EP0688356A1 - Wässrige textilweichmacher-zusammensetzung - Google Patents
Wässrige textilweichmacher-zusammensetzungInfo
- Publication number
- EP0688356A1 EP0688356A1 EP94909087A EP94909087A EP0688356A1 EP 0688356 A1 EP0688356 A1 EP 0688356A1 EP 94909087 A EP94909087 A EP 94909087A EP 94909087 A EP94909087 A EP 94909087A EP 0688356 A1 EP0688356 A1 EP 0688356A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alkyl
- alkenyl
- weight
- group
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
- D06M13/17—Polyoxyalkyleneglycol ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/262—Sulfated compounds thiosulfates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Definitions
- the invention relates to a process for increasing the viscosity of relatively low-concentration aqueous textile plasticizer dispersions based on cationic plasticizers of the quaternary ammonium compound type with at least two long alkyl, alkenyl or acyl groups by adding relatively small amounts of alkyl or alkenyl sulfate salts or of alkyl or alkenyl ether sulfate salts with 12-22 carbon atoms in the alkyl or alkenyl group.
- the textile plasticizers of the type of quaternary ammonium compounds with at least two long-chain alkyl or acyl groups which are customary in rinse aids are not very soluble in water and are therefore also in the range of low concentrations of less than z. B. 10 wt .-% in water as a dispersion.
- These dispersions have the property that at higher concentrations of more than 15% by weight they are very highly viscous and poorly flowable in water, in the range of lower concentrations below 10% by weight, that is to say in the con usual for household laundry softeners concentration range, however, these dispersions are very thin. This is disadvantageous for the storage stability of the dispersions and also complicates the handling and metering of such products. Thickening by addition of known water-soluble polymers would be possible, but such polymers have disadvantages in their effect on the textile fabric to be softened and also in their biodegradability.
- the task was therefore to thicken aqueous textile plasticizer preparations based on quaternary ammonium compounds by means of suitable, biodegradable additives.
- alkyl ether sulfates had a viscosity Reduce other preparations of fatty acid alkanols in condensates.
- the invention therefore relates to aqueous textile softener compositions which
- the textile plasticizer compositions according to the invention have a significantly increased viscosity without the flowability of the preparations being adversely affected in the range according to the invention.
- the laundry softener dispersions according to the invention also have good shear stability. By shear stress as z. B. by prolonged pumping of the dispersion or by storage of the dispersions, there are still slight increases in viscosity, but overall, the fabric softener dispersions according to the invention show high storage stability and good application behavior.
- QAVs with at least two long-chain alkyl, alkenyl or acyl groups are suitable as dispersed cationic plasticizers of the quaternary ammonium compound (QAV) type.
- QAV quaternary ammonium compound
- examples of such compounds are e.g. B. the distearyl-dimethyl-ammonium chloride or the l-methyl- (l-stearoylamino) -ethyl-2-heptadecyl-imidazolinium methosulfate.
- Textile plasticizer compositions according to the invention which contain a compound of the formula I as QAC are particularly preferred
- QACs can be prepared, for example, by reacting triethanolamine with fatty acid esters and subsequent quaternization of the reaction product with methyl chloride or dimethyl sulfate from technical mixtures of vegetable or animal fatty acids, e.g. acyl groups derived from palm oil fatty acid or from tallow fatty acid be included.
- Suitable components (B) are the sulfuric acid monoester salts of fatty alcohols with 12-22 carbon atoms or of ethylene oxide adducts of 1-6 mol ethylene oxide with such fatty alcohols.
- Suitable fatty alcohols for this are s-.ch synthetic, also slightly methyl-branched, saturated primary alcohols such as z. B. are accessible by hydrofor ylation from alpha olefins or by Ziegler synthesis from ethylene.
- the sulfate salts and ether sulfate salts of saturated and unsaturated natural fatty alcohols are preferably suitable, for. B.
- the alkyl sulfates and alkyl ether sulfates should be present as water-soluble salts, preferably as alkali, magnesium or ammonium salts.
- Suitable diols are e.g. B. ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,3-butanediol; suitable polyols are e.g. B. glycerol, erythritol, pentaerythritol, trimethylolpropane and sorbitol, suitable polyalkylene glycols z.
- a preferred embodiment of the fabric softener composition according to the invention contains
- the textile plasticizer compositions according to the invention may also contain further additives customary in such products.
- fragrances should be mentioned above all, since in addition to the fabric softening effect, scenting of the textile goods is usually also desirable.
- Suitable perfume oils can e.g. B. in amounts of 0.1 to 1 wt .-%.
- further auxiliaries e.g. B.
- the components are dissolved or dispersed in succession in water.
- the preparation is preferably carried out in such a way that a homogeneous melt (pre-ix solution) is prepared from components (A), (B) and optionally (C) and this is dispersed in water or in the aqueous solution of the other components .
- Polyethylene glycol (MW: 400) 0.5 0.5
- a cationic plasticizer (A) was a compound of the formula
- R ⁇ CO was an oleoyl residue derived from tallow fatty acid and which is commercially available as a paste containing approx. 90% isopropanol under the name Stepantex VS 90 (STEPAN).
- the commercial product Sulfopon T55 (Henkel KGaA), an approx. 50% aqueous paste, was used as tallow fatty alcohol sulfate (B1).
- the commercial product Sulfopon KT115 (Hen ⁇ kel KGaA), an approximately 40% aqueous paste, was used as coconut tallow (1: 1) fatty alcohol sulfate (B2).
- the percentages in the table relate to active substance contents.
- polyester test fabric washed three times with a commercially available detergent (PERSIL supra, without special soil repellent additive) at 40 ° C in a washing machine.
- PERSIL supra without special soil repellent additive
- Half of the samples were rinsed with a fabric softener according to the invention (according to Example 2, dosage 100 ml in the rinse cycle of the washing machine).
- the polyester test fabric was washed, rinsed and soiled as before.
- a detergent with a "soil repellent active ingredient (PERSIL supra with 1% by weight Repel-0-Te ⁇ ( R )) was used.
- the soil repellent active ingredient Repel-0-Te ⁇ ( R ) is a polyester from dimethyl terephthalate, ethylene glycol and polyethylene glycol, available from Rhone-Poulenc.
- Fabric softener according to Example 2 (invention): 0.52 Fabric softener according to Example 1 (comparison): 1.15.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4307186A DE4307186A1 (de) | 1993-03-08 | 1993-03-08 | Wäßrige Textilweichmacher-Zusammensetzung |
DE4307186 | 1993-03-08 | ||
PCT/EP1994/000580 WO1994020596A1 (de) | 1993-03-08 | 1994-02-28 | Wässrige textilweichmacher-zusammensetzung |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0688356A1 true EP0688356A1 (de) | 1995-12-27 |
EP0688356B1 EP0688356B1 (de) | 1997-04-23 |
Family
ID=6482189
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94909087A Expired - Lifetime EP0688356B1 (de) | 1993-03-08 | 1994-02-28 | Wässrige textilweichmacher-zusammensetzung |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0688356B1 (de) |
DE (2) | DE4307186A1 (de) |
ES (1) | ES2100703T3 (de) |
WO (1) | WO1994020596A1 (de) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4420514A1 (de) * | 1994-06-13 | 1995-12-14 | Henkel Kgaa | Wäßrige Dispersionen anionischer und kationischer Tenside |
US6369025B1 (en) | 1995-07-11 | 2002-04-09 | The Procter & Gamble Company | Concentrated, water dispersible, stable, fabric softening compositions |
CA2438655A1 (en) * | 1995-07-11 | 1997-01-30 | Errol Hoffman Wahl | Concentrated, stable fabric softening compositions with low organic solvent level |
WO1997003169A1 (en) * | 1995-07-11 | 1997-01-30 | The Procter & Gamble Company | Concentrated, stable fabric softening composition |
JP3102894B2 (ja) * | 1996-03-22 | 2000-10-23 | ザ、プロクター、エンド、ギャンブル、カンパニー | 布帛柔軟化化合物/組成物 |
DE19629666A1 (de) * | 1996-07-23 | 1998-01-29 | Henkel Kgaa | Verfahren zur hydrophilen Ausrüstung von Fasern oder Vliesstoffen |
CA2264087A1 (en) * | 1996-08-30 | 1998-03-05 | Hugo Jean-Marie Demeyere | Concentrated premix with reduced flammability for forming fabric softening composition |
GB9810655D0 (en) * | 1998-05-18 | 1998-07-15 | Unilever Plc | Stable ammonium compositions |
GB9810656D0 (en) * | 1998-05-18 | 1998-07-15 | Unilever Plc | Stable ammonium compositions |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS598392B2 (ja) * | 1979-06-29 | 1984-02-24 | 花王株式会社 | 洗浄剤組成物 |
EP0026528B2 (de) * | 1979-09-29 | 1992-08-19 | THE PROCTER & GAMBLE COMPANY | Reinigungsmittelzusammensetzungen |
AU619502B2 (en) * | 1987-11-05 | 1992-01-30 | Colgate-Palmolive Company, The | Liquid softergent formulations having improved stability and softening properties |
US4857213A (en) * | 1988-02-08 | 1989-08-15 | The Procter & Gamble Company | Liquid detergent containing conditioning agent and high levels of alkyl sulfate/alkyl ethoxylated sulfate |
-
1993
- 1993-03-08 DE DE4307186A patent/DE4307186A1/de not_active Withdrawn
-
1994
- 1994-02-28 DE DE59402536T patent/DE59402536D1/de not_active Expired - Fee Related
- 1994-02-28 WO PCT/EP1994/000580 patent/WO1994020596A1/de active IP Right Grant
- 1994-02-28 EP EP94909087A patent/EP0688356B1/de not_active Expired - Lifetime
- 1994-02-28 ES ES94909087T patent/ES2100703T3/es not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO9420596A1 * |
Also Published As
Publication number | Publication date |
---|---|
ES2100703T3 (es) | 1997-06-16 |
DE59402536D1 (de) | 1997-05-28 |
DE4307186A1 (de) | 1994-09-15 |
EP0688356B1 (de) | 1997-04-23 |
WO1994020596A1 (de) | 1994-09-15 |
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