EP2480631A1 - Verfahren zum betrieb einer koksofenanordnung - Google Patents
Verfahren zum betrieb einer koksofenanordnungInfo
- Publication number
- EP2480631A1 EP2480631A1 EP10742854A EP10742854A EP2480631A1 EP 2480631 A1 EP2480631 A1 EP 2480631A1 EP 10742854 A EP10742854 A EP 10742854A EP 10742854 A EP10742854 A EP 10742854A EP 2480631 A1 EP2480631 A1 EP 2480631A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- gas
- coke oven
- synthesis gas
- synthesis
- generated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B21/00—Heating of coke ovens with combustible gases
- C10B21/02—Heating of coke ovens with combustible gases with lean gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/24—Hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/108—Hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
- C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/048—Composition of the impurity the impurity being an organic compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
- C10J2300/1618—Modification of synthesis gas composition, e.g. to meet some criteria
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1643—Conversion of synthesis gas to energy
- C10J2300/165—Conversion of synthesis gas to energy integrated with a gas turbine or gas motor
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1671—Integration of gasification processes with another plant or parts within the plant with the production of electricity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
Definitions
- the invention relates to a method for operating a coke oven arrangement, wherein the coke oven gas occurring in the coking process is supplied as useful gas to a material utilization.
- the coke oven gas obtained in a coking process is usually burned and thus only used energetically, although coke oven gas contains large amounts of the valuable components hydrogen and methane. Reservations against use result from the fact that coke oven gas is no longer available as fuel gas in case of material use and the lack of heating energy has to be provided elsewhere.
- the present invention has for its object to allow for the operation of a coke oven assembly, a flexible and efficient use of the resulting Koksofengases.
- the object of the invention and solution of the problem is a method for operating a coke oven arrangement with the features described above, which is characterized in that for providing at least a portion of the required for the coking process thermal energy as fuel gas, a synthesis gas is supplied, which by means of a gasification process fossil fuel is generated.
- a synthesis gas is supplied, which by means of a gasification process fossil fuel is generated.
- the use of a fossil fuel to produce the synthesis gas results in a particularly high flexibility of the method for operating a coke oven arrangement.
- the provision of the fossil fuel and the implementation of the gasification process for producing the synthesis gas are associated with additional investment and process costs, the recovery of the valuable components contained in the coke oven gas results in overall economic advantages. This is particularly the case when coal is used as the fossil fuel, which is comparatively cheap compared to other fossil fuels suitable for carrying out the gasification process, such as natural gas, and which is already available for carrying out the coking process.
- inventive method can thus be used independently of other production cities such as coal mines or blast furnaces.
- a blast furnace system is provided in the immediate vicinity, it is also possible to supply an additional portion of the generated synthesis gas for thermal utilization to a blast furnace.
- the process for the coking process and possibly also a blast furnace missing amount of energy by means of Gasification from the fossil fuel produced synthesis gas is replaced.
- the raw synthesis gas produced usually only needs to be desulphurized before it is supplied as a fuel gas to provide a portion of the thermal energy required for the coking process and used in particular for undercutting coke oven batteries.
- the synthesis gas formed from the fossil fuel can be provided to use the synthesis gas formed from the fossil fuel exclusively for the provision of thermal energy as fuel gas. According to a preferred embodiment of the invention, however, more synthesis gas is generated than is necessary for the replacement of the inventively recycled Koksofengases. Thus, it can be provided that a first portion of the synthesis gas produced is used as fuel gas and that an additional portion of the synthesis gas generated is used for further conversion and material utilization.
- the coke oven gas obtained in the coking process is first freed in a manner known per se from impurities such as tar, naphthalene, aromatic hydrocarbons (BTX components), sulfur and ammonia, as in the prior art in a conventional coking process is provided.
- the previously purified coke oven gas for the separation of hydrogen and / or hydrocarbons is compressed.
- a pressure swing adsorption (PSA) can be provided in a PSA plant, wherein the hydrogen is recovered on the pressure side of the PSA plant in highly pure form.
- PSA pressure swing adsorption
- the pressure swing absorption can be carried out both in a conventional PSA plant or a vacuum PSA plant (VPSA plant).
- a methane-rich gas is recovered, which is separated in further treatment steps of the remaining gas components, in particular carbon monoxide (CO), carbon dioxide (CO 2 ), nitrogen, acetylene and hydrogen still containing.
- the removal of nitrogen, carbon monoxide and hydrogen still contained can be carried out for example by a cryogenic distillation, with previously carbon dioxide and steam with suitable methods, eg. B. by means of an Armin wash and / or a molecular sieve drying are to be removed.
- the hydrocarbon components thus obtained as useful gas can be supplied to a natural gas network and / or kept ready for further synthesis.
- the gas components obtained from the coking gas can be used as end products or in even higher quality products be converted, for further synthesis and conversion and a proportion of the synthesis gas formed in the gasification of the fossil fuel can be used.
- Advantageous possibilities of use are explained below.
- the separated hydrogen can generally be used as hydrogenating hydrogen in adjacent chemical plants, for example refineries. According to a preferred embodiment, it is provided to subject the hydrogen produced and a portion of the synthesis gas formed by the gasification of the fossil fuel to further conversion, the hydrogen being reacted with a portion of the carbon monoxide of the synthesis gas to give higher-value products.
- a synthesis of methanol and beyond the production of fuel by an MTG process methanol to gasoline
- the synthesis of diesel by a Fischer-Tropsch process or the synthesis of ammonia can be provided.
- the use of the recovered hydrogen with the synthesis gas obtained from the fossil fuel, which essentially comprises carbon monoxide is provided for a further synthesis, there is the advantage that a specific hydrogen / carbon monoxide ratio is released by a corresponding inflow control in a wide range can be chosen.
- a proportion of the synthesis gas produced to undergo CO conversion can be made for a proportion of the synthesis gas produced to undergo CO conversion.
- the CO conversion can be carried out with the addition of water vapor, after a desulfurization of the converted synthesis gas carbon-
- this thermally recovered off-gas is a proportion of the total required to provide the thermal energy fuel gas.
- part of the thermal energy required for the coking process is provided by a synthesis gas as fuel gas, which is obtained by means of a gasification process from the fossil fuel, preferably by coal gasification.
- a synthesis gas as fuel gas obtained by means of a gasification process from the fossil fuel, preferably by coal gasification.
- the residual and exhaust gases produced in various subsequent process stages can also be used for combustion.
- the off-gas of the preferably provided PSA plant usually still contains large amounts of combustible components that can be thermally recycled by combustion.
- high-quality fuels with a higher calorific value, such as natural gas can also be admixed. Such admixture may be required to set a desired Wobbe number or to balance an energy requirement not yet covered by the other fuel gases.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Industrial Gases (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009042520A DE102009042520A1 (de) | 2009-09-22 | 2009-09-22 | Verfahren zum Betrieb einer Koksofenanordnung |
PCT/EP2010/062024 WO2011035993A1 (de) | 2009-09-22 | 2010-08-18 | Verfahren zum betrieb einer koksofenanordnung |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2480631A1 true EP2480631A1 (de) | 2012-08-01 |
Family
ID=43027473
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10742854A Withdrawn EP2480631A1 (de) | 2009-09-22 | 2010-08-18 | Verfahren zum betrieb einer koksofenanordnung |
Country Status (12)
Country | Link |
---|---|
US (1) | US20120217148A1 (zh) |
EP (1) | EP2480631A1 (zh) |
JP (1) | JP2013505342A (zh) |
KR (1) | KR20120074294A (zh) |
CN (1) | CN102639675A (zh) |
AU (1) | AU2010297521A1 (zh) |
CA (1) | CA2774898A1 (zh) |
DE (1) | DE102009042520A1 (zh) |
IN (1) | IN2012DN03166A (zh) |
RU (1) | RU2533149C2 (zh) |
TW (1) | TW201118161A (zh) |
WO (1) | WO2011035993A1 (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130153395A1 (en) * | 2010-02-05 | 2013-06-20 | The Texas A&M University System | Devices and Methods for a Pyrolysis and Gasification System for Biomass Feedstock |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR350020A (fr) * | 1904-06-25 | 1905-08-24 | Paul Leon Hulin | Récupération de gaz de houille dans la fabrication du coke métallurgique |
US1375477A (en) * | 1919-08-25 | 1921-04-19 | Koppers Co Inc | Ammonia and tar recovery process |
US1838294A (en) * | 1926-06-12 | 1931-12-29 | Koppers Co Inc | Coke oven battery |
SU23906A1 (ru) * | 1927-08-27 | 1931-10-31 | Коппе и Ко Эванс | Регенеративна коксовальна печь |
DE2659782B2 (de) * | 1976-12-31 | 1979-06-21 | Didier Engineering Gmbh, 4300 Essen | Verfahren zur Weiterverarbeitung von Koksofengas |
DE2733785A1 (de) * | 1977-07-27 | 1979-02-08 | Didier Eng | Verfahren zur weiterverarbeitung von koksofengas |
DE3308304A1 (de) * | 1983-03-09 | 1984-09-13 | Didier Engineering Gmbh, 4300 Essen | Verfahren zur erzeugung von erdgasersatzgas |
DE3308305A1 (de) * | 1983-03-09 | 1984-09-13 | Didier Engineering Gmbh, 4300 Essen | Verfahren zur erzeugung von wasserstoff |
DE3424424A1 (de) | 1984-07-03 | 1986-01-16 | Didier Engineering Gmbh, 4300 Essen | Verfahren zur nutzung von koksofengas |
DE3515250A1 (de) | 1985-04-27 | 1986-10-30 | Hoesch Ag, 4600 Dortmund | Verfahren zur herstellung von chemierohstoffen aus koksofengas und huettengasen |
DE3805397A1 (de) | 1988-02-20 | 1989-08-24 | Ruhrkohle Ag | Verfahren zur herstellung von fuel-methanol (treibstoff) aus koksofengas und huettengas |
US5423891A (en) * | 1993-05-06 | 1995-06-13 | Taylor; Robert A. | Method for direct gasification of solid waste materials |
JP4224240B2 (ja) * | 2002-02-07 | 2009-02-12 | 株式会社荏原製作所 | 液体燃料合成システム |
JP4337354B2 (ja) * | 2003-01-23 | 2009-09-30 | Jfeスチール株式会社 | 製鉄所副生ガスの利用方法 |
WO2004101829A2 (en) * | 2003-05-15 | 2004-11-25 | Hylsa, S.A. De C.V. | Method and apparatus for improved use of primary energy sources in integrated steel plants |
DE112005001881T5 (de) * | 2004-08-03 | 2007-06-21 | Hylsa S.A. De C.V., Monterrey | Verfahren und Vorrichtung zum Herstellen von reinen reduzierenden Gasen aus Koksofengas |
EP1984097A4 (en) * | 2005-06-15 | 2009-08-26 | Questair Technologies Inc | ADSORPTION MASS SEPARATION FOR GAS FLOW VALUATION |
US20070072949A1 (en) * | 2005-09-28 | 2007-03-29 | General Electric Company | Methods and apparatus for hydrogen gas production |
CN1974732A (zh) * | 2006-12-13 | 2007-06-06 | 太原理工大学 | 气化煤气和热解煤气共制合成气工艺 |
DE102007042502B4 (de) * | 2007-09-07 | 2012-12-06 | Uhde Gmbh | Vorrichtung zur Zuführung von Verbrennungsluft oder verkokungsbeeinflussenden Gasen in den oberen Bereich von Verkokungsöfen |
DE102008012735B4 (de) * | 2008-03-05 | 2013-05-08 | Thyssenkrupp Uhde Gmbh | Verfahren und Vorrichtung zur Abscheidung von Fremdgasen aus einem reduzierenden Nutzgas durch dampfbetriebene Druckwechseladsorption |
CN101343580A (zh) * | 2008-08-22 | 2009-01-14 | 四川天一科技股份有限公司 | 一种以焦炉气和高炉气制取甲醇合成气的方法 |
US8287696B2 (en) * | 2008-09-05 | 2012-10-16 | Purdue Research Foundation | Multipurpose coke plant for synthetic fuel production |
CN101538483B (zh) * | 2009-04-03 | 2013-04-17 | 中国科学院山西煤炭化学研究所 | 一种利用煤制气和焦炉气为原料多联产的工艺 |
DE102009022509B4 (de) * | 2009-05-25 | 2015-03-12 | Thyssenkrupp Industrial Solutions Ag | Verfahren zur Herstellung von Synthesegas |
DE102010013279B3 (de) * | 2010-03-29 | 2011-07-28 | Uhde GmbH, 44141 | Verfahren und Vorrichtung zur Verarbeitung eines kohlendioxidreichen Sauergases in einem Claus-Prozess |
-
2009
- 2009-09-22 DE DE102009042520A patent/DE102009042520A1/de not_active Withdrawn
-
2010
- 2010-08-18 WO PCT/EP2010/062024 patent/WO2011035993A1/de active Application Filing
- 2010-08-18 CA CA2774898A patent/CA2774898A1/en not_active Abandoned
- 2010-08-18 EP EP10742854A patent/EP2480631A1/de not_active Withdrawn
- 2010-08-18 JP JP2012530196A patent/JP2013505342A/ja active Pending
- 2010-08-18 US US13/497,361 patent/US20120217148A1/en not_active Abandoned
- 2010-08-18 KR KR1020127010109A patent/KR20120074294A/ko not_active Application Discontinuation
- 2010-08-18 AU AU2010297521A patent/AU2010297521A1/en not_active Abandoned
- 2010-08-18 RU RU2012116149/05A patent/RU2533149C2/ru not_active IP Right Cessation
- 2010-08-18 CN CN2010800505839A patent/CN102639675A/zh active Pending
- 2010-09-21 TW TW099132072A patent/TW201118161A/zh unknown
-
2012
- 2012-04-12 IN IN3166DEN2012 patent/IN2012DN03166A/en unknown
Non-Patent Citations (1)
Title |
---|
See references of WO2011035993A1 * |
Also Published As
Publication number | Publication date |
---|---|
KR20120074294A (ko) | 2012-07-05 |
CN102639675A (zh) | 2012-08-15 |
WO2011035993A1 (de) | 2011-03-31 |
JP2013505342A (ja) | 2013-02-14 |
CA2774898A1 (en) | 2011-03-31 |
TW201118161A (en) | 2011-06-01 |
IN2012DN03166A (zh) | 2015-09-18 |
RU2533149C2 (ru) | 2014-11-20 |
US20120217148A1 (en) | 2012-08-30 |
AU2010297521A1 (en) | 2012-05-03 |
DE102009042520A1 (de) | 2011-03-24 |
RU2012116149A (ru) | 2013-10-27 |
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