ES2034487T3 - Procedimiento para la fabricacion de e7/z9-alcadien-1-oles y sus derivados protegidos en el grupo hidroxilo. - Google Patents
Procedimiento para la fabricacion de e7/z9-alcadien-1-oles y sus derivados protegidos en el grupo hidroxilo.Info
- Publication number
- ES2034487T3 ES2034487T3 ES89108673T ES89108673T ES2034487T3 ES 2034487 T3 ES2034487 T3 ES 2034487T3 ES 89108673 T ES89108673 T ES 89108673T ES 89108673 T ES89108673 T ES 89108673T ES 2034487 T3 ES2034487 T3 ES 2034487T3
- Authority
- ES
- Spain
- Prior art keywords
- alcadien
- oles
- alkyl
- procedure
- manufacture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/29—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by introduction of oxygen-containing functional groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/09—Geometrical isomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/55—Design of synthesis routes, e.g. reducing the use of auxiliary or protecting groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
OBTENCION DE E7/Z9-ALCADIEN-1-OLES DE FORMULA I, (CON R1 = C1 C8 - ALQUILO, R (AL CUADRADO) = H O GRUPO PROTECTOR HIDROXILO BASEESTABLE), HACIENDO REACCIONAR UN 7 - HIDROXIHEPTANAL II (EN SU CASO, PROTEGIDO EN LA FUNCION OH), CON UN FOSFORILID III, EN EL QUE R3, R4 SON UN GRUPO ALQUILO BAJOMOLECULAR O ESTAN ENLAZADOS PARA FORMAR UN SISTEMA DIOXANO O DIOXOLANO EN SU CASO C1 - C4 ALQUILSUSTITUIDO, Y R5 ES ALQUILO, CICLOALQUILO O FENILO (SUSTITUIDO), EN LA FORMA PREVISTA EN UNA REACCION WITTIG PARA OBTENER COMPUESTOS DE LA FORMULA IV, QUE SE TRANSPONEN POR EFECTO DE ACIDO EN 2 - NONENAL TRANS -CONFIGURADO V, QUE SE HACE REACCIONAR EN UNA NUEVA REACCION WITTIG CON UN FOSFORILID VI, DONDE R1 Y R5 TIENEN LA SIGNIFICACION DADA ANTES, PARA CONSEGUIR E7/Z9-ALCADIENOLES I, QUE SE OBTIENEN DE LA MEZCLA REACTIVA EN FORMA YA CONOCIDA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19883817399 DE3817399A1 (de) | 1988-05-21 | 1988-05-21 | Verfahren zur herstellung von e7/z9-alkadien-1-olen und deren an der hydroxylgruppe geschuetzten derivaten |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2034487T3 true ES2034487T3 (es) | 1993-04-01 |
Family
ID=6354883
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES89108673T Expired - Lifetime ES2034487T3 (es) | 1988-05-21 | 1989-05-13 | Procedimiento para la fabricacion de e7/z9-alcadien-1-oles y sus derivados protegidos en el grupo hidroxilo. |
Country Status (6)
Country | Link |
---|---|
US (1) | US5089659A (es) |
EP (1) | EP0343468B1 (es) |
JP (1) | JP2690356B2 (es) |
DE (2) | DE3817399A1 (es) |
ES (1) | ES2034487T3 (es) |
HU (1) | HU206302B (es) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4219510C1 (de) * | 1992-06-13 | 1993-12-02 | Boehringer Ingelheim Kg | Verfahren zur Herstellung von (S)- und (R)-But-3-en-2-ol und deren Derivaten aus L- bzw. D-Milchsäureestern |
EP0630877B1 (en) * | 1993-06-21 | 1997-03-12 | Shin-Etsu Chemical Co., Ltd. | Workup of Wittig reaction products |
CA2243527A1 (en) * | 1996-01-18 | 1997-07-24 | University Of New Mexico | Soft actuators and artificial muscles |
US6485979B1 (en) | 1999-08-05 | 2002-11-26 | 3M Innovative Properties Company | Electronic system for tracking and monitoring articles to be sterilized and associated method |
US6884394B1 (en) | 1999-08-05 | 2005-04-26 | 3M Innovative Properties Company | Chemical indicator reader |
CN100437093C (zh) * | 2000-06-23 | 2008-11-26 | 梁传信 | 光导纤维化学传感器及其制造方法 |
US20040047535A1 (en) * | 2002-09-09 | 2004-03-11 | Ljerka Ukrainczyk | Enhanced fiber-optic sensor |
US20050069243A1 (en) * | 2003-09-30 | 2005-03-31 | Ljerka Ukrainczyk | Fiber-optic sensor probe for sensing and imaging |
US6838576B1 (en) | 2003-10-23 | 2005-01-04 | 3M Innovative Properties Company | Process for preparing functional group-containing olefinic compounds |
US7235688B1 (en) | 2004-11-04 | 2007-06-26 | University Of Notre Dame Du Lac | Process for preparing histone deacetylase inhibitors and intermediates thereof |
FR3063729B1 (fr) * | 2017-03-10 | 2019-06-07 | Universite de Bordeaux | Nouvelle composition d'isomeres du 7,9-dodecadienyl-1-acetate et son procede de fabrication |
CN109678662B (zh) * | 2018-12-29 | 2020-05-19 | 云南大学 | 一种乙酸7e,9z-十二碳二烯酯的合成方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3845108A (en) * | 1973-08-31 | 1974-10-29 | W Roelofs | Trans-7-cis-9-dodecadien-1-yl acetate |
HU181328B (en) * | 1981-05-15 | 1983-07-28 | Egyt Gyogyszervegyeszeti Gyar | Process for producing 7-bracket-e-bracket closed, 9-bracket-z-bracket closed-alkadienol derivatives |
-
1988
- 1988-05-21 DE DE19883817399 patent/DE3817399A1/de not_active Withdrawn
-
1989
- 1989-05-13 ES ES89108673T patent/ES2034487T3/es not_active Expired - Lifetime
- 1989-05-13 DE DE8989108673T patent/DE58902184D1/de not_active Expired - Lifetime
- 1989-05-13 EP EP19890108673 patent/EP0343468B1/de not_active Expired - Lifetime
- 1989-05-19 US US07/354,203 patent/US5089659A/en not_active Expired - Lifetime
- 1989-05-19 JP JP12461289A patent/JP2690356B2/ja not_active Expired - Lifetime
- 1989-05-19 HU HU892511A patent/HU206302B/hu unknown
Also Published As
Publication number | Publication date |
---|---|
EP0343468A3 (en) | 1990-03-21 |
JPH0217142A (ja) | 1990-01-22 |
EP0343468A2 (de) | 1989-11-29 |
HU206302B (en) | 1992-10-28 |
US5089659A (en) | 1992-02-18 |
EP0343468B1 (de) | 1992-09-02 |
DE58902184D1 (de) | 1992-10-08 |
DE3817399A1 (de) | 1989-11-30 |
JP2690356B2 (ja) | 1997-12-10 |
HUT50097A (en) | 1989-12-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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