ES2054957T3 - Procedimiento para la reduccion de oxidos de nitrogeno contenidos en gases de escape mediante un catalizador conteniendo zeolita. - Google Patents

Procedimiento para la reduccion de oxidos de nitrogeno contenidos en gases de escape mediante un catalizador conteniendo zeolita.

Info

Publication number
ES2054957T3
ES2054957T3 ES89115327T ES89115327T ES2054957T3 ES 2054957 T3 ES2054957 T3 ES 2054957T3 ES 89115327 T ES89115327 T ES 89115327T ES 89115327 T ES89115327 T ES 89115327T ES 2054957 T3 ES2054957 T3 ES 2054957T3
Authority
ES
Spain
Prior art keywords
procedure
reduction
nitrogen oxides
oxides contained
exhaust gases
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES89115327T
Other languages
English (en)
Other versions
ES2054957T5 (es
Inventor
Wolfgang Dr Held
Axel Dr Konig
Lothar Dr Puppe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6362271&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2054957(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Bayer AG filed Critical Bayer AG
Publication of ES2054957T3 publication Critical patent/ES2054957T3/es
Application granted granted Critical
Publication of ES2054957T5 publication Critical patent/ES2054957T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066—Selective catalytic reduction [SCR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B01D53/56—Nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9431—Processes characterised by a specific device
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9495—Controlling the catalytic process
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2067—Urea
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/01—Engine exhaust gases
    • B01D2258/012—Diesel engines and lean burn gasoline engines
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/10—Adding substances to exhaust gases the substance being heated, e.g. by heating tank or supply line of the added substance
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Toxicology (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)

Abstract

EN UN PROCEDIMIENTO, QUE UTILIZA UN CATALIZADOR CON ZEOLITAS, PARA LA REDUCCION DE OXIDOS DE NITROGENO CONTENIDOS EN GASES SALIENTES SE UTILIZA UREA COMO MEDIO REDUCTOR A AÑADIR AL GAS SALIENTE.
ES89115327T 1988-09-03 1989-08-19 Procedimiento para la reduccion de oxidos de nitrogeno contenidos en gases de escape mediante un catalizador conteniendo zeolita. Expired - Lifetime ES2054957T5 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3830045A DE3830045C2 (de) 1988-09-03 1988-09-03 Verfahren zur Reduktion von in Abgasen enthaltenen Stickoxiden mittels eines zeolithhaltigen Katalysators

Publications (2)

Publication Number Publication Date
ES2054957T3 true ES2054957T3 (es) 1994-08-16
ES2054957T5 ES2054957T5 (es) 1997-10-16

Family

ID=6362271

Family Applications (1)

Application Number Title Priority Date Filing Date
ES89115327T Expired - Lifetime ES2054957T5 (es) 1988-09-03 1989-08-19 Procedimiento para la reduccion de oxidos de nitrogeno contenidos en gases de escape mediante un catalizador conteniendo zeolita.

Country Status (6)

Country Link
US (1) US4946659A (es)
EP (1) EP0364694B2 (es)
JP (1) JP2931332B2 (es)
KR (1) KR0127757B1 (es)
DE (2) DE3830045C2 (es)
ES (1) ES2054957T5 (es)

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JPH07106300B2 (ja) * 1989-12-08 1995-11-15 財団法人産業創造研究所 燃焼排ガス中の窒素酸化物除去法
DE4003515A1 (de) * 1990-02-06 1991-08-08 Bayer Ag Verfahren zur reduktion von in abgasen enthaltenen stickoxiden
KR100229731B1 (ko) * 1990-07-27 1999-11-15 브룬너 하인리히 페터 울리히 대형 디젤엔진
US5240688A (en) * 1990-08-01 1993-08-31 Fuel Tech Gmbh Process for the in-line hydrolysis of urea
DE4203807A1 (de) * 1990-11-29 1993-08-12 Man Nutzfahrzeuge Ag Vorrichtung zur katalytischen no(pfeil abwaerts)x(pfeil abwaerts)-reduktion
DE4038054A1 (de) * 1990-11-29 1992-06-04 Man Technologie Gmbh Verfahren und vorrichtung zur selektiven katalytischen no(pfeil abwaerts)x(pfeil abwaerts)-reduktion in sauerstoffhaltigen abgasen
JP2887933B2 (ja) * 1991-03-13 1999-05-10 トヨタ自動車株式会社 内燃機関の排気浄化装置
US5149511A (en) * 1991-10-07 1992-09-22 Ford Motor Company Method of selectively reducing NOx
DE4141581A1 (de) * 1991-12-17 1993-06-24 Didier Werke Ag Verfahren zur minderung der stickoxidkonzentration in verbrennungsabgasen unter zugabe einer waessrigen harnstoffloesung
EP0555746B1 (de) * 1992-02-10 1997-09-10 MAN Nutzfahrzeuge Aktiengesellschaft Vorrichtung zur katalytischen NOX-Reduktion
CA2088713C (en) * 1992-02-24 1999-11-16 Hans Thomas Hug Cleaning exhaust gases from combustion installations
DE69318461T2 (de) * 1992-03-27 1998-12-17 Nippon Shokubai Co. Ltd., Osaka Verfahren und Vorrichtung zur Entfernung von Stickoxyden
EP0577853B1 (de) * 1992-05-08 1995-05-10 Siemens Aktiengesellschaft Einrichtung zur Entstickung von Abgas eines Verbrennungsmotors
DE4217552C1 (es) * 1992-05-27 1993-08-19 Mercedes-Benz Aktiengesellschaft, 7000 Stuttgart, De
DE4237705A1 (de) * 1992-11-07 1994-05-11 Mtu Friedrichshafen Gmbh Verfahren zum Steuern der Zugabemenge an Stickoxid-Reduktionsmitteln in das durch eine Abgasreinigungsanlage für Dieselmotoren strömendes Abgas
EP0617199B1 (de) * 1993-03-26 1996-01-31 Siemens Aktiengesellschaft Katalysator zur Stickoxidminderung im Abgas eines Verbrennungsmotors
JPH09500164A (ja) * 1993-07-12 1997-01-07 プラチナム プラス インコーポレーテッド ディーゼルエンジンからのＮＯｘ及び微粒子の排出を減少させる方法
US5354544A (en) * 1993-12-27 1994-10-11 Ford Motor Company Selective reduction of nitric oxide
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DE4440833A1 (de) * 1994-11-15 1996-02-08 Bayerische Motoren Werke Ag Katalysator-Anordnung zur Reduktion von Stickoxiden in sauerstoffhaltigen Abgasen einer Brennkraftmaschine, insbesondere Dieselmotor
CA2141734C (en) * 1995-01-25 2000-06-06 Raj Narain Pandey Selective catalytic reduction of nitrogen oxides
DE19719998C2 (de) * 1997-05-13 2003-10-30 Daimler Chrysler Ag Verfahren und Vorrichtung zur Stickoxidreduktion im Abgas einer Verbrennungseinrichtung
DE19728343C5 (de) * 1997-07-03 2013-02-21 Robert Bosch Gmbh Verfahren und Vorrichtung zur selektiven katalytischen NOx-Reduktion
DE19728344A1 (de) * 1997-07-03 1999-01-07 Abb Research Ltd Verfahren und Vorrichtung zur Entstickung der Abgase von Verbrennungsanlagen
DE19729003C2 (de) * 1997-07-07 1999-05-27 Siemens Ag Tank für ein Fahrzeug mit reduktionsmittelbetriebener Abgas-Reinigungsanlage
DE19813722C1 (de) 1998-03-27 2000-03-23 Siemens Ag Verfahren und Vorrichtung zur katalytischen Reduzierung von Stickoxiden im Abgas einer Verbrennungsanlage
JP3482874B2 (ja) * 1998-05-28 2004-01-06 トヨタ自動車株式会社 内燃機関の排気浄化装置
JP3580163B2 (ja) * 1998-06-04 2004-10-20 トヨタ自動車株式会社 内燃機関の排気浄化装置
US6223526B1 (en) 1998-06-17 2001-05-01 Siemens Aktiengesellschaft Dual compartment fuel storage tank
DE19843960A1 (de) * 1998-09-24 2000-03-30 Siemens Ag Verfahren und Vorrichtung zur katalytischen Verringerung des Schadstoffgehalts im Abgas einer Verbrennungsanlage
US6125629A (en) * 1998-11-13 2000-10-03 Engelhard Corporation Staged reductant injection for improved NOx reduction
DE10047512A1 (de) * 2000-09-22 2002-08-22 Bosch Gmbh Robert Vorrichtung zur Dosierung eines Reduktionsmittels
JP5261189B2 (ja) * 2005-12-14 2013-08-14 ビーエーエスエフ コーポレーション Ｎｏｘ選択的触媒還元効率の改善されたゼオライト触媒
DE202007019640U1 (de) 2006-06-08 2014-10-17 Inergy Automotive Systems Research (Société A.) System zur Lagerung von Motorgasadditiven
CN103110524B (zh) * 2006-12-20 2017-06-09 Edgewell个人护理品牌有限责任公司 用于婴儿奶瓶的排气阀组件
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Also Published As

Publication number Publication date
EP0364694B2 (de) 1997-08-06
EP0364694A1 (de) 1990-04-25
JPH02139019A (ja) 1990-05-29
DE3830045C2 (de) 1993-09-30
JP2931332B2 (ja) 1999-08-09
EP0364694B1 (de) 1994-06-29
KR0127757B1 (ko) 1997-12-30
DE58907982D1 (de) 1994-08-04
DE3830045A1 (de) 1990-03-15
KR900004391A (ko) 1990-04-12
ES2054957T5 (es) 1997-10-16
US4946659A (en) 1990-08-07

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