EP3486564A1 - Adsorption de fluide à refoulement de gaz inerte - Google Patents
Adsorption de fluide à refoulement de gaz inerte Download PDFInfo
- Publication number
- EP3486564A1 EP3486564A1 EP18198588.8A EP18198588A EP3486564A1 EP 3486564 A1 EP3486564 A1 EP 3486564A1 EP 18198588 A EP18198588 A EP 18198588A EP 3486564 A1 EP3486564 A1 EP 3486564A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- working fluid
- adsorbent
- inert gas
- closed
- housing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012530 fluid Substances 0.000 title claims abstract description 53
- 239000011261 inert gas Substances 0.000 title claims abstract description 20
- 238000001179 sorption measurement Methods 0.000 title description 8
- 238000006073 displacement reaction Methods 0.000 title description 2
- 239000003463 adsorbent Substances 0.000 claims abstract description 23
- 230000000274 adsorptive effect Effects 0.000 claims abstract description 14
- 238000012546 transfer Methods 0.000 claims abstract description 6
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 30
- 239000001294 propane Substances 0.000 claims description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- 238000000465 moulding Methods 0.000 claims description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
- 239000001569 carbon dioxide Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 8
- 239000003570 air Substances 0.000 description 18
- 239000003507 refrigerant Substances 0.000 description 14
- 239000002594 sorbent Substances 0.000 description 7
- 238000005057 refrigeration Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 238000004880 explosion Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000009423 ventilation Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000012267 brine Substances 0.000 description 3
- 238000003795 desorption Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 238000004378 air conditioning Methods 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 241001136792 Alle Species 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- 241001295925 Gegenes Species 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 241000264877 Hippospongia communis Species 0.000 description 1
- 206010028813 Nausea Diseases 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 208000035475 disorder Diseases 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002757 inflammatory effect Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000003533 narcotic effect Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000008693 nausea Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B49/00—Arrangement or mounting of control or safety devices
- F25B49/005—Arrangement or mounting of control or safety devices of safety devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2500/00—Problems to be solved
- F25B2500/22—Preventing, detecting or repairing leaks of refrigeration fluids
Definitions
- the invention relates to irregular conditions in refrigeration circuits, in which a working fluid acting as a refrigerant is conducted in a thermodynamic cycle, such as the Rankine cycle.
- thermodynamic cycle such as the Rankine cycle.
- These are mainly heat pumps, air conditioners and refrigerators, as they are used in residential buildings.
- Residential buildings are private homes, rental housing complexes, hospitals, hotel complexes, restaurants, combined residential and commercial buildings and businesses in which people permanently live or work, in contrast to mobile devices such as air conditioning systems or transport boxes, or industrial equipment or medical devices. What they all have in common is that they use energy to generate useful heat or useful cooling and form heat-transfer systems.
- thermodynamic cycles have long been known, as well as the safety problems that can arise when using suitable working fluids.
- the best known working fluids at the time are combustible and poisonous.
- safety refrigerants consisting of fluorinated hydrocarbons.
- these safety refrigerants damage the ozone layer, lead to global warming, and that their safety-related harmlessness led to constructive inattentiveness.
- Up to 70% of the turnover was accounted for by the refill demand of leaking equipment and its leakage losses, which was accepted as long as this was considered economically justifiable in individual cases and promoted the need for replacement procurement.
- the lower ignition limit of propane as working fluid is about 1.7% by volume in air, which corresponds to 38 g / m 3 in air.
- Propane is also heavier than air, so sinks in still air on the ground and accumulates there. So if a part of the propane in a flow-poor zone of the closed space in which the disturbed unit is collect, the local explosion limits can be achieved much faster than can be expected from the quotient of total volume of volume to leaked amount of propane.
- the WO 2015/032905 A1 seeks to solve this problem by an electric current generator in the opening or its interlocking this space is integrated and when actuated in a first step generates and provides the electrical energy with which the sensor is activated, and in the event of an alarm Lock then does not release, but causes a ventilation of the enclosed space, and only in a second step, an unlocking and opening allows.
- the DE-PS 553 295 describes an encapsulated compression refrigeration machine in which the refrigerant compressor 1, its drive motor 2, evaporator 3, condenser 4 and control valve 5 are enclosed in a double-walled capsule 6 and 7, respectively. In the space between the double-walled capsule, a negative pressure is created and leaks, which could occur at the openings for cooling water and brine, sucked. The aspirated working fluid can subsequently be recovered if necessary. It should be noted that there is no ambient air within the encapsulated space and due to the negative pressure in the double jacket also can not penetrate into the encapsulated interior.
- the DE 10 2011 116 863 A1 describes a method for securing a device for a thermodynamic cycle, which is operated with a process fluid containing or consisting of at least one environmentally hazardous, toxic and / or inflammatory substance.
- a process fluid particularly ammonia, propane or propene
- the adsorbent is regenerated after use.
- the adsorbent may be in the form of a bed, a shaped body, a paint, a Spray film or a coating to be equipped.
- the support structure of the molding may consist of microstructure, lamellar structure, tube bundle, pipe register and sheet metal and must be mechanically stable and strong surface enlarging.
- a circulation of the potentially contaminated air is usually continuous, but can also be initiated by a sensor that turns on the ventilation after reaching a threshold value or in the event of a detected accident.
- the adsorption can be carried out inside or outside a closed space.
- the DE 195 26 980 A1 describes an apparatus and method for cleaning closed space air having gaseous contamination. Once the contaminant is detected by a gas sensor, it controls a compressor which directs the air through an absorber in that space, thereby absorbing the contaminant. The cleaned air leaves the absorber in the closed room.
- the DE 195 25 064 C1 describes a refrigerator with a gas-tight housing, which accommodates all refrigerant-carrying components of the machine, a space connecting the interior of the gas-tight housing with an outlet space is provided, and the space is filled with a refrigerant sorbing substance.
- the amount of sorbent material is dimensioned so that the entire amount of any escaping refrigerant can be absorbed and kept away from the environment.
- the space filled with the sorbent material is open to the environment. For refrigerants that are heavier than air, the space is open at the bottom, for those that are lighter, it is open at the top, so that a delivery fan is not required.
- the sorbent is introduced into the housing and encloses the chiller and the refrigerant-carrying facilities completely. On its way out, baffles are provided to prevent short circuit currents and force escaping gas through the sorbent. Also a double-walled embodiment in which the sorbent is arranged in the double jacket, is possible. At the exit of the space filled with the sorbent substance to the environment, a measuring device for refrigerant can be provided.
- the EP 3 106 780 A1 describes a heat pump system housed in a binder lined airtight housing.
- an adsorption unit can be arranged with a forced ventilation, which cleans the air in the housing in the recirculation mode.
- This recirculation mode can be continuous or only in case of failure or at regular intervals.
- a pilot burner, a pilot flame, a catalytic burner or a heating wire can be arranged, which burns possibly residual combustible impurities.
- a fresh air supply in connection with the discharge of purified exhaust air.
- the object of the invention is therefore to provide an improved lining device which solves the problems presented better and no longer has the disadvantages.
- heat transfer fluids are here all gaseous or liquid media to understand, with which heat is transferred, such as air, water, brine, heat transfer oils or the like.
- the advantage here is that in the case of a leakage with release of the working fluid, a displacement of the inert gas from the adsorbent takes place with simultaneous adsorption of the working fluid.
- the displaced inert gas thereby inertizes the interior of the container and at the same time reduces the danger of explosion.
- the desorption of the displaced inert gas causes the adsorptive heating of the adsorbent during adsorption significantly lower, since no longer the entire heat of adsorption is free, but only the difference between the heat of adsorption of the working fluid and the heat of desorption of the inert gas. This also prevents already adsorbed working fluid is expelled by heat development again.
- propane is used as the working fluid, activated carbon as the adsorbent and carbon dioxide as the inert gas.
- the activated carbon can be in Known manner be doped such that optimal loading is done by propane, but a chemisorption is to avoid this, since then the same desorption of carbon dioxide fails.
- such a lining is preferably made by dimensionally stable mats or moldings containing the adsorbent and can be easily removed and removed after opening the housing. They are typically permeable to gas and liquid on the side facing the interior of the container by means of a holding grid, while the dimensional stability is ensured by a stable rear-side structure.
- these mats or moldings on the inside facing the housing have a flat surface and on its upper side pull-down foil-like blinds that are pulled in the event of disassembly as a bag over the surface and then for the Disassembly and removal must be kept closed.
- this device is also used for assembly in order to prevent the inert gas from prematurely diffusing out of the lining.
- Fig. 1 shows a schematic diagram of a refrigerant circuit 1 with a compressor 2, a condenser 3, a pressure reduction 4 and an evaporator 5 in a closed housing 6.
- the housing 6 has a heat source connection 7, a heat source flow 8, a heat sink flow. 9 and a heat sink connection 10.
- the refrigerant circuit 1 is operated in this example with the flammable working fluid propane, which is also known under the name R290. Propane is heavier than air, therefore, it tends to sink in case of leakage in the refrigeration circuit 1 in the housing 6 down. Due to temperature differences in the housing and corresponding convection, leakage-induced propane is also found in the rest of the housing interior. This housing 6 is therefore completely lined with the adsorptive lining 11.
- Fig. 2 shows an adsorptive molded body of the type in the housing may have several or should be, these moldings can also completely enclose the housing interior, especially on the bottom, since leaking due to leakage of propane in air drops. Incidentally, such shaped articles also contribute to the reduction of noise emissions.
- the exemplary adsorptive shaped body 12 has in its interior an activated carbon mat 13, which consists either of activated carbon fibers or of activated carbon pellets, which are fixed in a permeable matrix. Also honeycombs are possible. On the back there is a supporting structure with click fasteners 14, with which the adsorptive molded body 12 is fixed to the inside of the housing 6. On the opposite side is a permeable retaining grid 15th
- a shutter device 16 For assembly and disassembly of the adsorptive molded body on a shutter device 16, which consists of rollers on which can be pulled up and rolled up on the front and back before use films before use and pulled down after use and closed down.
- the slides on the front and back can be there also form a bag, which has a pull closure and gas-tightly seals the adsorptive shaped body before and after use.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Separation Of Gases By Adsorption (AREA)
- Devices That Are Associated With Refrigeration Equipment (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL18198588T PL3486564T3 (pl) | 2017-11-16 | 2018-10-04 | Urządzenie do bezpiecznej realizacji lewobieżnego procesu termodynamicznego Clausiusa-Rankine’a, opartego na adsorpcji płynu roboczego z wypieraniem gazu obojętnego |
HRP20201206TT HRP20201206T1 (hr) | 2017-11-16 | 2020-07-31 | Uređaj za sigurnu provedbu skretanja u lijevo termodinamičnog clausius-rankine postupka; temeljeno na adsorpciji radne tekućine sa uklanjanjem inertnog plina |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102017126947.9A DE102017126947A1 (de) | 2017-11-16 | 2017-11-16 | Fluidadsorption mit Inertgasverdrängung |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3486564A1 true EP3486564A1 (fr) | 2019-05-22 |
EP3486564B1 EP3486564B1 (fr) | 2020-05-13 |
Family
ID=63762357
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP18198588.8A Active EP3486564B1 (fr) | 2017-11-16 | 2018-10-04 | DISPOSITIF POUR UNE MISE EN OEUVRE SÉCURITAIRE D'UN PROCESSUS DE RANKINE CLAUSIUS THERMODYNAMIQUE À COMMUTATION GAUCHE
BASÉ SUR UNE ADSORPTION DE FLUIDE DE TRAVAIL À REFOULEMENT DE GAZ INERTE |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP3486564B1 (fr) |
DE (1) | DE102017126947A1 (fr) |
DK (1) | DK3486564T3 (fr) |
ES (1) | ES2811054T3 (fr) |
HR (1) | HRP20201206T1 (fr) |
PL (1) | PL3486564T3 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102019118977A1 (de) * | 2019-02-06 | 2020-08-20 | Vaillant Gmbh | Adsorberkühlung |
EP3748257A1 (fr) * | 2019-06-03 | 2020-12-09 | Vaillant GmbH | Dispositif pour la performance sûre d'un procédé circulaire thermodynamique à rotation à gauche au moyen d'un fluide de travail inflammable avec adsorption de fluide |
EP4209728A1 (fr) | 2022-01-07 | 2023-07-12 | Vaillant GmbH | Pompe à chaleur avec adsorbeur et catalyseur |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000105003A (ja) * | 1998-09-28 | 2000-04-11 | Sanyo Electric Co Ltd | 冷凍機ユニット |
DE102011116863A1 (de) * | 2011-10-25 | 2013-04-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Sicherung einer Vorrichtung für einen thermodynamischen Kreisprozess und abgesicherte Vorrichtung für einen thermodynamischen Kreisprozess |
EP3106780A1 (fr) * | 2015-06-17 | 2016-12-21 | Vaillant GmbH | Installation de pompes a chaleur |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE553295C (de) | 1931-02-03 | 1932-06-23 | Bbc Brown Boveri & Cie | Gekapselte Kompressionskaeltemaschine |
DE19525064C1 (de) | 1995-07-10 | 1996-08-01 | Joachim Dr Ing Paul | Kältemaschine |
DE19526980A1 (de) | 1995-07-25 | 1997-01-30 | York Int Gmbh | Verfahren und eine Vorrichtung zur Reinigung von Luft |
AU2013379388A1 (en) * | 2013-02-25 | 2015-08-20 | Electrolux Appliances Aktiebolag | A heat pump laundry drying machine and a method for operating a heat pump laundry drying machine |
WO2015032905A1 (fr) | 2013-09-05 | 2015-03-12 | Holger König | Procédé permettant d'empêcher une fuite d'un contenant et contenant pourvu d'un dispositif anti-fuite |
-
2017
- 2017-11-16 DE DE102017126947.9A patent/DE102017126947A1/de active Pending
-
2018
- 2018-10-04 DK DK18198588.8T patent/DK3486564T3/da active
- 2018-10-04 PL PL18198588T patent/PL3486564T3/pl unknown
- 2018-10-04 ES ES18198588T patent/ES2811054T3/es active Active
- 2018-10-04 EP EP18198588.8A patent/EP3486564B1/fr active Active
-
2020
- 2020-07-31 HR HRP20201206TT patent/HRP20201206T1/hr unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000105003A (ja) * | 1998-09-28 | 2000-04-11 | Sanyo Electric Co Ltd | 冷凍機ユニット |
DE102011116863A1 (de) * | 2011-10-25 | 2013-04-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Sicherung einer Vorrichtung für einen thermodynamischen Kreisprozess und abgesicherte Vorrichtung für einen thermodynamischen Kreisprozess |
EP3106780A1 (fr) * | 2015-06-17 | 2016-12-21 | Vaillant GmbH | Installation de pompes a chaleur |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102019118977A1 (de) * | 2019-02-06 | 2020-08-20 | Vaillant Gmbh | Adsorberkühlung |
EP3748257A1 (fr) * | 2019-06-03 | 2020-12-09 | Vaillant GmbH | Dispositif pour la performance sûre d'un procédé circulaire thermodynamique à rotation à gauche au moyen d'un fluide de travail inflammable avec adsorption de fluide |
EP4209728A1 (fr) | 2022-01-07 | 2023-07-12 | Vaillant GmbH | Pompe à chaleur avec adsorbeur et catalyseur |
DE102022100269A1 (de) | 2022-01-07 | 2023-07-13 | Vaillant Gmbh | Katalytische Abluftbehandlung für eine Wärmepumpe |
Also Published As
Publication number | Publication date |
---|---|
DK3486564T3 (da) | 2020-08-10 |
PL3486564T3 (pl) | 2020-11-02 |
DE102017126947A1 (de) | 2019-05-16 |
HRP20201206T1 (hr) | 2021-02-05 |
EP3486564B1 (fr) | 2020-05-13 |
ES2811054T3 (es) | 2021-03-10 |
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