DE69726440T2 - Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne turm-verfahren - Google Patents

Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne turm-verfahren Download PDF

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Publication number: DE69726440T2
Authority: DE; Germany
Prior art keywords: surfactant; mixer; agglomerates; detergent; mixtures
Prior art date: 1996-10-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

DE69726440T

Other languages

German (de)

English (en)

Other versions

DE69726440D1 (de

Inventor

Edward Wayne BEIMESCH

Manivannan Kandasamy

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Procter and Gamble Co

Original Assignee

Procter and Gamble Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-10-04

Filing date

1997-06-05

Publication date

2004-09-09

1997-06-05 Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co

2004-01-08 Application granted granted Critical

2004-01-08 Publication of DE69726440D1 publication Critical patent/DE69726440D1/de

2004-09-09 Publication of DE69726440T2 publication Critical patent/DE69726440T2/de

2017-06-06 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title claims description 84
238000000034 method Methods 0.000 title claims description 70
239000000203 mixture Substances 0.000 title claims description 55
238000004519 manufacturing process Methods 0.000 title description 14
239000004094 surface-active agent Substances 0.000 claims description 44
230000008569 process Effects 0.000 claims description 38
239000000843 powder Substances 0.000 claims description 29
239000007788 liquid Substances 0.000 claims description 26
229910000323 aluminium silicate Inorganic materials 0.000 claims description 19
-1 fatty alcohol sulfates Chemical class 0.000 claims description 19
239000012530 fluid Substances 0.000 claims description 15
229920000642 polymer Polymers 0.000 claims description 14
150000004760 silicates Chemical class 0.000 claims description 14
239000000243 solution Substances 0.000 claims description 14
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
239000003945 anionic surfactant Substances 0.000 claims description 12
239000011248 coating agent Substances 0.000 claims description 12
239000007921 spray Substances 0.000 claims description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
238000005243 fluidization Methods 0.000 claims description 10
235000019832 sodium triphosphate Nutrition 0.000 claims description 10
125000000217 alkyl group Chemical group 0.000 claims description 9
150000004649 carbonic acid derivatives Chemical class 0.000 claims description 7
238000002156 mixing Methods 0.000 claims description 6
229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
235000017550 sodium carbonate Nutrition 0.000 claims description 6
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical class [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 5
239000002736 nonionic surfactant Substances 0.000 claims description 5
229910052938 sodium sulfate Inorganic materials 0.000 claims description 5
235000011152 sodium sulphate Nutrition 0.000 claims description 5
239000003093 cationic surfactant Substances 0.000 claims description 4
238000000576 coating method Methods 0.000 claims description 4
229910019142 PO4 Inorganic materials 0.000 claims description 3
150000008051 alkyl sulfates Chemical class 0.000 claims description 3
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 3
235000021317 phosphate Nutrition 0.000 claims description 3
150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
235000013162 Cocos nucifera Nutrition 0.000 claims description 2
244000060011 Cocos nucifera Species 0.000 claims description 2
150000001860 citric acid derivatives Chemical class 0.000 claims description 2
239000002563 ionic surfactant Substances 0.000 claims description 2
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 2
239000002888 zwitterionic surfactant Substances 0.000 claims description 2
239000000463 material Substances 0.000 description 21
239000002245 particle Substances 0.000 description 19
238000005054 agglomeration Methods 0.000 description 18
239000008187 granular material Substances 0.000 description 18
230000002776 aggregation Effects 0.000 description 15
239000004615 ingredient Substances 0.000 description 14
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 13
229920005646 polycarboxylate Polymers 0.000 description 13
238000005342 ion exchange Methods 0.000 description 11
239000002253 acid Substances 0.000 description 10
150000003839 salts Chemical class 0.000 description 10
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
239000011734 sodium Substances 0.000 description 9
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
239000011230 binding agent Substances 0.000 description 7
229920001577 copolymer Polymers 0.000 description 7
229910052708 sodium Inorganic materials 0.000 description 7
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 7
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
150000007942 carboxylates Chemical group 0.000 description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
229920000768 polyamine Polymers 0.000 description 6
239000002994 raw material Substances 0.000 description 6
238000001694 spray drying Methods 0.000 description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
101710194948 Protein phosphatase PhpP Proteins 0.000 description 5
229910052783 alkali metal Inorganic materials 0.000 description 5
150000001340 alkali metals Chemical class 0.000 description 5
125000002947 alkylene group Chemical group 0.000 description 5
125000000129 anionic group Chemical group 0.000 description 5
125000004432 carbon atom Chemical group C* 0.000 description 5
235000014113 dietary fatty acids Nutrition 0.000 description 5
239000000194 fatty acid Substances 0.000 description 5
229930195729 fatty acid Natural products 0.000 description 5
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 5
239000000047 product Substances 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
239000004115 Sodium Silicate Substances 0.000 description 4
150000003863 ammonium salts Chemical class 0.000 description 4
239000007795 chemical reaction product Substances 0.000 description 4
238000007906 compression Methods 0.000 description 4
230000006835 compression Effects 0.000 description 4
238000010924 continuous production Methods 0.000 description 4
238000001035 drying Methods 0.000 description 4
150000004665 fatty acids Chemical class 0.000 description 4
229910052739 hydrogen Inorganic materials 0.000 description 4
239000001257 hydrogen Substances 0.000 description 4
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
239000011976 maleic acid Substances 0.000 description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
235000019351 sodium silicates Nutrition 0.000 description 4
239000007858 starting material Substances 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 3
241000196324 Embryophyta Species 0.000 description 3
108090000790 Enzymes Proteins 0.000 description 3
102000004190 Enzymes Human genes 0.000 description 3
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
229930182556 Polyacetal Natural products 0.000 description 3
239000002202 Polyethylene glycol Substances 0.000 description 3
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
229910004298 SiO 2 Inorganic materials 0.000 description 3
229910021536 Zeolite Inorganic materials 0.000 description 3
230000008901 benefit Effects 0.000 description 3
229960003237 betaine Drugs 0.000 description 3
229910001424 calcium ion Inorganic materials 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
239000006260 foam Substances 0.000 description 3
238000005469 granulation Methods 0.000 description 3
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229920001223 polyethylene glycol Polymers 0.000 description 3
238000006116 polymerization reaction Methods 0.000 description 3
229920006324 polyoxymethylene Polymers 0.000 description 3
229910052700 potassium Inorganic materials 0.000 description 3
239000011591 potassium Substances 0.000 description 3
159000000001 potassium salts Chemical class 0.000 description 3
239000002243 precursor Substances 0.000 description 3
125000001453 quaternary ammonium group Chemical group 0.000 description 3
239000010457 zeolite Substances 0.000 description 3
PSZAEHPBBUYICS-UHFFFAOYSA-N 2-methylidenepropanedioic acid Chemical compound OC(=O)C(=C)C(O)=O PSZAEHPBBUYICS-UHFFFAOYSA-N 0.000 description 2
229910017090 AlO 2 Inorganic materials 0.000 description 2
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 2
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
229920002873 Polyethylenimine Polymers 0.000 description 2
239000004990 Smectic liquid crystal Substances 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
239000012190 activator Substances 0.000 description 2
125000002252 acyl group Chemical group 0.000 description 2
150000001335 aliphatic alkanes Chemical group 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
125000004450 alkenylene group Chemical group 0.000 description 2
150000001450 anions Chemical class 0.000 description 2
125000003710 aryl alkyl group Chemical group 0.000 description 2
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125000000732 arylene group Chemical group 0.000 description 2
238000010923 batch production Methods 0.000 description 2
239000011575 calcium Substances 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
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150000001875 compounds Chemical class 0.000 description 2
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239000001530 fumaric acid Substances 0.000 description 2
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125000001183 hydrocarbyl group Chemical group 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
229910052698 phosphorus Inorganic materials 0.000 description 2
239000011574 phosphorus Substances 0.000 description 2
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150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
125000006702 (C1-C18) alkyl group Chemical group 0.000 description 1
125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
SFRLSTJPMFGBDP-UHFFFAOYSA-N 1,2-diphosphonoethylphosphonic acid Chemical class OP(O)(=O)CC(P(O)(O)=O)P(O)(O)=O SFRLSTJPMFGBDP-UHFFFAOYSA-N 0.000 description 1
CXLSDGHWWXDHEE-UHFFFAOYSA-N 2-(dimethylazaniumyl)hexanoate Chemical compound CCCCC(N(C)C)C(O)=O CXLSDGHWWXDHEE-UHFFFAOYSA-N 0.000 description 1
WCSAPKHLAQFSIW-UHFFFAOYSA-N 3-(dimethylamino)-2-hydroxypropane-1-sulfonic acid Chemical compound CN(C)CC(O)CS(O)(=O)=O WCSAPKHLAQFSIW-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
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DSNYLLPFCFOBIB-UHFFFAOYSA-N CCC(N)S(=O)(=O)OCC(O)O Chemical compound CCC(N)S(=O)(=O)OCC(O)O DSNYLLPFCFOBIB-UHFFFAOYSA-N 0.000 description 1
PIEBLDUKOUPLRJ-UHFFFAOYSA-N CN(C)C(CCCCC)S(=O)(=O)O Chemical compound CN(C)C(CCCCC)S(=O)(=O)O PIEBLDUKOUPLRJ-UHFFFAOYSA-N 0.000 description 1
GXGJIOMUZAGVEH-UHFFFAOYSA-N Chamazulene Chemical group CCC1=CC=C(C)C2=CC=C(C)C2=C1 GXGJIOMUZAGVEH-UHFFFAOYSA-N 0.000 description 1
RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
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WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
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SXKQTYJLWWQUKA-UHFFFAOYSA-N O.O.O.O.O.O.O.O.O.O.OB(O)O.OB(O)O.OB(O)O.OB(O)O Chemical compound O.O.O.O.O.O.O.O.O.O.OB(O)O.OB(O)O.OB(O)O.OB(O)O SXKQTYJLWWQUKA-UHFFFAOYSA-N 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
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229920000954 Polyglycolide Polymers 0.000 description 1
229920000388 Polyphosphate Chemical class 0.000 description 1
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ZUBJEHHGZYTRPH-KTKRTIGZSA-N [(z)-octadec-9-enyl] hydrogen sulfate Chemical compound CCCCCCCC\C=C/CCCCCCCCOS(O)(=O)=O ZUBJEHHGZYTRPH-KTKRTIGZSA-N 0.000 description 1
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239000000654 additive Substances 0.000 description 1
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150000005215 alkyl ethers Chemical class 0.000 description 1
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ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical class [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
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XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
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238000007046 ethoxylation reaction Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
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WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
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229910052744 lithium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
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239000003505 polymerization initiator Substances 0.000 description 1
239000001205 polyphosphate Chemical class 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
239000001267 polyvinylpyrrolidone Substances 0.000 description 1
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
230000003014 reinforcing effect Effects 0.000 description 1
238000004626 scanning electron microscopy Methods 0.000 description 1
238000012216 screening Methods 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
235000019830 sodium polyphosphate Nutrition 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
239000013042 solid detergent Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000000375 suspending agent Substances 0.000 description 1
238000005494 tarnishing Methods 0.000 description 1
229940095064 tartrate Drugs 0.000 description 1
235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
- C11D11/0088—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads the liquefied ingredients being sprayed or adsorbed onto solid particles
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

DE69726440T 1996-10-04 1997-06-05 Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne turm-verfahren Expired - Fee Related DE69726440T2 (de)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
WOPCT/US96/15881		1996-10-04
PCT/US1996/015881 WO1998014549A1 (fr)	1996-10-04	1996-10-04	Procede de production d'une composition de detergent de faible densite par un processus sans colonne
PCT/US1997/009791 WO1998014553A1 (fr)	1996-10-04	1997-06-05	Procede de production d'une composition detergente sans l'utilisation d'une tour

Publications (2)

Publication Number	Publication Date
DE69726440D1 DE69726440D1 (de)	2004-01-08
DE69726440T2 true DE69726440T2 (de)	2004-09-09

Family

ID=22255901

Family Applications (5)

Application Number	Title	Priority Date	Filing Date
DE69726440T Expired - Fee Related DE69726440T2 (de)	1996-10-04	1997-06-05	Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne turm-verfahren
DE69721287T Expired - Fee Related DE69721287T2 (de)	1996-10-04	1997-06-05	Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren
DE69723986T Expired - Fee Related DE69723986T2 (de)	1996-10-04	1997-06-05	Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren
DE69715224T Expired - Fee Related DE69715224T2 (de)	1996-10-04	1997-06-05	Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren
DE69726439T Expired - Fee Related DE69726439T2 (de)	1996-10-04	1997-06-05	Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren

Family Applications After (4)

Application Number	Title	Priority Date	Filing Date
DE69721287T Expired - Fee Related DE69721287T2 (de)	1996-10-04	1997-06-05	Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren
DE69723986T Expired - Fee Related DE69723986T2 (de)	1996-10-04	1997-06-05	Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren
DE69715224T Expired - Fee Related DE69715224T2 (de)	1996-10-04	1997-06-05	Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren
DE69726439T Expired - Fee Related DE69726439T2 (de)	1996-10-04	1997-06-05	Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren

Country Status (12)

Country	Link
EP (9)	EP0929645A1 (fr)
JP (9)	JP3305327B2 (fr)
CN (8)	CN1239995A (fr)
AR (6)	AR010729A1 (fr)
AT (5)	ATE246726T1 (fr)
AU (9)	AU7388196A (fr)
BR (7)	BR9612732A (fr)
CA (9)	CA2267291C (fr)
DE (5)	DE69726440T2 (fr)
ES (5)	ES2178778T3 (fr)
MX (2)	MX219076B (fr)
WO (9)	WO1998014549A1 (fr)

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ES2150113T3 (es) *	1995-04-03	2000-11-16	Novartis Ag	Derivados de pirazol y procedimientos para la preparacion de los mismos.
GB9526097D0 (en) *	1995-12-20	1996-02-21	Unilever Plc	Process
GB9712580D0 (en) *	1997-06-16	1997-08-20	Unilever Plc	Production of detergent granulates
GB9712583D0 (en)	1997-06-16	1997-08-20	Unilever Plc	Production of detergent granulates
GB9713748D0 (en) *	1997-06-27	1997-09-03	Unilever Plc	Production of detergent granulates
EP1002043B1 (fr)	1997-07-14	2007-08-22	The Procter & Gamble Company	Procede de production d'une composition detergente de faible densite par agglomeration controlee dans un sechoir a lit fluide
ES2226153T3 (es)	1997-07-14	2005-03-16	THE PROCTER & GAMBLE COMPANY	Procedimiento para fabricar una composicion detergente de baja densidad controlando la aglomeracion mediante el tamaño de particulas.
WO1999003965A1 (fr)	1997-07-15	1999-01-28	The Procter & Gamble Company	Procede de production d'agglomerats detergents fortement actifs par injection d'une pate tensioactive en plusieurs etapes
US6440342B1 (en)	1998-07-08	2002-08-27	The Procter & Gamble Company	Process for making a low density detergent composition by controlling nozzle height in a fluid bed dryer
EP1105455B1 (fr)	1998-08-20	2006-08-16	The Procter & Gamble Company	Procede de fabrication de detergent haute densite comportant un melangeur/densificateur a vitesse moderee
US6794354B1 (en) *	1998-09-18	2004-09-21	The Procter & Gamble Company	Continuous process for making detergent composition
ES2184523T3 (es) *	1998-10-26	2003-04-01	Procter & Gamble	Procedimientos para obtener una composicion detergente granular que tiene un aspecto y solubilidad mejoradas.
GB9825558D0 (en) *	1998-11-20	1999-01-13	Unilever Plc	Granular detergent components and particulate detergent compositions containing them
GB9913546D0 (en)	1999-06-10	1999-08-11	Unilever Plc	Granular detergent component containing zeolite map and laundry detergent compositions containing it
US6894018B1 (en)	1999-06-21	2005-05-17	The Procter & Gamble Company	Process for making granular detergent in a fluidized bed granulator having recycling of improperly sized particles
WO2000078913A1 (fr) *	1999-06-21	2000-12-28	The Procter & Gamble Company	Procede de fabrication d'une composition granulaire detergente
GB0009877D0 (en) †	2000-04-20	2000-06-07	Unilever Plc	Granular detergent component and process for its preparation
EP2123742A1 (fr)	2008-05-14	2009-11-25	The Procter and Gamble Company	Compositions de détergent solide pour lessive comprenant du sel de silicate à faible densité
WO2011061045A1 (fr)	2009-11-20	2011-05-26	Unilever Nv	Granulé de détergent et son procédé de fabrication
MX2016013263A (es)	2014-04-10	2017-01-16	Procter & Gamble	Granulos detergentes compuestos y composiciones para lavanderia que comprenden estos.
US11214763B2 (en)	2018-01-26	2022-01-04	Ecolab Usa Inc.	Solidifying liquid amine oxide, betaine, and/or sultaine surfactants with a carrier
CA3089624A1 (fr)	2018-01-26	2019-08-01	Ecolab Usa Inc.	Solidification de tensioactifs d'oxyde d'amine, de betaine et/ou de sultaine liquide a l'aide d'un liant et d'un eventuel un vecteur
US11377628B2 (en)	2018-01-26	2022-07-05	Ecolab Usa Inc.	Solidifying liquid anionic surfactants

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US3625902A (en) *	1968-10-11	1971-12-07	Stauffer Chemical Co	Method of preparing agglomerated detergent composition
US4169806A (en) *	1978-08-09	1979-10-02	The Procter & Gamble Company	Agglomeration process for making granular detergents
US4992079A (en) *	1986-11-07	1991-02-12	Fmc Corporation	Process for preparing a nonphosphate laundry detergent
GB2209172A (en) *	1987-08-28	1989-05-04	Unilever Plc	Preparation of solid particulate components for detergents
KR0170424B1 (ko) *	1990-07-05	1999-01-15	호르스트 헤를레,요한 글라슬	세제 및 청정제용 표면 활성제 과립의 제조방법
HUT64391A (en) *	1990-11-14	1993-12-28	Procter & Gamble	Nonphosphated dishwashing compositions with oxygen belach systems and method for producing them
DE69332270T3 (de) *	1992-06-15	2006-08-17	The Procter & Gamble Company, Cincinnati	Verfahren zum herstellen von kompakten waschmittelzusammensetzungen
CN1136824A (zh) *	1993-10-15	1996-11-27	普罗格特-甘布尔公司	制造高密度洗涤剂颗粒的连续方法
GB9322530D0 (en) *	1993-11-02	1993-12-22	Unilever Plc	Process for the production of a detergent composition
PT663439E (pt) *	1994-01-17	2000-12-29	Procter & Gamble	Processo para a preparacao de granulos de detergente
US5516448A (en) *	1994-09-20	1996-05-14	The Procter & Gamble Company	Process for making a high density detergent composition which includes selected recycle streams for improved agglomerate
US5489392A (en) *	1994-09-20	1996-02-06	The Procter & Gamble Company	Process for making a high density detergent composition in a single mixer/densifier with selected recycle streams for improved agglomerate properties
US5554587A (en) *	1995-08-15	1996-09-10	The Procter & Gamble Company	Process for making high density detergent composition using conditioned air

1996
- 1996-10-04 CA CA002267291A patent/CA2267291C/fr not_active Expired - Fee Related
- 1996-10-04 MX MX9903193A patent/MX219076B/es not_active IP Right Cessation
- 1996-10-04 EP EP96936168A patent/EP0929645A1/fr not_active Withdrawn
- 1996-10-04 JP JP53523397A patent/JP3305327B2/ja not_active Expired - Fee Related
- 1996-10-04 BR BR9612732A patent/BR9612732A/pt not_active IP Right Cessation
- 1996-10-04 AU AU73881/96A patent/AU7388196A/en not_active Abandoned
- 1996-10-04 MX MX9903195A patent/MX219077B/es not_active IP Right Cessation
- 1996-10-04 WO PCT/US1996/015881 patent/WO1998014549A1/fr not_active Application Discontinuation
1997
- 1997-06-05 JP JP51649098A patent/JP3299982B2/ja not_active Expired - Fee Related
- 1997-06-05 DE DE69726440T patent/DE69726440T2/de not_active Expired - Fee Related
- 1997-06-05 CN CN97180298.XA patent/CN1239995A/zh active Pending
- 1997-06-05 CA CA002268062A patent/CA2268062C/fr not_active Expired - Fee Related
- 1997-06-05 EP EP97931059A patent/EP0929654A1/fr not_active Withdrawn
- 1997-06-05 WO PCT/US1997/009796 patent/WO1998014558A1/fr active Application Filing
- 1997-06-05 CA CA002268055A patent/CA2268055C/fr not_active Expired - Fee Related
- 1997-06-05 BR BR9711865A patent/BR9711865A/pt not_active IP Right Cessation
- 1997-06-05 CN CNB971802971A patent/CN1156563C/zh not_active Expired - Fee Related
- 1997-06-05 AT AT97929815T patent/ATE246726T1/de not_active IP Right Cessation
- 1997-06-05 BR BR9711861A patent/BR9711861A/pt not_active Application Discontinuation
- 1997-06-05 BR BR9713249-7A patent/BR9713249A/pt not_active Application Discontinuation
- 1997-06-05 AU AU34783/97A patent/AU3478397A/en not_active Abandoned
- 1997-06-05 JP JP51648998A patent/JP3299981B2/ja not_active Expired - Fee Related
- 1997-06-05 BR BR9712490-7A patent/BR9712490A/pt not_active IP Right Cessation
- 1997-06-05 CA CA002268052A patent/CA2268052C/fr not_active Expired - Fee Related
- 1997-06-05 JP JP51649298A patent/JP3345022B2/ja not_active Expired - Fee Related
- 1997-06-05 JP JP51649198A patent/JP3299983B2/ja not_active Expired - Fee Related
- 1997-06-05 WO PCT/US1997/009795 patent/WO1998014557A1/fr active IP Right Grant
- 1997-06-05 DE DE69721287T patent/DE69721287T2/de not_active Expired - Fee Related
- 1997-06-05 EP EP97931058A patent/EP0929653B1/fr not_active Expired - Lifetime
- 1997-06-05 CN CNB971802793A patent/CN1156560C/zh not_active Expired - Fee Related
- 1997-06-05 JP JP51649698A patent/JP3299987B2/ja not_active Expired - Fee Related
- 1997-06-05 CA CA002267424A patent/CA2267424C/fr not_active Expired - Fee Related
- 1997-06-05 EP EP97932153A patent/EP0929655A1/fr not_active Ceased
- 1997-06-05 WO PCT/US1997/009789 patent/WO1998014551A1/fr active IP Right Grant
- 1997-06-05 CA CA002268063A patent/CA2268063C/fr not_active Expired - Fee Related
- 1997-06-05 BR BR9712492-3A patent/BR9712492A/pt not_active IP Right Cessation
- 1997-06-05 AU AU35683/97A patent/AU3568397A/en not_active Abandoned
- 1997-06-05 ES ES97928871T patent/ES2178778T3/es not_active Expired - Lifetime
- 1997-06-05 AU AU34785/97A patent/AU3478597A/en not_active Abandoned
- 1997-06-05 CA CA002268060A patent/CA2268060C/fr not_active Expired - Fee Related
- 1997-06-05 AU AU33031/97A patent/AU3303197A/en not_active Abandoned
- 1997-06-05 JP JP51649498A patent/JP3299985B2/ja not_active Expired - Fee Related
- 1997-06-05 DE DE69723986T patent/DE69723986T2/de not_active Expired - Fee Related
- 1997-06-05 EP EP97931057A patent/EP0929652A1/fr not_active Ceased
- 1997-06-05 ES ES97931056T patent/ES2210544T3/es not_active Expired - Lifetime
- 1997-06-05 AT AT97931056T patent/ATE255160T1/de not_active IP Right Cessation
- 1997-06-05 JP JP51649598A patent/JP3299986B2/ja not_active Expired - Fee Related
- 1997-06-05 JP JP51649398A patent/JP3299984B2/ja not_active Expired - Fee Related
- 1997-06-05 CN CNB971802939A patent/CN1133739C/zh not_active Expired - Fee Related
- 1997-06-05 WO PCT/US1997/009791 patent/WO1998014553A1/fr active IP Right Grant
- 1997-06-05 EP EP97928872A patent/EP0929649B1/fr not_active Expired - Lifetime
- 1997-06-05 DE DE69715224T patent/DE69715224T2/de not_active Expired - Fee Related
- 1997-06-05 ES ES97931058T patent/ES2193386T3/es not_active Expired - Lifetime
- 1997-06-05 BR BR9713246-2A patent/BR9713246A/pt not_active IP Right Cessation
- 1997-06-05 AT AT97928871T patent/ATE223476T1/de not_active IP Right Cessation
- 1997-06-05 WO PCT/US1997/009792 patent/WO1998014554A1/fr not_active Application Discontinuation
- 1997-06-05 AU AU33030/97A patent/AU3303097A/en not_active Abandoned
- 1997-06-05 ES ES97929815T patent/ES2201305T3/es not_active Expired - Lifetime
- 1997-06-05 CA CA002268068A patent/CA2268068C/fr not_active Expired - Fee Related
- 1997-06-05 WO PCT/US1997/009793 patent/WO1998014555A1/fr not_active Application Discontinuation
- 1997-06-05 CA CA002268067A patent/CA2268067C/fr not_active Expired - Fee Related
- 1997-06-05 EP EP97929815A patent/EP0929650B1/fr not_active Expired - Lifetime
- 1997-06-05 AT AT97931058T patent/ATE238409T1/de not_active IP Right Cessation
- 1997-06-05 EP EP97928871A patent/EP0929648B1/fr not_active Expired - Lifetime
- 1997-06-05 AT AT97928872T patent/ATE255159T1/de not_active IP Right Cessation
- 1997-06-05 CN CNB971802807A patent/CN1156561C/zh not_active Expired - Fee Related
- 1997-06-05 WO PCT/US1997/009790 patent/WO1998014552A1/fr active IP Right Grant
- 1997-06-05 AU AU34784/97A patent/AU3478497A/en not_active Abandoned
- 1997-06-05 ES ES97928872T patent/ES2212109T3/es not_active Expired - Lifetime
- 1997-06-05 CN CNB971802963A patent/CN1156562C/zh not_active Expired - Fee Related
- 1997-06-05 WO PCT/US1997/009794 patent/WO1998014556A1/fr active IP Right Grant
- 1997-06-05 CN CNB971802785A patent/CN1133738C/zh not_active Expired - Fee Related
- 1997-06-05 CN CN97180294.7A patent/CN1239992A/zh active Pending
- 1997-06-05 EP EP97931056A patent/EP0929651B1/fr not_active Expired - Lifetime
- 1997-06-05 DE DE69726439T patent/DE69726439T2/de not_active Expired - Fee Related
- 1997-06-05 AU AU34782/97A patent/AU3478297A/en not_active Abandoned
- 1997-06-05 AU AU33785/97A patent/AU3378597A/en not_active Abandoned
- 1997-10-03 AR ARP970104577A patent/AR010729A1/es unknown
- 1997-10-03 AR ARP970104574A patent/AR010507A1/es unknown
- 1997-10-03 AR ARP970104575A patent/AR010508A1/es unknown
- 1997-10-03 AR ARP970104578A patent/AR010510A1/es unknown
- 1997-10-03 AR ARP970104576A patent/AR010509A1/es unknown
- 1997-10-03 AR ARP970104579A patent/AR010511A1/es unknown

Also Published As

Publication number	Publication date
JP3305327B2 (ja)	2002-07-22
CN1239992A (zh)	1999-12-29
BR9711865A (pt)	1999-08-24
AR010511A1 (es)	2000-06-28
DE69721287T2 (de)	2004-03-11
JP2000503720A (ja)	2000-03-28
EP0929653A1 (fr)	1999-07-21
EP0929654A1 (fr)	1999-07-21
DE69726440D1 (de)	2004-01-08
EP0929648A1 (fr)	1999-07-21
WO1998014553A1 (fr)	1998-04-09
AR010729A1 (es)	2000-07-12
JP2000503721A (ja)	2000-03-28
CA2267291A1 (fr)	1998-04-09
EP0929649B1 (fr)	2003-11-26
CA2268060C (fr)	2003-04-22
ES2193386T3 (es)	2003-11-01
CN1239993A (zh)	1999-12-29
MX219076B (en)	2004-02-10
EP0929655A1 (fr)	1999-07-21
CN1156561C (zh)	2004-07-07
AR010509A1 (es)	2000-06-28
AU3303097A (en)	1998-04-24
CA2268068C (fr)	2003-06-03
ES2210544T3 (es)	2004-07-01
DE69723986T2 (de)	2004-06-03
WO1998014552A1 (fr)	1998-04-09
JP2000503717A (ja)	2000-03-28
JP2000503716A (ja)	2000-03-28
JP2000503715A (ja)	2000-03-28
EP0929649A1 (fr)	1999-07-21
JP3299984B2 (ja)	2002-07-08
CA2268063A1 (fr)	1998-04-09
BR9713246A (pt)	1999-11-03
MX9903195A (en)	1999-09-30
WO1998014551A1 (fr)	1998-04-09
BR9711861A (pt)	1999-08-24
EP0929650B1 (fr)	2003-08-06
CN1239506A (zh)	1999-12-22
WO1998014554A1 (fr)	1998-04-09
MX219077B (en)	2004-02-10
JP2000503718A (ja)	2000-03-28
DE69723986D1 (de)	2003-09-11
CA2268067C (fr)	2004-01-06
BR9712490A (pt)	1999-10-19
AU3478597A (en)	1998-04-24
CA2268062C (fr)	2002-11-12
DE69715224T2 (de)	2003-08-07
CA2268062A1 (fr)	1998-04-09
ATE255160T1 (de)	2003-12-15
JP3299985B2 (ja)	2002-07-08
CN1133739C (zh)	2004-01-07
EP0929650A1 (fr)	1999-07-21
MX9903193A (en)	2000-01-31
CN1133738C (zh)	2004-01-07
CA2268052C (fr)	2003-12-30
AU3478497A (en)	1998-04-24
AU3478397A (en)	1998-04-24
DE69721287D1 (de)	2003-05-28
JP2000503719A (ja)	2000-03-28
ATE246726T1 (de)	2003-08-15
ES2212109T3 (es)	2004-07-16
AR010510A1 (es)	2000-06-28
CA2268067A1 (fr)	1998-04-09
CA2268055A1 (fr)	1998-04-09
ES2201305T3 (es)	2004-03-16
ATE238409T1 (de)	2003-05-15
EP0929653B1 (fr)	2003-04-23
JP3299982B2 (ja)	2002-07-08
WO1998014549A1 (fr)	1998-04-09
AU3303197A (en)	1998-04-24
CN1239508A (zh)	1999-12-22
ATE255159T1 (de)	2003-12-15
CA2268052A1 (fr)	1998-04-09
AR010507A1 (es)	2000-06-28
CN1239507A (zh)	1999-12-22
WO1998014557A1 (fr)	1998-04-09
EP0929651B1 (fr)	2003-11-26
CN1156560C (zh)	2004-07-07
DE69726439D1 (de)	2004-01-08
EP0929648B1 (fr)	2002-09-04
DE69715224D1 (de)	2002-10-10
BR9713249A (pt)	1999-11-03
WO1998014558A1 (fr)	1998-04-09
CN1156563C (zh)	2004-07-07
CA2267291C (fr)	2002-12-10
ES2178778T3 (es)	2003-01-01
JP3299983B2 (ja)	2002-07-08
AU3568397A (en)	1998-04-24
DE69726439T2 (de)	2004-09-09
CN1239991A (zh)	1999-12-29
AU3478297A (en)	1998-04-24
JP3345022B2 (ja)	2002-11-18
BR9712492A (pt)	1999-10-19
AU7388196A (en)	1998-04-24
EP0929651A1 (fr)	1999-07-21
WO1998014556A1 (fr)	1998-04-09
ATE223476T1 (de)	2002-09-15
CA2268063C (fr)	2002-10-29
CA2268060A1 (fr)	1998-04-09
JP3299986B2 (ja)	2002-07-08
CA2267424A1 (fr)	1998-04-09
JP3299987B2 (ja)	2002-07-08
CA2268055C (fr)	2004-02-03
BR9612732A (pt)	1999-08-24
WO1998014555A1 (fr)	1998-04-09
CN1239995A (zh)	1999-12-29
CN1156562C (zh)	2004-07-07
EP0929652A1 (fr)	1999-07-21
AR010508A1 (es)	2000-06-28
JP3299981B2 (ja)	2002-07-08
JP2000504062A (ja)	2000-04-04
CA2268068A1 (fr)	1998-04-09
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Publication	Publication Date	Title
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DE69827005T2 (de)	2005-02-24	Herstellung von waschmittelgranulaten
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DE60217889T2 (de)	2007-05-31	Verfahren zur herstellung von waschmittelgranulaten