DK1633905T3 - Belægning af metaloverflader med phosphateringsoplösninger, der indeholder hydrogenperoxid og nitroguanidin - Google Patents

Belægning af metaloverflader med phosphateringsoplösninger, der indeholder hydrogenperoxid og nitroguanidin

Info

Publication number
DK1633905T3
DK1633905T3 DK04733319T DK04733319T DK1633905T3 DK 1633905 T3 DK1633905 T3 DK 1633905T3 DK 04733319 T DK04733319 T DK 04733319T DK 04733319 T DK04733319 T DK 04733319T DK 1633905 T3 DK1633905 T3 DK 1633905T3
Authority
DK
Denmark
Prior art keywords
nitroguanidine
hydrogen peroxide
coating
containing hydrogen
solutions containing
Prior art date
Application number
DK04733319T
Other languages
Danish (da)
English (en)
Inventor
Thomas Nitschke
Ruediger Rein
Eckart Schoenfelder
Peter Schubach
Juergen Specht
Original Assignee
Chemetall Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemetall Gmbh filed Critical Chemetall Gmbh
Application granted granted Critical
Publication of DK1633905T3 publication Critical patent/DK1633905T3/da

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
    • C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
    • C23C22/364—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also manganese cations
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/12—Orthophosphates containing zinc cations
    • C23C22/16—Orthophosphates containing zinc cations containing also peroxy-compounds
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/18—Orthophosphates containing manganese cations
    • C23C22/182—Orthophosphates containing manganese cations containing also zinc cations
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/18—Orthophosphates containing manganese cations
    • C23C22/182—Orthophosphates containing manganese cations containing also zinc cations
    • C23C22/184—Orthophosphates containing manganese cations containing also zinc cations containing also nickel cations
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
    • C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
    • C23C22/364—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also manganese cations
    • C23C22/365—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also manganese cations containing also zinc and nickel cations
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T50/00—Aeronautics or air transport
    • Y02T50/60—Efficient propulsion technologies, e.g. for aircraft

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Paints Or Removers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
DK04733319T 2003-05-23 2004-05-17 Belægning af metaloverflader med phosphateringsoplösninger, der indeholder hydrogenperoxid og nitroguanidin DK1633905T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10323305A DE10323305B4 (de) 2003-05-23 2003-05-23 Verfahren zur Beschichtung von metallischen Oberflächen mit einer Wasserstoffperoxid enthaltenden Phosphatierungslösung, Phosphatierlösung und Verwendung der behandelten Gegenstände
PCT/EP2004/005282 WO2004104266A1 (de) 2003-05-23 2004-05-17 Verfahren und lösung zur beschichtung von metallischen oberflächen mit einer wasserstoffperoxid enthaltenden phosphatierungslösung, hergestellte metallgenstand und verwendung des gegenstandes

Publications (1)

Publication Number Publication Date
DK1633905T3 true DK1633905T3 (da) 2008-01-14

Family

ID=33441188

Family Applications (1)

Application Number Title Priority Date Filing Date
DK04733319T DK1633905T3 (da) 2003-05-23 2004-05-17 Belægning af metaloverflader med phosphateringsoplösninger, der indeholder hydrogenperoxid og nitroguanidin

Country Status (13)

Country Link
US (2) US20060278307A1 (pt)
EP (1) EP1633905B1 (pt)
JP (1) JP2006528280A (pt)
CN (1) CN1826429B (pt)
AT (1) ATE373117T1 (pt)
AU (1) AU2004241000B2 (pt)
BR (1) BRPI0410585B1 (pt)
DE (2) DE10323305B4 (pt)
DK (1) DK1633905T3 (pt)
ES (1) ES2294498T3 (pt)
PT (1) PT1633905E (pt)
WO (1) WO2004104266A1 (pt)
ZA (1) ZA200509144B (pt)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005047424A1 (de) * 2005-09-30 2007-04-05 Henkel Kgaa Phosphatierlösung mit Wasserstoffperoxid und chelatbildenden Carbonsäuren
DE102006052919A1 (de) 2006-11-08 2008-05-15 Henkel Kgaa Zr-/Ti-haltige Phosphatierlösung zur Passivierung von Metallverbundoberflächen
JP5528115B2 (ja) * 2006-12-01 2014-06-25 日本パーカライジング株式会社 高過酸化物自己析出浴
DE102008000600B4 (de) * 2008-03-11 2010-05-12 Chemetall Gmbh Verfahren zur Beschichtung von metallischen Oberflächen mit einem Passivierungsmittel, das Passivierungsmittel, die hiermit erzeugte Beschichtung und ihre Verwendung
DE102008038653A1 (de) * 2008-08-12 2010-03-25 Henkel Ag & Co. Kgaa Sukzessive korrosionsschützende Vorbehandlung von Metalloberflächen in einem Mehrstufenprozess
IT1397902B1 (it) * 2010-01-26 2013-02-04 Np Coil Dexter Ind Srl Processi di pretrattamento alla verniciatura, a basso impatto ambientale, alternativi ai trattamenti tradizionali di fosfatazione.
DE102010030697A1 (de) * 2010-06-30 2012-01-05 Henkel Ag & Co. Kgaa Verfahren zur selektiven Phosphatierung einer Verbundmetallkonstruktion
PL2503025T3 (pl) * 2011-03-22 2013-12-31 Henkel Ag & Co Kgaa Chroniąca przed korozją, wielostopniowa obróbka metalowych elementów konstrukcyjnych o powierzchniach cynkowych
CN103422082B (zh) * 2012-05-17 2017-07-18 中化化工科学技术研究总院 钕铁硼磁性材料锌系磷化液及其使用方法
CN107683348A (zh) * 2015-04-07 2018-02-09 凯密特尔有限责任公司 专用于调节转化涂层的电导率的方法
KR20190043155A (ko) 2016-08-24 2019-04-25 피피지 인더스트리즈 오하이오 인코포레이티드 금속 기판을 처리하기 위한 알칼리성 조성물
ES2770152T3 (es) * 2017-04-21 2020-06-30 Henkel Ag & Co Kgaa Procedimiento para fosfatación al zinc, libre de lodos, de componentes metálicos en serie para formar capas
EP3392376A1 (de) 2017-04-21 2018-10-24 Henkel AG & Co. KGaA Verfahren zur schichtbildenden zinkphosphatierung von metallischen bauteilen in serie
CN111742079A (zh) * 2018-02-19 2020-10-02 凯密特尔有限责任公司 复合金属结构的选择性磷化方法
CN108342723B (zh) * 2018-03-19 2020-02-07 常州市春雷浩宇环保科技有限公司 一种适用于锌系磷化液的无渣促进剂
FR3090694B1 (fr) * 2018-12-20 2023-05-26 Univ De Pau Et Des Pays De Ladour Solution de traitement anticorrosion et utilisations
JPWO2021210458A1 (pt) * 2020-04-14 2021-10-21
CN112899672B (zh) * 2021-01-14 2023-03-17 厦门腾兴隆化工有限公司 一种黑色磷化剂及其制备方法

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US2375468A (en) * 1938-02-04 1945-05-08 Parker Rust Proof Co Phosphate coating of metals
DE977633C (de) * 1950-07-06 1967-11-02 Galvapol Ges Fuer Galvanotechn Verfahren zur Herstellung von Phosphatueberzuegen auf eisenhaltigen Metallgegenstaenden
US3676224A (en) * 1970-10-16 1972-07-11 Lubrizol Corp Phosphating solution with scale suppressing characteristics
DE2327304C3 (de) * 1973-05-29 1982-01-21 Metallgesellschaft Ag, 6000 Frankfurt Verfahren zum Aufbringen von Phosphatüberzügen auf Metalle
JPS5339945A (en) * 1976-09-25 1978-04-12 Nippon Packaging Kk Surface treatment of zinc or zinc alloy
GB2148950B (en) * 1983-10-26 1987-02-04 Pyrene Chemical Services Ltd Phosphating composition and processes
DE3800835A1 (de) * 1988-01-14 1989-07-27 Henkel Kgaa Verfahren zur phosphatierung von metalloberflaechen
DE3920296A1 (de) * 1989-06-21 1991-01-10 Henkel Kgaa Verfahren zur herstellung von mangan- und magnesiumhaltigen zinkphosphatueberzuegen
DE4306446A1 (de) * 1993-03-02 1994-09-08 Metallgesellschaft Ag Verfahren zur Erleichterung der Kaltumformung
JPH08302477A (ja) * 1994-12-06 1996-11-19 Nippon Parkerizing Co Ltd 金属材料用りん酸亜鉛系化成処理液および処理方法
DE19634685A1 (de) * 1996-08-28 1998-03-05 Metallgesellschaft Ag Wässrige Lösung und Verfahren zur Phosphatierung metallischer Oberflächen
CA2300276A1 (en) * 1997-08-06 1999-02-18 Henkel Kommanditgesellschaft Auf Aktien Phosphating method accelerated by n-oxides
DE19834796A1 (de) * 1998-08-01 2000-02-03 Henkel Kgaa Verfahren zur Phosphatierung, Nachspülung und kathodischer Elektrotauchlackierung
DE19958192A1 (de) * 1999-12-02 2001-06-07 Henkel Kgaa Verfahren zur Phosphatierung, Nachspülung und kathodischer Elektrotauchlackierung
DE10010355A1 (de) * 2000-03-07 2001-09-13 Chemetall Gmbh Verfahren zum Aufbringen eines Phosphatüberzuges und Verwendung der derart phosphatierten Metallteile
US6530999B2 (en) * 2000-10-10 2003-03-11 Henkel Corporation Phosphate conversion coating
DE10110833B4 (de) * 2001-03-06 2005-03-24 Chemetall Gmbh Verfahren zum Aufbringen eines Phosphatüberzuges und Verwendung der derart phosphatierten Metallteile
DE10110834B4 (de) * 2001-03-06 2005-03-10 Chemetall Gmbh Verfahren zur Beschichtung von metallischen Oberflächen und Verwendung der derart beschichteten Substrate
DE10118552A1 (de) * 2001-04-14 2002-10-17 Henkel Kgaa Bestimmung der Beschleunigerkonzentration in Phosphatierbäder
DE10155976A1 (de) * 2001-11-14 2003-05-22 Henkel Kgaa Steuerung der Beschleunigerkonzentration in Phosphatierbäder
DE10320313B4 (de) * 2003-05-06 2005-08-11 Chemetall Gmbh Verfahren zum Beschichten von metallischen Körpern mit einer Phosphatierungslösung, Phosphatierungslösung und die Verwendung des beschichteten Gegenstandes

Also Published As

Publication number Publication date
AU2004241000B2 (en) 2009-05-14
EP1633905A1 (de) 2006-03-15
BRPI0410585A (pt) 2006-06-20
DE502004004961D1 (de) 2007-10-25
DE10323305B4 (de) 2006-03-30
AU2004241000A1 (en) 2004-12-02
EP1633905B1 (de) 2007-09-12
US20110180186A1 (en) 2011-07-28
CN1826429B (zh) 2012-08-08
ATE373117T1 (de) 2007-09-15
ZA200509144B (en) 2007-03-28
US20060278307A1 (en) 2006-12-14
DE10323305A1 (de) 2004-12-16
ES2294498T3 (es) 2008-04-01
PT1633905E (pt) 2007-12-20
BRPI0410585B1 (pt) 2014-09-16
JP2006528280A (ja) 2006-12-14
WO2004104266A1 (de) 2004-12-02
CN1826429A (zh) 2006-08-30

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