ES2031251T3 - Procedimiento para la preparacion en emulsion suspendida de polimeros y copolimeros insolubles en sus composiciones monomeras o comonomeras. - Google Patents

Procedimiento para la preparacion en emulsion suspendida de polimeros y copolimeros insolubles en sus composiciones monomeras o comonomeras.

Info

Publication number
ES2031251T3
ES2031251T3 ES198888400597T ES88400597T ES2031251T3 ES 2031251 T3 ES2031251 T3 ES 2031251T3 ES 198888400597 T ES198888400597 T ES 198888400597T ES 88400597 T ES88400597 T ES 88400597T ES 2031251 T3 ES2031251 T3 ES 2031251T3
Authority
ES
Spain
Prior art keywords
monomer
composition
copolymers
procedure
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES198888400597T
Other languages
English (en)
Inventor
Pierre Nogues
Francois Erard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Elf Atochem SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Elf Atochem SA filed Critical Elf Atochem SA
Application granted granted Critical
Publication of ES2031251T3 publication Critical patent/ES2031251T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/909—Polymerization characterized by particle size of product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

PROCEDIMIENTO DE PREPARACION DE POLIMEROS Y COPOLIMEROS, ESENCIALMENTE DE TIPO VINILICO, INSOLUBLES EN SUS COMPOSICIONES MONOMEROS O CO-MONOMEROS, POR POLIMERIZAMICON EN EMULSION SUSPENDIDA DEL O DE LOS MONOMEROS CORRESPONDIENTES. SE DISPERSA, EN FORMA FINAMENTE DIVIDIDA, UNA SOLUCION ACUOSA DE AL MENOS UNA PARTE DE UN SISTEMA CEBADOR EN UNA COMPOSICION MONOMERO O CO-MONOMERO DE TIPO VINILICO Y SE REALIZA LA POLIMERIZACION DE DICHA COMPOSICION. LA CANTIDAD DE AGUA DE DICHA SOLUCION ACUOSA REPRESENTA AL MENOS UN 19% Y PREFERENTEMENTE AL MENOS UN 20% EN EPSO EN RELACION A DICHA COMPOSICION MONOMERO O CO-MONOMERO. EN EL CASO DE LA POLIMERIZACION DE UNA COMPOSICION MONOMERO O CO-MONOMERO A BASE DE CLORURO DE VINILO, EL PROCEDIMIENTO PERMITE OBTENER, CON UNA TASA DE CONVERSION DE LA COMPOSICION MONOMERO O COMONERO SUPERIOR AL 50% QUE PUEDE EXCEDER UN 65%, POLIMEROS Y COPOLIMEROS FORMADOS DE PARTICULAS CON UN DIAMETRO MEDIO SUPERIOR A 10 (MU)M QUE PRESENTAN A LA VEZ UNA MASA VOLUMICA APARENTEQUE PUEDE EXCEDER DE 0,55 G/CM3 Y UNA POROSIDAD EVALUADA CON UN VALOR DE CHASIS DE PLASTIFICANTE A TEMPERATURA AMBIENTE QUE PUEDE SOBREPASAR 30 G DE DI (ETIL-2 HEXIL) FTALATO POR 100 G DE RESINA.
ES198888400597T 1987-03-17 1988-03-14 Procedimiento para la preparacion en emulsion suspendida de polimeros y copolimeros insolubles en sus composiciones monomeras o comonomeras. Expired - Lifetime ES2031251T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8703636A FR2612520A1 (fr) 1987-03-17 1987-03-17 Procede de preparation en emulsion suspendue de polymeres et copolymeres insolubles dans leurs compositions monomeres ou comonomeres

Publications (1)

Publication Number Publication Date
ES2031251T3 true ES2031251T3 (es) 1992-12-01

Family

ID=9349064

Family Applications (1)

Application Number Title Priority Date Filing Date
ES198888400597T Expired - Lifetime ES2031251T3 (es) 1987-03-17 1988-03-14 Procedimiento para la preparacion en emulsion suspendida de polimeros y copolimeros insolubles en sus composiciones monomeras o comonomeras.

Country Status (9)

Country Link
US (2) US5047488A (es)
EP (1) EP0286476B1 (es)
JP (1) JPH0757763B2 (es)
KR (1) KR930003794B1 (es)
CN (1) CN1016421B (es)
CA (1) CA1337007C (es)
DE (1) DE3870968D1 (es)
ES (1) ES2031251T3 (es)
FR (1) FR2612520A1 (es)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
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FR2612520A1 (fr) * 1987-03-17 1988-09-23 Atochem Procede de preparation en emulsion suspendue de polymeres et copolymeres insolubles dans leurs compositions monomeres ou comonomeres
FR2668155B1 (fr) * 1990-10-19 1992-12-31 Atochem Polymeres et resines a base de chlorure de vinyle a grains lisses et a homogeneite de structure interne amelioree, leur procede de preparation.
FR2673184A1 (fr) * 1991-02-21 1992-08-28 Atochem Elf Sa Procede de preparation de (co)polymeres solubles dans leurs compositions (co)monomeres.
US5342906A (en) * 1991-04-09 1994-08-30 Shin-Etsu Chemical Co., Ltd. Method for the suspension polymerization of vinyl chloride monomer
KR100335866B1 (ko) * 2000-01-06 2002-05-10 박호군 폴리아세트산비닐 코어/폴리비닐알코올 외피의 2중 구조를갖는 미세구형 색전재료 및 그의 제조방법
KR100716021B1 (ko) * 2005-03-10 2007-05-08 박지호 테트라플로로에틸렌 중합체를 포함하는 현탁 입자 및 그 제조 방법
USRE45940E1 (en) 2006-03-24 2016-03-22 Akzo Nobel N.V. Continuous process for the production of vinyl chloride (co)polymers
KR101359595B1 (ko) * 2006-03-24 2014-02-07 아크조 노벨 엔.브이. 비닐 클로라이드 (코)폴리머의 연속 제조 방법
US7326849B2 (en) * 2006-04-06 2008-02-05 Fender Musical Instruments Corporation Foot-operated docking station for electronic modules used with musical instruments
CN101255614B (zh) * 2008-03-28 2010-10-06 刘燕平 无机固相组合粉体、母粒及制造方法、纤维及制造方法
CN102311515A (zh) * 2010-07-09 2012-01-11 新疆石河子中发化工有限责任公司 共聚树脂悬浮法生产中加料及温度控制方法
AU2012251125B2 (en) * 2011-05-04 2016-03-10 Uniseal Solutions Inc. Improved polymeric composition for cement based substructures
CN102603955A (zh) * 2012-03-19 2012-07-25 中国石油化工集团公司 不含甲醛的醋酸乙烯-乙烯共聚物乳液的制法
CN103044600B (zh) * 2013-01-01 2015-08-26 江苏荣昌新材料科技有限公司 一种阳离子型水性氯偏金属防腐蚀涂料的制造方法
US9969899B2 (en) 2013-02-18 2018-05-15 Honeywell International Inc. Fluoropolymers containing a copolymerized fluoromonomer and a functional hydrocarbon comonomer and articles made from such fluoropolymers
FR3022785B1 (fr) 2014-06-25 2017-10-13 Pylote Utilisation de materiaux incorporant des microparticules pour eviter la proliferation de contaminants.
CN108485161A (zh) * 2018-03-23 2018-09-04 长沙小新新能源科技有限公司 一种环保门窗材料的制备方法
CN111704689B (zh) * 2020-06-29 2022-04-26 天津城建大学 用于金属表面的高附着力水性偏氯乙烯共聚乳液及其制备方法
JP7132316B2 (ja) * 2020-12-28 2022-09-06 高圧ガス工業株式会社 二液型硬化性組成物

Family Cites Families (29)

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Publication number Priority date Publication date Assignee Title
US2689242A (en) * 1951-03-20 1954-09-14 Monsanto Chemicals ph control in the emulsion polymerization of vinyl chloride
US2890199A (en) * 1954-06-10 1959-06-09 Diamond Alkali Co Polymerization employing polyvinyl pyrrolidone in combination with secondary dispersants as suspension stabilizers
US2917494A (en) * 1956-06-20 1959-12-15 Monsanto Chemicals Vinyl halide suspension polymerization process
GB991536A (en) * 1963-02-13 1965-05-12 Solvay Process for polymerising or copolymerising vinyl chloride in aqueous emulsion
US3428582A (en) * 1966-05-06 1969-02-18 Monsanto Co Interpolymer aqueous dispersions and paper coated therewith
FR1603046A (es) * 1967-08-02 1971-03-15
US3547857A (en) * 1967-10-16 1970-12-15 Uniroyal Inc Continuous emulsion polymerization of styrene and acrylonitrile by addition of monomers in plural stages with all of emulsifier added in first stage
US3678021A (en) * 1969-01-21 1972-07-18 Pechiney Saint Gobain Process for preparing vinyl based polymers and copolymers insoluble in their monomers
FR2029247A5 (en) * 1969-01-21 1970-10-16 Pechiney Saint Gobain Poly(vinyl chloride) in the form of fine particles
US3917548A (en) * 1970-12-14 1975-11-04 Stauffer Chemical Co Process for the suspension polymerization of polyvinyl chloride
US3714298A (en) * 1971-01-05 1973-01-30 Monsanto Co Polyblend of ethylene/vinyl chloride/acrylamide interpolymer and polyacrylamide
BE785830A (fr) * 1971-07-05 1973-01-04 Bp Chem Int Ltd Nouveau procede de polymerisation
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JPS5915321B2 (ja) * 1980-06-30 1984-04-09 積水化学工業株式会社 血清学的診断試薬用ラテツクスの製造方法
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US4458057A (en) * 1982-10-27 1984-07-03 The Bf Goodrich Company Process for producing spherical and porous vinyl resin particles
DE3312255A1 (de) * 1983-04-05 1984-10-11 Wacker-Chemie GmbH, 8000 München Verfahren zur herstellung von waessrigen copolymerdispersionen und deren verwendung
DE3313922A1 (de) * 1983-04-16 1984-10-25 Hoechst Ag, 6230 Frankfurt Emulgator- und schutzkolloidfreie emulsionspolymerisate, verfahren zu ihrer herstellung und ihre verwendung
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JPH0745525B2 (ja) * 1986-03-11 1995-05-17 積水化学工業株式会社 診断試薬用塩化ビニル重合体ラテックスおよびその製造方法
US4668707A (en) * 1986-03-31 1987-05-26 The B. F. Goodrich Company Process for producing porous spherical polyvinyl chloride particles
FR2601373B1 (fr) * 1986-07-11 1988-10-21 Atochem Procede de preparation en emulsion ou en microsuspension d'homo- et copolymeres du chlorure de vinyle
FR2612520A1 (fr) * 1987-03-17 1988-09-23 Atochem Procede de preparation en emulsion suspendue de polymeres et copolymeres insolubles dans leurs compositions monomeres ou comonomeres
US4775702A (en) * 1987-04-14 1988-10-04 The B. F. Goodrich Company Inversion process for producing low-skin porous friable particles of crosslinked PVC resin

Also Published As

Publication number Publication date
CA1337007C (fr) 1995-09-12
KR930003794B1 (ko) 1993-05-13
US5578689A (en) 1996-11-26
EP0286476A1 (fr) 1988-10-12
JPS63264603A (ja) 1988-11-01
EP0286476B1 (fr) 1992-05-13
CN1031089A (zh) 1989-02-15
JPH0757763B2 (ja) 1995-06-21
DE3870968D1 (de) 1992-06-17
US5047488A (en) 1991-09-10
KR880011203A (ko) 1988-10-27
CN1016421B (zh) 1992-04-29
FR2612520A1 (fr) 1988-09-23

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