EP2240621A1 - Anlage zur gehärteten galvanisierung eines stahlbands - Google Patents

Anlage zur gehärteten galvanisierung eines stahlbands

Info

Publication number
EP2240621A1
EP2240621A1 EP08761864A EP08761864A EP2240621A1 EP 2240621 A1 EP2240621 A1 EP 2240621A1 EP 08761864 A EP08761864 A EP 08761864A EP 08761864 A EP08761864 A EP 08761864A EP 2240621 A1 EP2240621 A1 EP 2240621A1
Authority
EP
European Patent Office
Prior art keywords
zone
liquid mixture
installation according
preparation device
coating tank
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP08761864A
Other languages
English (en)
French (fr)
Inventor
Stéphane Barjon
Benjamin Grenier
Arnaud Halluin
Laurent Cloutot
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clecim SAS
Original Assignee
Siemens VAI Metals Technologies SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens VAI Metals Technologies SAS filed Critical Siemens VAI Metals Technologies SAS
Publication of EP2240621A1 publication Critical patent/EP2240621A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/003Apparatus
    • C23C2/0034Details related to elements immersed in bath
    • C23C2/00342Moving elements, e.g. pumps or mixers
    • C23C2/00344Means for moving substrates, e.g. immersed rollers or immersed bearings
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/003Apparatus
    • C23C2/0038Apparatus characterised by the pre-treatment chambers located immediately upstream of the bath or occurring locally before the dipping process
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/14Removing excess of molten coatings; Controlling or regulating the coating thickness
    • C23C2/16Removing excess of molten coatings; Controlling or regulating the coating thickness using fluids under pressure, e.g. air knives
    • C23C2/18Removing excess of molten coatings from elongated material
    • C23C2/20Strips; Plates

Definitions

  • the present invention relates to a dip galvanizing installation of a steel strip according to the preamble of claim 1.
  • the dipping galvanization of continuously rolling laminated steel strips is a known technique which essentially comprises two variants, that in which the strip emerging from a galvanizing furnace slopes obliquely into a bath of liquid metal comprising at least one metal adapted to the galvanizing such as zinc, aluminum, and is then deflected vertically and upward by a roll immersed in said bath of liquid metal.
  • the other alternative is to deflect the strip vertically and upward from its exit from the oven and then to scroll through a vertical channel containing magnetically levitated liquid zinc.
  • the liquid metal bath is a zinc alloy with varying proportions of aluminum or magnesium or manganese. For the sake of clarity, only the case of a zinc and aluminum alloy will be described.
  • the purpose of the operation is to create on the surface of the steel strip a continuous adherent deposit of a liquid mixture of zinc and aluminum in which said strip travels.
  • the kinetics of formation of this deposit is known to those skilled in the art, it has been the subject of numerous communications among which "Modeling of galvanizing reactions” by Giorgi and AIl. in “La Revue de Metallurgie - CIT" of October 2004.
  • EP 1 070 765 describes a series of variants of a galvanizing installation comprising, in addition to the coating tank in which dross is formed, an auxiliary tank to which the dross will be evacuated.
  • EP 0 429 351 discloses a method and a device which aims at organizing a circulation of liquid mixture between a coating zone of the metal strip and a zone of purification of the galvanizing bath containing liquid zinc, to ensure the separation of the dross in the purification zone and then to bring back to the coating zone a liquid mixture "whose iron content is close to or less than the solubility limit".
  • this document does not give any indication allowing the skilled person to implement them, in particular how to control simultaneously a cooling by a heat exchanger and a heating by induction of the same purification zone.
  • there any indication of how to determine a flow rate of liquid zinc is there any indication of how to determine a flow rate of liquid zinc.
  • An object of the present invention is to provide a dip galvanizing installation of a steel strip in a liquid mixture, for which a circulation circuit of the liquid mixture is thermally optimized.
  • the invention thus presents a galvanization installation by dipping a continuous rolled strip of steel in which the strip is immersed in a coating tank containing a liquid mixture of metal, for example zinc and aluminum, with drop on the tape.
  • the liquid mixture is circulated continuously between said coating pan and a preparation device, wherein the temperature liquid mixture is deliberately lowered in order to reduce a solubility threshold of iron and sufficiently high to activate a melting of at least one ingot comprising a zinc-aluminum alloy Zn-Al in a said melting zone of the preparation device thus ensuring a additional supply of liquid mixture (Zn, Al), in an amount necessary to compensate for the liquid mixture consumed by deposition on the strip.
  • the preparation device comprises a first and a second zone coupled by means for transferring the liquid mixture (or a partition device in the form of an open wall at its center),
  • a flow path of the liquid mixture is imposed sequentially from the coating tank, through the first zone ensuring the ingot melt and the decantation of the dross, through the transfer means (or the separation device) and to the second zone receiving a purified liquid mixture of dross, itself recirculated in the coating tank by a reflux path of the purified liquid mixture, the reflux path being physically distinct from the flow path such as for a loop,
  • Thermal adjustment means are distributed along the liquid mixture flow path also providing a thermal loop between an outlet of the flow out of the second zone and a reflux inlet in the coating tank, the outlet and the entrance being distinct.
  • a galvanization by dipping rolled steel strips in continuous scrolling is advantageously implemented for which the strip is immersed in the coating tank containing the liquid mixture.
  • zinc and aluminum circulating permanently between said coating pan and the preparation device in where the temperature of the liquid mixture is deliberately lowered in order to reduce the solubility threshold of the iron.
  • the flow and reflux pathways are established and managed in such a way that: - from the speed of the steel strip and from its thickness and width reaching the coating tank, it is determined a power supplied by said incoming band at a first temperature in the liquid mixture bath of the coating tank.
  • a second temperature of the recovery bath is thus set at a predetermined level lower than the first temperature.
  • a comparator between the two preceding powers is then activated, making it possible to discern two modes (points a and b) of decision on the thermal looping to adopt: a) in the case where the power supplied by the band is greater than that required for the melting of the quantity of zinc consumed, a control unit transmits a set point for reducing the temperature of the strip, possibly associated with a set point for decreasing the strip running speed in order to maintain a determined balance or gap.
  • Temperature adjustment means finally make it possible to adjust a fifth temperature of the liquid mixture at the outlet of the preparation device in order to provide, as a function of the first flow rate, a complement of power necessary for the targeted thermal equilibrium with a next reflux entry into the liner pan.
  • means for controlling and maintaining / regulating the iron dissolution rate (rate of iron content per unit of time) in the coating tank makes it possible to check and maintain overall the iron content of the mixture. liquid below its dissolution threshold.
  • the invention provides means for determining, controlling or regulating the powers, temperature, flow (flow and content) being thus sequentially and therefore adequately placed at several points in the physical loop of flow and flow. reflux of the liquid mixture, in order to allow a profile adapted in terms of zinc, aluminum and iron content resulting in an associated thermal profile and a loop thermal equilibrium as described above and in the following description.
  • FIG. 1 Schematic diagram of the installation
  • FIG. 2 Schematic diagram of a variant of the installation
  • FIG. 1 shows a block diagram of the installation according to the invention.
  • a steel strip (1) is introduced, ideally in continuous scrolling, obliquely in a coating tank (2) through a connecting pipe to a galvanizing furnace (3) (not shown upstream of the coating tank).
  • the strip is deflected vertically by a roller (4) and passes through a liquid coating mixture (5) contained in the said coating pan.
  • the deflection of the band can be achieved by means of a roller (4) horizontal accompanying the scrolling of the band.
  • a channel (6) allows the flow of the overflow of liquid mixture to a preparation device (7) composed of two zones, a first zone (71) in which is ensured the melting of at least one ingot of Zn-Al alloy (8) in an amount necessary to compensate for the liquid mixture consumed by depositing on the strip in the coating tank and during the inevitable losses (material), and a second zone (72) sequentially juxtaposed with the first zone and in a direction (FL) of flow path of the liquid mixture (coating tank to first zone then second zone).
  • These two areas (71, 72) can be located in two separate trays placed side by side as shown in Figure 1 and connected by a transfer means (74) or can be combined in a single tray in which they are separated by a separation device, such as an open wall in its central part.
  • a thermal adjustment means may comprise a cooling device (6, 62) for the liquid mixture at the outlet of the coating tank or in the ingot melt zone (8), said cooling resulting in a minimum temperature threshold in the first region (71) of the preparation apparatus sufficiently high for the ingot melt.
  • a cooling device (6, 62) for the liquid mixture at the outlet of the coating tank or in the ingot melt zone (8) said cooling resulting in a minimum temperature threshold in the first region (71) of the preparation apparatus sufficiently high for the ingot melt.
  • surface drosses (81) are formed and bottom (82) retained in the direction (FL) of the flow stream through the final wall of the first zone (71).
  • a transfer means (74) collecting the liquid mixture between the two layers of dross (81) and (82) allows the transfer in the second zone (72) of the preparation device which thus receives a purified liquid mixture which can be heated by heating means (75) preferably by induction.
  • a tubing (9) recovers the liquid mixture in the second zone (72) and, in the case of FIG. 1, under the action of a pumping device (10) and a tubing as a reflux path (11) feeds the coating tank (2) via a chute (12) at a purified liquid mixture flow rate.
  • Devices make it possible to evacuate the dross out of the preparation device (first zone (71)).
  • the first zone (71) of the preparation device comprises partitions (not shown) isolating liquid mixture portions disposed between several ingots (8), arranged perpendicularly to the direction (FL) of the flow path. These can be achieved by means of an open wall in its middle part, thus allowing to concentrate the bottom dross (82) and surface (81) ingot by ingot according to their aluminum content.
  • the first zone (71) of the preparation device comprises a means for regulating the melting flow rate of at least two ingots, ideally by dipping or selective removal of at least one ingot in the first zone (71).
  • the first zone (71) of the preparation device comprises a local control means (6, 62) for a lowering of temperature (T) which can, if necessary, contribute to the temperature reduction of the required liquid mixture which is ideally realized. by dive or selective removal of at least one ingot in the first zone (71).
  • the continuous melting of the ingots (8) in the preparation device (71) is ensured at their total melting rate. It is then advantageous for a plurality of ingots immersed simultaneously in the liquid-mixing bath, each of which may have a different aluminum content and at least one of them has an aluminum content greater than a required content in the device. in order to be able to establish a profile in content (or a flow rate of fusion) variable according to the time.
  • This required content is itself determinable from an aluminum consumption measured or estimated in the coating tank, in the combination layer Fe 2 Al 5 Zn x formed on the surface of the strip and in the dross formed in the preparation device.
  • the melt flow rate of each of the ingots is also controllable individually so as to adjust the aluminum content in the preparation device to the required content while maintaining the required total melting rate.
  • the continuous melting of the ingots in the preparation device leads locally to a cooling of the liquid mixture of the second temperature (T 2 ) (outlet of the coating tank) at the third predetermined temperature (T 3 ) in the first zone (71). in order to lower the solubility threshold of the iron and to allow the localized formation of dross in said preparation device up to the threshold of solubility at the predetermined temperature.
  • the so-called "surface” dross with a high aluminum content are then formed preferentially in the vicinity of immersed ingots with a high aluminum content and then decanted towards the surface, and the so-called “bottom” dross with a high zinc content preferentially form in the vicinity of immersed ingots with low aluminum content and sediment towards the bottom.
  • the rate of renewal of the liquid mixture entering the coating tank with an iron content equal to the solubility threshold of the iron at the predetermined temperature makes it possible to limit an increase in the dissolved iron content below the solubility threshold at the second temperature.
  • the installation thus allows the implementation of a galvanizing method characterized in that cooperate together: - the coating tank (2) which consists of a first metal casing in contact with the liquid mixture (5) and a second envelope of refractory material separated from the first envelope by a space in which are arranged heating means.
  • These heating means are advantageously electrical resistors acting by radiation on the metal casing in order to guarantee a homogeneous distribution of heat and to avoid hot spots inside the tank.
  • the heating of the coating tank is mainly intended for the compensation of thermal losses specific to the tank itself.
  • the preparation device which ensures the melting of the Zn-Al alloy linots in an amount necessary to compensate for the liquid mixture consumed by deposition on the strip and during the unavoidable losses comparable to an additional consumption.
  • the controlled smelting of the ingots is accompanied by a controlled decrease in the temperature of the liquid mixture which makes it possible to locate the formation of the dross in the single preparation device.
  • These dross are separated in the preparation device in order to purify the liquid mixture before it is transferred to the coating tank.
  • a circulation circuit which ensures the transfer of the liquid mixture, for example by pumping and by gravity flow, between the coating tank and the pre-treatment device; paration and between certain constituent elements of the preparation device.
  • the coating tank (2) is equipped with a sealing system ensuring the connection between the inlet of the strip moving towards said tank and an outlet channel of the galvanizing furnace downstream of said tank (not shown for reasons clarity).
  • a cover covering the coating tank By means of a cover covering the coating tank, the entire surface of the liquid mixture is thus also protected from oxidation by the neutral atmosphere of the galvanizing furnace on the inlet side of the strip in the tank. and on the side of the band outlet of the same tank, a slight overpressure of neutral gas introduced by a tubular (61) and which also ensures the protection of the surface of the liquid mixture in the preparation device.
  • the preparation device (7) can be composed of two tanks, one ensuring the fusion of the ingots and locating the formation of the dross, the other locating the heating means of the liquid mixture, the transfer of the liquid mixture of a tank the other being provided by pumping or gravity through filtering chutes that can be fed in turn or together by shutters. This aspect will be better described later.
  • the preparation device (7) can also be composed of a single tank comprising the first and the second zone (71, 72) separated, for example, by a filtering wall, the first zone ensuring the fusion of the ingots and locating forming the dross, the second zone (72) receiving the purified liquid mixture.
  • the second zone is equipped with a heating means (75), advantageously induction heating, ensuring the reheating of the purified liquid mixture before it returns to the coating tank, so as to ensure a thermal closure of reflux pathway (RFL) in end of flow channel to the beginning of a new stream (FL).
  • RNL thermal closure of reflux pathway
  • the circulation circuit may consist of at least one lifting pump (10) drawing via a pipe (9) into the purified zone of the preparation device and, after transit on a pipe (11) as a reflux path ( RFL), feeding either directly the return chute (12) to the coating tank (2), or permeable filter channels feeding an additional tank equipped with an induction heating means for heating the liquid mixture before returning it. gravity to the liner pan by the return chute.
  • RFL reflux path
  • permeable filter channels feeding an additional tank equipped with an induction heating means for heating the liquid mixture before returning it. gravity to the liner pan by the return chute.
  • Figure 1 thus presents a first dipping galvanization installation scheme of a strip (1) continuous rolled steel strip in which the strip is immersed in a coating tank (2) containing a liquid mixture of metal (5), such as zinc and aluminum, to be deposited on the permanently circulated strip between said coating tank and a preparation device (7) in which the temperature of the liquid mixture is deliberately lowered in order to decrease a solubility threshold of iron and sufficiently high to activate a melting of at least one Zn-Al ingot (8) in a said melting zone of the preparation device, in an amount necessary to compensate for the liquid mixture consumed by deposition on the strip .
  • the installation is defined by the following features: - the preparation device (7) comprises a first and a second zone (71, 72) in two separate containers or in one single tank where they are separated by a transfer means (74) or a separation device,
  • a flow of the liquid mixture is imposed sequentially from the coating tank, through the first zone (71) ensuring the ingot melt, possibly through the transfer means (74) or the separation device (73) adapted filtering the dross from the liquid mixture in the first zone and transferring the filtered liquid mixture of dross to the second zone (72) receiving a pure liquid mixture of dross, which is then recirculated in the coating tank by a reflux path (11) of the purified liquid mixture,
  • thermal adjustment means are distributed along the flow of liquid mixture providing a thermal loop between an outlet (9) of the flow out of the second zone (72) and a reflux inlet (12) in the coating tank.
  • One of the thermal adjustment means comprises a first heating means (75) of the purified liquid mixture in the second zone (72). This advantageously allows a thermal continuity looping between respective inputs and outputs of the flow path and the reflux path.
  • One of the thermal adjustment means comprises a second heating means (1) for the liquid mixture in the coating tank.
  • This heating means and at least its maintenance and its adjustment around a temperature threshold, is also provided or complemented by the strip itself coming out of a galvanizing furnace and plunging into the coating tank at a higher temperature to that of the liquid mixture in the coating tank.
  • This advantageous aspect as a second heating means is thus carried out by thermal transfer by delivering a running power of the strip to be immersed in the liquid mixture (5) necessary to bring a quantity of liquid mixture to a temperature of 30.degree. quise.
  • the temperature of the liquid mixture in the coating tank undergoes, after heating or holding in temperature with the aid of the moving strip, the temperature drop previously described as input to the first zone (71) of bullion fusion.
  • a basic step of thermal looping on the flow path is then advantageously carried out.
  • the preparation device comprises the transfer means (74) coupling the two zones or separate tanks (71, 72) placed side by side between which the liquid mixture is transferred.
  • the transfer means (74) comprises a pump (742) or a connecting channel.
  • the transfer means (74) includes a lifting pump (742) having a pumping inlet (741) located at a central height of the first zone (71) and a pumping outlet (743) in the second zone ( 72), said first and second zones (71, 72) being physically separated in the form of two separate trays.
  • the level of the pump inlet (741) in the first zone (71) or the level of the connecting channel are advantageously located between the upper zone of settling of the surface dross (81) and the lower zone of sedimentation of the bottom dross (82) or in the middle third of the height of the first zone (71). It is important that the pump inlet (741) be located in a free void of dross to avoid pumping.
  • the settling and sedimentation zones form an increasing gradual accumulation which, for a given flow rate of liquid mixture on the flow path (FL), makes it possible for a free pumping pumping window to be ensured in the first zone (71).
  • FIG. 2 shows a variant of the schematic diagram of the installation according to FIG. 1 for which the initial coating tank is subdivided into a first deflection compartment (15) of the strip (without liquid mixture) and in a tray coating material (13) comprising a liquid mixing bath (5) maintained by magnetic levitation.
  • the present installation thus implements a variant of the method in which the liquid mixing bath (5) is maintained by magnetic levitation in a coating tank (13) connected to the preparation device as in Figure 1.
  • the levitation effect is provided in known manner by electromagnetic devices (14).
  • a compartment (15) provides the connection to the oven and the deflection of the strip (1) by the roller (4).
  • FIG. 3 shows a general diagram of the coating pan according to the variant embodiment described in FIG. 1.
  • This type of pan (if emptied) can also be adapted for the coating pan according to FIG. 2 as a means of introducing the tape in the magnetic levitation liner.
  • the steel strip (1) coming from the galvanizing furnace (not shown) is deflected vertically upwards by the roller (4) (with horizontal axis of rotation) immersed in the liquid mixture (5). After deflection by the roll (4), the vertically scrolling strip then contacts an anti-tile roll (41) and a roll securing a pass line (42) through an upper opening of the cover pan. .
  • the coating tank is composed of a first metal casing (2) whose shape with dimensions close to the running path of the band is adapted to reduce the volume of liquid mixture and thus allow its rapid renewal with neighboring flow pumps for example 100 tons per hour.
  • a second envelope of refractory materials (not shown) protects the environment of the tank against heat radiation and limits heat losses.
  • heating resistances (not shown) are available between these two shells in order to compensate for the low heat losses of the tank.
  • Draining (6) and return (12) troughs allow easy placing of the trough in the circulation circuit (flow path / reflux path) of the mixture. quide.
  • a movable sealing system (31) allows the connection of the tank inlet with the outlet channel of a galvanizing furnace downstream of the scroll. The free surface of the liquid mixture has, in this zone, a protection against oxidation by the inert atmosphere of the furnace.
  • Figure 4 shows an arrangement of the installation according to a first embodiment.
  • a submerged roller coating pan (2) as described in FIG. 1 or 3 or a magnetic levitation coating pan (13) as depicted in FIG. 2 pours its overflow of liquid mixture into the preparation device (7) , more precisely in its first zone (71).
  • This preparation device is in fact here divided into two zones (71) and (72) as in FIG. 1.
  • the ingots (8) are melted and the localized precipitation of dross.
  • the purified liquid mixture by natural separation of the bottom dross (by sedimentation) and surface (by settling) is collected in the second zone (72) where it is heated by the induction device (75).
  • the transfer from the first to the second zone can be achieved by the transfer means (74) (by lifting pump (742) as shown in Figure 1) or by a simple communication channel.
  • at least one lifting pump (10) circulates the liquid mixture between the purified zone (72) of the preparation device and the trough (12) of the coating tank via a return line (reflux line ).
  • two lifting pumps (10) are placed in parallel, one being in service and the other in stand-by in case the first lifting pump had to show a need for maintenance, a malfunction or an alteration. related to wear.
  • FIG. 5 shows an arrangement of the installation according to a second embodiment.
  • at least one lifting pump (10) such as the pump (742) of the transfer means (74), from which one of the pumps (10, 742) ) to economize
  • at least one lifting pump (10) ensures the circulation of the liquid mixture from an outlet of the first zone (71) of the preparation device to the second zone (72) provided with induction heating means (75) and placed just upstream of the trough (12) supplying the coating tank (2) that feeds by gravity.
  • the transfer of the liquid mixture from a lift pump outlet channel into the second zone (72) is optionally carried out through at least one filter channel (76), here two interchangeable valves adapted so as to be able to be put in service alternately.
  • one chute is in service, while the other is on stand-by.
  • An additional bucket can also be used and put into maintenance, while the other two are attached to the plant.
  • the filtered and heated liquid mixture in the second zone (72) is reintroduced via a gravity outlet into the trough (12) of the coating pan to provide the last reflux path stage.
  • Figure 6 shows an arrangement of the installation according to a third embodiment.
  • the second zone (72) may be disposed near the outlet of the first zone (71) of the preparation device.
  • this arrangement makes it possible to reduce the lifting height of each of two lift pumps (742, 10) arranged in series on the reflux path.
  • An outlet of the second zone (72) is coupled to an inlet of the second lift pump (10), an outlet of which leads to the chute (12) for feeding the cladding tank.
  • several filtering ducts (76) are interchangeable between the outlet of the first lift pump (10) and the inlet of the second zone (72)
  • FIG. 7 shows the arrangement of the installation according to a fourth embodiment related to FIG. 4, of which it is differentiated by the fact that the means for transferring (74) the liquid mixture between the first zone (71) and the second zone (72) of the preparation device is made by gravity through filter channels (76) fed alternately, for example by positioning one in service and the other in stand-by.
  • An additional filter chute can then be placed in maintenance by distributors (77) holding the filter channels above the second tank (7b).
  • the inlet of an arm serving the filter chutes (77) is placed as described above at a height of wall free of any accumulation of dross.
  • FIG. 8 shows a different arrangement of the principle described in FIG. 1 in which the preparation device (7) composed of two zones, a first zone (71) in which the fusion of at least one ingot (8) in quantity is ensured. necessary to compensate for the liquid mixture consumed by deposition on the strip in the coating tank and during the inevitable losses (material), and a second zone (72) sequentially juxtaposed to the first zone (71) and following a flow path direction (FL) of the liquid mixture (coating tank to first zone then second zone).
  • These two zones (71, 72) are located in the same tank as indicated and separated by a separating device (74, 73), such as an open wall or at least a filter wall of dross in its central part (731). .
  • the first zone (71) melts the ingots and locates the formation of dross out of the central portion (731), the second zone (72) receives the purified liquid mixture through the central portion (731).
  • the second zone is equipped with an induction heating means (75) ensuring the heating of the purified liquid mixture before it returns to the coating tank via the lifting pump (10), so as to ensure a thermal loop of the reflux path at the end of the flow path to the beginning of a new flow path.
  • the opening of the separating device (73) can be equipped with a filter cap intended to retain the dross which would not be decanted on the surface or at the bottom of the tank. It can also be replaced by an interchangeable filter wall.
  • This embodiment is also applicable together with an auxiliary heating tank.
  • the preparation device is devoid of induction heating means and the relative arrangement of the preparation device and the heating tank may be one of those described between the first and the second zone of the preparation device in Figures 4, 5, 6 and 7.
  • the transfer means (74) or at least a vertically central part of the preparation device can be additionally provided with a filtering wall (73) as in FIG. 8, for example located so as to isolate the pumping input (741) from the transfer means (74) from a first part (from fusion of ingots) of the first zone (71). This ensures that the pumping input will never be closed by a dross.
  • the transfer means (74) may comprise, by substitution with a pumping device, a separation device in the form of a single vertical wall (73) open at its center (731), such that at the figure 8.
  • FIG. 9 shows an embodiment of the installation (seen from above opposite the side views of the preceding figures) for all embodiments requiring at least one lift pump placed on the reflux path of the liquid mixture.
  • the preparation device comprises at least a portion of flow path (FL) of the liquid mixture from an outlet (Cl) of the coating tank (2, 13) being juxtaposed side by side to a portion the reflux path (RFL) of the liquid mixture via an inlet (C2) in the coating tank.
  • the flow and reflux paths are parallel in this view from above, or at least form a channel provided with an outgoing U-turn and rejoining the coating tank.
  • the flow path portion is included in the first zone (71) and the reflux path portion is included in the second zone (72) according to the definitions of the zones described in the preceding figures.
  • This configuration therefore makes it possible to carry out the reflux path by means of the second zone (72) such as as a purification tank.
  • a pipe (11) of reflux is no longer necessary.
  • This embodiment also advantageously eliminates the lifting pump. Thermal loopback is also simplified, since outgoing pump discharge heat losses are avoided.
  • the flow path portion and the reflux path portion have opposite ends to the liner being connected by means of at least one connector (CR) (here a channel) to provide a flow direction change. liquid mixture.
  • the connecting channel could, however, to have another shape, for example in half-ring extending outflow path and inlet of the reflux path or be a central opening disposed between two common sides of the flow path and the reflux path.
  • a separating device (73) such as that described for FIG. 8 is arranged upstream of the connection channel in a direction of flow of the liquid mixture. If the two juxtaposed bins (71, 72) are contiguous, a lateral opening between the two bins provided with a filtering wall is sufficient to play alone the role of the connecting channel.
  • the reflux path portion may comprise at least one flow pump.
  • Means, ideally continuously activatable, for measuring the temperature and concentration of one or more elements of the liquid mixture, for example aluminum, are arranged on at least the flow path from its entry into the coating tank to the exit of the preparation device;
  • Means, ideally continuously activatable, for maintaining and regulating the flow and temperature of the liquid mixture are arranged at at least one point of the flow path;
  • Means, ideally continuously activatable, for maintaining and regulating the temperature of the strip at the outlet of a galvanizing furnace connected to the coating tank are placed downstream of the coating tank or / and at its inlet;
  • - Means, ideally continuously activatable, measuring a width and a strip thickness downstream of the coating tank are also taken into account in the thermal looping;
  • - Means, ideally continuously activatable, for maintaining and regulating a dynamic introduction of the ingots in a melting zone of the preparation device are preferably placed above the first zone (71) of the preparation device;
  • a dynamic measurement parameter control unit and a parameter adjustment unit linked to the strip, to the coating tank and to the preparation device is connected to the measurement and regulation (or maintenance) means.
  • the controller may include predictive parametric controls, a real-time control system, and / or a self-learning method.
  • the adjustment unit may comprise external control inputs and parallel to the adjustment unit in order to be able to carry out a manual or forced adjustment, for example by a registration of parameters resulting from new measurement values of a content in alloying element, for example aluminum, a temperature variation, a scrolling band property variation, etc.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating With Molten Metal (AREA)
EP08761864A 2008-02-08 2008-02-08 Anlage zur gehärteten galvanisierung eines stahlbands Withdrawn EP2240621A1 (de)

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PCT/FR2008/000164 WO2009098363A1 (fr) 2008-02-08 2008-02-08 Installation de galvanisation au trempe d'une bande d'acier

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US8464654B2 (en) 2013-06-18
US20100307412A1 (en) 2010-12-09
AU2008350134B2 (en) 2014-01-30
AU2008350134A1 (en) 2009-08-13
BRPI0822326A2 (pt) 2019-02-26
KR101520136B1 (ko) 2015-05-13
WO2009098363A1 (fr) 2009-08-13
CN102037149A (zh) 2011-04-27
CA2714475C (en) 2015-06-30
JP5586478B2 (ja) 2014-09-10
KR20100108617A (ko) 2010-10-07
JP2011511166A (ja) 2011-04-07
CA2714475A1 (en) 2009-08-13
CN102037149B (zh) 2013-05-29

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