EP1089944A1 - Method for melting rock material for mineral fibre production - Google Patents

Method for melting rock material for mineral fibre production

Info

Publication number
EP1089944A1
EP1089944A1 EP99913327A EP99913327A EP1089944A1 EP 1089944 A1 EP1089944 A1 EP 1089944A1 EP 99913327 A EP99913327 A EP 99913327A EP 99913327 A EP99913327 A EP 99913327A EP 1089944 A1 EP1089944 A1 EP 1089944A1
Authority
EP
European Patent Office
Prior art keywords
rock material
furnace
melting
additive
melt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP99913327A
Other languages
German (de)
French (fr)
Inventor
Peter Laur N
Kimmo Tamminen
Michael Perander
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Paroc Hold Oy AB
Original Assignee
Paroc Group Oy AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Paroc Group Oy AB filed Critical Paroc Group Oy AB
Publication of EP1089944A1 publication Critical patent/EP1089944A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B3/00Charging the melting furnaces
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/12Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in shaft furnaces

Definitions

  • the present invention relates to a method of melting rock material into a smelt used for manufacturing mineral fiber.
  • the method according to the invention is implemented by performing the melting in a shaft furnace in which the rock material and the amount of fuel proportionated according to the quantity of the rock material is fed into the furnace via an inlet at the top thereof .
  • the rock material is crushed to a proper particle size.
  • the particle size of coke conventionally used as the fuel is selected appropriately.
  • the rock material and coke are charged into this type of furnace in layers, whereby the pile of layered raw materials sinks in the furnace downward as the lower end of the pile melts in the melting zone formed in the bottom part of the furnace and is discharged from the furnace bottom.
  • air is injected upward at a suitable height from the furnace bottom into the mixture of rock material and fuel.
  • the flue gases formed in the fuel combustion process rise through the pile of rock material and fuel until reaching the top of the furnace to be discharged therefrom.
  • the particle size in the pile must be sufficiently large to provide an appropriate free space about the particles.
  • injection nozzles of a special construction are used to feed the combustion air into the melting zone.
  • the melt formed is collected on the furnace bottom into a pool of suitable height by allowing the excess melt to discharge over a weir disposed slightly above the level of the furnace bottom.
  • This pool formation serves to equalize the short-term fluctuations of the melt qualities.
  • the average composition of the melt must be controlled by adjusting the composition of the raw materials to be melted, that is, by adding suitable ingredients to the in- feed material mix.
  • the composition of materials being melted is controlled by sampling the melt, and based thereon, adding the required raw material components to the top of the furnace, into the infeed mix of rock material and fuel.
  • a melt control technique is primarily hampered by the finite transport delay of the added component along with the rock material to the bottom of the furnace. This delay brings about a significant uncertainty factor to the material composition control and, in spite of predictive calculations and estimations, inaccuracy of control results.
  • the composition of the melt is difficult to keep within the set limits.
  • the additive ingredients tra- veiling downward in the raw material pile will be subjected to a relatively long period in contact with the hot flue gases, which leads to loss of additive ingredients 3 through evaporation. Particularly apatite and boron compounds are problematic in this respect.
  • some of the additive ingredients such as bauxite and titanium compounds are slowly melting requiring their grinding to a substantially smaller particle size than the rock material and the fuel .
  • the fine particulate matter causes problems to the passage of flue gases through the material pile as well as loss of material due to entrained transport of material dust, whereby the elimination of these problems necessitates briquetting of additive ingredients into sufficiently large agglomerates.
  • additive ingredient can be introduced along with a carrier medium directly into the melting zone or its immediate vicinity.
  • the additive ingredient can be introduced into the furnace along with the combustion air.
  • the additive ingredient can be mixed with an auxiliary fuel which may be a gaseous, liquid or fine-ground solid fuel.
  • the combinations of the above carriers can be used for introducing the additive ingredient.
  • the melt composition can be primarily controlled using conventional coarse control techniques, so that the initial charge of 4 basic materials known beforehand to be in short supply in the melt and also known to behave rather unproblematical- ly in the melting process, are added slightly undercompensated into the melting furnace. Then, the special cha- racter of the present invention can be utilized for fine control of the melt composition and the introduction of hard-to-melt additive ingredients.
  • the introduction of the additive ingredient along with its carrier medium can be complemented by feeding enriching oxygen into the melting zone, whereby the feed rate of oxygen addition is adjusted compatible with the actual composition of additive ingredients thus creating advan- tageous conditions for the melting thereof in melting zone. Due to the presence of carbon, the overall conditions in the melting zone are reducing. The degree of reducing conditions can be decreased by the oxygen addition, or even reversed into oxidizing conditions if the excess amount of oxygen addition is sufficiently large.
  • the introduction of the enriching oxygen is advantageously carried out separately from the introduction of additive ingredients and also is provided with an independent control facility. This can be accomplished by different types of injection nozzle constructions having separate channels on one hand for the additive ingredient (s) and its carrier and on the other hand for the enriching oxygen.
  • melt viscosity is primarily affected by the melt composition and temperature.
  • the available raw material and/or the raw material 5 mix giving the desired melt composition may be such that melts at a high temperature requiring the melt to kept at a high melt temperature, too.
  • This melt pool temperature may be excessively high to maintain the optimal viscosity, which subsequently causes problems in the fi- berizing stage.
  • the method according to the invention can offer a solution to problem by allowing the introduction of such an additive ingredient that has no significant effect on the melt composition.
  • the mel- ting of such an additive ingredient binds heat thus lowering the melt temperature.
  • One useable additive for this purpose is recycled fiber, preferably in milled form.
  • the control of melt composition by virtue of the method according to the invention may also be used for controlling the composition-dependent viscosity of the melt.
  • the implementation of the invention may be accomplished by means of conventional infeed equipment based on, e.g., the use a carrier gas flow into which solid particulate matter is introduced with the help of a separate feed apparatus .
  • the feed apparatus in an embodiment of such equipment comprises a rotating compartmental feeder adapted centrally in a cylindrical container, said feeder having its compartments bordered by the cylindrical shell of the container and its end surfaces.
  • the carrier gas flow is provided with opposite aligned inlet and outlet nozzles, respectively, at the opposite ends of the cylindrical container thus permitting the carrier gas flow to entrain the solid particulate matter loaded in the com- partments as they sequentially meet the opposed nozzles.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention is related to a method of melting rock material for the manufacture of mineral fiber. In the method, the crushed rock material and the amount of fuel, proportionated according to the quantity of the rock material, together with a possible introduction of additive ingredients, are introduced into a shaft furnace, and combustion air possibly complemented with auxiliary fuel is introduced into the bottom part of the furnace in order to create a melting zone. The melted rock material is discharged from the furnace bottom. According to the method, at least a portion of said additive ingredients is introduced along with a carrier medium directly into the melting zone or its immediate vicinity.

Description

Method for melting rock material for mineral fibre production
The present invention relates to a method of melting rock material into a smelt used for manufacturing mineral fiber.
The method according to the invention is implemented by performing the melting in a shaft furnace in which the rock material and the amount of fuel proportionated according to the quantity of the rock material is fed into the furnace via an inlet at the top thereof . The rock material is crushed to a proper particle size. Also the particle size of coke conventionally used as the fuel is selected appropriately. Typically, the rock material and coke are charged into this type of furnace in layers, whereby the pile of layered raw materials sinks in the furnace downward as the lower end of the pile melts in the melting zone formed in the bottom part of the furnace and is discharged from the furnace bottom. To maintain the melt zone at the bottom of the furnace, air is injected upward at a suitable height from the furnace bottom into the mixture of rock material and fuel. The flue gases formed in the fuel combustion process rise through the pile of rock material and fuel until reaching the top of the furnace to be discharged therefrom. To ensure an unobstructed passage of flue gases through the pile, the particle size in the pile must be sufficiently large to provide an appropriate free space about the particles.
To feed the combustion air into the melting zone, injection nozzles of a special construction are used. The melt formed is collected on the furnace bottom into a pool of suitable height by allowing the excess melt to discharge over a weir disposed slightly above the level of the furnace bottom. This pool formation serves to equalize the short-term fluctuations of the melt qualities. However, 2 the average composition of the melt must be controlled by adjusting the composition of the raw materials to be melted, that is, by adding suitable ingredients to the in- feed material mix.
In conventional techniques, the composition of materials being melted is controlled by sampling the melt, and based thereon, adding the required raw material components to the top of the furnace, into the infeed mix of rock material and fuel. Such a melt control technique is primarily hampered by the finite transport delay of the added component along with the rock material to the bottom of the furnace. This delay brings about a significant uncertainty factor to the material composition control and, in spite of predictive calculations and estimations, inaccuracy of control results. Hence, the composition of the melt is difficult to keep within the set limits.
In the view of present knowledge, however, it is most essential for certain properties of manufactured fiber to keep the mutual proportions of prescribed raw material components within tight limits. It may be required from a fiber with a composition falling within these limits to provide, e.g., such physiological compatibility require- ents that are set for the fiber by authorities as a prerequisite for its use in some specific application. These properties are generally controlled by complementing the rock material to be melted with additive ingredients such as bauxite for adjusting the aluminium compound content, apatite for adjusting the phosphorus compound content, boron compounds and titanium compounds. The introduction of these additive ingredients at the top of the furnace into the mix of rock material and fuel causes problems of a different type. Firstly, the additive ingredients tra- veiling downward in the raw material pile will be subjected to a relatively long period in contact with the hot flue gases, which leads to loss of additive ingredients 3 through evaporation. Particularly apatite and boron compounds are problematic in this respect. On the other hand, some of the additive ingredients such as bauxite and titanium compounds are slowly melting requiring their grinding to a substantially smaller particle size than the rock material and the fuel . When mixed into the pile of coarser materials, the fine particulate matter causes problems to the passage of flue gases through the material pile as well as loss of material due to entrained transport of material dust, whereby the elimination of these problems necessitates briquetting of additive ingredients into sufficiently large agglomerates.
An essential improvement regarding the above-described problems associated with the introduction of additive ingredients has been found by virtue of the present method according to which at least a portion of said additives is introduced along with a carrier medium directly into the melting zone or its immediate vicinity. Then, the additive ingredient can be introduced into the furnace along with the combustion air. Alternatively, the additive ingredient can be mixed with an auxiliary fuel which may be a gaseous, liquid or fine-ground solid fuel. Also the combinations of the above carriers can be used for introducing the additive ingredient.
In the method according to the invention, a change in the feed rate of an additive ingredient will affect the melt composition with a substantially shorter delay, which obviously offers an improved control precision over the prior art. Also the other problems mentioned above in regard to evaporation, dusting and slow melting rate are better controlled by virtue of the present invention.
In the method according to the invention, the melt composition can be primarily controlled using conventional coarse control techniques, so that the initial charge of 4 basic materials known beforehand to be in short supply in the melt and also known to behave rather unproblematical- ly in the melting process, are added slightly undercompensated into the melting furnace. Then, the special cha- racter of the present invention can be utilized for fine control of the melt composition and the introduction of hard-to-melt additive ingredients.
According to a specific embodiment of the invention, the introduction of the additive ingredient along with its carrier medium can be complemented by feeding enriching oxygen into the melting zone, whereby the feed rate of oxygen addition is adjusted compatible with the actual composition of additive ingredients thus creating advan- tageous conditions for the melting thereof in melting zone. Due to the presence of carbon, the overall conditions in the melting zone are reducing. The degree of reducing conditions can be decreased by the oxygen addition, or even reversed into oxidizing conditions if the excess amount of oxygen addition is sufficiently large.
The introduction of the enriching oxygen is advantageously carried out separately from the introduction of additive ingredients and also is provided with an independent control facility. This can be accomplished by different types of injection nozzle constructions having separate channels on one hand for the additive ingredient (s) and its carrier and on the other hand for the enriching oxygen.
One problematic issue particularly concerning the preparation of melt for the manufacture of mineral wool deals with the physical properties of the melt. The most important of these is the viscosity of the incoming melt at the fiberizing unit. The melt viscosity is primarily affected by the melt composition and temperature. For instance, the available raw material and/or the raw material 5 mix giving the desired melt composition may be such that melts at a high temperature requiring the melt to kept at a high melt temperature, too. This melt pool temperature, however, may be excessively high to maintain the optimal viscosity, which subsequently causes problems in the fi- berizing stage. The method according to the invention can offer a solution to problem by allowing the introduction of such an additive ingredient that has no significant effect on the melt composition. Advantageously, the mel- ting of such an additive ingredient binds heat thus lowering the melt temperature. One useable additive for this purpose is recycled fiber, preferably in milled form. The control of melt composition by virtue of the method according to the invention may also be used for controlling the composition-dependent viscosity of the melt.
The implementation of the invention may be accomplished by means of conventional infeed equipment based on, e.g., the use a carrier gas flow into which solid particulate matter is introduced with the help of a separate feed apparatus . The feed apparatus in an embodiment of such equipment comprises a rotating compartmental feeder adapted centrally in a cylindrical container, said feeder having its compartments bordered by the cylindrical shell of the container and its end surfaces. The carrier gas flow is provided with opposite aligned inlet and outlet nozzles, respectively, at the opposite ends of the cylindrical container thus permitting the carrier gas flow to entrain the solid particulate matter loaded in the com- partments as they sequentially meet the opposed nozzles.

Claims

6Claims
1. Method of melting rock material for the manufacture of mineral fiber, in which method the crushed rock mate- rial and the amount of fuel, such as coke, proportionated according to the quantity of the rock material, together with a possible addition of additive ingredients, are introduced into a shaft furnace, combustion air possibly complemented with auxiliary fuel is introduced into the bottom part of the furnace in order to create a melting zone, and the melted rock material is discharged from the furnace bottom, characterized in that at least a portion of said additive ingredients is introduced along with a carrier medium directly into the melting zone or its im- mediate vicinity.
2. Method according to claim 1, characterized in that the combustion air and/or the auxiliary fuel is used as the carrier medium.
3. Method according to claim 1 or 2 , characterized in that the feed rate of the additive ingredient (s) is controlled by monitoring the melt qualities such as its composition and/or temperature.
4. Method according to any of foregoing claims, characterized in that besides the introduction of the additive ingredient along with the carrier medium, also enriching oxygen is fed into the melting zone.
5. Method according to claim 4, characterized in that the feed rate of enriching oxygen is controlled based on the composition of the additive ingredient (s) .
EP99913327A 1998-03-27 1999-03-26 Method for melting rock material for mineral fibre production Withdrawn EP1089944A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI980710A FI980710A (en) 1998-03-27 1998-03-27 Process for smelting rock material for mineral wool production
FI980710 1998-03-27
PCT/FI1999/000249 WO1999050196A1 (en) 1998-03-27 1999-03-26 Method for melting rock material for mineral fibre production

Publications (1)

Publication Number Publication Date
EP1089944A1 true EP1089944A1 (en) 2001-04-11

Family

ID=8551405

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99913327A Withdrawn EP1089944A1 (en) 1998-03-27 1999-03-26 Method for melting rock material for mineral fibre production

Country Status (4)

Country Link
EP (1) EP1089944A1 (en)
AU (1) AU3148999A (en)
FI (1) FI980710A (en)
WO (1) WO1999050196A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8176754B2 (en) 2001-06-27 2012-05-15 Rockwool International A/S Process and apparatus for making mineral fibres
CN1277769C (en) * 2001-06-27 2006-10-04 罗克伍尔国际公司 Process and appts. for making mineral fibers

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4277274A (en) * 1977-12-27 1981-07-07 Owens-Corning Fiberglas Corporation Process for controlling molten glass variables
DK267186D0 (en) * 1986-06-06 1986-06-06 Rockwool Int MINERAL WOOL PRODUCTION
US4877449A (en) * 1987-07-22 1989-10-31 Institute Of Gas Technology Vertical shaft melting furnace and method of melting
DK158382C (en) * 1987-10-15 1990-10-22 Rockwool Int PROCEDURE FOR PREPARING A MELT FOR THE FORMATION OF MINERAL WOOL AND APPARATUS FOR EXERCISING THE PROCEDURE

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9950196A1 *

Also Published As

Publication number Publication date
WO1999050196A1 (en) 1999-10-07
FI980710A0 (en) 1998-03-27
AU3148999A (en) 1999-10-18
FI980710A (en) 1999-09-28

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