EP2803478B1 - Feuille à plusieurs couches en plastique - Google Patents
Feuille à plusieurs couches en plastique Download PDFInfo
- Publication number
- EP2803478B1 EP2803478B1 EP14183261.8A EP14183261A EP2803478B1 EP 2803478 B1 EP2803478 B1 EP 2803478B1 EP 14183261 A EP14183261 A EP 14183261A EP 2803478 B1 EP2803478 B1 EP 2803478B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- outer layer
- layer
- multilayer film
- plastic multilayer
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920003023 plastic Polymers 0.000 title claims description 57
- 239000004033 plastic Substances 0.000 title claims description 57
- 239000010410 layer Substances 0.000 claims description 148
- 239000010408 film Substances 0.000 claims description 100
- 239000012792 core layer Substances 0.000 claims description 64
- -1 polypropylene Polymers 0.000 claims description 27
- 239000004698 Polyethylene Substances 0.000 claims description 20
- 229920000573 polyethylene Polymers 0.000 claims description 20
- 239000004743 Polypropylene Substances 0.000 claims description 7
- 229920001155 polypropylene Polymers 0.000 claims description 7
- 239000013039 cover film Substances 0.000 claims description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 6
- 238000005259 measurement Methods 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 2
- 238000005187 foaming Methods 0.000 description 23
- 238000004519 manufacturing process Methods 0.000 description 20
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- 239000000155 melt Substances 0.000 description 18
- 238000001125 extrusion Methods 0.000 description 16
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- 239000011148 porous material Substances 0.000 description 9
- 239000004604 Blowing Agent Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229920000092 linear low density polyethylene Polymers 0.000 description 5
- 239000004707 linear low-density polyethylene Substances 0.000 description 5
- 230000003287 optical effect Effects 0.000 description 4
- 239000006057 Non-nutritive feed additive Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
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- 239000007789 gas Substances 0.000 description 3
- 238000009499 grossing Methods 0.000 description 3
- 229920001684 low density polyethylene Polymers 0.000 description 3
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- 239000000203 mixture Substances 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
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- 239000012968 metallocene catalyst Substances 0.000 description 2
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- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000006911 nucleation Effects 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 230000003313 weakening effect Effects 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 1
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
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- 230000007423 decrease Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
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- 238000005304 joining Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 229920004889 linear high-density polyethylene Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000009420 retrofitting Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910001868 water Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
- B32B5/20—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material foamed in situ
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/065—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2266/00—Composition of foam
- B32B2266/02—Organic
- B32B2266/0214—Materials belonging to B32B27/00
- B32B2266/025—Polyolefin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/408—Matt, dull surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/04—Polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/10—Polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2553/00—Packaging equipment or accessories not otherwise provided for
Definitions
- the invention relates to the technical field of plastic multilayer films with at least one foamed film layer.
- the invention specifically relates to a plastic multilayer film having a thickness between 20 microns and 250 microns comprising a foamed core layer, a first non-foamed, preferably heat-sealable outer layer and a second unfoamed outer layer having a thickness of less than 70 microns.
- the plastic multilayer film can be provided in the context of the invention for various applications, wherein the second unfoamed outer layer should be visible to a user.
- a typical application for the plastic multilayer film according to the invention is the production of packaging, wherein the second outer layer is visibly arranged on the outside of the packaging and the first unfoamed outer layer on the inside. If the first unfoamed outer layer is then heat sealable according to a preferred embodiment, a package can be particularly easily formed by heat sealing, either forming a film blank or continuous web by folding into a package or at least joining two film blanks or two film webs through sealing seams.
- the plastic multilayer film has special specific advantages due to the foamed core layer, so that the plastic multilayer film is also suitable as a surface protection film, for the formation of adhesive tapes or as a kind of paper substitute.
- the plastic multilayer film can be used both in a so-called FFS (Form Fill and Seal) method in which a bag-shaped package is formed directly in the packaging of the filling material, as well as in the production of prefabricated Packaging, which is then filled later.
- FFS Form Fill and Seal
- plastic multilayer film can be used for example as a cover sheet.
- the foaming of a film layer can be done for various reasons.
- foaming results in a lower basis weight relative to the resulting thickness of the film and thus a saving of material.
- the mechanical properties are also improved by the greater thickness.
- a foamed core layer is combined with unfoamed cover layers, there is a kind of plywood effect which can less easily be deformed against each other by the increase in volume of the core layer compared to a non-foamed embodiment further apart outer layers.
- by foaming at least a film layer also affects the other physical properties of the resulting coextruded film.
- a foamed film layer is used as a mechanical buffer in order to increase the puncture resistance or to compensate to a certain degree for mechanical deformation through the product.
- At least one foamed film layer can also be used for thermal insulation.
- Appropriate approaches are out JP 2001-130586 A . US Pat. No. 6,913,389 B2 . KR 2004-0005806 and KR 2004-0007381 known.
- a foamed film layer in a film can also cause weakening which promotes tearing in a desired manner. Due to the lower density and the free spaces within the at least one foamed film layer, it can be torn relatively easily in its thickness direction. Depending on the specific embodiment, the foaming can also facilitate the layer separation with respect to an adjacent film layer, these properties can be used for the production of tear-open packaging. Moreover, even when the film tears perpendicularly to its thickness, in particular in the case of crack propagation along the production direction, weakening due to foaming ensues.
- a pronounced anisotropy can also be attributed, depending on the production process, to the fact that the pores or cavities formed during foaming are aligned in one production direction so that tearing can be particularly easy along the longitudinal direction of these cavities or pores (ie along the production direction).
- the use of foamed film layers for setting defined Tearing properties is for example in GB 2 110 215 B . US 4,762,230 . U.S. 4,781,294 . EP 673 756 A1 . JP 3823967 and DE 20 2005 002 615 U1 described.
- the foaming of at least one film layer also leads to increased roughness or waviness of the film surface, this effect according to DE 2 038 557 A1 .
- JP 2001- 055242 A and EP 1 237 751 B1 B1 is used as an advantage.
- the ripple or roughness of the surface resulting from the foaming is in many cases also undesirable if, for example, in packaging a surface which is as uniform as possible, smooth and has a high-quality appearance is desired.
- Another effect of a foamed film layer is known from practice that the corresponding film has a higher haze and opacity.
- the use of color particles can also be reduced by providing a non-transparent or translucent film by foaming.
- the increase in opacity and the use of this effect are in the EP 83 167 B1 described.
- foaming can be carried out in particular by a chemical reaction or a physical process.
- substances contained in the polymer melt during extrusion may volatilize or react to form a gas.
- a blowing agent is added in the extruder to the molten plastic mass under high pressure.
- propellants for example, water, nitrogen or carbon dioxide are suitable.
- the foamed layer has a particularly fine-cell foam structure, which can be formed, for example, by the so-called MuCell process.
- Devices for carrying out the process or retrofitting conventional extruders are sold by Drexel Inc., USA.
- the MuCell method is used in particular in US 5,866,053 . US 6 051 174 . EP 923 443 B1 . EP 1 275 485 . EP 377 650 A1 . EP 580 777 B1 . US 6,231,942 . EP 996 536 A2 .
- EP 1 040 158 B2 EP 1 131 387 B1 .
- EP 1 539 868 B1 EP 1 337 387 A1 and EP 1 575 763 B1 described. More particularly, the present invention relates to polyethylene coextruded films in which the foamed core layer is formed according to the described MuCell method.
- a blowing agent is added to the melt for the core layer to be foamed, which causes foaming during the extrusion or immediately after it leaves the extrusion gap.
- the previously added under pressure of the melt blowing agent undergoes a sudden relaxation at the exit from the nozzle gap of the coextrusion.
- the propellant is usually present within the extruder as a supercritical fluid, which combines the incompressibility of a liquid and the solution properties of a gas.
- the blowing agent goes into solution in the polymer melt and forms there distributed a single-phase system with the plastic melt.
- the gas dissolves out of the melt, leaving a very fine, even Foam structure is formed.
- Particles in the core layer can favor the formation of especially many small nucleation nuclei.
- the particles do not serve, or at least not exclusively as a favorable volume material, but are also used as a functional constituent for improving the film properties, namely for the formation of particularly many and small cavities or cells. Nevertheless, the particles can also be referred to as nucleating agents.
- KR 2013-0100597 A and WO 2013/179947 A1 relate to other films or other plastic articles with a foamed layer or their preparation.
- the present invention concretely relates to a plastic multilayer film having a thickness between 20 ⁇ m and 250 ⁇ m comprising a foamed core layer, a first unfoamed, preferably heat-sealable outer layer and a second unfoamed outer layer having a thickness of less than 70 ⁇ m.
- the plastic multilayer film or at least a part of the layers of the plastic multilayer film can in particular be manufactured using the MuCell method described above, wherein blown film extrusion is preferred for simple, cost-efficient production.
- the person skilled in various measures are known to reduce the unevenness of the second unfoamed outer layer.
- the unevenness caused by the underlying core layer can be somewhat equalized, but then the manufacturing cost and the basis weight of the plastic multilayer film disadvantageously increase.
- the still molten film can be introduced into a nip between two rolls or between a roll and a smoothing belt for smoothing.
- the smoothing belt can enclose the associated roller over a larger angular range, so that the film guided therebetween is supported over a correspondingly large area, in which case a smooth surface can be achieved when the two outer layers solidify in the gap.
- a smooth surface can be achieved when the two outer layers solidify in the gap.
- the present invention has for its object to provide a plastic multilayer film, which is easy to manufacture and is characterized by a uniform appearance.
- the object of the invention and the solution of the problem is a plastic multilayer film according to claim 1.
- the second outer layer has a matte surface with a reflectometer according to DIN 67530 at a measuring angle of 85 ° of less than 40.
- the reflectometer value thus determined is less than 30, and more preferably between 10 and 25.
- the present invention is based in this context on the finding that the waviness still present on the second outer layer in the plastic multilayer film according to the invention is surprisingly no longer visible to a user due to the structure of the foamed core layer arranged underneath, if the plastic multilayer film adjoins the second outer layer is very dull. Even though these measures do not reduce the actual unevenness at all or at least do not significantly reduce it, the waviness is no longer visible due to the diffuse refraction of light. Astonishingly, this applies precisely to the structure resulting from foaming, which gives the user the impression of uneven waves or dents in the case of a glossy surface.
- the reflectometer value is usually used for a comparison at a measurement angle of 85 °, although the matte properties are also evident in the measurement angles of 60 ° and 20 ° proposed according to DIN 67530.
- the reflectometer value of the plastic multilayer film according to the invention according to DIN 67530 at a measuring angle of 60 ° is usually less than 30, preferably less than 20 and in particular between 5 and 15.
- the reflectometer value is usually less than 10, preferably less as 5 and in particular between 1 and 3.
- the foamed core layer together with the first unfoamed outer layer and the second unfoamed outer layer are completely coextruded, in which case a corresponding matt plastic material for the second outer layer must be provided already in this coextrusion process.
- the plastic multilayer film thus formed can be subsequently printed only on its two outer layers. Since the plastic multilayer film alone is at least opaque due to the foaming of the core layer independently of the addition of color particles, such an imprint is preferably carried out on the second outer layer. At least if the imprint extends over larger areas, a matt ink should be used, because otherwise the existing wave structure is visible to the user again at the printed areas.
- the second outer layer can also be provided with a coating, for example a thin matt lacquer, in order to achieve the reflectometer value according to the invention.
- the plastic multilayer film is formed by a Kaschierverbund, on the one hand a film comprising the core layer and on the other hand, a film comprising the second outer layer, preferably by adhesive, laminated.
- the core layer with the first outer layer and opposite the first outer layer is co-extruded with an intermediate layer, wherein the coextrusion film thus formed is laminated to the intermediate layer with a cover film which comprises at least the second outer layer.
- the cover film can also be designed as a monofilm so that it exclusively comprises the second outer layer.
- the plastic multilayer film is formed as Kaschierverbund, can be done in a particularly advantageous manner, an internal imprint, so that it is then optimally protected. Since this imprint is then also arranged under the hard surface of the second outer layer, there are no special requirements with regard to the quality and abrasion resistance of such an ink.
- Orientation in the film production means stretching the film after the polymer has cooled, thereby aligning the polymer chains. Since the plastic is no longer molten in the orientation, the chains can no longer realign after stretching and remain in an elongated state corresponding to the elongation ratio.
- the second outer layer may contain as main component preferably polypropylene (PP) or polyester, in particular polyethylene terephthalate (PET).
- PP polypropylene
- PET polyethylene terephthalate
- the second outer layer thus contains at least 50% by weight of PP or PET.
- the second outer layer may consist entirely of polypropylene or polyethylene terephthalate, with the exception of customary fillers and additives, processing aids or the like.
- the materials mentioned are suitable both for coextrusion with the foamed core layer and the first outer layer and for the formation of a separate cover film.
- biaxial orientation is particularly preferred for improving mechanical and optical properties.
- the second outer layer preferably has an average waviness W a in accordance with DIN EN ISO 4287 of more than 2 ⁇ m, in particular more than 4 ⁇ m.
- the average waviness W a is the arithmetic mean of the profile coordinate after the short-wave component (the roughness) has been calculated out by a corresponding filter on a cross section through the surface profile. Accordingly, according to the specified average waviness, the surface of the second outer layer is uneven to a considerable extent, wherein this unevenness is not visible through the mat embodiment according to the invention.
- the cross-sectional structure differs to some extent in the direction of production and in the transverse direction, because the cavities formed by foaming or pores of the core layer are usually elongated in the direction of production.
- the unevenness can therefore be assigned a greater wavelength in a section along the production direction than in the transverse direction, so that a glossy surface on the second outer layer can also result in a user-visible disturbing strip structure. Even such existing strip-like structures are no longer visible due to the present invention matte design.
- the distance between a trough and an adjacent wave tip of a cross-sectional profile between 0.1 mm and 5 mm the height difference between wave trough and wave tip typically between 4 ⁇ m and 20 microns.
- the second outer layer can be made thin, because it optically conceals the wavy structure by the matt configuration and should not compensate as a kind of buffer with variable thickness.
- the thickness of the second unfoamed outer layer is preferably between 15 and 40 ⁇ m.
- the core layer and the first outer layer may in particular be formed on the basis of polyethylene as the main component.
- the coextrusion film is preferably designed in three layers, in which case the foamed core layer is arranged between the first outer layer and an intermediate layer in the coextrusion film, wherein the intermediate layer forms a surface with respect to the coextrusion film alone the cover sheet with the second outer layer is subsequently arranged. It has been found that in such a three-layer structure of the coextrusion film by suitable measures, the ripple still relatively can be kept low, so that then result in connection with the matte design of the second outer layer particularly advantageous optical properties.
- the polymer layer comprises a polyethylene or a mixture based on polyethylene, which has a melt flow rate (MFR) according to DIN EN ISO 1133 of more than 5 g / 10 min at 190 ° C and 2.16 kg.
- MFR melt flow rate
- the melt mass flow rate is used to characterize the flow behavior of a thermoplastic under given pressure and temperature conditions.
- the melt mass flow rate is often used as a comparative figure to characterize the flow properties of various plastics. It is defined according to DIN ISO EN 1133 as the mass of plastic, which flows through a capillary fixed dimension in 10 min at a given temperature and pressure.
- the viscosity of a thermoplastic increases with the chain length of the polymers as well as with the degree of branching, which correspondingly decreases the melt mass flow rate.
- the core layer can be formed, in particular, from particles and the polymer component based on polyethylene and optionally further processing aids, usually with a proportion of less than 10% by weight.
- the entire polymer component based on polyethylene has a melt mass flow rate (MFR) of more than 6 g / 10 min at 190 ° C. and 2.16 kg and is therefore comparatively thin.
- MFR melt mass flow rate
- particles can be very uniform in the core layer at the specified melt mass flow rate in the production after exiting the gap of a coextrusion distributed form small cavities, wherein during the extrusion process after exiting the extrusion die relatively low-viscosity core layer between the first outer layer and the intermediate layer is arranged, whereby the inclusion of the core layer takes place to the outside.
- the first outer layer and the intermediate layer have a low waviness and roughness on the surfaces of the outer layers in comparison to known polyethylene coextrusion films with a foamed core layer.
- the melt mass flow rate the entire polymer component of the core layer is to be used.
- the melt mass flow rate for the corresponding polymer blend must be determined.
- the proportion of the particles in the core layer is usually between 5 and 50 wt .-%, preferably between 10 and 30 wt .-%.
- the first outer layer and the intermediate layer serve in the coextrusion and in the foaming of the core layer as a kind of boundary, which also build up a certain back pressure with regard to the expansion of the core layer.
- the first outer layer and the intermediate layer have a significantly higher viscosity and thus a significantly lower melt mass flow rate according to DIN ISO EN 1133 at 190 ° C and 2.16 kg.
- the melt mass flow rate (MFR) of the two polymer components is preferably below 2 g / 10 min, more preferably below 1 g / 10 min.
- the ratio of the melt mass flow rate of the polymer component of the core layer to the melt mass flow rate of the polymer components of the first outer layer or of the intermediate layer is at least 2.5, preferably at least 3 and particularly preferably at least 6. It is also readily possible within the scope of the invention Ratios of more than 10 can be achieved. The ratio formed in this way makes it clear that the first outer layer and the intermediate layer are significantly more viscous than the core layer. Taking these requirements into consideration, films with a relatively uniform, flat surface could be formed in the course of orienting tests.
- first outer layer and the intermediate layer with a low melt mass flow rate immediately upon extrusion cause an increased counterpressure in the expansion of the core layer
- the comparatively viscous layers through the formation of individual cavities and bubbles in the core layer can be less deformed.
- the first outer layer and the intermediate layer are thus too viscous to be able to be greatly deformed starting from a substantially planar orientation.
- the first heat-sealable outer layer and the intermediate layer may comprise polymer blends having a same or approximately equal melt mass flow rate to effect approximately the same counterpressure in the expansion of the core layer as previously described.
- the first, heat-sealable outer layer has a higher melt mass flow rate than the intermediate layer.
- the first outer layer provided as the sealing layer is often arranged on the inside, so that a certain slight waviness can be tolerated there, while the usually outer intermediate layer should be as smooth as possible.
- the first outer layer may, for example, have a melt mass flow rate of 2 to 3 g / 10 min, while the intermediate layer has a melt mass flow rate of 1 g / 10 min. With such an asymmetric adjustment of the melt mass flow rate, the surface of the intermediate layer can ultimately be made even smoother, since the individual cells spread more strongly in the direction of the first outer layer during the foaming of the core layer and rather lead to unevennesses there.
- the MuCell method described in the introduction is preferably used for foaming the core layer, wherein a microcell structure is produced in the core layer.
- the microcell structure is characterized by a pore structure having an average pore size of less than 100 .mu.m, wherein the pore size can also be in the range between 0.1 .mu.m and 10 .mu.m.
- the volume of the closed cavities of the core layer is a suitable characteristic feature, the volume preferably less than 50000 .mu.m 3 , preferably less than 20,000 .mu.m 3 and for example, less than 5000 microns 3 .
- the core layer has correspondingly closed, nitrogen-filled cavities.
- the degree of foaming can be adjusted by the amount of the blowing agent added, the viscosity of the polymer components of the core layer and the other layers, and the extrusion conditions.
- the core layer has a density between 0.2 g / cm 3 and 0.8 g / cm 3 .
- the increase in thickness of the core layer compared to a non-foamed layer having the same amount of polymer is thus typically between about 20% and 500%, more preferably between about 40% and 200%, most preferably between 50% and 120%.
- the plastic multilayer film according to the invention is distinguished from a completely unfoamed film by a low weight per unit area and thus by a lower use of material, wherein adequate mechanical properties with regard to stiffness and tear strength can be achieved by suitable matching of the layer thicknesses.
- the thickness of the foamed core layer is between 20% and 70% of the total thickness of the entire plastic multilayer film.
- the two outer layers each have a thickness which is between about 15% and 30% of the total thickness of the polyethylene coextrusion film.
- the polymer component of the core layer may contain as a main component a linear polyethylene, including metallocene catalyst derived types. Suitable are linear polyethylenes of high (LHDPE), medium (LMDPE) and low (LLDPE) densities. In principle, all known linear types of polyethylenes, ie alpha-olefin copolymers on the basis of polyethylene into consideration. Preferred are copolymers with hexene (C6) and octene (C8).
- linear low density polyethylene is often advantageous to avoid overly rigid and brittle packaging.
- the polymer component of the core layer is also a mixture which contains in addition to the linear polyethylene, in particular a linear low density polyethylene (LLDPE) at least one further low density polyethylene.
- LLDPE linear low density polyethylene
- LDPE non-linear low density polyethylene
- mLLDPE linear low density polyethylene
- linear polyethylene is provided as the main constituent of the polymer component of the core layer.
- the core layer can be formed, for example, from 10 to 30 wt .-% of fillers including processing aids, 10 to 30% by weight of LDPE or mLLDPE and rest LLDPE.
- At least one of the two outer layers or the optionally provided intermediate layer contains color particles in order to obtain an overall opaque film. It can also be exploited that the core layer is clouded by the foaming at least to a certain extent, so that then the proportion of color particles compared to a non-foamed coextrusion film may optionally be reduced.
- the Fig. 1 shows a plastic multilayer film, which has a total thickness between 20 microns and 250 microns.
- the plastic multilayer film has a foamed core layer 1, a first unfoamed, heat-sealable outer layer 2 and a second unfoamed outer layer 3, which has a thickness of less than 70 ⁇ m and typically between 15 ⁇ m and 40 ⁇ m.
- the foamed core layer has cavities 4, so that the core layer 1 has a strong waviness due to the foaming. Since the two outer layers 2, 3 have a uniform or at least substantially uniform thickness, the waviness of the core layer is also present on the surfaces of the first outer layer 2 and the second outer layer 3.
- the described waviness is not a significant limitation.
- the second outer layer 3 is visibly arranged .
- the surface of the second outer layer is dull. Therefore the second outer layer has a matt surface with a reflectometer value according to DIN 6753 at a measuring angle of 85 ° of less than 40, preferably less than 30 and in particular between 10 and 25.
- the existing, relatively strong ripple is then no longer visible to a viewer as a disturbance.
- the structure shown is preferably formed by coextrusion, wherein then during the extrusion process, the core layer 1 between the first outer layer 2 and the second outer layer 3 is included.
- the Fig. 2 shows a plastic multilayer film in which the core layer 1 is coextruded together with the first outer layer 2 and an intermediate layer 5, wherein then on the intermediate layer, a cover sheet is laminated, which comprises as monofilm only the second outer layer.
- the lamination can be done with adhesive 6, wherein the intermediate layer 5 or the concealed in the plastic multilayer film side of the second outer layer 3 can be provided with a print before lamination, which is then covered in the plastic multilayer film and thus optimally protected.
Landscapes
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
Claims (11)
- Film de plastique multi-couches ayant une épaisseur entre 20 µm et 250 µm comprenant une couche de coeur (1), une première couche extérieure (2) non expansée et une seconde couche extérieure (3) non expansée ayant une épaisseur inférieure à 70 µm, caractérisé en ce que la seconde couche extérieure (3) présente une surface matte avec une valeur de réflectomètre selon DIN 67530 inférieure à 40 pour un angle de mesure de 85°.
- Film de plastique multi-couches selon la revendication 1, caractérisé en ce que la valeur de réflectomètre selon DIN 67530 est inférieure à 30, en particulier entre 10 et 25, pour un angle de mesure de 85°.
- Film de plastique multi-couches selon la revendication 1 ou 2, caractérisé en ce que la couche de coeur (1) est coextrudée avec la première couche extérieure (2) et la seconde couche extérieure (3).
- Film de plastique multi-couches selon la revendication 1 ou 2, caractérisé en ce que la couche de coeur (1) est coextrudée avec la première couche extérieure (2) et, à l'opposé de la première couche extérieure (2), avec une couche intermédiaire (5), dans lequel le film coextrudé ainsi formé est doublé d'une couche de couverture sur la couche intermédiaire, laquelle comprend au moins la seconde couche extérieure (3).
- Film de plastique multi-couches selon la revendication 4, caractérisé par une empreinte placée à l'intérieur.
- Film de plastique multi-couches selon la revendication 4 ou 5, caractérisé en ce que la couche de couverture est orientée biaxialement.
- Film de plastique multi-couches selon l'une des revendications 1 à 6, caractérisé en ce que la seconde couche extérieure (3) contient du polypropylène (PP) en tant que composante principale.
- Film de plastique multi-couches selon l'une des revendications 1 à 6, caractérisé en ce que la seconde couche extérieure (3) contient du polyester, en particulier du polyéthylènetéréphthalate (PET) en tant que composante principale.
- Film de plastique multi-couches selon l'une des revendications 1 à 8, caractérisé en ce que la seconde couche extérieure (3) présente une ondulation Wa moyenne selon DIN EN ISO 4287 supérieure à 2 µm.
- Film de plastique multi-couches selon l'une des revendications 1 à 9, caractérisé en ce que la seconde couche extérieure (3) présente une épaisseur entre 15 µm et 40 µm.
- Film de plastique multi-couches selon l'une des revendications 1 à 10, caractérisé en ce que la couche de coeur (1) et la première couche extérieure (2) sont formées à base de polyéthylène (PE) en tant que composante principale.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
HUE14183261A HUE030040T2 (en) | 2014-09-02 | 2014-09-02 | Multilayer plastic film |
EP14183261.8A EP2803478B1 (fr) | 2014-09-02 | 2014-09-02 | Feuille à plusieurs couches en plastique |
ES14183261.8T ES2586155T3 (es) | 2014-09-02 | 2014-09-02 | Lámina multicapa de plástico |
PL14183261T PL2803478T3 (pl) | 2014-09-02 | 2014-09-02 | Wielowarstwowa folia z tworzywa sztucznego |
US14/809,738 US20160059514A1 (en) | 2014-09-02 | 2015-07-27 | Plastic film laminate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14183261.8A EP2803478B1 (fr) | 2014-09-02 | 2014-09-02 | Feuille à plusieurs couches en plastique |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2803478A2 EP2803478A2 (fr) | 2014-11-19 |
EP2803478A3 EP2803478A3 (fr) | 2015-04-22 |
EP2803478B1 true EP2803478B1 (fr) | 2016-06-29 |
Family
ID=51453669
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP14183261.8A Active EP2803478B1 (fr) | 2014-09-02 | 2014-09-02 | Feuille à plusieurs couches en plastique |
Country Status (5)
Country | Link |
---|---|
US (1) | US20160059514A1 (fr) |
EP (1) | EP2803478B1 (fr) |
ES (1) | ES2586155T3 (fr) |
HU (1) | HUE030040T2 (fr) |
PL (1) | PL2803478T3 (fr) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016049049A1 (fr) | 2014-09-23 | 2016-03-31 | Dart Container Corporation | Récipient isolé et procédés de fabrication et d'assemblage |
DK3473674T3 (da) * | 2017-10-19 | 2022-06-20 | Abu Dhabi Polymers Co Ltd Borouge Llc | Polypropylensammensætning |
US20200156293A1 (en) * | 2018-11-16 | 2020-05-21 | Mucell Extrusion, Llc | Anisotropic thin foamed polyethylene sheet and applications thereof |
DE202019106036U1 (de) * | 2019-10-30 | 2019-12-02 | Vibracoustic Ag | Lagerstrukturbauteil |
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2014
- 2014-09-02 EP EP14183261.8A patent/EP2803478B1/fr active Active
- 2014-09-02 PL PL14183261T patent/PL2803478T3/pl unknown
- 2014-09-02 HU HUE14183261A patent/HUE030040T2/en unknown
- 2014-09-02 ES ES14183261.8T patent/ES2586155T3/es active Active
-
2015
- 2015-07-27 US US14/809,738 patent/US20160059514A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
ES2586155T3 (es) | 2016-10-11 |
PL2803478T3 (pl) | 2017-02-28 |
HUE030040T2 (en) | 2017-04-28 |
EP2803478A3 (fr) | 2015-04-22 |
EP2803478A2 (fr) | 2014-11-19 |
US20160059514A1 (en) | 2016-03-03 |
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