EP2621695A1 - Holzverbundwerkstoff - Google Patents
HolzverbundwerkstoffInfo
- Publication number
- EP2621695A1 EP2621695A1 EP11771058.2A EP11771058A EP2621695A1 EP 2621695 A1 EP2621695 A1 EP 2621695A1 EP 11771058 A EP11771058 A EP 11771058A EP 2621695 A1 EP2621695 A1 EP 2621695A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- binder
- wood composite
- composite material
- wood
- foaming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002023 wood Substances 0.000 title claims abstract description 83
- 239000002131 composite material Substances 0.000 title claims abstract description 45
- 239000011230 binding agent Substances 0.000 claims abstract description 49
- 239000006260 foam Substances 0.000 claims abstract description 23
- 238000013001 point bending Methods 0.000 claims abstract description 4
- 238000012360 testing method Methods 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 27
- 239000000835 fiber Substances 0.000 claims description 19
- 230000008961 swelling Effects 0.000 claims description 19
- 238000005187 foaming Methods 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 238000009415 formwork Methods 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 239000004814 polyurethane Substances 0.000 claims description 8
- 229920002635 polyurethane Polymers 0.000 claims description 8
- 238000010276 construction Methods 0.000 claims description 5
- 239000011148 porous material Substances 0.000 claims description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- 230000001681 protective effect Effects 0.000 claims description 2
- 238000009416 shuttering Methods 0.000 claims description 2
- 239000000969 carrier Substances 0.000 claims 1
- 238000010924 continuous production Methods 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- 239000000463 material Substances 0.000 description 32
- 230000008901 benefit Effects 0.000 description 15
- 239000007787 solid Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 230000003068 static effect Effects 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000011093 chipboard Substances 0.000 description 3
- 238000005056 compaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 229920000877 Melamine resin Polymers 0.000 description 2
- 241000218657 Picea Species 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000011094 fiberboard Substances 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000011120 plywood Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- ZEYUSQVGRCPBPG-UHFFFAOYSA-N 4,5-dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one Chemical compound OCN1C(O)C(O)N(CO)C1=O ZEYUSQVGRCPBPG-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 240000007182 Ochroma pyramidale Species 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000021736 acetylation Effects 0.000 description 1
- 238000006640 acetylation reaction Methods 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- -1 veneer Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/005—Manufacture of substantially flat articles, e.g. boards, from particles or fibres and foam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/04—Manufacture of substantially flat articles, e.g. boards, from particles or fibres from fibres
Definitions
- the present invention relates to a
- Wood composite material which is suitable for the production of supporting elements, and a method for its production.
- Material characteristic Materials with low density and nevertheless sufficiently high strength and stiffness offer advantages over materials with the same mechanical properties but higher density due to their lower deflection caused by their own weight.
- middle layer leads the lack of shear stiffness under bending loads to high deformations.
- most of the strength properties are insufficient for use as a support element.
- Wood composites made of macrofibres and a
- Binders consist, the strands, particles or fibers applied with binder and subsequently by a
- Conventional board materials such as chip and fiber board, OSB, etc. as well as the special wood materials such as squeeze, scrimber, TimTek, Srimtec, SST, etc. therefore have a more or less pronounced density profile over the board thickness.
- the entire material is highly compressed or it is very low density board materials ⁇ eg wood wool light plate, low density fiberboard, etc. ⁇ , which can not be compared with materials for supporting purposes in terms of their low strength values.
- the wood components of conventional board materials as well as the special wood materials such as squeeze, scrimber, TimTek, Srimtec, SST, etc. are significantly compressed in the production.
- the macrofibers and / or the binder must have sufficient (residual) moisture. Without the so-called
- Wood-based material on the market which combines a low density with a well-suited for support elements rigidity and in its manufacture, the disadvantages of
- Wood composite material having a density of 200- 550 kg / m 3 and a stiffness measured in the 4-point bending test according to EN 789 of 4,000-12,000 MPa, wherein the wood composite macrofibers with a
- Slimming ratio ratio of length to thickness of the fibers
- a binder comprises, and the
- Binder has a foam structure.
- the wood composite according to the invention has a density of 200-550 kg / m 3 , preferably 300-550 kg / m 3 .
- the stiffness measured in the 4-point bending test according to EN 789 is 4,000-12,000 MPa, preferably 5,000-12,000 MPa, particularly preferably 6,000-12,000 MPa. In a particularly preferred
- the wood composite material has a density of 300-550 kg / m 3 and a rigidity of 6,000-12,000 MPa.
- the wood composite according to the invention comprises macrofibres made of wood with a degree of slimming (ratio of length to thickness of the fibers) greater than 20.
- the macrofibers used have a length of 100-400 mm, more preferably 150-300 mm. It is obvious to the person skilled in the art that it can not be ruled out in terms of production technology that the fibers used always comprise a certain proportion of shorter fibers.
- the wood composite according to the invention further comprises a binder, which has a foam structure in the cured state.
- the binder preferably has a predominantly fine-pored foam structure.
- the binder has a foam structure in such a way that 90-95% of the pores have a pore size in the range of 30-500 ⁇ , preferably 50-300 ⁇ , measured by means of a microscope at a section through the material.
- Wood composite according to the invention a binder used, which forms a foam having a density of 30-300 kg / m 3 , preferably 80-200 kg / m 3 , with free foaming.
- the density of the free-foamed binder can be calculated from the previously determined volume and weight of the vessel and the weight of the foam-filled vessel.
- a binder which forms a closed-cell foam structure. Since the fiber in the wood composite according to the invention are almost completely sheathed by the foam and almost all voids between the fibers are foam-filled, a closed-pore structure of the foam becomes the
- the wood composite material according to the invention thus has a significantly lower swelling on exposure to moisture in comparison to conventional wood-based materials. This is in the range of solid wood or even lower, while conventional wood-based materials usually have a relation to the swelling of the raw wood used significantly increased swelling.
- thickness swelling dimensions according to DIN 52364 between 2.7% and 6% can be achieved, according to EN 317 between 1.5 and 5%.
- the spring size for solid spruce according to DIN 52364 is in
- the macro fibers used may be modified by suitable measures before further processing.
- suitable measures are, for example, acetylation or impregnation with suitable resins or chemicals such as melamine resin or DMDHEU, thermal modification or other known swell-compensating measures.
- Macrofibers are very easily impregnated. In contrast, the modification of solid wood fails in many cases due to the lack of impregnability of the wood.
- Macrofibers compared to solid wood as an advantage, as it captures the heat faster the entire wood.
- the thermal treatment required for such a modification can advantageously be integrated partially or even completely into the subsequent process of producing the wood composite material according to the invention.
- binder according to the invention is preferred
- polymer-based binder used.
- epoxy resin epoxy resin, isocyanate (including polyurethane),
- Melamine, urea, phenolic foams or mixtures thereof can be used. Particularly preferred is a
- Polyurethane system used, such. an on or
- multi-component polyurethane system in particular a
- the wood composite material according to the invention also contains particles that can be excited by fields, such as iron oxide particles.
- a field eg by induction, microwave, radio frequency, radiation, etc.
- the particles may be useful before preparing the
- Wood composite material are introduced into the binder, but they can also be used separately.
- Initiation or acceleration of the foaming and curing process of the binder can be used.
- the wood composite according to the invention can also have a wood composite with a wood composite with a wood composite with a wood composite according to the invention.
- suitable additives e.g. Foaming agents, fillers,
- Binders are added or introduced separately into the material. Such additives can be found in the
- wood composite material special properties such as greater hardness or shear resistance
- the wood composite according to the invention can be obtained by means of a process comprising the following steps: a) producing macro fibers;
- the binder is applied to the aligned macrofibers (sequence of steps: a, b, c, d and e).
- the binder may also be applied prior to aligning the macrofibre (sequence of steps: a, c, b, d and e).
- the method may advantageously be continuously, e.g. be carried out by means of a belt press.
- the macrofibers are dried and oriented substantially uniaxially (i.e., in parallel) on press sheets or dies.
- the binder is applied between and / or on the aligned macrofibers.
- the application of the binder can be carried out by methods established in the wood industry, e.g.
- the foaming time of the binder is so
- the binder system is chemically adjusted so that the start time for foaming is delayed such that the press or
- Press mold can be closed before it becomes one
- Macrofibers preferably only minimally compressed, so that the density of the wood composite material produced not
- Macrofibers are thus surrounded by a binder matrix and are thus well protected against moisture absorption.
- Polyurethane system as a binder, the advantage that only insignificantly heat must be supplied to start the cure.
- the necessary heat can already be obtained by slight preheating of the macrofibers ⁇ e.g. to 30-90 ° C, preferably 50 ° C) are introduced.
- Wood composite material the plates are not destroyed in contrast to conventional wood-based panels by so-called splitter. Due to a possible post-hardening, the wood composite material according to the invention merely causes attrition.
- the wood composite according to the invention is for everyone
- Suitable products made of solid wood or wood-based materials such as chipboard or OSB etc. Due to the lower density of the use of the wood composite material according to the invention leads to a lower weight of the products thus produced.
- Formwork products such as formwork beams, or parts thereof, such as belt or web,
- Wooden boards and furniture boards are Wooden boards and furniture boards (advantage: properties such as plywood in terms of statics, swelling,
- Macrofibers are dried by a warm (50 ° C) air stream and several days in a room climate of 20 ° C and 65% rel. Humidity stored, resulting in a
- Macrofibers are oriented as exactly as possible parallel to each other. 50% of the fibers are placed in an aluminum mold (30 ⁇ 12 cm) heated to 50 ° C. and mixed with 60 g of two components of polyurethane (from RAMPF No. 80 L86 / 4-1)
- the remaining 50% of the fibers are placed in the mold and the mold is closed, so that the inserted macrofibres are compressed to a height of 16 mm. Due to the chemical reaction of the two components of the polyurethane with the water available in the wood foams this strong. After 30 min. the foam is completely cured and the wood composite material can be removed from the mold.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Laminated Bodies (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL11771058T PL2621695T3 (pl) | 2010-10-01 | 2011-09-30 | Sposób wytwarzania drzewnego materiału kompozytowego i drzewny materiał kompozytowy |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102010047254.9A DE102010047254B4 (de) | 2010-10-01 | 2010-10-01 | Holzverbundwerkstoff |
PCT/EP2011/067133 WO2012042027A1 (de) | 2010-10-01 | 2011-09-30 | Holzverbundwerkstoff |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2621695A1 true EP2621695A1 (de) | 2013-08-07 |
EP2621695B1 EP2621695B1 (de) | 2018-01-03 |
Family
ID=44906023
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP11771058.2A Active EP2621695B1 (de) | 2010-10-01 | 2011-09-30 | Verfahren zur herstellung eines holzverbundwerkstoffs und holzverbundwerkstoff |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP2621695B1 (de) |
JP (1) | JP5997696B2 (de) |
KR (1) | KR101500925B1 (de) |
CN (1) | CN103153562B (de) |
BR (1) | BR112013007793A2 (de) |
DE (1) | DE102010047254B4 (de) |
ES (1) | ES2663007T3 (de) |
NO (1) | NO2621695T3 (de) |
PL (1) | PL2621695T3 (de) |
RU (1) | RU2541652C2 (de) |
WO (1) | WO2012042027A1 (de) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109702845B (zh) * | 2018-11-29 | 2022-03-29 | 南京林业大学 | 一种低密度无胶秸秆板、制备方法及其应用 |
EP4286123A1 (de) | 2022-05-30 | 2023-12-06 | ETH Zurich | Holzmaterialien auf stabbasis |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1118221A (en) * | 1965-09-16 | 1968-06-26 | Monsanto Chemicals | Composite materials |
US3671377A (en) * | 1970-07-29 | 1972-06-20 | Alan A Marra | Rigid composite products and process for the preparation thereof |
US4548861A (en) * | 1983-09-29 | 1985-10-22 | The Boeing Company | Foam rigidizing process and products produced therewith |
JPS61266203A (ja) * | 1985-05-20 | 1986-11-25 | Maruyoshi Ando Kk | 配向性積層木材の製造方法 |
DK171314B1 (da) * | 1990-09-21 | 1996-09-02 | Ejvind Sand Djernaes | Fremgangsmåde og anlæg til fremstilling af fast plademateriale af halm eller tilsvarende råmateriale |
RU2017599C1 (ru) * | 1991-06-27 | 1994-08-15 | Белорусский технологический институт им.С.М.Кирова | Способ изготовления древесностружечных плит |
CA2172154A1 (en) * | 1994-07-19 | 1996-02-01 | Hubert Geltinger | Process for producing interior trims for transport means and interior trims thus produced |
US20030125458A1 (en) * | 1995-07-17 | 2003-07-03 | Lothar Thiele | Process for producing cellulose/plastic composites and product of the process |
DE19526032A1 (de) | 1995-07-17 | 1997-02-20 | Henkel Kgaa | Polymerholz-Formkörper, ihre Herstellung und Verwendung |
US6197424B1 (en) * | 1998-03-27 | 2001-03-06 | Siemens Westinghouse Power Corporation | Use of high temperature insulation for ceramic matrix composites in gas turbines |
JP2000071216A (ja) * | 1998-08-27 | 2000-03-07 | Sekisui Chem Co Ltd | 木質材料及びその製造方法 |
JP2000280208A (ja) | 1999-03-29 | 2000-10-10 | Yamaha Corp | 木質繊維板及びその製造法 |
JP2000351106A (ja) * | 1999-06-10 | 2000-12-19 | Yamaha Corp | 木質材の製造法 |
US7670518B2 (en) * | 2000-11-23 | 2010-03-02 | Hi-Tech Engineering Limited | Composite products |
CN2595565Y (zh) * | 2002-10-28 | 2003-12-31 | 南京林业大学 | 杨木基复合板 |
EP1631532A2 (de) * | 2003-06-20 | 2006-03-08 | James Hardie International Finance B.V. | Dauerhafter bauartikel und herstellungsverfahren dafür |
JP2005075694A (ja) * | 2003-09-02 | 2005-03-24 | Ibiken Kk | ウッドセラミックス断熱材及びその製造方法 |
US8455574B2 (en) * | 2004-02-19 | 2013-06-04 | E I Du Pont De Nemours And Company | Composite compositions comprising cellulose and polymeric components |
DE102004019529A1 (de) * | 2004-04-22 | 2005-11-10 | Henkel Kgaa | Verfahren zur Herstellung von Formkörpern auf Basis von Polyurethan-Bindemitteln und cellulosehaltigem Material |
KR100588449B1 (ko) * | 2004-10-18 | 2006-06-14 | 주식회사 대성아이디 | 우드칩 포장재 |
CN1861341A (zh) * | 2006-06-12 | 2006-11-15 | 中林南星(湖州)合板有限公司 | 速生树种材制造的高强度高弹性木质复合材料的方法 |
CN101116994A (zh) * | 2006-07-31 | 2008-02-06 | 于传敏 | 一种新型草木复合管材的制备方法 |
CN101042018A (zh) * | 2007-04-10 | 2007-09-26 | 南京工业大学 | 一种复合材料模板 |
-
2010
- 2010-10-01 DE DE102010047254.9A patent/DE102010047254B4/de active Active
-
2011
- 2011-09-30 BR BR112013007793A patent/BR112013007793A2/pt not_active Application Discontinuation
- 2011-09-30 PL PL11771058T patent/PL2621695T3/pl unknown
- 2011-09-30 KR KR1020137009964A patent/KR101500925B1/ko active IP Right Grant
- 2011-09-30 RU RU2013120352/13A patent/RU2541652C2/ru active
- 2011-09-30 CN CN201180047233.1A patent/CN103153562B/zh active Active
- 2011-09-30 JP JP2013530755A patent/JP5997696B2/ja active Active
- 2011-09-30 EP EP11771058.2A patent/EP2621695B1/de active Active
- 2011-09-30 ES ES11771058.2T patent/ES2663007T3/es active Active
- 2011-09-30 WO PCT/EP2011/067133 patent/WO2012042027A1/de active Application Filing
- 2011-09-30 NO NO11771058A patent/NO2621695T3/no unknown
Non-Patent Citations (1)
Title |
---|
See references of WO2012042027A1 * |
Also Published As
Publication number | Publication date |
---|---|
ES2663007T3 (es) | 2018-04-10 |
CN103153562B (zh) | 2016-03-09 |
WO2012042027A1 (de) | 2012-04-05 |
RU2013120352A (ru) | 2014-11-20 |
DE102010047254A1 (de) | 2012-04-05 |
EP2621695B1 (de) | 2018-01-03 |
JP2013541444A (ja) | 2013-11-14 |
DE102010047254B4 (de) | 2017-02-02 |
RU2541652C2 (ru) | 2015-02-20 |
KR101500925B1 (ko) | 2015-03-10 |
CN103153562A (zh) | 2013-06-12 |
BR112013007793A2 (pt) | 2016-06-07 |
KR20130088157A (ko) | 2013-08-07 |
PL2621695T3 (pl) | 2018-04-30 |
NO2621695T3 (de) | 2018-06-02 |
JP5997696B2 (ja) | 2016-09-28 |
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