EP0696661B1 - Multifunktionelle Textilhilfsmittel-Zusammensetzungen - Google Patents
Multifunktionelle Textilhilfsmittel-Zusammensetzungen Download PDFInfo
- Publication number
- EP0696661B1 EP0696661B1 EP95810494A EP95810494A EP0696661B1 EP 0696661 B1 EP0696661 B1 EP 0696661B1 EP 95810494 A EP95810494 A EP 95810494A EP 95810494 A EP95810494 A EP 95810494A EP 0696661 B1 EP0696661 B1 EP 0696661B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- alkyl
- hydrogen
- methyl
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 53
- 239000004753 textile Substances 0.000 title claims description 44
- 239000007795 chemical reaction product Substances 0.000 claims description 34
- 239000001257 hydrogen Substances 0.000 claims description 30
- 229910052739 hydrogen Inorganic materials 0.000 claims description 30
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 28
- 238000009472 formulation Methods 0.000 claims description 28
- -1 aromatic alcohols Chemical class 0.000 claims description 27
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 22
- 239000002736 nonionic surfactant Substances 0.000 claims description 22
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 18
- 150000002431 hydrogen Chemical class 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 17
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 235000012208 gluconic acid Nutrition 0.000 claims description 15
- 229950006191 gluconic acid Drugs 0.000 claims description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 12
- 238000004061 bleaching Methods 0.000 claims description 10
- 239000003999 initiator Substances 0.000 claims description 10
- 125000001931 aliphatic group Chemical group 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 8
- 229920006395 saturated elastomer Polymers 0.000 claims description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 7
- 159000000003 magnesium salts Chemical class 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 6
- 150000007529 inorganic bases Chemical class 0.000 claims description 6
- 150000007530 organic bases Chemical class 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 239000003760 tallow Substances 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- KSDGSKVLUHKDAL-UHFFFAOYSA-L disodium;3-[2-carboxylatoethyl(dodecyl)amino]propanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCN(CCC([O-])=O)CCC([O-])=O KSDGSKVLUHKDAL-UHFFFAOYSA-L 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 150000001340 alkali metals Chemical group 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- 239000012456 homogeneous solution Substances 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 238000006386 neutralization reaction Methods 0.000 claims description 4
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical compound NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 claims description 4
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 claims description 3
- 239000002280 amphoteric surfactant Substances 0.000 claims description 3
- 239000012736 aqueous medium Substances 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- 150000002009 diols Chemical class 0.000 claims description 3
- 229940047642 disodium cocoamphodiacetate Drugs 0.000 claims description 3
- WSJWDSLADWXTMK-UHFFFAOYSA-L disodium;2-[2-(carboxylatomethoxy)ethyl-[2-(octanoylamino)ethyl]amino]acetate Chemical compound [Na+].[Na+].CCCCCCCC(=O)NCCN(CC([O-])=O)CCOCC([O-])=O WSJWDSLADWXTMK-UHFFFAOYSA-L 0.000 claims description 3
- 229920005862 polyol Polymers 0.000 claims description 3
- 150000003077 polyols Chemical class 0.000 claims description 3
- LLKGTXLYJMUQJX-UHFFFAOYSA-M sodium;3-[2-carboxyethyl(dodecyl)amino]propanoate Chemical compound [Na+].CCCCCCCCCCCCN(CCC(O)=O)CCC([O-])=O LLKGTXLYJMUQJX-UHFFFAOYSA-M 0.000 claims description 3
- QEKATQBVVAZOAY-UHFFFAOYSA-M sodium;4-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=C(S([O-])(=O)=O)C=C1 QEKATQBVVAZOAY-UHFFFAOYSA-M 0.000 claims description 3
- 125000005504 styryl group Chemical group 0.000 claims description 3
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 2
- 239000003352 sequestering agent Substances 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims 2
- 230000003165 hydrotropic effect Effects 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- 239000002738 chelating agent Substances 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 35
- 239000004435 Oxo alcohol Substances 0.000 description 26
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 26
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 18
- 238000003756 stirring Methods 0.000 description 14
- 239000000047 product Substances 0.000 description 13
- 239000002657 fibrous material Substances 0.000 description 11
- 150000003254 radicals Chemical class 0.000 description 11
- 125000000217 alkyl group Chemical group 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- 150000002191 fatty alcohols Chemical class 0.000 description 8
- 150000002978 peroxides Chemical class 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 7
- 150000001298 alcohols Chemical class 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
- 150000008051 alkyl sulfates Chemical class 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 239000000174 gluconic acid Substances 0.000 description 4
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 4
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 4
- 239000000347 magnesium hydroxide Substances 0.000 description 4
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- SJWFXCIHNDVPSH-UHFFFAOYSA-N octan-2-ol Chemical compound CCCCCCC(C)O SJWFXCIHNDVPSH-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229960004106 citric acid Drugs 0.000 description 3
- 235000015165 citric acid Nutrition 0.000 description 3
- 230000000536 complexating effect Effects 0.000 description 3
- 239000008139 complexing agent Substances 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 230000029087 digestion Effects 0.000 description 3
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- CTUVIUYTHWPELF-IYEMJOQQSA-L magnesium gluconate Chemical compound [Mg+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O CTUVIUYTHWPELF-IYEMJOQQSA-L 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Inorganic materials O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 3
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 3
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 description 2
- PQSMEVPHTJECDZ-UHFFFAOYSA-N 2,3-dimethylheptan-2-ol Chemical compound CCCCC(C)C(C)(C)O PQSMEVPHTJECDZ-UHFFFAOYSA-N 0.000 description 2
- BSYJHYLAMMJNRC-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-ol Chemical compound CC(C)(C)CC(C)(C)O BSYJHYLAMMJNRC-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- QDTDKYHPHANITQ-UHFFFAOYSA-N 7-methyloctan-1-ol Chemical compound CC(C)CCCCCCO QDTDKYHPHANITQ-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 0 CC*CC(C)C(*)(*)OC(*C)(P(C(*)(*)OC(C)(P(O)=O)P(N=O)(O)=O)(O)=O)P(O)(O)=O Chemical compound CC*CC(C)C(*)(*)OC(*C)(P(C(*)(*)OC(C)(P(O)=O)P(N=O)(O)=O)(O)=O)P(O)(O)=O 0.000 description 2
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000004439 Isononyl alcohol Substances 0.000 description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical class OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical class CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229940091250 magnesium supplement Drugs 0.000 description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- SDOFMBGMRVAJNF-SLPGGIOYSA-N (2r,3r,4r,5s)-6-aminohexane-1,2,3,4,5-pentol Chemical compound NC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO SDOFMBGMRVAJNF-SLPGGIOYSA-N 0.000 description 1
- QKYOCTCEIBOKGV-YFKPBYRVSA-N (2s)-2-[bis(phosphonomethyl)amino]pentanedioic acid Chemical compound OC(=O)CC[C@@H](C(O)=O)N(CP(O)(O)=O)CP(O)(O)=O QKYOCTCEIBOKGV-YFKPBYRVSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical class OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 1
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- PPUCMDNDOHRYFQ-UHFFFAOYSA-N 1-phenoxypropan-2-ol;2-phenoxypropan-2-ol Chemical compound CC(O)COC1=CC=CC=C1.CC(C)(O)OC1=CC=CC=C1 PPUCMDNDOHRYFQ-UHFFFAOYSA-N 0.000 description 1
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- DBHODFSFBXJZNY-UHFFFAOYSA-N 2,4-dichlorobenzyl alcohol Chemical compound OCC1=CC=C(Cl)C=C1Cl DBHODFSFBXJZNY-UHFFFAOYSA-N 0.000 description 1
- TZYRSLHNPKPEFV-UHFFFAOYSA-N 2-ethyl-1-butanol Chemical compound CCC(CC)CO TZYRSLHNPKPEFV-UHFFFAOYSA-N 0.000 description 1
- MHGOKSLTIUHUBF-UHFFFAOYSA-N 2-ethylhexyl sulfate Chemical compound CCCCC(CC)COS(O)(=O)=O MHGOKSLTIUHUBF-UHFFFAOYSA-N 0.000 description 1
- PFNHSEQQEPMLNI-UHFFFAOYSA-N 2-methyl-1-pentanol Chemical compound CCCC(C)CO PFNHSEQQEPMLNI-UHFFFAOYSA-N 0.000 description 1
- IIVWHGMLFGNMOW-UHFFFAOYSA-N 2-methylpropane Chemical compound C[C](C)C IIVWHGMLFGNMOW-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- XYYUAOIALFMRGY-UHFFFAOYSA-N 3-[2-carboxyethyl(dodecyl)amino]propanoic acid Chemical compound CCCCCCCCCCCCN(CCC(O)=O)CCC(O)=O XYYUAOIALFMRGY-UHFFFAOYSA-N 0.000 description 1
- SECKOSOTZOBWEI-UHFFFAOYSA-N 5-methylheptan-3-ol Chemical compound CCC(C)CC(O)CC SECKOSOTZOBWEI-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2034—Monohydric alcohols aromatic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2048—Dihydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2058—Dihydric alcohols aromatic
-
- C—CHEMISTRY; METALLURGY
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
Definitions
- the present invention relates to storage-stable, low-foam, silicone-free, aqueous Textile auxiliaries, their production and multiple uses e.g. as a wetting agent, Detergents, dispersants or as stabilizers in peroxide bleaching liquors.
- Components (a) to (g) can each consist of individual compounds or else be composed of several individual connections.
- the substituents R 6 and R 7 in the formulas (4) and (5) advantageously represent the hydrocarbon radical of a saturated aliphatic monoalcohol.
- the hydrocarbon radical can be straight-chain or branched.
- aliphatic saturated monoalcohols natural alcohols, such as, for example, lauryl alcohol, myristyl alcohol, cetyl alcohol or stearyl alcohol, and synthetic alcohols, such as, for example, 2-ethylhexanol, 1,1,3,3-tetramethylbutanol, octan-2-ol, isononyl alcohol, trimethylhexanol, trimethylnonyl alcohol
- Decanol, C 9 -C 11 oxo alcohol, tridecyl alcohol, isotridecanol or linear primary alcohols (alfoles) can be used. Some representatives of these alfoles are Alfol (8-10), Alfol (9-11), Alfol (10-14), Alfol (12-13) or Alfol (16-18).
- Alfol is a registered trademark).
- the alcohol residues can be present individually or in the form of mixtures of two or more components.
- are preferably divalent radicals of the formulas R 4 represents the straight-chain hydrocarbon radical of a saturated aliphatic monoalcohol with 8 to 14 carbon atoms, ie n-octyl, n-nonyl, n-decyl, n-undecyl, n-dodecyl, n-tridecyl or n-tetradecyl.
- R 5 in formula (3) in the meaning of C 1 -C 8 alkyl is the methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl or tert-butyl radical.
- R 5 is preferably the n-butyl radical.
- cycloaliphatic radical examples include cycloheptyl, cyclooctyl or preferably Cyclohexyl.
- nonionic surfactants which correspond to component (a) are Addition products of 3 to 15 mol, preferably 4 to 10 mol, of alkylene oxides, in particular Ethylene oxide, where individual ethylene oxide units are substituted by substituted epoxides, such as propylene oxide, can be replaced, to higher saturated fatty alcohol with 8 to 13 or 8 to 18 carbon atoms, or mixtures of these compounds.
- monomeric starting compounds for the preparation of the polymeric compounds of Component (b) are called acrylic acid and methacrylic acid.
- Free radicals are preferably used as catalysts for the production of component (b) forming organic initiators used.
- Suitable initiators for implementation radical polymerization are e.g. symmetrical aliphatic azo compounds such as azo-bis-isobutyronitrile, azo-bis-2-methylvaleronitrile, 1,1'-azo-bis-1-cyclohexanitrile and 2,2'-azo-bis-isobutyric acid alkyl ester; symmetrical diacyl peroxides, such as e.g.
- Suitable peroxides are: tert-butyl hydroperoxide, Di-tert-butyl peroxide, cumene hydroperoxide, di-cumene peroxide and tert-butyl perpivalate.
- Another suitable compound is potassium persulfate, which is used in the manufacture component (b) is preferably used.
- the catalysts are generally used in amounts of 0.1 to 10% by weight, preferably 0.5 to 2 wt .-%, based on the starting products, used.
- Component (b) is preferably in the form of a partially neutralized compound Has a pH of 3 to 6.
- the polymeric compound is produced e.g. by reacting acrylic acid or methacrylic acid in the presence of a nonionic Surfactants of the formula (5) or in the presence of mixtures of nonionic surfactants Formula (5).
- the reaction product is then mixed with an inorganic and / or organic base to a pH of 3 to 6, preferably 4 to 5, partially neutralized.
- bases one uses e.g. 1 to 8% by weight inorganic or organic bases, such as.
- the polymerization is advantageously carried out in an inert atmosphere, e.g. in the presence of Nitrogen.
- Exemplary compounds of the formula (6) are benzyl alcohol, 2,4-dichlorobenzyl alcohol, Phenylethanol, phenoxyethanol, 1-phenoxy-2-propanol (phenoxyisopropanol) and cinnamon alcohol.
- organic acids mentioned can also be in the form of their water-soluble salts, such as the alkali metal, in particular sodium or potassium salts or the amine salts are present.
- alkyl sulfate is present as a salt, sodium, potassium or Ammonium salts into consideration.
- the sodium salt is preferred.
- the aliphatic saturated radical R 11 is derived from monoalcohols. Natural or synthetic alcohols can be used. Examples of natural alcohols are lauryl, myristyl, cetyl, stearyl, arachidyl or behenyl alcohol.
- R 11 is derived from branched aliphatic synthetic alcohols having 4 to 12, in particular 4 to 8, carbon atoms, for example isobutyl alcohol, sec-butanol, tert-butanol, isoamyl alcohol, 2-ethylbutanol, 2-methylpentanol, 5-methylheptane -3-ol, 2-ethylhexanol, 1,1,3,3-tetramethylbutanol, octan-2-ol, isononyl alcohol, trimethylhexanol, trimethylnonyl alcohol, n-decanol or C 9 -C 11 oxo alcohol.
- alkyl sulfates can already be in the form of their salts and alone or as (Technical) mixture with each other used in the wetting agent according to the invention become.
- hydrotroping agents of the formula (7) are 2-ethylhexyl sulfate.
- alkyl sulfates are prepared by reaction in a manner known per se the corresponding alcohols with e.g. Sulfuric acid, oleum, chlorosulfonic acid or sulfur trioxide.
- hydrotroping agents used according to the invention are the amphoteric surfactants: Sodium laurimino dipropionate, dihydroxyethyl tallow fat glycinate, disodium cocoamphodiacetate, Disodium capryloamphodiacetate or preferably disodium dicarboxyethyl cocopropylene diamine or tallow amphopolycarboxyglycinate.
- Examples of the end-capped nonionic surfactants of component (d) are C 10 -C 12 fatty alcohol-ethylene oxide or ethylene oxide / propylene oxide addition products or the reaction product of one mole of a C 10 fatty alcohol with 6 moles of ethylene oxide and 1 mole of butylene oxide name, where the addition products can be end-capped with C 1 -C 4 alkyl, preferably methyl or butyl.
- the nonionic surfactants of the formulas (4) and (5) are prepared in a manner known per se, for example by reacting the corresponding alkylene oxide adducts with thionyl chloride and then reacting the chlorine compound formed with a saturated aliphatic C 8 -C 13 or C 8 -C 18 mono alcohol.
- the end-capped nonionic surfactants of the formula (3) are prepared in a manner known per se, for example by reacting ethylene oxide and / or propylene oxide and / or butylene oxide in the corresponding molar ratios with one mole of the alcohol R 4 -OH, and subsequent reaction of the adduct formed with an alkyl halide R 5 -Hal, preferably C 1 -C 4 -alkyl chloride.
- the optional component (s) are salts of gluconic acid, citric acid, Malic acid, lactic acid, L-glutamic acid and L-aspartic acid.
- the magnesium salts of gluconic acid are used as component (e) and especially magnesium mono- or magnesium digluconate.
- the magnesium gluconate can be in the composition according to the invention as such and preferably be used as a solid.
- this can Gluconate can also be formed from gluconic acid and magnesium oxide or in situ preferably magnesium hydroxide.
- Gluconic acid or its sodium salt can also be used in Combination with a water-soluble magnesium salt can be used.
- water soluble Magnesium salt comes here the acetate, especially the sulfate or its Heptahydrate and especially the chloride or its hexahydrate.
- the Magnesium salt is usually used as a solid, with solid magnesium chloride hexahydrate is in the foreground.
- the mixtures of the monomeric and oligomeric compounds of the type indicated are known per se and are prepared by known methods.
- the mixture of the formulas (10a) and (10b) is preferably prepared by reacting phosphorus trichloride, acetic acid and optionally acetic anhydride in an aqueous medium.
- the oligomeric components (f 1 ) are at least partially hydrolyzed in the aqueous composition according to the invention in the presence of an alkali metal hydroxide to give the corresponding monomeric compounds.
- component (f 1 ) of the compositions according to the invention are also, above all, monomeric compounds of one of the formulas (9a) or (10a).
- Component (f 1 ) is preferably used in the composition according to the invention as 35 to 90, preferably 40 to 85, in particular 40 to 60 percent by weight aqueous solution.
- component (f 4 ) examples include nitrilotrimethylenephosphonic acid, the Na salt of ethylenediamine-tetramethylenephosphonic acid, the Na salt of diethylenetriamine-pentamethylenephosphonic acid or N, N-bis (phosphonomethyl) glutamic acid.
- Compounds of component (f) act as complexing agents for alkaline earth and heavy metals in aqueous liquors containing a per-compound, e.g. Contain hydrogen peroxide, in pretreatment, especially in bleaching processes of cellulosic fiber materials.
- a per-compound e.g. Contain hydrogen peroxide
- the presence of these components causes decomposition the per-connection by free, i.e. heavy metals not present as a complex, which are present in the process water of the fiber material or in the added alkali can suppressed.
- Suitable as component (g) are dihydric or polyhydric alcohols.
- bivalent Alcohols are in particular those with 2 to 6 carbon atoms in the alkylene part, such as ethylene glycol, 1,2- or 1,3-propanediol, 1,3-, 1,4- or 2,3-butanediol, 1,5-pentanediol and 1,6-hexanediol or to name 2-methyl-2,4-pentanediol.
- the latter connection is in the composition according to the invention is preferably used.
- polyhydric alcohols examples include glycerol, erythritol, the pentites, e.g. arabitol, Adonite and xylitol as well as the hexites such as D-sorbitol, D-mannitol and dulcitol.
- the textile auxiliaries according to the invention can be prepared by adding components (a), (b), (c), and optionally (d), (e), (f) and (g) in water (component (h)) or by mixing the corresponding components with stirring and add deionized water until a homogeneous solution is obtained. It is about a purely mechanical process, which may take place at elevated temperature, for example from 30 to 40 ° C is carried out. A chemical reaction takes place not instead.
- component (b) is first reacted from 5 to 45 % By weight of a nonionic surfactant of the formula (5) with 45 to 5% by weight of acrylic acid or methacrylic acid in the presence of a free radical class catalyst forming organic initiators, and then partial neutralization to one pH of 3 to 6 with 1 to 8 wt .-% of an inorganic or organic base manufactures, adjusts the pH to about 4.5 and then the remaining components add until a homogeneous solution is obtained.
- a nonionic surfactant of the formula (5) with 45 to 5% by weight of acrylic acid or methacrylic acid in the presence of a free radical class catalyst forming organic initiators, and then partial neutralization to one pH of 3 to 6 with 1 to 8 wt .-% of an inorganic or organic base manufactures, adjusts the pH to about 4.5 and then the remaining components add until a homogeneous solution is obtained.
- the finished textile auxiliaries have a pH of z. B. 2 to 5, preferably from 2.5 to 3.5.
- the pH value always refers to a 1% aqueous solution of the formulation according to the invention.
- the desired pH is used e.g. magnesium hydroxide, Potassium hydroxide, mono-, di- or triethanolamine and especially sodium hydroxide.
- the new formulations provide storage-stable, single-phase, low-foam and silicone-free Textile auxiliaries with good complexing and sequestering properties dirt-removing effect. They show good emulsifying power and are alkaline Fleet stable. In alkaline bleaching liquors, they have no creams or deposits on. They also have good peroxide-stabilizing properties and cause good rewettability of the textile goods. In addition, the wording readily biodegradable. They are characterized by their liquid trading form easy handling, which is why they are particularly suitable for modern dosing systems are suitable.
- the universal applicability of the formulations according to the invention enables various applications. For example, as a wetting agent, textile detergent, Dispersant or used as a stabilizer in peroxide bleaching liquors become. They are also ideal as a universal household detergent.
- the present invention accordingly also relates to a method for wetting, Washing and / or bleaching fiber materials, which is characterized in that to these materials in an aqueous medium in the presence of one defined in claim 1 Textile auxiliaries treated.
- the amounts in which the textile auxiliaries according to the invention are added to the treatment liquors added are 0.1 to 60, preferably 1 to 20 g per liter of treatment liquor.
- These fleets can also contain other additives, e.g. desizing, Dyes, optical brighteners, alkalis such as sodium hydroxide and hydrogen peroxide.
- Possible fiber materials are: cellulose, in particular untreated natural ones Cellulose such as Hemp, linen, jute, rayon, viscose, acetate treyon, native cellulose fiber and especially raw cotton, wool, polyamide, polyacrylonitrile or polyester fiber materials as well as fiber blends, e.g. those made of polyacrylonitrile / cotton or polyester / cotton.
- the fiber material to be treated can be in different processing stages, so e.g. the cellulose-containing material as loose material, yarn, woven or knitted fabric. As a rule, these are always textile fiber materials made from pure textile cellulose fibers or from mixtures of textile cellulose fibers with textile synthetic fibers getting produced.
- the fiber material can be continuous or discontinuous be treated in an aqueous liquor.
- the aqueous treatment liquors can be applied to the fiber materials in a known manner be applied, advantageously by impregnation on the foulard, the liquor intake is about 70 to 120% by weight.
- the padding process comes in particular for pad-steam and pad-batch processes.
- the impregnation can be carried out at 10 to 60 ° C, but preferably at room temperature become.
- the cellulose material optionally heat treatment, e.g. Subject at temperatures from 80 to 140 ° C.
- the heat treatment is preferably carried out by steaming at 95 to 140, in particular at 100 to 106 ° C. Depending on the type of heat development and the temperature range the heat treatment can take 30 seconds to 60 minutes.
- the impregnated goods are rolled up without drying and then optionally wrapped with plastic wrap, and at room temperature 1 to 24 Stored for hours.
- the treatment of the fiber materials can also in long liquors with a liquor ratio from e.g. 1: 3 to 1: 100, preferably 1: 4 to 1:25 and 10 to 100, preferably 60 to 98 ° C for about 1/4 to 3 hours under normal conditions, i.e. under atmospheric pressure in conventional equipment, e.g. a jigger, jet or one Reel skids take place. If necessary, however, the treatment can also be carried out up to 150 ° C., preferably 105 to 140 ° C under pressure in so-called high-temperature equipment (HT equipment) be performed.
- HT equipment high-temperature equipment
- the fiber materials are then, if required by the process, with hot Water from about 90 to 98 ° C and then with warm and finally with cold water rinsed thoroughly, neutralized if necessary and then preferably at elevated Temperatures dried.
- Example 3 The following components are mixed with one another with stirring:
- the formulation is used as a textile auxiliary for alkaline digestion processes, Leach and mercerize.
- Example 4 The following components are mixed with one another with stirring:
- the formulation is used as a textile auxiliary for alkaline Digestion process, leaching and mercerization.
- Example 5 The following components are mixed with one another with stirring:
- the formulation is used as a textile aid for cold storage peroxide bleaching.
- Example 6 The following components are mixed with one another with stirring:
- the formulation is used as a textile aid for boiling and bleaching processes.
- Example 7 The following components are mixed with one another with stirring:
- the formulation is used as a textile aid for pad steam peroxide bleaching.
- Example 8 The following components are mixed with one another with stirring:
- the formulation is used as a textile aid for pad steam peroxide bleaching.
- Example 9 The following components are mixed with one another with stirring:
- Example 10 The following components are mixed with one another with stirring:
- Example 11 The following components are mixed with one another with stirring:
- Example 12 The following components are mixed with one another with stirring:
- Example 13 The following components are mixed with one another with stirring:
- Example 14 Alkaline digestion using the pad-steam method
- Raw cotton fabric is impregnated on a foulard at room temperature with a treatment liquor of the following composition: 2 g / l of the textile auxiliary produced according to Example 4 and 30 g / l NaOH (100%).
- the fleet intake is 100%.
- the goods are then fed into a steamer with saturated steam at 102 ° C for 10 minutes and then washed out with hot water.
- the result is a desized product with high absorbency.
- Example 1 5 Cold storage peroxide bleach
- Raw cotton fabric is impregnated on a foulard at room temperature with a treatment liquor of the following composition: 12 g / l the textile auxiliary produced according to Example 5, 30 g / l NaOH (100%) and 50 ml / l Hydrogen peroxide.
- the fleet intake is 100%.
- the damp goods are wound up on a dock, packed with plastic wrap and with slow rotation of the dock 20 hours Stored at room temperature. The goods are then washed out with hot water. The result is an absorbent fabric with a high degree of whiteness and only low Fiber damage.
- Raw cotton fabric is sprayed with a treatment liquor of the following composition: 20 g / l of the textile auxiliary produced according to Example 8 40 g / l NaOH (100%) and 30 ml / l Hydrogen peroxide (35%).
- the spraying takes place e.g. in a Raco-Yet system from Rimisch-Kleinwefers.
- the order quantity is 140%.
- the damp goods are kept in a steamer for 2 hours treated with saturated steam at 102 ° C and then washed out with hot water.
- the result is an absorbent fabric with a high degree of whiteness and little fiber damage.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Emergency Medicine (AREA)
- Health & Medical Sciences (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Biological Depolymerization Polymers (AREA)
- Paper (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH2486/94 | 1994-08-11 | ||
CH248694 | 1994-08-11 | ||
CH248694 | 1994-08-11 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0696661A1 EP0696661A1 (de) | 1996-02-14 |
EP0696661B1 true EP0696661B1 (de) | 2002-10-23 |
Family
ID=4234892
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95810494A Expired - Lifetime EP0696661B1 (de) | 1994-08-11 | 1995-08-02 | Multifunktionelle Textilhilfsmittel-Zusammensetzungen |
Country Status (8)
Country | Link |
---|---|
US (1) | US6200948B1 (es) |
EP (1) | EP0696661B1 (es) |
JP (1) | JPH0881696A (es) |
KR (1) | KR100344327B1 (es) |
BR (1) | BR9503609A (es) |
DE (1) | DE59510431D1 (es) |
ES (1) | ES2182880T3 (es) |
TW (1) | TW293051B (es) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2163606T3 (es) * | 1995-05-19 | 2002-02-01 | Ciba Sc Holding Ag | Materia prima detergente multifuncional. |
DE19809359A1 (de) * | 1998-03-05 | 1999-09-09 | Bayer Ag | Gleichzeitiges Waschen und Bleichen nativer Fasern und textiler Erzeugnisse daraus |
DE19859294A1 (de) * | 1998-12-22 | 2000-06-29 | Bayer Ag | Textilbehandlungsmittel, Verfahren zu deren Herstellung sowie deren Verwendung |
US6537662B1 (en) * | 1999-01-11 | 2003-03-25 | 3M Innovative Properties Company | Soil-resistant spin finish compositions |
AU3290200A (en) * | 1999-03-29 | 2000-10-16 | Bayer Aktiengesellschaft | Treatment agents for textiles, method of producing same and their use |
US6143479A (en) * | 1999-08-31 | 2000-11-07 | Kodak Polychrome Graphics Llc | Developing system for alkaline-developable lithographic printing plates |
ATE301737T1 (de) * | 1999-10-16 | 2005-08-15 | Ciba Sc Pfersee Gmbh | Zusammensetzung für die vorbehandlung von fasermaterialien |
EP1149945A1 (de) * | 2000-04-29 | 2001-10-31 | Ciba Spezialitätenchemie Pfersee GmbH | Zusammensetzung für die Vorbehandlung von Fasermaterialien |
DE10118236A1 (de) * | 2001-04-11 | 2002-10-17 | Ciba Sc Pfersee Gmbh | Zusammensetzung für die Vorbehandlung von Fasermaterialien |
CN1271275C (zh) | 2001-07-11 | 2006-08-23 | 克莱里安特财务(Bvi)有限公司 | 纺织纤维脱脂剂、其生产方法和其用途 |
EP1658401A1 (en) * | 2003-08-21 | 2006-05-24 | Clariant Finance (BVI) Limited | Multifunctional textile-pretreating agent |
JP5710847B2 (ja) * | 2012-02-24 | 2015-04-30 | 日華化学株式会社 | 精練漂白助剤及び精練漂白方法 |
CN102995468B (zh) * | 2012-11-26 | 2015-04-15 | 浙江安诺其助剂有限公司 | 一种涤纶织物染色除油剂及其制备方法 |
US20150368589A1 (en) * | 2012-12-06 | 2015-12-24 | Sandeepak PANDIT | Amphoteric detergent compatible softeners based on alkyl ammonium backbone |
GB2529138A (en) | 2014-07-02 | 2016-02-17 | Basf Se | Detergent |
JP2018062548A (ja) * | 2016-10-11 | 2018-04-19 | ライオン株式会社 | 漂白剤組成物 |
JP6991048B2 (ja) * | 2017-12-01 | 2022-01-12 | ライオン株式会社 | 液体洗浄剤組成物 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4494952A (en) * | 1982-09-08 | 1985-01-22 | Ciba-Geigy Corporation | Wetting agents and their use as mercerizing assistants |
DE3433593A1 (de) * | 1984-09-13 | 1986-03-20 | Henkel KGaA, 4000 Düsseldorf | Verwendung von ethersulfonaten als schaumarme netzmittel in waessrigen, sauren und alkalischen technischen behandlungsmitteln |
DE3435841A1 (de) * | 1984-09-29 | 1986-04-17 | Henkel KGaA, 4000 Düsseldorf | Verwendung von ethersulfonaten als antistatika |
DE3823454A1 (de) * | 1988-07-11 | 1990-01-25 | Henkel Kgaa | Mercerisier- und/oder laugiernetzmittel |
US5156761A (en) | 1988-07-20 | 1992-10-20 | Dorrit Aaslyng | Method of stabilizing an enzymatic liquid detergent composition |
DE3828226A1 (de) * | 1988-08-19 | 1990-02-22 | Henkel Kgaa | Verwendung von mischungen, enthaltend (a) alkali-, ammonium- und/oder aminsalze sulfonierter, ungesaettigter fettsaeuren und (b) alkoxylierte alkyl- und/oder alkenylalkohole und/oder sulfobernsteinsaeureester als netzmittel |
DE3914060A1 (de) * | 1989-04-28 | 1990-10-31 | Henkel Kgaa | Netzmittel zur verwendung in waessrigen, alkalischen behandlungsmitteln fuer garne oder textile flaechengebilde |
DK0420802T3 (da) * | 1989-09-26 | 1995-09-18 | Ciba Geigy Ag | Vandigt, lagerstabilt, lavtskummende befugtningsmiddel |
SE467927B (sv) * | 1990-12-21 | 1992-10-05 | Kommentus Ecogreen Ab | Tvaettmedel innehaallande tensid och komplexbildare samt foerfarande foer dess framstaellning |
US5458847A (en) * | 1993-09-22 | 1995-10-17 | National Science Council | Electroless plating method of NI-Al intermetallic compound |
-
1995
- 1995-08-02 EP EP95810494A patent/EP0696661B1/de not_active Expired - Lifetime
- 1995-08-02 DE DE59510431T patent/DE59510431D1/de not_active Expired - Fee Related
- 1995-08-02 ES ES95810494T patent/ES2182880T3/es not_active Expired - Lifetime
- 1995-08-09 JP JP7202640A patent/JPH0881696A/ja active Pending
- 1995-08-10 KR KR1019950024635A patent/KR100344327B1/ko not_active IP Right Cessation
- 1995-08-10 BR BR9503609A patent/BR9503609A/pt not_active IP Right Cessation
- 1995-08-12 TW TW084108418A patent/TW293051B/zh active
-
1997
- 1997-08-08 US US08/908,875 patent/US6200948B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
TW293051B (es) | 1996-12-11 |
KR960007926A (ko) | 1996-03-22 |
BR9503609A (pt) | 1996-04-09 |
KR100344327B1 (ko) | 2002-11-30 |
US6200948B1 (en) | 2001-03-13 |
ES2182880T3 (es) | 2003-03-16 |
EP0696661A1 (de) | 1996-02-14 |
DE59510431D1 (de) | 2002-11-28 |
JPH0881696A (ja) | 1996-03-26 |
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