EP2094401A2 - Procede d'application d 'un revetement anticorrosion sur les pieces d'une canalisation, incluant l'utilisation de solution aqueuse de silane et de peinture poudre epoxy - Google Patents
Procede d'application d 'un revetement anticorrosion sur les pieces d'une canalisation, incluant l'utilisation de solution aqueuse de silane et de peinture poudre epoxyInfo
- Publication number
- EP2094401A2 EP2094401A2 EP07858414A EP07858414A EP2094401A2 EP 2094401 A2 EP2094401 A2 EP 2094401A2 EP 07858414 A EP07858414 A EP 07858414A EP 07858414 A EP07858414 A EP 07858414A EP 2094401 A2 EP2094401 A2 EP 2094401A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- silane
- substrate
- coating
- applying
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
- B05D7/146—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies to metallic pipes or tubes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
- B05D7/148—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies using epoxy-polyolefin systems in mono- or multilayers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
- C23C22/74—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process for obtaining burned-in conversion coatings
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/10—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
- B05D3/102—Pretreatment of metallic substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/12—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by mechanical means
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/20—Use of solutions containing silanes
Definitions
- the invention relates generally to the field of corrosion protection of pipelines.
- a pipeline is a line or conduit for the remote transport of fluids such as water, petroleum products, gas, or sanitation products.
- the invention relates, according to a first aspect, to a method for applying a monolayer or multilayer anticorrosive coating on a metal substrate forming part of a tube or an accessory of a pipeline intended to be buried or immersed for the transport of fluid, such as water, petroleum products, gas, or sanitation products.
- the corrosion protection of a pipeline in other words a buried or submerged pipe used in particular to transport water, oil, or gas, is based on the same principle for decades: an adherent organic coating, passive barrier with water and with oxygen, coupled with an electrochemical active protection consisting in bringing the material constituting the pipeline to a potential such that any oxidation of the iron used in the composition of these materials is inhibited. Since always, it is done either by the method of a sacrificial anode, or by imposed current. It's about cathodic protection.
- Organic coatings intended for the corrosion protection of pipelines are subject to service constraints that combine temperature and humidity. Indeed, the pipes can be buried in more or less wet soil or placed on the seabed. On the other hand, the fluid can be heated in order to lower its viscosity in order to minimize the pressure drops that occur during transport within the pipe network, the length of which may represent several hundred to several thousand kilometers.
- the operating temperature can vary from 20 to 150 degrees Celsius ( 0 C).
- the temperature-humidity combination causes an acceleration of the penetration of water within the coating material. This phenomenon results in a loss of adhesion of the coating with respect to the metal support constituting the pipeline. The loss of adhesion is detrimental to the durability of the corrosion protection.
- the pipe parts are conventionally subjected to a surface preparation which may consist of mechanically etching the substrate.
- a surface preparation which may consist of mechanically etching the substrate.
- chemical treatments of metal surfaces may also be employed after this surface preparation. These chemical treatments are conventionally based on chromates or phosphates.
- the application of solutions based on chromates or phosphates has several disadvantages. It involves rinsing operations that complicate the application process and generate the formation of additional waste. It involves, after drying, an operation of thermal conversion of chromates or phosphates, which makes the process expensive. It involves the use of toxic products for the case of chromates.
- the object of the present invention is to propose a method free of at least one of the limitations mentioned above.
- the invention relates to a method for applying a monolayer or multilayer anticorrosive coating on a metal substrate forming part of a pipe intended to be buried or immersed for the transport of fluid, such as water, petroleum products, gas, or sanitizers, characterized in that it comprises: a) a preparation of the surface of the substrate, solely mechanical, including abrasive blasting, in particular to obtain a surface cleanliness of at least Sa 2.5 and a roughness Rz of at least 40 micrometers; b) an application of an adhesion promoter on the prepared surface consisting of an aqueous solution of at least one silane, without additional chemical treatment; c) applying a layer of epoxy resin powder paint to the coated surface of the adhesion promoter; and d) at least one heat treatment of at least the surface of the substrate; at least one heat treatment step d) being carried out between steps a) and b) or between steps b) and c).
- the invention has the advantage of proposing the replacement of chromates
- thermosetting resins such as epoxy resins (or epoxy resins, or epoxy or epoxy resins), used as internal or external coating metal tubes and accessories from pipelines for the transport of fluid, such as gas, water, petroleum products, or sanitation products.
- metal accessory any piece, preferably steel or cast iron, which is integrated in the pipe network, other than tubes. It may be for example a valve, an elbow, or a flange.
- the silane solution is an aqueous solution free of organic solvent, which is advantageous for the environment as well as for the health and safety of users.
- the surface preparation includes: - drying the substrate in order to eliminate any trace of moisture;
- Such a surface preparation is intended to obtain a surface cleanliness between Sa 2.5 and Sa 3 or at Sa level 2.5, and a roughness Rz of between 40 and 150 micrometers or between 70 and 90 micrometers.
- the substrate is made of a metal including essentially iron, and is preferably made of steel.
- the silane may be any silane used as an adhesion promoter of general formula R 'Si (OR) 3 where R' is a group containing at least one reactive organic radical and where OR is an alkoxy radical.
- said at least one silane is chosen from aminosilanes or epoxysilanes.
- the silane may be N- (beta-aminoethyl) -gamma-aminopropyltrimethoxysilane or gamma-glycidyloxypropyltrimethoxysilane.
- the silane may be advantageously a prehydrolysed silane, such as prehydrolysed 3-aminopropylsilane.
- the aqueous solution comprises between 0.5 and 20% by weight, preferably between 1 and 10% by weight, of silane.
- the aqueous silane solution is preferably applied to the surface of the substrate in a grammage of between 10 and 100 grams per square meter, preferably between 30 and 70 grams per square meter.
- a single step d) of heat treatment is performed between steps a) and b) or between steps b) and c).
- the heating temperature is advantageously between 110 and 250 degrees Celsius, preferably between 150 and 240 degrees Celsius.
- the maximum temperature of 250 ° C. is particularly suitable in the case where the silane application is carried out before heating, in that it does not cause the degradation of the silane.
- the surface preparation is devoid of any chemical treatment.
- the method according to the invention further comprises: e) applying an intermediate layer of a polyolefin adhesive to the epoxy resin coated surface; and f) applying a polyolefin topcoat selected from polyethylenes or polypropylenes to the coated surface of the intermediate layer.
- the metal substrate may be a tube of the pipe, or may be an accessory of the pipeline. Tubes and accessories are parts of a pipe.
- the method according to the invention makes it possible to treat the internal and external surfaces of these pipe pieces.
- a monolayer coating is generally applied, ie a coating devoid of an intermediate layer and a topcoat.
- the inner and outer surfaces are treated successively, and for an accessory, all the surfaces are treated simultaneously.
- the invention also relates to a metal piece of pipe, such as a pipe or a pipeline accessory, intended to be buried or immersed for the transport of fluid, such as water, petroleum products, or gas, having at least one surface treated according to the method of the invention.
- a metal piece of pipe such as a pipe or a pipeline accessory, intended to be buried or immersed for the transport of fluid, such as water, petroleum products, or gas, having at least one surface treated according to the method of the invention.
- the surface of the metal substrate is treated to receive a coating which is: either monolayer, that is to say from the application of a powder paint containing epoxy resin undergoing crosslinking through a hardener; or multilayer, that is to say consisting of a primer which is derived from the application of a powder paint containing epoxy resin undergoing crosslinking by means of a hardener, and at least one layer additional, for example based on epoxy or polyolefin.
- a multilayer coating may be in particular a tri-layer coating, consisting of the primer, an intermediate layer which is a polyolefin-based adhesive, and a polyolefin topcoat such as polyethylene or polypropylene.
- the silane is applied, prior to the application of the single-layer or multilayer coating, on the surface of the metal tubes or accessories.
- the type of silane that is the subject of the process of the invention is in solution in water. No organic solvent is added. This preparation eliminates problems related to organic solvents, environmental, safety and hygiene.
- the type of silane that is the subject of the process of the invention is either a pure silane, diluted in water before its application, or a silane that is already in aqueous solution, that is to say, previously hydrolyzed.
- the pure silane may in particular be of general formula (I) below:
- n represents an integer equal to 1, 2 or 3.
- the index y represents an integer equal to 1 or 2.
- y is equal to 1.
- OR groups are each selected from methoxy groups CH 3 O-, ethoxy CH 3 CH 2 O-, or propoxy C 3 H 7 O-, or combinations thereof.
- the group Z represents a primary amine or secondary amine function, or a function epoxy borne by a glycidyl ether group or a cycloaliphatic group.
- Z is a secondary amine, and where y is 1, Z may be attached to a group X to give a silane of formula (II).
- the groups X, R 1 and R 2 can each be chosen from an aliphatic, cycloaliphatic or aromatic carbon group. These carbonaceous groups may include one or more heteroatoms such as sulfur, nitrogen or oxygen. These carbon-containing groups may be grafted with one or more radicals chosen from alkyl, alkene or aryl radicals, or radicals containing at least one functional group chosen from amine, amide, urea, acyl, carboxylic, phenolic, ketonic, ether and ester functions. , or mercaptan.
- the pure silane undergoes, in the presence of water, during its dilution, a hydrolysis which transforms the alkoxy function Si- (OR) of the silane in silanol function Si- (OH) and alcohol ROH.
- the Si- (OH) function is responsible for the chemical grafting on the metal and thus ensures a solid bond with it.
- Si- (OH) functions can, after condensation, lead to the siloxane bond formation Si-O-Si, which is not only detrimental for the stability of the silane in solution, but also for the reaction yield grafting between the silane and the metal support.
- An adjustment of the pH of the solution can lead to a compromise between the rate of formation by hydrolysis of the Si- (OH) function, necessary for grafting on the metal, and storage stability.
- silanes in aqueous solution, or prehydrolysed silanes which can also be used in the invention are of the R '- Si (OH) n type .
- R ' is a group containing at least one reactive organic radical.
- R ' is preferably chosen from carbon groups containing a secondary amine and / or a primary amine, which give the silanes a particularly advantageous stability in water.
- silanes in aqueous solution have two main advantages.
- the first advantage is that the pre-hydrolyzed form of these silanes allows the use of a solution free of alkoxy Si-OR function, which avoids the formation of alcohol ROH in water through the process of hydrolysis, which is a co-solvent, detrimental to the environment and the health of users.
- the second advantage is that these silanes have been developed to give the aqueous solution a very high stability, up to several months.
- 3-aminopropylsilane prehydrolyzed containing silanol functions without alkoxy group is marketed by Degussa as a 40% by weight aqueous solution of silane as "Dynasilan ®" reference
- the particularity of this silane is that it has a very high stability in water despite the presence of Si- (OH) functions.
- silane in the aqueous phase of the trade "Silquest ®" A-1106, containing primary amines of formula (H 2 N (CH 2) 3 SiO 5) n can also be advantageously used as part of the method of the present invention.
- silane solution does not require chemical treatment of the metal support before the application of the silane solution, nor rinsing after the application thereof.
- the silane solution which is the subject of the process of the present invention, may contain a dye diluted in water, so that it is easier to visualize the application of the silane solution on the metal support.
- the process of the present invention is in accordance with the rules of the art relating to the application, on the walls of metal tubes, of thermosetting resins based coatings. These rules or recommendations are described in several standards, including NFA 49716, NFA 49706, NFA 49710, NFA 49711, and CAN / CSA-Z245.20-02.
- the epoxy layer is in contact with the metal support. It is therefore the epoxy which, in the coating systems concerned by the invention, ensures adhesion to the metal support. It is therefore essential that the adhesion performance of the epoxy layer remain optimal when the coating undergoes temperature and humidity constraints.
- EXAMPLE 1 Process for surface treatment of a metal tube and application of a monolayer coating based on epoxy powder paint.
- the process is as follows: 1) The tubes are dried to remove any moisture. The drying is done by passing through an oven or flame. 2) After drying, the outer surface of the metal tubes is mechanically etched by blasting abrasives such as grit, sand, alumina and / or corundum. This stripping operation gives the surface a roughness profile whose Rz (according to the description of the ISO 4287-1 standard) is between 40 and 150 micrometers ( ⁇ m), preferably between 60 and 90 micrometers.
- the surface cleanliness resulting from these operations must be between Sa 2.5 and Sa 3 as described in the ISO 8501-1 standard.
- the silane solution has an amount of active ingredient, that is to say pure silane, of between 0.5 and 20%, preferably between 1 and 10%, by weight relative to the total weight of the solution.
- the silane solution is applied by mixed spraying or without air using a machine type "airmix” or “airless”, or by brush, or roller, or by spreading or dipping.
- the silane solution is applied to the metal support in a grammage of between 10 and 100 grams per square meter (g / m 2 ), preferably between 30 and 70 g / m 2 .
- the surface of the tube is not rinsed and is directly subjected to a rise in temperature to a temperature of between 110 and 250 degrees Celsius ( 0.degree. ), preferably between 15O 0 C and 24O 0 C.
- the temperature rise is conditioned by the kinetics of the crosslinking reaction of the epoxy resin and not by the need for thermal conversion of the silane, unlike the chromate solutions that require thermal conversion temperatures which are generally above 220 ° C.
- the advantage of this process is that it allows the use of aqueous solutions without causing rapid oxidation and thus rust formation on the metal, since the heating operation of the tube is done immediately after application of the aqueous silane solution.
- Heating the tube causes the immediate drying of the silane solution, by evaporation of water, and therefore prevents this water from leading to the oxidation process.
- Heating the tube, before application of the epoxy powder is provided either by passing the tube through an inductor, or by passing the tube in a furnace heated with gas, fuel oil or electrically powered.
- a variant of this process consists of applying the silane solution after heating the tube, in other words to reverse steps 4) and 5).
- Application of the hot supported silane solution causes the water to evaporate immediately and thereby prevents oxidation and rusting on the surface of the metal.
- the epoxy powder is applied by an electrostatic or triboelectric process.
- the epoxy powder coating applied on the preheated support passes through three phases of transformation: melting, gelling and solidification. This process is ensured by the intake of calories at the surface of the tube which leads to the mechanism of the crosslinking.
- the thermal inertia of the tubes is generally sufficient for the crosslinking of the epoxy to be completed. Post-baking may be used to complete this crosslinking.
- an accelerated cooling step which consists in projecting water on the coated support, thus allowing the tubes to be handled more rapidly, may optionally be put in place.
- a variant of this process is not to preheat the tube before the application of the powder.
- the silane solution applied on the tube must be dry (all the water in the solution must be evaporated), and after-cooking, after the application of the epoxy powder, must be ensured for the crosslinking of the epoxy.
- EXAMPLE 2 Surface treatment method of a metal tube and application of a tri-layer coating comprising a layer based on epoxy powder paint.
- the surface treatment method for the application of a tri-layer coating comprising a layer based on epoxy powder paint is identical to the process described in Example 1, from step 1) to step 6) included.
- the thickness of the epoxy, which serves as the primary is generally between 50 and 500 micrometers.
- the adhesive is applied. Indeed, the lapse time of the epoxy layer by the adhesive, determined by taking into account both the temperature of the support and the reactivity of the epoxy powder, is generally between 5 and 60 seconds.
- the application of the adhesive is done either by extrusion or by dusting.
- the extrusion temperature is between 200 ° C. and 250 ° C.
- the thicknesses of adhesive deposited are generally between 200 and 500 microns.
- the application of the adhesive is immediately followed by that of the topcoat made of polyethylene MD (medium density), BD (low density), or HD (high density), or polypropylene.
- the application of the topcoat is also done by extrusion.
- the deposited topcoat thicknesses are generally between 1.5 and 4 millimeters (mm).
- the tubes are cooled by spraying water on their surface coated with the topcoat.
- EXAMPLE 3 Method for surface treatment of metal accessories and application of a monolayer coating based on epoxy powder paint.
- the process includes steps 1) to 7) of Example 1.
- An epoxy powder paint is applied using an electrostatic gun whose polarity is set at a voltage of +70 kV (kilovolts). Steel plates 200 mm long, 100 mm wide and 10 mm thick are used as metal substrates.
- the epoxy powder paint has the following composition:
- the percentages indicated are percentages by weight relative to the total weight of the composition.
- the freezing time of this epoxy powder paint at 180 ° C. determined according to the ISO 8130-6 standard, is 70 ⁇ 5 seconds.
- the steel plates Prior to the application of the powder, the steel plates are sandblasted by abrasive blasting
- Rugos 2000 ® grade 20-30 up to a roughness Rz of between 70 and 90 micrometers.
- These abrasives are based on aluminum silicate. Their average chemical composition includes 51% SiO 2 (total silica combined in the form of silicates) and 27% Al 2 O 3 .
- the free silica content is less than 0.1%, the chlorine and fluorine content is less than 100 ppm.
- the apparent density of the abrasive is 1.3 and the hardness is between 6 and 7 Mohs.
- the particle size is between 0.40 and 1.60 mm. This product does not contain any heavy metals. These plates are then dusted by blowing with compressed air. The surface cleanliness obtained at the end of these operations corresponds to the level Sa 2.5.
- the plates are then preheated to 220 ° C. in a ventilated oven. As soon as the temperature of the steel reaches 220 ° C., the plates are taken out of the oven and connected to the earth.
- the powder is immediately applied to the metal support using the electrostatic gun described above. After application of the powder, the plates are put in an oven at 200 ° C for a post-cooking of 10 minutes.
- the plates are then cooled to room temperature. We can also talk about specimens at this stage.
- a control sample is used for the evaluation of the adhesion before immersion in hot water.
- the evaluation of the adhesion is done according to two methods.
- the first method corresponds to a tensile measurement made according to the ISO 4624 standard. This method consists of using a 20 mm diameter steel or aluminum stud stuck to the coating using an "Araldite ® " type glue. . Before application of the glue, the coating is frosted with sandpaper to improve the adhesion of the glue, that is to say improve its adhesive power.
- the stud is pulled using a traction device.
- the pulling force necessary to tear off the stud is determined as well as the fracture facies.
- the tensile force is indicated in Newton per unit area, more particularly in Newton per square millimeter (N / mm 2 ).
- the fracture facies may correspond to: an adhesive rupture, that is to say a separation of the coating from its metallic substrate;
- a cohesive failure that is to say a rupture of the coating in the mass without separation of the coating of its metal substrate; this scenario is preferable to the previous scenario;
- a semi-adhesive / semi-cohesive rupture that is a combination of the first two scenarios
- Breakage of the glue that is to say a separation of the glue from the surface of the coating; in this case, the force which corresponds to the adhesion of the coating vis-à-vis its metal substrate is indeterminate, but is considered equal to or greater than the breaking force of the glue; this case is favorable.
- the second method of assessing adhesion is the evaluation of adhesion through a peel test as described in EN 10290 and EN 10289.
- the tip of the knife is inserted horizontally (the flat of the blade) under the coating at the point of intersection of the incisions so that the tip of the blade is in contact with the surface of the metal.
- the plate of the blade By levering against a fulcrum such as a steel rod, the plate of the blade is moved away from the metal surface in one movement and vertically, that is to say in a 90 degree direction. degrees of the surface. The purpose of this operation is to try to tear off the coating.
- the loss of adhesion of the coating is evaluated by the length in millimeters which corresponds to the part torn off (or peeled) since the point of intersection.
- test specimens are immersed in city water.
- the water bath is maintained at a temperature of 80 ⁇ 20 ° C.
- the specimens are removed from the hot water bath and cooled to room temperature after different immersion times.
- the cooled test pieces are subjected to the evaluation of adhesion according to the two methods described above.
- Solution 2 5% N- (beta-aminoethyl) -gamma-aminopropyltrimetoxysilane ("Dynasilan ® " A-1120) and 95% city water.
- Solution 3 2.5% N- (beta-aminoethyl) -gamma-aminopropyltrimetoxysilane ("Dynasilan ® " A-1120) and 97.5% city water.
- - Solution 4 12.5% aqueous solution at 40% by weight of 3-aminopropylsilane ( "Dynasilan ®" 1151) (5% pure silane) and 87.5% of city water.
- the metal substrates undergo sandblasting and dedusting as in Example 4A.
- the metal substrates are preheated to 40 ° C. in an oven and then immersed in one of the silane solutions.
- the immersion time which corresponds to a quenched silane application operation, lasts 4 + 1 seconds.
- the basis weight of the silane solution deposited on the metal substrate is determined by weighing.
- the basis weight is 50 ⁇ 10 g / m 2 .
- the metal substrates are put in an oven to preheat at 220 ° C.
- the temperature of the substrates is 220 ° C.
- they are taken out of the oven and coated with the epoxy powder paint of Example 4A.
- the application of the powder paint is exactly according to the method described in Example 4A.
- the plates are post-baked in an oven at 200 ° C., according to the method of Example 4A. The plates are then cooled to room temperature. For tests, only specimens for which the epoxy thickness is between 350 and 450 micrometers are retained.
- Example 4C relates to the application of a tri-layer coating.
- the coating consists of a primer epoxy powder, an adhesive and a topcoat.
- the epoxy powder has the following composition:
- the percentages are percentages by weight relative to the total weight of the composition.
- the gel time at 180 ° C. of this composition is 40 ⁇ 5 seconds.
- the adhesive is a polyolefin whose softening point, determined by differential scanning calorimetry or DSC, is 135 ° C., grafted by radicals based on maleic anhydride.
- the adhesive is a grafted adhesive "Orevac ® " 18510 marketed by Arkema.
- the finishing layer consists of HDPE (high density polyethylene).
- the silane solution comprises 94.5% of city water, 5% silane "Dynasilan ®" 1151, and 0.5% dye.
- the coating is applied to the outer wall of a steel tube 7 mm thick and 116 mm outside diameter.
- the silane solution is brushed onto the surface of the tube.
- the basis weight is 50 + 10 g / m 2 .
- the tube passes into an inductor which raises the temperature of the steel at 220 ° C.
- the powder primer is applied using an electrostatic gun, set at 75 kV.
- the deposited thickness is 120 ⁇ 30 ⁇ m.
- the adhesive which is extruded at a temperature of 230 ° C., is applied to the primer with a recovery time of 20 seconds.
- the adhesive film thickness deposited is 250 ⁇ 20 ⁇ m.
- the topcoat which is also extruded at a temperature of 230 ° C, covers the adhesive at a time of 10 seconds.
- the thickness of this layer is between 2.5 and 3 mm.
- Pressure rollers compress the entire coating to optimize contact between the different layers.
- the tube then passes into the cooling tunnel 2 seconds after the topcoat is applied.
- the cooling process involves spraying cold water onto the surface of the topcoat.
- the tube is cut into pieces of 10 cm long to provide test pieces for undergoing immersion tests.
- the tri-layer coating is incised throughout its thickness, that is to say up to the surface of the metal.
- two incisions 2.5 cm apart are thus made around the circumference.
- a second tube is coated from the same coating system and by the same method. The difference is that the silane solution is not used.
- test pieces After applying the coating, the test pieces are prepared in the same manner as before.
- This second series of test pieces constitutes the series of control samples, free from silane.
- Both sets of test pieces are immersed in water at 80 ° C., which is particularly severe. Indeed, the incisions made on the coating facilitate the insertion of water at the epoxy-metal substrate interface. This process quickly leads to a loss of adhesion of the epoxy to the steel. After 900 hours of immersion, the test pieces were taken out of the bath for a qualitative evaluation of the adhesion.
- An incision is made, along the axis of the specimen, on the coating strip 2.5 cm wide, between the two incisions made prior to the immersion step.
- the tip of the knife is inserted horizontally (the flat of the blade) under the coating from the incision made along the axis of the specimen, so that the tip of the blade is in contact with the surface of the blade. metal.
- the plate of the blade By levering against a fulcrum such as a steel rod, the plate of the blade is moved away from the metal surface in a single movement and vertically, that is, in a 90 degree direction. the surface. The purpose of this operation is to try to tear off the coating.
- Peeling by peeling of the coating is very easy with regard to the series of test pieces.
- the 2.5 cm wide band is peeled around the circumference of the test pieces.
- test pieces obtained according to the same procedure as in Example 4C, are used to test the influence of the application of the silane solution, according to the process of the present invention, on the peel strength performance. cathode.
- the principle of the test is to create a defect in the coating to expose the metal.
- the defect is in contact with a saline solution, which serves as an electrolyte.
- the metal is set to a potential, corresponding to the cathodic protection, such that any oxidation of the iron entering the composition of the substrate is inhibited.
- This voltage generates an electrolytic reaction which leads to the formation of OH " ions and to the release hydrogen.
- the effect of this electrolytic reaction may be more or less harmful with respect to the adhesion of the coating to the periphery of the initial defect. It is therefore necessary to ensure the good compatibility of the cathodic protection with respect to the adhesion of the coating.
- This process is quantified through the length of the detachment of the coating around the defect, at the end of a given time of application of the cathodic protection. This peel length is often called the peel radius.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0610232A FR2908787B1 (fr) | 2006-11-22 | 2006-11-22 | Procede d'application d'un revetement anticorrosion sur les pieces d'une canalisation, incluant l'utilisation de solution aqueuse de silane et de peinture poudre epoxy. |
PCT/FR2007/001647 WO2008062108A2 (fr) | 2006-11-22 | 2007-10-09 | Procede d'application d 'un revetement anticorrosion sur les pieces d'une canalisation, incluant l'utilisation de solution aqueuse de silane et de peinture poudre epoxy |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2094401A2 true EP2094401A2 (fr) | 2009-09-02 |
Family
ID=38093408
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07858414A Withdrawn EP2094401A2 (fr) | 2006-11-22 | 2007-10-09 | Procede d'application d 'un revetement anticorrosion sur les pieces d'une canalisation, incluant l'utilisation de solution aqueuse de silane et de peinture poudre epoxy |
Country Status (7)
Country | Link |
---|---|
US (1) | US8221839B2 (ru) |
EP (1) | EP2094401A2 (ru) |
CA (1) | CA2670219C (ru) |
FR (1) | FR2908787B1 (ru) |
NO (1) | NO20092128L (ru) |
RU (1) | RU2442666C2 (ru) |
WO (1) | WO2008062108A2 (ru) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8852685B2 (en) | 2010-04-23 | 2014-10-07 | Lam Research Corporation | Coating method for gas delivery system |
IT1403637B1 (it) * | 2011-01-20 | 2013-10-31 | Saipem Spa | Metodo di giunzione di spezzoni di tubo per realizzare tubazioni per idrocarburi, in particolare tubazioni sottomarine |
EP2532769A1 (en) * | 2011-06-10 | 2012-12-12 | Amcor Flexibles Kreuzlingen Ltd. | Method of producing a chromium-free conversion coating on a surface of an aluminium or aluminium alloy strip |
WO2014033589A2 (en) * | 2012-08-31 | 2014-03-06 | Kimberly-Clark Worldwide, Inc. | Method of manufacture of article for delivering health-benefit agent |
CN102935423A (zh) * | 2012-10-19 | 2013-02-20 | 洛阳高登回转支承有限公司 | 一种金属表面防腐处理的方法 |
CN104415900A (zh) * | 2013-08-23 | 2015-03-18 | 上海图博可特石油管道涂层有限公司 | 石油输送管用ub滑套的防腐工艺 |
JP6399056B2 (ja) * | 2015-08-24 | 2018-10-03 | Jfeスチール株式会社 | ポリエチレン被覆鋼管およびその製造方法 |
JP6399055B2 (ja) * | 2015-08-24 | 2018-10-03 | Jfeスチール株式会社 | ポリエチレン被覆鋼管およびその製造方法 |
JP6610685B2 (ja) * | 2017-02-22 | 2019-11-27 | Jfeスチール株式会社 | ポリエチレン被覆鋼管およびその製造方法 |
JP6607265B2 (ja) * | 2017-02-22 | 2019-11-20 | Jfeスチール株式会社 | ポリエチレン被覆鋼管およびその製造方法 |
RU183884U1 (ru) * | 2017-12-11 | 2018-10-08 | Акционерное общество "Научно-исследовательский и конструкторский институт монтажной технологии - Атомстрой" (АО "НИКИМТ-Атомстрой") | Труба из нержавеющей стали с наружным защитным покрытием |
CN115780220A (zh) * | 2022-12-27 | 2023-03-14 | 西安天元合成材料有限公司 | 一种含切削液的石油管道防腐涂装工艺 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4322437C1 (de) * | 1993-07-06 | 1995-03-30 | Basf Lacke & Farben | Pulverlack, Verfahren zur Außenbeschichtung von Metallrohren sowie Verwendung des Pulverlacks zur einschichtigen Außenbeschichtung von Metallrohren |
US5633038A (en) * | 1994-10-25 | 1997-05-27 | Atlantic Richfield Company | Method of treatment of pipelines and other steel surfaces for improved coating adhesion |
US6065781A (en) * | 1998-05-29 | 2000-05-23 | Power Lone Star, Inc. | Method and apparatus for protecting the weld area of polyolefin coated pipe |
ES2623850T3 (es) * | 2000-10-11 | 2017-07-12 | Chemetall Gmbh | Procedimiento para el revestimiento de superficies metálicas antes de la conformación con un revestimiento similar a un barniz, y utilización de los substratos revestidos de tal manera |
US6444325B1 (en) * | 2000-12-22 | 2002-09-03 | Bayer Corporation | Two-component coating compositions containing silane adhesion promoters |
DE10308237B4 (de) * | 2003-02-25 | 2014-01-16 | Chemetall Gmbh | Verfahren zur Beschichtung von metallischen Oberflächen, zugehörige Zusammensetzung und ihre Verwendung |
-
2006
- 2006-11-22 FR FR0610232A patent/FR2908787B1/fr not_active Expired - Fee Related
-
2007
- 2007-10-09 EP EP07858414A patent/EP2094401A2/fr not_active Withdrawn
- 2007-10-09 WO PCT/FR2007/001647 patent/WO2008062108A2/fr active Application Filing
- 2007-10-09 CA CA2670219A patent/CA2670219C/fr not_active Expired - Fee Related
- 2007-10-09 RU RU2009123463/05A patent/RU2442666C2/ru not_active IP Right Cessation
- 2007-10-09 US US12/515,570 patent/US8221839B2/en not_active Expired - Fee Related
-
2009
- 2009-06-02 NO NO20092128A patent/NO20092128L/no not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO2008062108A2 * |
Also Published As
Publication number | Publication date |
---|---|
CA2670219A1 (fr) | 2008-05-29 |
RU2009123463A (ru) | 2010-12-27 |
WO2008062108A3 (fr) | 2008-07-24 |
RU2442666C2 (ru) | 2012-02-20 |
US20100055327A1 (en) | 2010-03-04 |
FR2908787A1 (fr) | 2008-05-23 |
CA2670219C (fr) | 2012-11-27 |
NO20092128L (no) | 2009-08-14 |
US8221839B2 (en) | 2012-07-17 |
WO2008062108A2 (fr) | 2008-05-29 |
FR2908787B1 (fr) | 2009-01-16 |
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