EP1901995A2 - Nanoparticules de carbone, leur production et leur utilisation - Google Patents
Nanoparticules de carbone, leur production et leur utilisationInfo
- Publication number
- EP1901995A2 EP1901995A2 EP06762488A EP06762488A EP1901995A2 EP 1901995 A2 EP1901995 A2 EP 1901995A2 EP 06762488 A EP06762488 A EP 06762488A EP 06762488 A EP06762488 A EP 06762488A EP 1901995 A2 EP1901995 A2 EP 1901995A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- carbon nanoparticles
- carbon
- nanoparticles according
- spherical
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000011852 carbon nanoparticle Substances 0.000 title claims abstract description 43
- 238000004519 manufacturing process Methods 0.000 title abstract description 10
- 239000003054 catalyst Substances 0.000 claims abstract description 57
- 239000002245 particle Substances 0.000 claims abstract description 24
- 229910052751 metal Inorganic materials 0.000 claims abstract description 14
- 239000002184 metal Substances 0.000 claims abstract description 14
- 239000000835 fiber Substances 0.000 claims abstract description 13
- 239000002243 precursor Substances 0.000 claims abstract description 12
- 238000005229 chemical vapour deposition Methods 0.000 claims abstract description 11
- 150000002739 metals Chemical class 0.000 claims abstract description 11
- 239000000654 additive Substances 0.000 claims abstract description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 6
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 6
- 239000000919 ceramic Substances 0.000 claims abstract description 4
- 239000002131 composite material Substances 0.000 claims abstract description 4
- 239000000758 substrate Substances 0.000 claims abstract description 4
- 239000011149 active material Substances 0.000 claims abstract description 3
- 239000003463 adsorbent Substances 0.000 claims abstract description 3
- 239000011521 glass Substances 0.000 claims abstract description 3
- 229910001092 metal group alloy Inorganic materials 0.000 claims abstract description 3
- 229920000642 polymer Polymers 0.000 claims abstract description 3
- 239000004753 textile Substances 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 11
- 239000002105 nanoparticle Substances 0.000 claims description 3
- 238000004146 energy storage Methods 0.000 claims description 2
- 238000001914 filtration Methods 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 25
- 239000000047 product Substances 0.000 description 25
- 238000001878 scanning electron micrograph Methods 0.000 description 19
- 229910052799 carbon Inorganic materials 0.000 description 13
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 13
- 238000003917 TEM image Methods 0.000 description 10
- 239000002041 carbon nanotube Substances 0.000 description 10
- 229910021393 carbon nanotube Inorganic materials 0.000 description 10
- 239000002048 multi walled nanotube Substances 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000004913 activation Effects 0.000 description 6
- 239000002134 carbon nanofiber Substances 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000002086 nanomaterial Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 5
- 238000009826 distribution Methods 0.000 description 4
- 229910052734 helium Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000010891 electric arc Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000001307 helium Substances 0.000 description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000000608 laser ablation Methods 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000012452 mother liquor Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 230000000877 morphologic effect Effects 0.000 description 2
- 239000002071 nanotube Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 235000005811 Viola adunca Nutrition 0.000 description 1
- 240000009038 Viola odorata Species 0.000 description 1
- 235000013487 Viola odorata Nutrition 0.000 description 1
- 235000002254 Viola papilionacea Nutrition 0.000 description 1
- 244000172533 Viola sororia Species 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 239000002082 metal nanoparticle Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000011027 product recovery Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000011163 secondary particle Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000759 toxicological effect Toxicity 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
- C01B32/162—Preparation characterised by catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/02—Single-walled nanotubes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/06—Multi-walled nanotubes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/20—Nanotubes characterized by their properties
- C01B2202/36—Diameter
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2918—Rod, strand, filament or fiber including free carbon or carbide or therewith [not as steel]
Definitions
- Carbon nanoparticles their preparation and their use
- the present invention relates to carbon nanoparticles of fibers or tubes which are morphologically present in the form of separate spherical and / or spherical secondary agglomerates, a process for their preparation and their use.
- Nanomaterials Solid substances with nanoscopic particle sizes are called nanomaterials. Compared to microscopic particle sizes, this can lead to sudden changes in properties or even new product properties. Nanomaterials are attributed a high technical application potential. Compared with the variety of new nanoscopic material systems, however, only a few nanomaterials have already been established on the market.
- carbon nanoparticles in the form of tubes or fibers also referred to as carbon nanotubes or fibers
- arc discharge a carbon gas is generated between two carbon electrodes, from which carbon nanotubes are formed in the presence of a catalyst or even without a catalyst.
- CVD Chemical Vapor Deposition
- a carbon target is evaporated under Ar or He atmosphere by means of a laser. Upon cooling, the carbon units condense and form carbon nanomaterials.
- a gaseous carbon source under reaction conditions for example methane, ethene or CO, as well as a catalyst, which usually contains active components from the series of transition elements Fe, Co and Ni, are used.
- a catalyst which usually contains active components from the series of transition elements Fe, Co and Ni.
- carbon nanotubes are deposited on the catalyst particles.
- the Navonoubes are entangled here and fall in loose powder form.
- Carbon, Vol. 41 (2003), pp. 539-547 describes the production of carbon nanotubes by a CVD process in which acetylene is used as carbon source and an iron catalyst. Again, the carbon nanotubes form entanglements.
- the invention is therefore based on the object to provide carbon nanoparticles of fibers or tubes, in which the emission of nanoscopic units including carbon nanoparticles and metal nanoparticles is reduced to the environment and in terms of their separation and processing and Further processing in technically advanced processes are improved. Furthermore, a simple process for their production should be specified.
- the invention thus provides carbon nanoparticles of fibers or tubes or combinations thereof, which are morphologically present in the form of macroscopic, mutually delimited spherical and / or spherical secondary agglomerates.
- the invention further provides a process for the preparation of the carbon nanoparticles by a CVD process using nanoporous catalyst particles having a spherical and / or spherical secondary structure which contain as catalytically active components nanoparticulate metals and / or metal oxides or their precursors.
- the invention relates to the use of the carbon nanoparticles, for example as adsorbents, additives or active materials in energy storage systems, in supercapacitors, as filter media, as supports for catalysts, as sensors or as a substrate for sensors or as additives for polymers, ceramics, Metals and metal alloys, glasses, textiles and composites, such as carbon composites.
- the carbon nanoparticles according to the invention differ from conventional carbon nanoparticles in that they are morphologically present in the form of macroscopic, sharply delimited spherical and / or spherical secondary agglomerates.
- the carbon nanoparticles according to the invention can be better used and optimized with respect to their technical further processing in comparison to the prior art.
- the fibers or tubes of the carbon nanoparticles according to the invention typically have a diameter of 1-500 nm, preferably 10-100 nm, more preferably 10-50 nm.
- the size of the secondary agglomerates is controllable by the size of the catalyst particles, the composition of the catalyst and the choice of synthesis parameters, such as carbon source, concentrations, temperatures and reaction time.
- the shape of the final product is determined by the catalyst predetermined morphology.
- the secondary agglomerates according to the invention preferably have a diameter of 500 nm to 1000 ⁇ m. The relative particle size distribution remains in the final product in comparison to the particle size distribution of the catalyst despite a strong volume increase.
- the carbon originating from gaseous carbon sources dissolves in the catalytically active metal and can then be deposited again in nanoscopic form.
- the secondary agglomerates contain no core of the catalyst particle, but consist entirely of carbon nanomaterials that are entangled in one another.
- the carbon nanofibers of the present invention may be herringbone type as well as platelet-type and screw-type.
- the carbon nanotubes can be of the single-walled or multi-walled type or of the loop type.
- the circumference Up of the nanoparticles in two-dimensional projection and the circumference of a circle of equal area Uk in a ratio in the range of Uk: Up is from 1.0 to 0.65.
- the preparation of the carbon nanoparticles according to the invention is carried out by a CVD method using nanoporous catalyst particles having a spherical and / or spheroidal secondary structure which contain nanoparticulate metals or their precursors as catalytically active components.
- These catalyst particles may additionally contain metal oxides or their precursors, which serve as a substrate for the actually catalytically active metals.
- the catalyst metal is in particular Fe, Co, Ni and Mn. Both the pure metals and metal oxide / metal composites can be used, as well as their precursors.
- sparingly soluble compounds such as hydroxides, carbonates or other compounds that can be converted into catalytically active metals or metal / support composites can be used.
- the carbon source used is the carbonaceous compounds used according to the prior art, which are reacted at the respective reaction temperature. be present in the gas, such as methane. Ethene, acetylene, CO,
- Figures 2a, 2b and 2c are SEM images of the product of Example 1
- Figures 5a, 5b and 5c are SEM images of the product of Example 2.
- Figures 7a and 7b are SEM images of the catalyst used in Example 3.
- Figures 8a, 8b, 8c and 8d are SEM images of the product of Example 3.
- FIGS. 10a and 10b SEM images of the catalyst from Example 4.
- Figures 13a and 13b are SEM images of the catalyst from Example 5
- Figures 14a, 14b, 14c and 14d are SEM images of the product of Example 5.
- Example 1 Preparation of Multi-walled Carbon Nanotube Spherical Aggregates via a Co / Mn-Based Catalyst
- the catalyst is prepared by continuously combining three educt solutions.
- Solution II 3130 ml of a solution of 960.4 g of Co (NO 3 ) 2 .6H 2 O and
- the individual solutions are metered simultaneously with a constant metering rate over a period of 24 h in a 1 1 reactor, which allows intensive mixing and is equipped with an overflow, is continuously discharged through the product suspension.
- the precipitation reaction takes place at 50 0 C.
- the product is taken from the overflow.
- the suspension has a deep blue-violet color.
- the solid is separated on a suction filter from the mother liquor, then washed six times with 100 ml of demineralized water and then dried at 80 0 C for 30 h in a drying oven.
- a pulverulent, readily flowable, violet precursor having a spherical particle morphology is obtained.
- Figure 4 shows a size comparison between the catalyst particles used and the carbon nanoproduct obtained.
- Example 2 Production of multi-walled carbon nanotube aggregates via a (Co, Mn) CO 3 catalyst
- a catalyst according to Example 1 is used directly without prior activation for the production of multi-walled carbon nanotubes.
- the conversion to multi-walled carbon nanotubes takes place as in Example 1 without a preceding reduction step.
- the product shows a uniform distribution in the thickness of the nanotubes, as can be seen from the SEM images in Figures 5a, 5b, and 5c.
- the TEM images in Figures 6a and 6b demonstrate the presence of multi-walled carbon nanotubes.
- Example 3 Production of multi-walled carbon nanotube aggregates with narrow particle distribution over a (Co, Mn) CO 3 catalyst
- a catalyst according to Example 1 is classified by sieving size and a particle size fraction of 20 microns - 32 microns used without prior activation directly as a catalyst.
- Figures 7a and 7b show SEM images of the catalyst sieve fraction used.
- Figures 10a and 10b show SEM images of the catalyst.
- the activation of the catalyst takes place during heating between 300 0 C and 600 0 C by reduction of the precursor with H 2 for about 20 min. (Gas mixture 24 l / h C 2 H 4 , 6 l / h H 2 ).
- the synthesis takes place at 500-600 0 C 2 h with a mixture of 32 l / h C 2 H 4 , 81 / h H 2 instead.
- Figures I I a and I Ib show SEM images of the product. The morphological expression as sharply demarcated spherical and / or spherical secondary structures is preserved.
- Figures 13a and 13b show SEM images of the catalyst sieve fraction> 20 ⁇ m.
- the carbon nanofibers are synthesized under carbon monoxide / hydrogen (20: 8) over a four-hour period. A black voluminous product is obtained.
Abstract
L'invention concerne des nanoparticules de carbone à base de fibres ou de tubes ou de combinaisons des deux, se présentant sous forme d'agglomérats secondaires morphologiquement macroscopiques, sphériques et/ou sphéroïdes, délimités les uns par rapport aux autres. L'invention concerne en outre un procédé permettant de produire des nanoparticules de carbone par un procédé de dépôt chimique en phase vapeur, au moyen de particules de catalyseur nanoporeuses de structure sphérique et/ou sphéroïde, qui contiennent comme constituants à action catalytique, des métaux nanoparticulaires et/ou des oxydes métalliques ou leurs précurseurs. Lesdites particules de carbone selon l'invention peuvent s'utiliser comme adsorbants, additifs ou matériaux actifs dans des systèmes d'accumulation d'énergie, dans des supercondensateurs, comme milieux filtrants, comme catalyseurs ou excipients pour catalyseurs, comme détecteurs ou comme substrats de détecteurs, comme additifs pour polymères, céramiques, métaux et alliages métalliques, verres, textiles et matériaux composites.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005032072A DE102005032072A1 (de) | 2005-07-08 | 2005-07-08 | Kohlenstoff-Nanopartikel, deren Herstellung und deren Verwendung |
PCT/EP2006/006680 WO2007006511A2 (fr) | 2005-07-08 | 2006-07-07 | Nanoparticules de carbone, leur production et leur utilisation |
Publications (1)
Publication Number | Publication Date |
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EP1901995A2 true EP1901995A2 (fr) | 2008-03-26 |
Family
ID=37461558
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06762488A Withdrawn EP1901995A2 (fr) | 2005-07-08 | 2006-07-07 | Nanoparticules de carbone, leur production et leur utilisation |
Country Status (6)
Country | Link |
---|---|
US (1) | US20090081454A1 (fr) |
EP (1) | EP1901995A2 (fr) |
JP (1) | JP2009500281A (fr) |
KR (1) | KR20080048457A (fr) |
DE (1) | DE102005032072A1 (fr) |
WO (1) | WO2007006511A2 (fr) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080053922A1 (en) * | 2006-09-01 | 2008-03-06 | Honsinger Charles P Jr | Nanostructured materials comprising support fibers coated with metal containing compounds and methods of using the same |
EA028873B1 (ru) | 2009-04-17 | 2018-01-31 | СИРСТОУН ЭлЭлСи | Способ производства твердого углерода путем восстановления оксидов углерода |
WO2013158161A1 (fr) | 2012-04-16 | 2013-10-24 | Seerstone Llc | Procédé et systèmes de capture et de séquestration de carbone et de réduction de la masse des oxydes de carbone dans un courant de gaz d'échappement |
EP2838837A4 (fr) | 2012-04-16 | 2015-12-23 | Seerstone Llc | Procédés et structures de réduction d'oxydes de carbone avec des catalyseurs non ferreux |
US9475699B2 (en) | 2012-04-16 | 2016-10-25 | Seerstone Llc. | Methods for treating an offgas containing carbon oxides |
NO2749379T3 (fr) | 2012-04-16 | 2018-07-28 | ||
MX354529B (es) | 2012-04-16 | 2018-03-07 | Seerstone Llc | Métodos para producir carbono sólido mediante la reducción de dióxido de carbono. |
US9896341B2 (en) | 2012-04-23 | 2018-02-20 | Seerstone Llc | Methods of forming carbon nanotubes having a bimodal size distribution |
JP6284934B2 (ja) | 2012-07-12 | 2018-02-28 | シーアストーン リミテッド ライアビリティ カンパニー | カーボンナノチューブを含む固体炭素生成物およびそれを形成する方法 |
US10815124B2 (en) | 2012-07-12 | 2020-10-27 | Seerstone Llc | Solid carbon products comprising carbon nanotubes and methods of forming same |
CN104619640B (zh) | 2012-07-13 | 2017-05-31 | 赛尔斯通股份有限公司 | 用于形成氨和固体碳产物的方法和*** |
US9779845B2 (en) | 2012-07-18 | 2017-10-03 | Seerstone Llc | Primary voltaic sources including nanofiber Schottky barrier arrays and methods of forming same |
US9650251B2 (en) | 2012-11-29 | 2017-05-16 | Seerstone Llc | Reactors and methods for producing solid carbon materials |
US9783421B2 (en) | 2013-03-15 | 2017-10-10 | Seerstone Llc | Carbon oxide reduction with intermetallic and carbide catalysts |
EP3129133A4 (fr) | 2013-03-15 | 2018-01-10 | Seerstone LLC | Systèmes de production de carbone solide par réduction d'oxydes de carbone |
WO2014151138A1 (fr) | 2013-03-15 | 2014-09-25 | Seerstone Llc | Réacteurs, systèmes et procédés de formation de produits solides |
US10115844B2 (en) | 2013-03-15 | 2018-10-30 | Seerstone Llc | Electrodes comprising nanostructured carbon |
US9783416B2 (en) | 2013-03-15 | 2017-10-10 | Seerstone Llc | Methods of producing hydrogen and solid carbon |
US11752459B2 (en) | 2016-07-28 | 2023-09-12 | Seerstone Llc | Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same |
Family Cites Families (6)
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JP3074170B1 (ja) * | 1999-05-27 | 2000-08-07 | 大澤 映二 | ナノサイズ真球状黒鉛製造方法 |
JP3491747B2 (ja) * | 1999-12-31 | 2004-01-26 | 喜萬 中山 | カーボンナノコイルの製造方法及び触媒 |
US7550129B2 (en) * | 2000-09-08 | 2009-06-23 | Catalytic Materials, Llc | Graphite nanofibers having graphite sheets parallel to the growth axis |
US7135160B2 (en) * | 2002-04-02 | 2006-11-14 | Carbon Nanotechnologies, Inc. | Spheroidal aggregates comprising single-wall carbon nanotubes and method for making the same |
JP3606855B2 (ja) * | 2002-06-28 | 2005-01-05 | ドン ウン インターナショナル カンパニー リミテッド | 炭素ナノ粒子の製造方法 |
FR2857955B1 (fr) * | 2003-07-23 | 2006-12-01 | Univ Claude Bernard Lyon | Procede de fabrication de nanocomposes de carbone graphitique et en particulier de nanoperles, en vrac ou de facon individualisee |
-
2005
- 2005-07-08 DE DE102005032072A patent/DE102005032072A1/de not_active Ceased
-
2006
- 2006-07-07 KR KR1020087003219A patent/KR20080048457A/ko not_active Application Discontinuation
- 2006-07-07 JP JP2008519869A patent/JP2009500281A/ja active Pending
- 2006-07-07 US US11/922,753 patent/US20090081454A1/en not_active Abandoned
- 2006-07-07 WO PCT/EP2006/006680 patent/WO2007006511A2/fr active Application Filing
- 2006-07-07 EP EP06762488A patent/EP1901995A2/fr not_active Withdrawn
Non-Patent Citations (3)
Title |
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FENELONOV, DEREVYANKIN, OKKEL, AVDEEVA, ZAIKOVSKII, MOROZ, SALANOV, RUDINA, LIKHOLOBOV, SHAIKHUTDINOV: "Structure and Texture of Filamentous Carbons Produced by Methane Decomposition on Ni and Ni-Cu Catalysts", CARBON, vol. 35, no. 8, 1997, pages 1129 - 1140 * |
W. TEUNISSEN: "Tailoring of Carbon Fiber and Carbon-Coated Ferromagnetic Catalyst Supports", 25 April 2000, Utrecht, pages: 13 - 40 * |
W. TEUNISSEN: "Tailoring of Carbon Fiber and Carbon-Coated Ferromagnetic Catalyst Supports", 25 April 2000, Utrecht, pages: 87 - 105 * |
Also Published As
Publication number | Publication date |
---|---|
KR20080048457A (ko) | 2008-06-02 |
DE102005032072A1 (de) | 2007-01-11 |
US20090081454A1 (en) | 2009-03-26 |
WO2007006511A3 (fr) | 2007-04-26 |
WO2007006511A2 (fr) | 2007-01-18 |
JP2009500281A (ja) | 2009-01-08 |
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