-02-16 |
Family
ID=10673588
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES91301563T Expired - Lifetime ES2080888T3 (es) | 1990-03-30 | 1991-02-26 | Preparacion de particulas polimeras. |
Country Status (12)
Country | Link |
---|---|
US (1) | US5229209A (es) |
EP (1) | EP0451940B1 (es) |
JP (1) | JP3084080B2 (es) |
KR (1) | KR100194121B1 (es) |
AU (1) | AU636456B2 (es) |
CA (1) | CA2038258A1 (es) |
DE (1) | DE69115546T2 (es) |
DK (1) | DK0451940T3 (es) |
ES (1) | ES2080888T3 (es) |
FI (1) | FI99231C (es) |
GB (2) | GB9007199D0 (es) |
ZA (1) | ZA911604B (es) |
Families Citing this family (58)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2790381B2 (ja) * | 1990-02-03 | 1998-08-27 | 三井化学株式会社 | 有芯多層構造エマルション粒子 |
DE69130936T3 (de) † | 1990-07-16 | 2007-01-11 | Mitsui Chemicals, Inc. | Multischalenteilchen in Emulsion und Verfahren zu ihrer Herstellung |
US5798152A (en) * | 1990-07-24 | 1998-08-25 | Novon International | Biodegradable composite polymeric articles comprising polyvinyl alcohol |
SG84480A1 (en) * | 1992-04-10 | 2001-11-20 | Rohm & Haas | Polymeric particles |
DE69413777T3 (de) * | 1993-04-27 | 2002-04-18 | Asahi Chemical Ind | Schaumstoffperlen aus kautschukmodifiziertem styrolharz |
DK0741005T3 (da) * | 1995-05-05 | 2000-12-18 | Minnesota Mining & Mfg | Kompositfilm og anvendelse deraf |
WO1997012965A1 (en) * | 1995-10-04 | 1997-04-10 | Monsanto Company | Porous polymeric biosupports and their use in the biotreatment of aqueous waste streams |
US6045700A (en) * | 1996-07-29 | 2000-04-04 | Solutia Inc. | Retrievable organic carbon scavengers for cleaning of contaminated surface water sediments |
US6187862B1 (en) * | 1998-05-01 | 2001-02-13 | Bayer Corporation | Weatherable resinous composition having improved opacity and impact strength |
FI991051A (fi) * | 1999-05-07 | 2000-11-08 | Neste Chemicals Oy | Huokosia sisältävien polymeerihiukkasten valmistamismenetelmä |
AUPQ164299A0 (en) * | 1999-07-14 | 1999-08-05 | Orica Australia Pty Ltd | Aqueous polymer dispersion |
JP4650595B2 (ja) * | 2000-09-28 | 2011-03-16 | Jsr株式会社 | 中空ポリマー粒子の製造方法 |
US6673451B2 (en) * | 2000-10-12 | 2004-01-06 | Rohn And Haas Company | Process for forming an aqueous polymeric dispersion |
AU2002317533A1 (en) * | 2002-01-07 | 2003-07-24 | Rohm And Haas Company | Process for preparing emulsion polymers and polymers formed therefrom |
WO2003106148A1 (de) * | 2002-06-18 | 2003-12-24 | Daimlerchrysler Ag | Partikel und verfahren für die herstellung eines dreidimensionalen gegenstandes |
DE10260065A1 (de) * | 2002-12-19 | 2004-07-01 | Röhm GmbH & Co. KG | Kern-Schale-Teilchen zur Schlagzähmodifizierung von Poly(meth)acrylat-Formmassen |
DE10321083A1 (de) * | 2003-05-09 | 2004-11-25 | Basf Ag | Polymerdispersion mit Farbeffekt |
EP2272923A1 (en) * | 2004-09-02 | 2011-01-12 | Rohm and Haas Company | Method of using hollow sphere polymers |
CN101330969B (zh) * | 2005-10-14 | 2011-06-29 | 维乌纳米股份有限公司 | 复合纳米颗粒、纳米颗粒和制备它们的方法 |
US7589158B2 (en) * | 2005-11-30 | 2009-09-15 | Columbia Insurance Company | Polymers with improved shelf stability |
MX2009005690A (es) * | 2006-11-30 | 2009-06-08 | Dow Global Technologies Inc | Proceso de calor que trata particulas polimericas estructuradas. |
EP1947151B1 (en) | 2007-01-19 | 2010-12-29 | Seiko Epson Corporation | Oil-based ink composition for ink-jet recording |
CN100562358C (zh) * | 2007-05-17 | 2009-11-25 | 浙江大学 | 以水凝胶微球为模板制备中空微球的方法 |
US10226919B2 (en) | 2007-07-18 | 2019-03-12 | Voxeljet Ag | Articles and structures prepared by three-dimensional printing method |
US9255198B2 (en) * | 2009-12-01 | 2016-02-09 | The University Of Sydney | Water swellable polymer materials comprising particulate core and water swellable R.A.F.T polymer shell |
DE102010013732A1 (de) | 2010-03-31 | 2011-10-06 | Voxeljet Technology Gmbh | Vorrichtung zum Herstellen dreidimensionaler Modelle |
DE102010014969A1 (de) | 2010-04-14 | 2011-10-20 | Voxeljet Technology Gmbh | Vorrichtung zum Herstellen dreidimensionaler Modelle |
DE102010015451A1 (de) | 2010-04-17 | 2011-10-20 | Voxeljet Technology Gmbh | Verfahren und Vorrichtung zum Herstellen dreidimensionaler Objekte |
DE102010056346A1 (de) | 2010-12-29 | 2012-07-05 | Technische Universität München | Verfahren zum schichtweisen Aufbau von Modellen |
DE102011007957A1 (de) | 2011-01-05 | 2012-07-05 | Voxeljet Technology Gmbh | Vorrichtung und Verfahren zum Aufbauen eines Schichtenkörpers mit wenigstens einem das Baufeld begrenzenden und hinsichtlich seiner Lage einstellbaren Körper |
DK2511312T3 (da) | 2011-03-21 | 2013-08-05 | Organik Kimya Sanayi Ve Tic A S | Fremgangsmåde til fremstilling af en emulsion indeholdende kerne-hylster-skal-polymerpartikler |
DE102012004213A1 (de) | 2012-03-06 | 2013-09-12 | Voxeljet Technology Gmbh | Verfahren und Vorrichtung zum Herstellen dreidimensionaler Modelle |
DE102012010272A1 (de) | 2012-05-25 | 2013-11-28 | Voxeljet Technology Gmbh | Verfahren zum Herstellen dreidimensionaler Modelle mit speziellen Bauplattformen und Antriebssystemen |
DE102012012363A1 (de) | 2012-06-22 | 2013-12-24 | Voxeljet Technology Gmbh | Vorrichtung zum Aufbauen eines Schichtenkörpers mit entlang des Austragbehälters bewegbarem Vorrats- oder Befüllbehälter |
DE102012020000A1 (de) | 2012-10-12 | 2014-04-17 | Voxeljet Ag | 3D-Mehrstufenverfahren |
DE102013004940A1 (de) | 2012-10-15 | 2014-04-17 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von dreidimensionalen Modellen mit temperiertem Druckkopf |
DE102012022859A1 (de) | 2012-11-25 | 2014-05-28 | Voxeljet Ag | Aufbau eines 3D-Druckgerätes zur Herstellung von Bauteilen |
DE102013003303A1 (de) | 2013-02-28 | 2014-08-28 | FluidSolids AG | Verfahren zum Herstellen eines Formteils mit einer wasserlöslichen Gussform sowie Materialsystem zu deren Herstellung |
DE102013018182A1 (de) | 2013-10-30 | 2015-04-30 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von dreidimensionalen Modellen mit Bindersystem |
DE102013018031A1 (de) | 2013-12-02 | 2015-06-03 | Voxeljet Ag | Wechselbehälter mit verfahrbarer Seitenwand |
DE102013020491A1 (de) | 2013-12-11 | 2015-06-11 | Voxeljet Ag | 3D-Infiltrationsverfahren |
EP2886307A1 (de) | 2013-12-20 | 2015-06-24 | Voxeljet AG | Vorrichtung, Spezialpapier und Verfahren zum Herstellen von Formteilen |
DE102014004692A1 (de) | 2014-03-31 | 2015-10-15 | Voxeljet Ag | Verfahren und Vorrichtung für den 3D-Druck mit klimatisierter Verfahrensführung |
EP2930266A1 (en) | 2014-04-09 | 2015-10-14 | Coatex | Paper coating composition comprising void latex particles and calcium carbonate |
DE102014007584A1 (de) | 2014-05-26 | 2015-11-26 | Voxeljet Ag | 3D-Umkehrdruckverfahren und Vorrichtung |
US10946556B2 (en) | 2014-08-02 | 2021-03-16 | Voxeljet Ag | Method and casting mold, in particular for use in cold casting methods |
US10351689B2 (en) | 2014-08-22 | 2019-07-16 | Arkema Inc. | Voided latex particles |
MX2017002256A (es) | 2014-08-22 | 2017-05-22 | Arkema Inc | Particulas de latex vacias. |
DE102015006533A1 (de) | 2014-12-22 | 2016-06-23 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen mit Schichtaufbautechnik |
DE102015006363A1 (de) | 2015-05-20 | 2016-12-15 | Voxeljet Ag | Phenolharzverfahren |
WO2017023830A1 (en) | 2015-08-04 | 2017-02-09 | Arkema Inc. | Voided latex particles containing functionalized outer shells |
DE102015011503A1 (de) | 2015-09-09 | 2017-03-09 | Voxeljet Ag | Verfahren zum Auftragen von Fluiden |
DE102015011790A1 (de) | 2015-09-16 | 2017-03-16 | Voxeljet Ag | Vorrichtung und Verfahren zum Herstellen dreidimensionaler Formteile |
DE102015015353A1 (de) | 2015-12-01 | 2017-06-01 | Voxeljet Ag | Verfahren und Vorrichtung zur Herstellung von dreidimensionalen Bauteilen mittels Überschussmengensensor |
DE102016002777A1 (de) | 2016-03-09 | 2017-09-14 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen mit Baufeldwerkzeugen |
EP3526002B1 (en) | 2016-10-11 | 2023-06-07 | Arkema Inc. | Use of hollow polymer particles for thermal insulation |
EP3587467A1 (de) * | 2018-06-25 | 2020-01-01 | Rudolf GmbH | Funktionelle mehrwandige kern-schale-partikel |
JP2020158638A (ja) * | 2019-03-27 | 2020-10-01 | 日本ゼオン株式会社 | 中空重合体粒子の製造方法 |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3359130A (en) * | 1963-11-12 | 1967-12-19 | Papex Corp | Double shelled foamable plastic particles |
US3379799A (en) * | 1965-10-20 | 1968-04-23 | Papex Corp | Method of making foamed plastics |
US3431319A (en) * | 1967-02-17 | 1969-03-04 | Koppers Co Inc | Foamed polystyrene articles coated with an unsaturated polyester resin having monovinyl ether monomer |
US4044176A (en) * | 1973-07-12 | 1977-08-23 | Pratt & Lambert, Inc. | Graphic arts and graphic media |
US4181769A (en) * | 1976-06-17 | 1980-01-01 | Rohm And Haas Company | Heteropolymer acrylic latices and textiles treated therewith |
US4107120A (en) * | 1976-06-17 | 1978-08-15 | Rohm And Haas Company | Heteropolymer acrylic latices and textiles treated therewith |
US4308912A (en) * | 1979-03-28 | 1982-01-05 | Knecht Bernath L | Heat transfer system |
CA1180474A (en) * | 1979-06-26 | 1985-01-02 | Alexander Kowalski | Sequential heteropolymer dispersion and a particulate material obtainable therefrom useful in coating compositions as a thickening and/or opacifying agent |
DE2951045C2 (de) * | 1979-12-19 | 1983-12-22 | Röhm GmbH, 6100 Darmstadt | Herstellung von schlagzähen Harzen |
US4325856A (en) * | 1980-01-02 | 1982-04-20 | The Dow Chemical Company | Sequential emulsion polymerization process |
US4468498A (en) * | 1980-06-12 | 1984-08-28 | Rohm And Haas Company | Sequential heteropolymer dispersion and a particulate materal obtainable therefrom, useful in coating compositions as a thickening and/or opacifying agent |
US4427836A (en) * | 1980-06-12 | 1984-01-24 | Rohm And Haas Company | Sequential heteropolymer dispersion and a particulate material obtainable therefrom, useful in coating compositions as a thickening and/or opacifying agent |
JPS6017406B2 (ja) * | 1981-06-03 | 1985-05-02 | 旭化成株式会社 | 多層構造アクリル系樹脂成形材料の製造方法 |
US4419496A (en) * | 1982-02-22 | 1983-12-06 | The Dow Chemical Company | Particle agglomeration in rubber latices |
US4497917A (en) * | 1982-09-29 | 1985-02-05 | Eastman Kodak Company | Latex composition comprising core-shell polymer particles |
US4469825A (en) * | 1983-03-09 | 1984-09-04 | Rohm And Haas Company | Sequential heteropolymer dispersion and a particulate material obtainable therefrom, useful in coating compositions as an opacifying agent |
US4916171A (en) * | 1984-07-25 | 1990-04-10 | Rohm And Haas Company | Polymers comprising alkali-insoluble core/alkali-soluble shell and copositions thereof |
US4594363A (en) * | 1985-01-11 | 1986-06-10 | Rohm And Haas Company | Production of core-sheath polymer particles containing voids, resulting product and use |
US4677003A (en) * | 1985-04-30 | 1987-06-30 | Rohm And Haas Company | Microsuspension process for preparing solvent core sequential polymer dispersion |
US4717750A (en) * | 1985-07-29 | 1988-01-05 | The Dow Chemical Company | Structure reinforced latex particles |
US4791151A (en) * | 1986-07-14 | 1988-12-13 | Rohm And Haas Company | Multilobals |
GB8718036D0 (en) * | 1987-07-30 | 1987-09-03 | Tioxide Group Plc | Polymeric particles |
GB8729399D0 (en) * | 1987-12-17 | 1988-02-03 | Tioxide Group Plc | Polymeric particles & their preparation |
US4880842A (en) * | 1988-05-20 | 1989-11-14 | Rohm & Haas Company | Multi-stage opacifying polymer particles containing non-polymeric acid absorbed therein |
US5026782A (en) * | 1988-09-23 | 1991-06-25 | Union Oil Company Of California | Polymeric opaque particles and process for making same |
US5053441A (en) * | 1988-09-23 | 1991-10-01 | Union Oil Company Of California | Core/shell particles and process for making same |
-
1990
- 1990-03-30 GB GB909007199A patent/GB9007199D0/en active Pending
-
1991
- 1991-02-26 DK DK91301563.2T patent/DK0451940T3/da active
- 1991-02-26 DE DE69115546T patent/DE69115546T2/de not_active Expired - Fee Related
- 1991-02-26 ES ES91301563T patent/ES2080888T3/es not_active Expired - Lifetime
- 1991-02-26 EP EP91301563A patent/EP0451940B1/en not_active Expired - Lifetime
- 1991-02-26 GB GB9104013A patent/GB2242437B/en not_active Expired - Fee Related
- 1991-03-05 AU AU72613/91A patent/AU636456B2/en not_active Ceased
- 1991-03-05 ZA ZA911604A patent/ZA911604B/xx unknown
- 1991-03-14 CA CA002038258A patent/CA2038258A1/en not_active Abandoned
- 1991-03-21 US US07/672,932 patent/US5229209A/en not_active Expired - Fee Related
- 1991-03-28 FI FI911544A patent/FI99231C/fi active
- 1991-03-28 JP JP03064690A patent/JP3084080B2/ja not_active Expired - Fee Related
- 1991-03-29 KR KR1019910004942A patent/KR100194121B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
AU636456B2 (en) | 1993-04-29 |
KR100194121B1 (ko) | 1999-06-15 |
GB9007199D0 (en) | 1990-05-30 |
FI99231C (fi) | 1997-11-10 |
EP0451940A3 (en) | 1992-05-27 |
GB9104013D0 (en) | 1991-04-10 |
EP0451940B1 (en) | 1995-12-20 |
AU7261391A (en) | 1991-10-03 |
EP0451940A2 (en) | 1991-10-16 |
CA2038258A1 (en) | 1991-10-01 |
US5229209A (en) | 1993-07-20 |
FI911544A0 (fi) | 1991-03-28 |
JPH04224803A (ja) | 1992-08-14 |
GB2242437B (en) | 1994-01-12 |
KR910016824A (ko) | 1991-11-05 |
DE69115546T2 (de) | 1996-05-02 |
DE69115546D1 (de) | 1996-02-01 |
JP3084080B2 (ja) | 2000-09-04 |
ZA911604B (en) | 1991-12-24 |
FI99231B (fi) | 1997-07-31 |
GB2242437A (en) | 1991-10-02 |
FI911544A (fi) | 1991-10-01 |
DK0451940T3 (da) | 1996-01-29 |
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