EP1141189A1 - Klare weichspülmittelformulierungen - Google Patents
Klare weichspülmittelformulierungenInfo
- Publication number
- EP1141189A1 EP1141189A1 EP99940160A EP99940160A EP1141189A1 EP 1141189 A1 EP1141189 A1 EP 1141189A1 EP 99940160 A EP99940160 A EP 99940160A EP 99940160 A EP99940160 A EP 99940160A EP 1141189 A1 EP1141189 A1 EP 1141189A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fabric softener
- fatty acids
- parts
- mass
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
Definitions
- the invention relates to fabric softener formulations based on one or more cationic surfactants and at least one further
- the object of the present invention was therefore to avoid these disadvantages of the prior art and to provide fabric softener formulations which have an activity spectrum which is at least as good as that of the comparable products of the prior art, but which also have a clear and water-bright appearance , whose production can be carried out with reduced energy expenditure and whose handling ensures problem-free use for the end users.
- fabric softener formulations consisting predominantly of cationic surfactants and 5-30% by weight, based on the total formulation, of a further compound meet these requirements.
- the invention therefore relates to clear and light-colored fabric softener formulations comprising
- R -CH 3 , -CH 2 -CH (R 4 ) -OR 1 , -CH 2 -CH (R 5 ) -OR 2 , wherein
- a " anion of a quaternizing agent, in particular dimethyl sulfate, diethyl sulfate, methyl chloride, and
- Alkanolamines methyldiethanolamine, methylethanolisopropanolamine, methyldiisopropanolamine, triisopropanolamine or triethanolamine can be used.
- aqueous fabric softeners based on esters from fatty acids and alkanolamines which are reacted in a molar ratio of 1: 1.6 to 1: 2.
- the quaternary compounds of the general formula (I) used in accordance with the invention are, according to the methods generally known in this field, by esterification of alkanolamines such as triethanolamine (TEA), methyl diethanolamine (MDEA), methyl diisopropanolamine (MDIA), methyl ethanol isopropanolamine ( MEIPA), triisopropanolamine (TIPA) with fatty acid and subsequent quaternization.
- alkanolamines such as triethanolamine (TEA), methyl diethanolamine (MDEA), methyl diisopropanolamine (MDIA), methyl ethanol isopropanolamine ( MEIPA), triisopropanolamine (TIPA) with fatty acid and subsequent quaternization.
- Ester compounds based on triethanolamine such as N-methyl, N, N-bis (beta-C-
- the fatty acids for the esterification or transesterification are the monobasic fatty acids known and customary in this field based on natural vegetable or animal oils with 6-22 carbon atoms, in particular with 14-18 carbon atoms, such as oleic acid, linoleic acid, linolenic acid and in particular rapeseed oil fatty acid , Soybean oil fatty acid, sunflower oil fatty acid, tall oil fatty acid which can be used alone or as a mixture in the form of their glycerides, methyl or ethyl esters or as free acids. In principle, all fatty acids with a similar chain distribution are suitable.
- the content of these fatty acids or fatty acid esters in unsaturated portions is - if necessary - adjusted to a desired iodine number by the known catalytic hydrogenation processes or achieved by mixing fully hydrogenated with non-hydrogenated fat components.
- the iodine number is the amount of iodine which is taken up by 100 g of the compound for saturating the double bonds.
- fatty acids with iodine numbers in the range from approximately 40 to 160 preference is given to fatty acids with iodine numbers in the range from approximately 40 to 160, but in particular rapeseed oil fatty acids, sunflower oil fatty acids, soybean oil fatty acids and tall oil fatty acids, with iodine numbers in the range from approximately 80 to 150.
- rapeseed oil fatty acids sunflower oil fatty acids
- soybean oil fatty acids and tall oil fatty acids
- the esterification or transesterification is carried out according to known methods.
- the alkanolamine with the desired degree of esterification corresponding amount of fatty acid or fatty acid ester, optionally in the presence of a catalyst, for.
- methanesulfonic acid reacted under nitrogen at 160-240 ° C and the water of reaction or the alcohol formed is distilled off continuously, the pressure being able to be reduced to complete the reaction.
- the fatty acids and the alkanolamine are first reacted in such a ratio that, in view of the desired application properties of the end products, a degree of esterification of 1.6 to 2.0 results; a degree of esterification of 1.8 is particularly preferred according to the invention to 2.0.
- the compounds produced in this way are technical reaction mixtures which are predominantly present as diesters.
- the subsequent quaternization is also carried out using known methods.
- the procedure according to the invention is such that equimolar amounts of the quaternizing agent are added to the ester, optionally with the use of a solvent, preferably isopropanol, ethanol, 1,2-propylene glycol and / or dipropylene glycol, at 60-90 ° C. with stirring, if appropriate under pressure and the completion of the reaction is monitored by controlling the total number of amines.
- Examples of the quaternizing agents used are organic or inorganic acids, but preferably short-chain dialkyl phosphates and sulfates such as, in particular, dimethyl sulfate, diethyl sulfate, dimethyl phosphate, diethyl phosphate, short-chain halogenated hydrocarbons, in particular methyl chloride.
- Oleic acid with an acid number of 198-204, an iodine number of approx. 95 and a C chain distribution of
- the components A1 - A5 were quaternized with dimethyl sulfate and contain 10 mass% isopropanol as a solvent.
- the following references to components A 1 to A 5 mean these quaternized compounds.
- optionally alkoxylated branched short-chain alcohols having 3 to 6 carbon atoms such as isopropanol, butanol-2, 2-methyl-propanol-1, 3-methyl-butanol-1, 2-methyl-butanol-1, and their alkoxylation products .
- the degree of alkoxylation is 0 to about 8, technical mixtures having an average degree of alkoxylation of 0 or> 2.5 to about 3.5 being preferred according to the invention.
- the compounds of component B can be used as a mixture with one another and / or with one another in amounts of about 5 to 30% by weight, based on the mixture as a whole, preferably in amounts of 10 to 25% by weight.
- the fabric softeners are prepared by emulsifying or dissolving the quaternized compounds A 1 - A 5 with the use of compounds of the general formula B, by adding the respective individual components to water with stirring. In principle, the usual procedures in this field can be applied.
- water is initially introduced at room temperature, with good stirring first the dye solution, then the optionally required antifoam emulsion and finally the plasticizer and component B) are stirred in as a mixture or in any order. Thereafter, perfume oil is metered in and, where appropriate, a certain amount of an electrolyte solution, reduce the viscosity of the finished formulation to ⁇ .
- the fabric softeners according to the invention can contain the specified components within the limits customary in this field, such as 15 to 35% by weight of the compounds of the general my Formula A; 5 to 30% by weight of at least one of the compounds of the general formula B; 0.5 to 18% by weight of one or more of the customary auxiliaries and additives, for example
- the fabric softeners according to the invention are added in the last rinse cycle after the actual washing process.
- the application concentration after dilution with water is in the range of 0.1 to 10 g of fabric softener per liter of treatment liquor, depending on the area of application.
- Demineralized water is initially introduced at room temperature, the dye solution is added and the quaternary ammonium compound (Quat; component A) is slowly mixed into the water phase with constant stirring. Subsequently, component B is added to the mixture of water and quat with stirring until it is clearly dissolved at 20 ° C. This formulation is then cooled to 4 ° C and must be clearly transparent at this temperature. If necessary, an additional amount of solubilizer B is stirred in until the mixture is clear at 4 ° C. At the same time as, before or after the addition of component B, alcohols, preferably glycols with boiling points> 120 ° C., can be stirred into the reaction mixture to increase the flash point of the finished formulation.
- solvents preferably glycols with boiling points> 120 ° C.
- the perfume oil is then added at room temperature with stirring and, if necessary, mineral salts are added to adjust the viscosity in the case of highly viscous solutions in order to improve the stirrability and flowability of the mixture.
- the chlorides of the alkali or alkaline earth metals can be used as mineral salts in amounts of about 0.1 to 1.5% by weight, preferably in the form of their 10 to 30% strength aqueous solutions, in particular an aqueous calcium chloride solution.
- Component A1 30.6 parts by mass
- Component B1 18.0 parts by mass
- Component B2 2.0 parts by mass
- Component A3 30.6 parts by mass
- Component B2 10.0 parts by mass
- Component A2 30.6 parts by mass
- Component B3 12.5 parts by mass
- Component A1 30.6 parts by mass
- Component B4 10.0 parts by mass
- Component B2 6.0 parts by mass
- Component A5 30.6 parts by mass
- Component B4 13.0 parts by mass
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Investigating Or Analysing Biological Materials (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
- Developing Agents For Electrophotography (AREA)
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP99940160A EP1141189B1 (de) | 1999-01-07 | 1999-08-06 | Klare weichspülmittelformulierungen |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP99100154A EP1018541A1 (de) | 1999-01-07 | 1999-01-07 | Klare Weichspülmittelformulierungen |
EP99100154 | 1999-01-07 | ||
PCT/EP1999/005692 WO2000040681A1 (de) | 1999-01-07 | 1999-08-06 | Klare weichspülmittelformulierungen |
EP99940160A EP1141189B1 (de) | 1999-01-07 | 1999-08-06 | Klare weichspülmittelformulierungen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1141189A1 true EP1141189A1 (de) | 2001-10-10 |
EP1141189B1 EP1141189B1 (de) | 2002-10-23 |
Family
ID=8237315
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99100154A Withdrawn EP1018541A1 (de) | 1999-01-07 | 1999-01-07 | Klare Weichspülmittelformulierungen |
EP99940160A Expired - Lifetime EP1141189B1 (de) | 1999-01-07 | 1999-08-06 | Klare weichspülmittelformulierungen |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99100154A Withdrawn EP1018541A1 (de) | 1999-01-07 | 1999-01-07 | Klare Weichspülmittelformulierungen |
Country Status (8)
Country | Link |
---|---|
US (1) | US6653275B1 (de) |
EP (2) | EP1018541A1 (de) |
AT (1) | ATE226621T1 (de) |
CA (1) | CA2359654C (de) |
DE (1) | DE59903208D1 (de) |
ES (1) | ES2188217T3 (de) |
PL (1) | PL348776A1 (de) |
WO (1) | WO2000040681A1 (de) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6966696B1 (en) | 1998-10-24 | 2005-11-22 | The Procter & Gamble Company | Methods for laundering delicate garments in a washing machine |
US6995124B1 (en) | 1998-10-24 | 2006-02-07 | The Procter & Gamble Company | Methods for laundering delicate garments in a washing machine |
US7185380B2 (en) | 1998-10-24 | 2007-03-06 | The Procter & Gamble Company | Methods for laundering delicate garments in a washing machine comprising a woven acrylic coated polyester garment container |
DE10120176A1 (de) * | 2001-04-24 | 2002-11-07 | Henkel Kgaa | Klare Weichspüler |
US8361953B2 (en) | 2008-02-08 | 2013-01-29 | Evonik Goldschmidt Corporation | Rinse aid compositions with improved characteristics |
EP2119821A1 (de) | 2008-05-13 | 2009-11-18 | The Procter and Gamble Company | Verfahren zur Bearbeitung von Gewebe |
US8188027B2 (en) | 2009-07-20 | 2012-05-29 | The Procter & Gamble Company | Liquid fabric enhancer composition comprising a di-hydrocarbyl complex |
JP5570651B2 (ja) * | 2010-04-01 | 2014-08-13 | エボニック デグサ ゲーエムベーハー | 織物柔軟剤活性組成物 |
CA2794084C (en) * | 2010-04-01 | 2014-09-02 | The Procter & Gamble Company | Fabric softener based on a bis-(2-hydroxyethyl)-dimethylammonium chloride fatty acid ester |
US20110239377A1 (en) * | 2010-04-01 | 2011-10-06 | Renae Dianna Fossum | Heat Stable Fabric Softener |
US8183199B2 (en) | 2010-04-01 | 2012-05-22 | The Procter & Gamble Company | Heat stable fabric softener |
ES2536849T3 (es) | 2010-04-01 | 2015-05-29 | Evonik Degussa Gmbh | Composición de sustancia activa suavizante de tejidos |
MX2012012340A (es) | 2010-04-28 | 2012-11-21 | Evonik Degussa Gmbh | Composicion suavizante de telas. |
US8507425B2 (en) | 2010-06-29 | 2013-08-13 | Evonik Degussa Gmbh | Particulate fabric softener comprising ethylenediamine fatty acid amides and method of making |
WO2013113453A1 (en) | 2012-01-30 | 2013-08-08 | Evonik Industries Ag | Fabric softener active composition |
PL2847307T3 (pl) | 2012-05-07 | 2016-10-31 | Aktywna kompozycja do zmiękczania tkanin i sposób jej wytwarzania | |
BR102014025172B1 (pt) | 2013-11-05 | 2020-03-03 | Evonik Degussa Gmbh | Método para fabricação de um éster de ácido graxo de metisulfato de tris-(2-hidroxietil)-metilamônio, e composição ativa de amaciante de roupa |
EP2997959B1 (de) | 2014-09-22 | 2019-12-25 | Evonik Operations GmbH | Formulierung enthaltend esterquats basierend auf isopropanolamin und tetrahydroxypropylethylenediamin |
EP2997958B1 (de) | 2014-09-22 | 2021-03-10 | Evonik Operations GmbH | Emulsion enthaltend flüssige esterquats und polymerverdicker |
UA119182C2 (uk) | 2014-10-08 | 2019-05-10 | Евонік Дегусса Гмбх | Активна композиція для пом'якшувача тканини |
WO2020061658A1 (en) | 2018-09-28 | 2020-04-02 | L'oreal | Hair treatment compositions comprising an esterquat |
JP7193405B2 (ja) * | 2019-04-01 | 2022-12-20 | 川研ファインケミカル株式会社 | 身体洗浄剤組成物 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3150178A1 (de) | 1981-12-18 | 1983-06-30 | Hoechst Ag, 6230 Frankfurt | "konzentrierte waescheweichspuelmittel" |
DK0687291T4 (da) * | 1993-03-01 | 2005-12-05 | Procter & Gamble | Koncentrerede, bionedbrydelige, kvarternær ammonium skyllemiddelsammensætninger og forbindelser indeholdende umættede fedtsyrekæder med mellemhöje iodtal |
US5399272A (en) * | 1993-12-17 | 1995-03-21 | The Procter & Gamble Company | Clear or translucent, concentrated biodgradable quaternary ammonium fabric softener compositions |
US5492636A (en) * | 1994-09-23 | 1996-02-20 | Quest International Fragrances Company | Clear concentrated fabric softener |
WO1997003169A1 (en) * | 1995-07-11 | 1997-01-30 | The Procter & Gamble Company | Concentrated, stable fabric softening composition |
GB9526182D0 (en) * | 1995-12-21 | 1996-02-21 | Unilever Plc | Fabric softening composition |
US5830845A (en) * | 1996-03-22 | 1998-11-03 | The Procter & Gamble Company | Concentrated fabric softening composition with good freeze/thaw recovery and highly unsaturated fabric softener compound therefor |
-
1999
- 1999-01-07 EP EP99100154A patent/EP1018541A1/de not_active Withdrawn
- 1999-08-06 EP EP99940160A patent/EP1141189B1/de not_active Expired - Lifetime
- 1999-08-06 AT AT99940160T patent/ATE226621T1/de not_active IP Right Cessation
- 1999-08-06 PL PL99348776A patent/PL348776A1/xx unknown
- 1999-08-06 ES ES99940160T patent/ES2188217T3/es not_active Expired - Lifetime
- 1999-08-06 US US09/856,581 patent/US6653275B1/en not_active Expired - Fee Related
- 1999-08-06 CA CA002359654A patent/CA2359654C/en not_active Expired - Fee Related
- 1999-08-06 WO PCT/EP1999/005692 patent/WO2000040681A1/de active IP Right Grant
- 1999-08-06 DE DE59903208T patent/DE59903208D1/de not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO0040681A1 * |
Also Published As
Publication number | Publication date |
---|---|
CA2359654C (en) | 2007-05-29 |
ATE226621T1 (de) | 2002-11-15 |
PL348776A1 (en) | 2002-06-17 |
ES2188217T3 (es) | 2003-06-16 |
EP1141189B1 (de) | 2002-10-23 |
EP1018541A1 (de) | 2000-07-12 |
CA2359654A1 (en) | 2000-07-13 |
DE59903208D1 (de) | 2002-11-28 |
WO2000040681A1 (de) | 2000-07-13 |
US6653275B1 (en) | 2003-11-25 |
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