EP1753698A1 - Procede et dispositif d'affinage et d'homogeneisation du verre et produits obtenus a l'aide de ce procede - Google Patents

Procede et dispositif d'affinage et d'homogeneisation du verre et produits obtenus a l'aide de ce procede

Info

Publication number
EP1753698A1
EP1753698A1 EP05766619A EP05766619A EP1753698A1 EP 1753698 A1 EP1753698 A1 EP 1753698A1 EP 05766619 A EP05766619 A EP 05766619A EP 05766619 A EP05766619 A EP 05766619A EP 1753698 A1 EP1753698 A1 EP 1753698A1
Authority
EP
European Patent Office
Prior art keywords
glass
compartment
rotation
refining
molten
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05766619A
Other languages
German (de)
English (en)
French (fr)
Inventor
Pierre Jeanvoine
Ramon Rodriguez Cuartas
Luis Grijalba Goicoechea
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saint Gobain Glass France SAS
Compagnie de Saint Gobain SA
Original Assignee
Saint Gobain Glass France SAS
Compagnie de Saint Gobain SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saint Gobain Glass France SAS, Compagnie de Saint Gobain SA filed Critical Saint Gobain Glass France SAS
Publication of EP1753698A1 publication Critical patent/EP1753698A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J11/00Gas-filled discharge tubes with alternating current induction of the discharge, e.g. alternating current plasma display panels [AC-PDP]; Gas-filled discharge tubes without any main electrode inside the vessel; Gas-filled discharge tubes with at least one main electrode outside the vessel
    • H01J11/20Constructional details
    • H01J11/34Vessels, containers or parts thereof, e.g. substrates
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/18Stirring devices; Homogenisation
    • C03B5/187Stirring devices; Homogenisation with moving elements
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/225Refining
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/225Refining
    • C03B5/2252Refining under reduced pressure, e.g. with vacuum refiners
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/225Refining
    • C03B5/2255Refining by centrifuging
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • C03C3/087Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J11/00Gas-filled discharge tubes with alternating current induction of the discharge, e.g. alternating current plasma display panels [AC-PDP]; Gas-filled discharge tubes without any main electrode inside the vessel; Gas-filled discharge tubes with at least one main electrode outside the vessel
    • H01J11/10AC-PDPs with at least one main electrode being out of contact with the plasma
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/133302Rigid substrates, e.g. inorganic substrates
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/50Glass production, e.g. reusing waste heat during processing or shaping
    • Y02P40/57Improving the yield, e-g- reduction of reject rates
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31Surface property or characteristic of web, sheet or block

Definitions

  • This operation consists in eliminating as much as possible gaseous inclusions of various sizes, called “broths”, bubbles or “chips”, the presence of which in the final product is often strictly controlled and sometimes prohibitive.
  • gaseous inclusions of various sizes, called “broths”, bubbles or “chips”, the presence of which in the final product is often strictly controlled and sometimes prohibitive.
  • the quality requirements in terms of refining are very strict for automotive applications (in particular windshields, which must ensure perfect visibility), and even more stringent for applications of flat glass in the electronic field, in particular as flat screen substrates such as liquid crystal screens (LCD), the presence of gaseous inclusions can then disturb the electrical operation and / or deform certain pixels constituting the image.
  • These gas inclusions have several origins. They mainly come from the air trapped between the grains of the pulverulent matter and from degassing due to certain chemical reactions occurring during the glass melting step.
  • the molten glass is preferably brought back to a substantially atmospheric pressure by the effect of its own gravity, an effect possibly coupled with an effect of centrifugal force, and then flows out of the mobile device in rotation. towards a forming stage.
  • This step of the process is carried out in the lower zone or cavity, preferably cylindrical, located under the vacuum compartment, and at the lower end of which is located the or each glass outlet orifice.
  • the rotation plays a role of homogenization until the step of removing the glass from the rotating device. It has in fact been observed that the shear stresses undergone by the glass due to the rotation considerably increase the chemical homogeneity of the glass, this much more effectively than can be done by homogenization by means of mechanical agitators sometimes called “stirrers”. ". In addition, a beneficial effect on the refining is also observed due to these same shear stresses, manifested by a fragmentation of the bubbles still present in a multitude of small invisible or easily absorbable bubbles in the glass. Above 500 revolutions / minute, the feasibility on an industrial scale is however compromised.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Glass Compositions (AREA)
  • Glass Melting And Manufacturing (AREA)
EP05766619A 2004-05-27 2005-05-24 Procede et dispositif d'affinage et d'homogeneisation du verre et produits obtenus a l'aide de ce procede Withdrawn EP1753698A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0451047A FR2870842B1 (fr) 2004-05-27 2004-05-27 Procede et dispositif de fabrication du verre et produits obtenus a l'aide de ce procede
PCT/FR2005/050354 WO2005118493A1 (fr) 2004-05-27 2005-05-24 Procede et dispositif d'affinage et d'homogeneisation du verre et produits obtenus a l'aide de ce procede

Publications (1)

Publication Number Publication Date
EP1753698A1 true EP1753698A1 (fr) 2007-02-21

Family

ID=34947288

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05766619A Withdrawn EP1753698A1 (fr) 2004-05-27 2005-05-24 Procede et dispositif d'affinage et d'homogeneisation du verre et produits obtenus a l'aide de ce procede

Country Status (8)

Country Link
US (1) US20080187686A1 (zh)
EP (1) EP1753698A1 (zh)
JP (1) JP2008500255A (zh)
KR (1) KR20070015212A (zh)
CN (1) CN101023036B (zh)
FR (1) FR2870842B1 (zh)
TW (1) TW200607773A (zh)
WO (1) WO2005118493A1 (zh)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5435267B2 (ja) 2008-10-01 2014-03-05 日本電気硝子株式会社 ガラスロール、ガラスロールの製造装置、及びガラスロールの製造方法
CN105110633A (zh) * 2008-12-18 2015-12-02 圣戈本陶瓷及塑料股份有限公司 套管块
DE102009000785B4 (de) * 2009-02-11 2015-04-02 Schott Ag Verfahren und Vorrichtung zur Herstellung von Glas
US8613806B2 (en) * 2010-08-30 2013-12-24 Corning Incorporated Method for eliminating carbon contamination of platinum-containing components for a glass making apparatus
CN103232160B (zh) * 2012-06-05 2018-07-24 杨德宁 一种具有低热膨胀系数的平板玻璃及其制造工艺
CN103145333A (zh) * 2012-06-05 2013-06-12 杨德宁 低热膨胀系数的玻璃、制备工艺及其玻璃制品
CN102928451A (zh) * 2012-11-01 2013-02-13 白雪冰 玻璃熔片均匀性的检验方法
US9227865B2 (en) * 2012-11-29 2016-01-05 Johns Manville Methods and systems for making well-fined glass using submerged combustion
US9637406B2 (en) 2013-03-15 2017-05-02 Owens-Brockway Glass Container Inc. Apparatus for melting and refining silica-based glass
CN103833221A (zh) * 2013-05-06 2014-06-04 杨德宁 一种具有低热膨胀系数的高铝平板玻璃及其制造工艺
CN107382030B (zh) * 2017-09-08 2023-08-22 中建材玻璃新材料研究院集团有限公司 一种用于电子显示玻璃铂金通道的密封结构
US11001519B2 (en) 2018-03-15 2021-05-11 Owens-Brockway Glass Container Inc. Vacuum refining of molten glass
US10858277B2 (en) 2018-03-15 2020-12-08 Owens-Brockway Glass Container Inc. Refining glass with reduced pressure
US11912608B2 (en) * 2019-10-01 2024-02-27 Owens-Brockway Glass Container Inc. Glass manufacturing
US11370686B2 (en) 2019-10-01 2022-06-28 Owens-Brockway Glass Container Inc. Fining submerged combustion glass

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US2097502A (en) * 1933-03-18 1937-11-02 Union Carbide & Carbon Corp Method of and apparatus for producing rods and the like of comminuted material
AU422827B2 (en) * 1967-10-03 1972-03-28 Monzino Riotinto Of Australia Limited Continuous degassing of metals
AT292230B (de) * 1968-10-15 1971-08-25 Zd Avtosteklo Verfahren zur Herstellung von glaskristallinem Tafelmaterial
US3754886A (en) * 1971-04-02 1973-08-28 Owens Illinois Inc Method for refining molten glass
US3674904A (en) * 1971-05-21 1972-07-04 Amersil Inc Furnace for making fused quartz hollow slugs
US4040795A (en) * 1974-06-04 1977-08-09 Lothar Jung Method for the conversion of crystalline silica raw materials into amorphous silica
US3938981A (en) * 1974-10-29 1976-02-17 Owens-Illinois, Inc. Method for removing gaseous inclusions from molten glass
DE3418284A1 (de) * 1984-05-17 1985-11-21 Schott Glaswerke, 6500 Mainz Verfahren und vorrichtung zum chargenweisen herstellen von glas
US4738938A (en) * 1986-01-02 1988-04-19 Ppg Industries, Inc. Melting and vacuum refining of glass or the like and composition of sheet
JPH08211198A (ja) * 1995-02-06 1996-08-20 Nikon Corp 中性子反射鏡
US5785726A (en) * 1996-10-28 1998-07-28 Corning Incorporated Method of reducing bubbles at the vessel/glass interface in a glass manufacturing system
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Also Published As

Publication number Publication date
JP2008500255A (ja) 2008-01-10
FR2870842B1 (fr) 2007-11-02
FR2870842A1 (fr) 2005-12-02
KR20070015212A (ko) 2007-02-01
US20080187686A1 (en) 2008-08-07
CN101023036A (zh) 2007-08-22
TW200607773A (en) 2006-03-01
CN101023036B (zh) 2010-07-21
WO2005118493A1 (fr) 2005-12-15

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