ES2064580T3 - Un componente de catalizador solido para la polimerizacion de olefinas y un catalizador de polimerizacion de olefinas. - Google Patents
Un componente de catalizador solido para la polimerizacion de olefinas y un catalizador de polimerizacion de olefinas.Info
- Publication number
- ES2064580T3 ES2064580T3 ES90117968T ES90117968T ES2064580T3 ES 2064580 T3 ES2064580 T3 ES 2064580T3 ES 90117968 T ES90117968 T ES 90117968T ES 90117968 T ES90117968 T ES 90117968T ES 2064580 T3 ES2064580 T3 ES 2064580T3
- Authority
- ES
- Spain
- Prior art keywords
- solid
- catalyst
- olefin polymerization
- specific
- activity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 3
- 239000011949 solid catalyst Substances 0.000 title abstract 3
- 239000002685 polymerization catalyst Substances 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title 1
- 239000000126 substance Substances 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 239000000725 suspension Substances 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 150000004996 alkyl benzenes Chemical class 0.000 abstract 1
- 239000002956 ash Substances 0.000 abstract 1
- XDKQUSKHRIUJEO-UHFFFAOYSA-N magnesium;ethanolate Chemical compound [Mg+2].CC[O-].CC[O-] XDKQUSKHRIUJEO-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000037048 polymerization activity Effects 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 239000011343 solid material Substances 0.000 abstract 1
- 230000000707 stereoselective effect Effects 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
UN COMPONENTE CATALIZADOR SOLIDO, PREPARADO EN CONDICIONES ESPECIFICAS MEDIANTE LA REACCION CON UN PRODUCTO REACTIVO OBTENIDO POR SUSPENSION DE DIETHOXILMAGNESIO EN UN ALKILBENZENO, Y PONIENDO LA SUSPENSION EN CONTACTO CON TETRACLOXIDO DE TITANIO DICLORIDO PHTHALOYL A 80-125 C Y LAVANDO EL MATERIAL SOLIDO RESULTANTE CON UN ALKYLBENZENO, SIENDO REACTIVADO EL MATERIAL SOLIDO EN PRESENCIA DE UN ALKYLBENZENO CON TETRACLORIDO DE TITANIO PARA FORMAR UNA SUSTANCIA SOLIDA, Y, REPITIENDO EL PROCESO SEGUN LAS SIGUIENTES FASES: (1), (2), (3), Y (4) DOS O CUATRO VECES. (1) LAVADO DE LAS SUBSTANCIAS CON UN ALKILBENZENO, (2) SUSPENSION DE LAS SUBSTANCIAS SOLIDAS EN UN ALKILBENZENO, (3) UNIFICANDO LA SOLUCION RESULTANTE CON TETRACLORIDO DE TITANIO, Y (4) ELIMINANDO LA SUBSTANCIA LIQUIDA DE LA REACCION LO MAS RAPIDO POSIBLE, ASI COMO UN CATALIZADOR DE OLEFINA QUE INCLUYE: (A) EL COMPONENTE SOLIDO CATALIZADOR, ANTERIORMENTE MENCIONADO, (B) UN COMPUESTO ESPECIFICO DE SILICONA, Y (C) UN COMPUESTO ESPECIFICO DE ORGANOALUMINIO. ESTE CATALIZADOR MUESTRA EN COMPARACION CON EL CATALIZADOR EXISTENTE DE POLIMERIZACION DE OLEFINAS, UN PROGRAMA CATALIZADOR DE ESMERADO ALTO NIVEL DE ACTIVIDAD DE POLIMERIZACION, UN PROGRAMA ESTEREOESPECIFICO DE LARGA DURACION DE LA ACTIVIDAD QUE FACILITA LA PRODUCCION DE POLIMEROS DE OLEFINA ESTEREOREGULARES EN UN ALTO CAUDAL DE PRODUCCION Y CON UN CONTENIDO INFIMO DE CENIZAS RESIDUALES.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2110214A JP2958923B2 (ja) | 1990-04-27 | 1990-04-27 | オレフィン類重合用固体触媒成分及び触媒 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2064580T3 true ES2064580T3 (es) | 1995-02-01 |
Family
ID=14529961
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES90117968T Expired - Lifetime ES2064580T3 (es) | 1990-04-27 | 1990-09-18 | Un componente de catalizador solido para la polimerizacion de olefinas y un catalizador de polimerizacion de olefinas. |
Country Status (7)
Country | Link |
---|---|
US (1) | US5130284A (es) |
EP (1) | EP0459009B1 (es) |
JP (1) | JP2958923B2 (es) |
DE (1) | DE69014863T2 (es) |
ES (1) | ES2064580T3 (es) |
FI (1) | FI99247C (es) |
NO (1) | NO175060B (es) |
Families Citing this family (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5308818A (en) * | 1992-06-08 | 1994-05-03 | Fina Technology, Inc. | Catalyst system for the polymerization of olefins |
WO1994007926A1 (en) * | 1992-09-25 | 1994-04-14 | Shell Oil Company | Process for polymerizing alpha-olefin |
US5414063A (en) * | 1993-03-30 | 1995-05-09 | Huntsman Polypropylene Corporation | Process for the production of polypropylene |
ES2117333T3 (es) * | 1994-08-02 | 1998-08-01 | Fina Research | Procedimiento mejorado para la produccion de polietileno de amplio peso molecular. |
US5521263A (en) * | 1994-10-18 | 1996-05-28 | Eastman Chemical Company | Catalysts and synthesis of high molecular weight amorphous polyolefins and recovery thereof |
JP3595864B2 (ja) * | 1995-06-07 | 2004-12-02 | 住友化学工業株式会社 | α−オレフィン重合用触媒ならびにα−オレフィン重合体の製造方法 |
US6187883B1 (en) * | 1996-08-23 | 2001-02-13 | Sumitomo Chemical Company, Limited | Solid catalyst component for α-olefin polymerization, catalyst for α-olefin polymerization, and process for producing α-olefin polymer |
JP3930082B2 (ja) | 1996-11-15 | 2007-06-13 | 松下冷機株式会社 | ダンパー装置 |
US6100351A (en) * | 1997-01-07 | 2000-08-08 | Huntsman Polymers Corporation | Olefin polymerization process and products thereof |
US5948720A (en) * | 1997-01-07 | 1999-09-07 | Huntsman Polymers Corporation | Catalyst for the production of flexible polyolefin compositions, methods for making and using same, and products thereof |
US6080818A (en) * | 1997-03-24 | 2000-06-27 | Huntsman Polymers Corporation | Polyolefin blends used for non-woven applications |
EA004063B1 (ru) * | 1997-12-23 | 2003-12-25 | Бореалис Текнолоджи Ой | Каталитический компонент, содержащий магний, титан, галоген и донор электронов, способ получения этого компонента и его применение |
EP1042331B1 (en) | 1997-12-23 | 2003-03-26 | Borealis Technology Oy | Soluble magnesium dihalide complex, preparation and use |
JP3885336B2 (ja) | 1998-02-19 | 2007-02-21 | 住友化学株式会社 | α−オレフィン重合用触媒ならびにα−オレフィン重合体の製造方法 |
KR100334165B1 (ko) | 1998-04-17 | 2002-11-27 | 삼성종합화학주식회사 | 에틸렌 중합 및 에틸렌/α-올레핀 공중합용 담지촉매의 제조방법 |
KR100524293B1 (ko) | 1999-05-27 | 2005-10-26 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
KR100546499B1 (ko) * | 1999-05-27 | 2006-01-26 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
US6800580B1 (en) | 1999-10-23 | 2004-10-05 | Samsung General Chemicals Co., Ltd. | Method for producing an improved catalyst for homo-and co-polymerization of olefin |
KR100361224B1 (ko) | 1999-12-01 | 2002-11-29 | 삼성종합화학주식회사 | 에틸렌 중합 및 공중합용 촉매의 제조방법 |
KR100351386B1 (ko) | 2000-04-24 | 2002-09-05 | 삼성종합화학주식회사 | 초고분자량 폴리에틸렌 제조용 촉매 및 이를 이용한초고분자량 폴리에틸렌 제조방법 |
KR100353960B1 (ko) | 2000-05-31 | 2002-09-27 | 삼성종합화학주식회사 | 에틸렌 중합체 및 공중합체의 제조방법 |
KR100359932B1 (ko) | 2000-06-15 | 2002-11-07 | 삼성종합화학주식회사 | 에틸렌 중합 및 공중합용 촉매 |
KR100387734B1 (ko) * | 2000-06-17 | 2003-06-18 | 삼성종합화학주식회사 | 올레핀 중합용 촉매 및 중합방법 |
KR100389475B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합 또는 공중합용 촉매의 제조 방법 |
KR100389477B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합체 및 공중합체 제조방법 |
KR100389476B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합체 및 공중합체 제조방법 |
KR100389962B1 (ko) * | 2000-11-10 | 2003-07-02 | 삼성종합화학주식회사 | 에틸렌 중합 또는 공중합용 촉매의 제조 방법 |
KR100421551B1 (ko) * | 2000-12-16 | 2004-03-09 | 삼성아토피나주식회사 | 올레핀 전중합 촉매 및 이를 이용한 올레핀 중합방법 |
EP1362131A4 (en) * | 2000-12-22 | 2005-03-02 | Samsung General Chemicals Co | POLYPROPYL FLAME RETARDANT COMPOSITION |
WO2002051933A1 (en) * | 2000-12-22 | 2002-07-04 | Samsung General Chemicals Co., Ltd. | Polypropylene resin composition with improved surface hardness and scratch resistance properties |
WO2002051934A1 (en) * | 2000-12-22 | 2002-07-04 | Samsung General Chemicals Co., Ltd. | Polyolefin resin composition |
US6872683B2 (en) * | 2000-12-22 | 2005-03-29 | Samsung Atofina Co., Ltd. | Method for preparing chelated catalyst for olefin polymerization |
KR100421553B1 (ko) | 2000-12-27 | 2004-03-09 | 삼성아토피나주식회사 | 알파 올레핀 중합 방법 |
US20030022786A1 (en) * | 2001-05-03 | 2003-01-30 | Epstein Ronald A. | Catalyst for propylene polymerization |
KR100496776B1 (ko) * | 2001-06-21 | 2005-06-22 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
KR100530794B1 (ko) * | 2001-06-21 | 2005-11-23 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
TW200300144A (en) | 2001-11-01 | 2003-05-16 | Idemitsu Petrochemical Co | Solid catalyst component for olefin polymerization, catalyst for olefin polymerization, and process for producing olefin polymer |
KR100530795B1 (ko) * | 2001-12-26 | 2005-11-23 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합 방법 |
KR101084937B1 (ko) * | 2004-03-11 | 2011-11-17 | 에스케이종합화학 주식회사 | 에틸렌 중합용 촉매의 제조방법 |
KR100715265B1 (ko) * | 2006-01-12 | 2007-05-04 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합 방법 |
TW200936610A (en) * | 2008-02-26 | 2009-09-01 | Samsung Total Petrochemicals | A preparation method of catalyst for ethylene polymerization and copolymerization |
KR20130100155A (ko) | 2010-09-16 | 2013-09-09 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 올레핀 중합용 촉매 담체, 고체 촉매 성분 및 촉매 |
MY162215A (en) | 2011-01-19 | 2017-05-31 | China Petroleum & Chem Corp | Solid catalyst component and catalyst for olefin polymerization |
US9714302B2 (en) | 2014-10-10 | 2017-07-25 | W. R. Grace & Co.—Conn. | Process for preparing spherical polymerization catalyst components for use in olefin polymerizations |
EP3489244A1 (en) * | 2017-11-28 | 2019-05-29 | Scg Chemicals Co. Ltd. | Magnesium compound, method for producing the same and use thereof |
US20230151125A1 (en) | 2020-04-30 | 2023-05-18 | Dow Global Technologies Llc | Ziegler-natta (pro)catalyst systems made with azaheterocyclic compound |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5298076A (en) * | 1976-02-13 | 1977-08-17 | Mitsubishi Chem Ind Ltd | Preparation of polyolefins |
JPS5952166B2 (ja) * | 1976-06-29 | 1984-12-18 | 三井化学株式会社 | ポリオレフインの製造方法 |
CA1141093A (en) * | 1979-05-17 | 1983-02-08 | Brian L. Goodall | Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions |
JPS5763309A (en) * | 1980-10-03 | 1982-04-16 | Idemitsu Kosan Co Ltd | Polymerization of alpha-olefin |
JPH0725806B2 (ja) * | 1985-02-27 | 1995-03-22 | 三菱油化株式会社 | オレフイン重合用触媒成分 |
JP2764286B2 (ja) * | 1987-12-26 | 1998-06-11 | 東邦チタニウム株式会社 | オレフイン類重合用固体触媒成分及び触媒 |
EP0322798B1 (en) * | 1987-12-26 | 1994-03-02 | Toho Titanium Co. Ltd. | A solid catalyst component for the polymerization of olefins and an olefin polymerization catalyst |
-
1990
- 1990-04-27 JP JP2110214A patent/JP2958923B2/ja not_active Expired - Lifetime
- 1990-09-14 US US07/582,415 patent/US5130284A/en not_active Expired - Lifetime
- 1990-09-17 NO NO904047A patent/NO175060B/no unknown
- 1990-09-18 EP EP90117968A patent/EP0459009B1/en not_active Expired - Lifetime
- 1990-09-18 ES ES90117968T patent/ES2064580T3/es not_active Expired - Lifetime
- 1990-09-18 DE DE69014863T patent/DE69014863T2/de not_active Expired - Fee Related
- 1990-09-19 FI FI904603A patent/FI99247C/fi not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
US5130284A (en) | 1992-07-14 |
NO175060B (no) | 1994-05-16 |
NO904047D0 (no) | 1990-09-17 |
FI99247B (fi) | 1997-09-15 |
EP0459009B1 (en) | 1994-12-07 |
NO175060C (es) | 1994-08-24 |
EP0459009A3 (en) | 1992-05-20 |
NO904047L (no) | 1991-10-28 |
DE69014863D1 (de) | 1995-01-19 |
FI904603A0 (fi) | 1990-09-19 |
JPH048709A (ja) | 1992-01-13 |
DE69014863T2 (de) | 1995-04-13 |
JP2958923B2 (ja) | 1999-10-06 |
FI99247C (fi) | 1997-12-29 |
FI904603A (fi) | 1991-10-28 |
EP0459009A2 (en) | 1991-12-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ES2064580T3 (es) | Un componente de catalizador solido para la polimerizacion de olefinas y un catalizador de polimerizacion de olefinas. | |
ES479521A1 (es) | Procedimiento para la preparacion de un catalizador para la polimerizacion de olefinas. | |
ES2134225T3 (es) | Procedimiento para la polimerizacion en fase gaseosa de olefinas. | |
IL114638A0 (en) | Process for the polymerization of olefins | |
DE69019046D1 (de) | Verfahren zur Polymerisation von Olefinen und Katalysator für Olefinpolymerisation. | |
DE68927765D1 (de) | Verfahren zur Anwendung von Triethylaluminium beim Herstellen eines Alumoxans auf einem Träger für einen aktiven Metallocen-Katalysator | |
ATE97670T1 (de) | Vermeidung von farbigen verunreinigungen bei der herstellung von ultrahochmolekularen ethylenpolymerisaten mittels eines titan enthaltenden katalysatorsystems. | |
YU27892A (sh) | Komponente i katalizatori za polimerizaciju olefina | |
ES8504216A1 (es) | Metodo para la preparacion de un catalizador ziegler soportado | |
CS9100655A2 (en) | Catalyst applied on carrier material for ethylene polymerization and for ethylene copolymerization with alpha-olefins, process of this catalyst preparation and application | |
MX167018B (es) | Procedimiento para preparar catalizadores para polimerizar poliolefinas | |
EP0170384A3 (en) | Polymerization catalyst | |
MX9191A (es) | Catalizadores para la polimerizacion de alfa olefinas y procedimiento para su preparacion. | |
ES2096234T3 (es) | Catalizador de polimerizacion de las olefinas, su procedimiento de obtencion. | |
ATE44036T1 (de) | Herstellung koerniger stereoregulaerer 1-butenpolymere in einem fliessbett. | |
ATE20075T1 (de) | Verfahren zur herstellung eines katalysatorbestandteils und polymerisation von 1- olefinen mit hilfe dieses katalysatorbestandteils. | |
NO955333L (no) | Katalysator og fremgangsmåte for (ko)polymerisering av etylen | |
AR246529A1 (es) | Un proceso para preparar un catalizador de polimerizacion de olefinas. | |
KR840000272A (ko) | 삼염화 티탄 촉매성분의 제조방법 | |
ES2120469T3 (es) | Procedimiento para la preparacion de (co)polimeros de etileno con una amplia distribucion de peso molecular. | |
ATE22090T1 (de) | Verfahren zur herstellung einer festen katalytischen titankomponente und polymerisationsverfahren von 1-alkylenen das diese verwendet. | |
JPS5494591A (en) | Production of olefin polymer | |
JPS646007A (en) | Production of alpha-olefin polymer | |
BR7805645A (pt) | Composicao da materia,processo para a producao de uma composicao contendo tricloreto de titanio,catalisador de polimerizacao de olefina,processo para a producao de um polimero ou copolimero de um monomero de olefina e copolimero de propileno e etileno | |
JPS55155003A (en) | Preparation of olefin polymer |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
Ref document number: 459009 Country of ref document: ES |