DE69818056D1 - Polymerisationsverfahren in der gasphase für die herstellung von propylen / 1-penten copolymeren - Google Patents

Polymerisationsverfahren in der gasphase für die herstellung von propylen / 1-penten copolymeren

Info

Publication number
DE69818056D1
DE69818056D1 DE69818056T DE69818056T DE69818056D1 DE 69818056 D1 DE69818056 D1 DE 69818056D1 DE 69818056 T DE69818056 T DE 69818056T DE 69818056 T DE69818056 T DE 69818056T DE 69818056 D1 DE69818056 D1 DE 69818056D1
Authority
DE
Germany
Prior art keywords
propylene
production
gas phase
polymerization process
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69818056T
Other languages
English (en)
Other versions
DE69818056T2 (de
Inventor
Ioan Tincul
Hendrik Potgieter
Dawid Johannes Joubert
Antonie Hermanus Potgieter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sasol Technology Pty Ltd
Original Assignee
Sasol Technology Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Technology Pty Ltd filed Critical Sasol Technology Pty Ltd
Application granted granted Critical
Publication of DE69818056D1 publication Critical patent/DE69818056D1/de
Publication of DE69818056T2 publication Critical patent/DE69818056T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Emergency Medicine (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)
DE69818056T 1997-07-04 1998-07-03 Polymerisationsverfahren in der gasphase für die herstellung von propylen / 1-penten copolymeren Expired - Fee Related DE69818056T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ZA975997 1997-07-04
ZA9705997 1997-07-04
PCT/GB1998/001969 WO1999001485A1 (en) 1997-07-04 1998-07-03 Gas-phase polymerization process for producing propylene/1-pentene copolymers

Publications (2)

Publication Number Publication Date
DE69818056D1 true DE69818056D1 (de) 2003-10-16
DE69818056T2 DE69818056T2 (de) 2004-04-08

Family

ID=25586472

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69818056T Expired - Fee Related DE69818056T2 (de) 1997-07-04 1998-07-03 Polymerisationsverfahren in der gasphase für die herstellung von propylen / 1-penten copolymeren

Country Status (16)

Country Link
US (1) US6391987B1 (de)
EP (1) EP0993474B1 (de)
JP (1) JP2002508019A (de)
KR (1) KR20010021512A (de)
CN (1) CN1107684C (de)
AT (1) ATE249484T1 (de)
AU (1) AU755262B2 (de)
BR (1) BR9810982A (de)
CA (1) CA2294798A1 (de)
DE (1) DE69818056T2 (de)
HK (1) HK1028054A1 (de)
HU (1) HUP0002365A2 (de)
ID (1) ID23869A (de)
IL (1) IL133738A0 (de)
PL (1) PL337968A1 (de)
WO (1) WO1999001485A1 (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
WO2000001766A1 (en) 1998-07-01 2000-01-13 Exxon Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
US20030008988A1 (en) * 2001-01-29 2003-01-09 Sasol Technology (Proprietary) Limited Polymerization
US20030225224A1 (en) * 2002-05-28 2003-12-04 Sasol Technology (Proprietary) Limited Polymerization
WO2011009704A1 (en) 2009-07-21 2011-01-27 Basell Poliolefine Italia S.R.L. Fibres made from copolymers of propylene and 1-pentene
EP3317311B1 (de) * 2015-06-30 2020-05-20 Borealis AG Verfahren zur herstellung von propylenpolymerzusammensetzungen
CN106565870B (zh) * 2015-10-12 2019-07-05 中国科学院化学研究所 烯烃聚合催化剂及其制备方法和烯烃聚合催化剂体系及其应用以及聚烯烃树脂的制备方法
CN106565883B (zh) * 2015-10-12 2019-07-05 中国科学院化学研究所 一种有机硅烷的应用以及聚烯烃树脂及其制备方法
WO2017063118A1 (zh) 2015-10-12 2017-04-20 中国科学院化学研究所 烯烃聚合催化剂及其制备方法和烯烃聚合催化剂体系及其应用以及聚烯烃树脂的制备方法
EP3363822B1 (de) 2015-10-12 2021-05-19 Institute Of Chemistry, Chinese Academy Of Sciences Verwendung von organischem siloxan und polyolefinharz und herstellungsverfahren dafür
EP3363825B1 (de) * 2015-10-12 2021-04-14 Institute Of Chemistry, Chinese Academy Of Sciences Verwendung von organosiloxan und reaktorinterne polyolefinlegierung und herstellungsverfahren dafür
CN110144022B (zh) * 2019-05-28 2020-02-21 国家能源集团宁夏煤业有限责任公司 Ziegler-Natta催化剂的工业制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1988002379A1 (en) * 1986-10-02 1988-04-07 Bp Chemicals Limited Process for polymerizing one or more 1-olefins in the gas phase in the presence of pulverulent inorganic material
KR900009719A (ko) * 1988-12-16 1990-07-05 엠. 데이비드 레오나이드 신규 에틸렌-프로필렌 공중합체
US5618895A (en) * 1990-04-06 1997-04-08 Basf Aktiengesellschaft Process for preparing copolymers of propylene with other 1-alkenes
ZA96626B (en) * 1995-02-09 1996-08-15 Sastech Pty Ltd Copolymerization

Also Published As

Publication number Publication date
JP2002508019A (ja) 2002-03-12
PL337968A1 (en) 2000-09-11
CA2294798A1 (en) 1999-01-14
DE69818056T2 (de) 2004-04-08
ID23869A (id) 2000-05-25
KR20010021512A (ko) 2001-03-15
IL133738A0 (en) 2001-04-30
ATE249484T1 (de) 2003-09-15
CN1268145A (zh) 2000-09-27
AU8230498A (en) 1999-01-25
EP0993474A1 (de) 2000-04-19
WO1999001485A1 (en) 1999-01-14
HUP0002365A2 (hu) 2000-11-28
BR9810982A (pt) 2000-08-08
US6391987B1 (en) 2002-05-21
CN1107684C (zh) 2003-05-07
HK1028054A1 (en) 2001-02-02
AU755262B2 (en) 2002-12-05
EP0993474B1 (de) 2003-09-10

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