EP3585933B1 - Verwendung einer wässrigen formulierung zur verbesserung der abriebbeständigkeit - Google Patents

Verwendung einer wässrigen formulierung zur verbesserung der abriebbeständigkeit Download PDF

Info

Publication number: EP3585933B1
Authority: EP; European Patent Office
Prior art keywords: wheel; waxes; weight; abrasion resistance; recipe
Prior art date: 2017-02-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

EP18705146.1A

Other languages

German (de)

English (en)

French (fr)

Other versions

EP3585933A1 (de

Inventor

Alfons Erb

André Weiss

Matthias Bauer

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

CHT Germany GmbH

Original Assignee

CHT Germany GmbH

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2017-02-22

Filing date

2018-02-14

Publication date

2021-06-09

2018-02-14 Application filed by CHT Germany GmbH filed Critical CHT Germany GmbH

2018-02-14 Priority to PL18705146T priority Critical patent/PL3585933T3/pl

2018-02-14 Priority to SI201830367T priority patent/SI3585933T1/sl

2020-01-01 Publication of EP3585933A1 publication Critical patent/EP3585933A1/de

2021-06-09 Application granted granted Critical

2021-06-09 Publication of EP3585933B1 publication Critical patent/EP3585933B1/de

Status Active legal-status Critical Current

2038-02-14 Anticipated expiration legal-status Critical

Links

238000005299 abrasion Methods 0.000 title claims description 41
239000000203 mixture Substances 0.000 title claims description 32
239000001993 wax Substances 0.000 claims description 48
239000006185 dispersion Substances 0.000 claims description 36
239000004753 textile Substances 0.000 claims description 26
238000009472 formulation Methods 0.000 claims description 18
238000002844 melting Methods 0.000 claims description 13
230000008018 melting Effects 0.000 claims description 12
239000004815 dispersion polymer Substances 0.000 claims description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
239000000463 material Substances 0.000 claims description 8
229920000642 polymer Polymers 0.000 claims description 8
150000002148 esters Chemical class 0.000 claims description 6
229920002635 polyurethane Polymers 0.000 claims description 6
239000004814 polyurethane Substances 0.000 claims description 6
230000000694 effects Effects 0.000 claims description 5
229920001296 polysiloxane Polymers 0.000 claims description 4
229920000058 polyacrylate Polymers 0.000 claims description 3
239000000654 additive Substances 0.000 claims description 2
239000006057 Non-nutritive feed additive Substances 0.000 claims 1
239000002518 antifoaming agent Substances 0.000 claims 1
239000003431 cross linking reagent Substances 0.000 claims 1
239000004014 plasticizer Substances 0.000 claims 1
230000004580 weight loss Effects 0.000 description 38
238000012360 testing method Methods 0.000 description 37
-1 polypropylene Polymers 0.000 description 19
238000000034 method Methods 0.000 description 16
239000000835 fiber Substances 0.000 description 13
239000004745 nonwoven fabric Substances 0.000 description 13
239000004698 Polyethylene Substances 0.000 description 10
239000000047 product Substances 0.000 description 10
239000004744 fabric Substances 0.000 description 9
239000006260 foam Substances 0.000 description 9
229920000573 polyethylene Polymers 0.000 description 9
239000000839 emulsion Substances 0.000 description 7
239000002994 raw material Substances 0.000 description 7
239000007787 solid Substances 0.000 description 7
229920003009 polyurethane dispersion Polymers 0.000 description 6
238000004519 manufacturing process Methods 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
239000007921 spray Substances 0.000 description 4
239000000758 substrate Substances 0.000 description 4
239000004952 Polyamide Substances 0.000 description 3
238000013459 approach Methods 0.000 description 3
125000002091 cationic group Chemical group 0.000 description 3
239000011248 coating agent Substances 0.000 description 3
239000004205 dimethyl polysiloxane Substances 0.000 description 3
235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
239000013067 intermediate product Substances 0.000 description 3
239000010410 layer Substances 0.000 description 3
239000012170 montan wax Substances 0.000 description 3
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
229920002647 polyamide Polymers 0.000 description 3
229920000728 polyester Polymers 0.000 description 3
229920000139 polyethylene terephthalate Polymers 0.000 description 3
239000005020 polyethylene terephthalate Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
239000012855 volatile organic compound Substances 0.000 description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
239000004743 Polypropylene Substances 0.000 description 2
239000012164 animal wax Substances 0.000 description 2
239000012223 aqueous fraction Substances 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
238000000576 coating method Methods 0.000 description 2
239000002131 composite material Substances 0.000 description 2
238000010276 construction Methods 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
238000001035 drying Methods 0.000 description 2
238000011835 investigation Methods 0.000 description 2
239000010985 leather Substances 0.000 description 2
239000012184 mineral wax Substances 0.000 description 2
239000012188 paraffin wax Substances 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920001155 polypropylene Polymers 0.000 description 2
229920002215 polytrimethylene terephthalate Polymers 0.000 description 2
239000000243 solution Substances 0.000 description 2
238000010561 standard procedure Methods 0.000 description 2
239000012178 vegetable wax Substances 0.000 description 2
239000002759 woven fabric Substances 0.000 description 2
DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
239000004166 Lanolin Substances 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
241000221095 Simmondsia Species 0.000 description 1
235000004433 Simmondsia californica Nutrition 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
239000013011 aqueous formulation Substances 0.000 description 1
235000013871 bee wax Nutrition 0.000 description 1
239000012166 beeswax Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
239000012185 ceresin wax Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000004043 dyeing Methods 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
238000007306 functionalization reaction Methods 0.000 description 1
229920001903 high density polyethylene Polymers 0.000 description 1
239000004700 high-density polyethylene Substances 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
239000012182 japan wax Substances 0.000 description 1
235000019388 lanolin Nutrition 0.000 description 1
229940039717 lanolin Drugs 0.000 description 1
239000004816 latex Substances 0.000 description 1
229920000126 latex Polymers 0.000 description 1
238000002156 mixing Methods 0.000 description 1
CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
230000035515 penetration Effects 0.000 description 1
238000004987 plasma desorption mass spectroscopy Methods 0.000 description 1
229920001281 polyalkylene Polymers 0.000 description 1
229920006149 polyester-amide block copolymer Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920005862 polyol Polymers 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
238000012552 review Methods 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000002904 solvent Substances 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
239000012209 synthetic fiber Substances 0.000 description 1
238000010998 test method Methods 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000010936 titanium Substances 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
239000002347 wear-protection layer Substances 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance

Definitions

the invention describes the use of an aqueous preparation based on waxes and polymer dispersions, which is applied to textile surfaces, woven fabrics, scrims, knitted fabrics, fibers, nonwovens and knitted fabrics and to leather in order to protect the material, to reduce the loss of mass under stress and thus improving the abrasion resistance or abrasion resistance.
Needle fleeces are generally single or multi-layer textile surfaces that consist of a solidified fiber fleece.
the synthetic fibers polyester, polyamide and polypropylene are mainly used in the manufacture of nonwovens, to a limited extent with the addition of cellulose or animal hair.
Needle fleeces are produced with a needling machine, which compacts the fiber and fiber padding layer using needles. Then the needle felt is mechanically and chemically or thermally bonded.
Needle fleece is very hard-wearing and, thanks to the fiber mix, is insensitive to dirt.
the quality of the wear layer is through the needle penetration density / m 2 is determined. It is between 1 and 4 million per square meter, the denser the better.
Substances such as pure polyurethanes, coarse-grained, high-melting polyethylenes, oily silicones or titanium carbides and combinations thereof show no or only marginal improvements in the abrasion behavior of textiles.
the compounds mentioned are not in aqueous form and therefore cannot be applied by processes customary in the textile industry, such as padding processes, spray application, or foam paste application.
U.S. 4,874,663 A describes how abrasion-resistant fabric can be woven from essentially untwisted polyester or polyamide yarn and treated with an overfinish composition to achieve improved abrasion resistance.
the overfinishing composition comprises effective amounts of a particular crystallizable copolymer consisting essentially of linear polyethylene terephthalate segments and polyoxyethylene terephthalate segments, a particular polyethylene glycol ester or alcohol and sodium dialkylnaphthalene.
US 2008/241532 A1 discloses a composition for yarns, fibers or filaments which can be deposited on these yarns, fibers or filaments in order to improve the properties of these yarns, fibers or filaments, in particular the abrasion resistance.
the disclosure also relates to a method for producing these yarns, fibers or filaments as well as a rope which comprises these yarns, fibers or filaments, and their use.
U.S. 4,767,646 A describes various aqueous overfinishing compositions and yarns treated therewith and processes for producing moisture-abrasion-resistant cordage from the yarn.
a yarn treated with the compositions described has improved wet abrasion resistance.
Such yarns are ideal for heavy rope and other industrial rope applications where abrasion resistance and strength in wet and dry conditions are desirable.
the product should be in aqueous form and it should be possible to apply it using processes customary in the textile industry, such as padding processes, spray application or foam paste application.
the product should not have any negative effects on other technological properties of the substrate such as color, graying, soiling and feel. It is also required that the necessary, temporary, superficial protective functionalization, which is absolutely necessary for protection during transport and thus for the completion of the manufacturing process, is not adversely affected.
the wax dispersions consist of waxes based on natural, semi-synthetic, synthetic waxes. Natural waxes are to be differentiated into mineral, vegetable and animal waxes, all of which can be used according to the invention. Vegetable waxes are, for example, Caranauba or Japan wax, mineral waxes, for example ceresin or montan waxes (raw montan waxes, acid waxes, ester waxes, partially saponified ester waxes, emulsifier-containing ester waxes, fully saponified montan waxes). Beeswax and lanolin are examples of animal waxes.
Synthetic waxes are those based on polyalkylene (polyethylene, polypropylene, polyolefin waxes), silicone waxes, polyol ether esters, Fischer-Tropsch waxes, oxidized PE and HDPE waxes, paraffins, amide waxes such as ethylene bisstearoyldiamide.
Semi-synthetic waxes are chemically modified waxes from native sources, such as hydrogenated jojoba waxes and sasol waxes.
the polymer dispersions contain polymers and / or copolymers as individual components or in mixtures from the groups of polyacrylates and polyurethanes.
Aqueous dispersions with water fractions of 20-95% by weight in each case are prepared from the waxes mentioned as well as from the polymers according to the respective prior art and methods known to the person skilled in the art. It is advantageous to provide formulations according to the invention with the lowest possible water fractions in order to save transport costs and to have to use as little energy as possible for drying.
water-based systems also have the advantage of having very low VOC values and being ecologically more sustainable.
VOC is the abbreviation for volatile organic compounds and is a collective term for organic, i.e. carbon-containing substances that are highly volatile or are already present as a gas at low temperatures (e.g. room temperature).
aqueous preparations used according to the invention based on a mixture of wax and polymer dispersion are used by means of standard applications in textile-technical processes, forced applications, in particular coating, Finishing by padding, spray processes, foam paste application, single thread application and / or dyeing, but also applied to the textile substrates by exhaust processes.
suitable processes such as padding, foam or paste application and spray processes, latex can be applied to the rear in the same work step to strengthen the solidification of the material.
All textile surfaces, woven fabrics, scrims, knitted fabrics, nonwovens and knitted fabrics and leather can be treated with the preparation according to the invention as substrates in order to improve their abrasion resistance or abrasion resistance.
the product was applied in the form of an unstable foam using a foam pad.
the goods were passed vertically through a foam padding from top to bottom.
As a foamer 7 g / l Tubicoat AOS were added to the liquor in each case and the foam liter weight was adjusted to 40 g / l.
TL 52442 compliant Dilour fleece This is a needle fleece made of spinneret-dyed polyester fibers, with 11dtex, which has been thermomechanically fixed.
the abrasion resistance of the finished goods was tested using a Taber Rotary Abraser 5135 available from Taber Industries, North Tonawanda, USA in accordance with DIN standard DIN EN ISO 5470.
Test series 1 Concentration series (according to the invention)
Tables 1a-1d show that from formulation 4, which, with its total solids concentration of 20%, corresponds to a use amount of 200 g / l, the average percentage weight loss in the Taber test is in the range of 1% or less. Compared to unequipped goods, this means an improvement of 65% and more.
Tables 2a-2d using formulations 7 and 14 not according to the invention, show that improvements in the area of a mixture cannot be achieved either by using the wax dispersion alone or by using the polymer dispersion. It can also be seen that significant improvements in abrasion can only be achieved by combining the two individual components according to the invention. The best results are achieved with formulations 9-13, which cover the range of the mixing ratio of wax / polyurethane dispersion between approx. 3: 1 and 1: 3.
Test series 3 Investigation of further additives such as polyethylene dispersions and an emulsion based on polydimethylsiloxane. In test series 3, the effects of the melting point of the waxes and that of emulsions on PDMS are examined.
Tables 3a-3c show that the formulations 15, 19 and 20 not according to the invention show almost no or only insignificant abrasion improvements compared to the raw material. This leads to the conclusion that neither polyethylene dispersions based on HD waxes nor the addition of PDMDS emulsions show any effect in terms of improving abrasion.
recipe 16 which is based on a wax dispersion with LD polyethylenes, the average abrasion is improved, but only by approx. 45% compared to the raw material.
Minimal weight loss due to abrasion in the Taber test is obtained with formulations 17 and 18. Both formulations contain waxes or paraffins with melting points below 80 ° C.
Tables 4a-4b show that recipes 21-23 based on wax dispersions in combination with hydrophilic polyurethane dispersions and two exemplarily selected acrylate dispersions also provide a clear improvement in the Taber abrasion resistance.
the dispersions that form rather soft films on drying, such as Arristan CPU and Tubicoat A 17 show better results than those that form rather hard films such as Tubicoat A 41.
the selection of the wax dispersion seems to have a greater influence than that of the Polymer dispersion.
Test series 5 Use of the products not according to the invention as individual components (not according to the invention)
Tables 5a-5d clearly show that none of the tested products, as individual components, provides an improvement in abrasion resistance that exceeds 50% compared to the raw material. As a result, the products as individual components do not even come close to the values of the formulations according to the invention, which provide improvements in Taber abrasion resistance of in some cases over 80% compared to the raw material.

Landscapes

Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Treatment And Processing Of Natural Fur Or Leather (AREA)
Compositions Of Macromolecular Compounds (AREA)

EP18705146.1A 2017-02-22 2018-02-14 Verwendung einer wässrigen formulierung zur verbesserung der abriebbeständigkeit Active EP3585933B1 (de)

Priority Applications (2)

Application Number	Priority Date	Filing Date	Title
PL18705146T PL3585933T3 (pl)	2017-02-22	2018-02-14	Zastosowanie wodnej formulacji do zwiększania odporności na ścieranie
SI201830367T SI3585933T1 (sl)	2017-02-22	2018-02-14	Uporaba vodnega pripravka za izboljšanje odpornosti proti drgnjenju

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE102017202827.0A DE102017202827A1 (de)	2017-02-22	2017-02-22	Wässrige Formulierung zur Verbesserung der Abriebbeständigkeit
PCT/EP2018/053710 WO2018153760A1 (de)	2017-02-22	2018-02-14	Wässrige formulierung zur verbesserung der abriebbeständigkeit

Publications (2)

Publication Number	Publication Date
EP3585933A1 EP3585933A1 (de)	2020-01-01
EP3585933B1 true EP3585933B1 (de)	2021-06-09

Family

ID=61223916

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP18705146.1A Active EP3585933B1 (de)	2017-02-22	2018-02-14	Verwendung einer wässrigen formulierung zur verbesserung der abriebbeständigkeit

Country Status (13)

Country	Link
US (1)	US11136712B2 (zh)
EP (1)	EP3585933B1 (zh)
CN (1)	CN110431266A (zh)
BR (1)	BR112019015713B1 (zh)
DE (1)	DE102017202827A1 (zh)
ES (1)	ES2880421T3 (zh)
HU (1)	HUE055388T2 (zh)
LT (1)	LT3585933T (zh)
MX (1)	MX2019009162A (zh)
PL (1)	PL3585933T3 (zh)
PT (1)	PT3585933T (zh)
SI (1)	SI3585933T1 (zh)
WO (1)	WO2018153760A1 (zh)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN112127149B (zh) *	2020-08-19	2023-04-14	杭州传化精细化工有限公司	一种筒子纱用亲水小层差平滑剂及其制备方法

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US4767646A (en) *	1985-10-24	1988-08-30	Allied Corporation	Wet abrasion resistant yarn and cordage
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- 2018-02-14 BR BR112019015713-1A patent/BR112019015713B1/pt active IP Right Grant
- 2018-02-14 CN CN201880010313.1A patent/CN110431266A/zh active Pending
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CN110431266A (zh)	2019-11-08
ES2880421T3 (es)	2021-11-24
HUE055388T2 (hu)	2021-11-29
EP3585933A1 (de)	2020-01-01
DE102017202827A1 (de)	2018-08-23
BR112019015713B1 (pt)	2023-10-10
SI3585933T1 (sl)	2021-11-30
PT3585933T (pt)	2021-06-28
BR112019015713A2 (pt)	2020-03-24
US20200056328A1 (en)	2020-02-20
MX2019009162A (es)	2019-12-16
PL3585933T3 (pl)	2021-12-06
LT3585933T (lt)	2021-07-12
WO2018153760A1 (de)	2018-08-30
US11136712B2 (en)	2021-10-05

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