DE69602329T2 - Katalysator für ethylenische Polymerisation - Google Patents

Katalysator für ethylenische Polymerisation

Info

Publication number
DE69602329T2
DE69602329T2 DE69602329T DE69602329T DE69602329T2 DE 69602329 T2 DE69602329 T2 DE 69602329T2 DE 69602329 T DE69602329 T DE 69602329T DE 69602329 T DE69602329 T DE 69602329T DE 69602329 T2 DE69602329 T2 DE 69602329T2
Authority
DE
Germany
Prior art keywords
catalyst
ethylenic polymerization
ethylenic
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69602329T
Other languages
English (en)
Other versions
DE69602329D1 (de
Inventor
Yasunori Takemoto
Takashi Monoi
Shintaro Inazawa
Shinya Waki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Holdings Corp
Original Assignee
Showa Denko KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Denko KK filed Critical Showa Denko KK
Application granted granted Critical
Publication of DE69602329D1 publication Critical patent/DE69602329D1/de
Publication of DE69602329T2 publication Critical patent/DE69602329T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61904—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with another component of C08F4/60
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69602329T 1995-09-14 1996-09-13 Katalysator für ethylenische Polymerisation Expired - Fee Related DE69602329T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23725095 1995-09-14

Publications (2)

Publication Number Publication Date
DE69602329D1 DE69602329D1 (de) 1999-06-10
DE69602329T2 true DE69602329T2 (de) 1999-09-23

Family

ID=17012631

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69602329T Expired - Fee Related DE69602329T2 (de) 1995-09-14 1996-09-13 Katalysator für ethylenische Polymerisation

Country Status (3)

Country Link
US (1) US5723399A (de)
EP (1) EP0763550B1 (de)
DE (1) DE69602329T2 (de)

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US6011127A (en) * 1996-05-20 2000-01-04 Showa Denko K.K. Process for the production of ethylenic polymers
DE19624581C2 (de) * 1996-06-20 1999-02-04 Targor Gmbh Übergangsmetallverbindung und ein Verfahren zu ihrer Herstellung, sowie ihre Verwendung
KR20000064271A (ko) * 1996-08-21 2000-11-06 우에다 마사히로 에틸렌계 중합체의 제조방법
KR20000068220A (ko) * 1996-08-21 2000-11-25 우에다 마사히로 올레핀중합용 촉매성분, 올레핀중합용 촉매 및 폴리올레핀의 제조방법
EP0839842B1 (de) 1996-10-31 2004-04-14 Mitsubishi Chemical Corporation Film, hergestellt aus einem Ethylen-Alphaolefin-Copolymer
EP0931796B1 (de) * 1997-04-09 2003-01-15 Showa Denko Kabushiki Kaisha Ethylenpolymere und verfahren zu ihrer herstellung
WO1998046653A1 (fr) * 1997-04-11 1998-10-22 Showa Denko K. K. Procede de preparation de polymere d'ethylene et catalyseur utilise a cet effet
GB9712663D0 (en) 1997-06-16 1997-08-20 Borealis As Process
US6051525A (en) * 1997-07-14 2000-04-18 Mobil Corporation Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution
EP0905147A1 (de) * 1997-09-27 1999-03-31 Fina Research S.A. Katalysatoren zur Herstellung von Polyäthylen und ihre Verwendung
US6225410B1 (en) * 1997-12-25 2001-05-01 Mitsui Chemicals Ethylene/α-olefin copolymer and process for preparing the same
GB9806407D0 (en) 1998-03-25 1998-05-20 Bp Chem Int Ltd Novel polymer compositions
US6245868B1 (en) 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
US7354880B2 (en) 1998-07-10 2008-04-08 Univation Technologies, Llc Catalyst composition and methods for its preparation and use in a polymerization process
US6255414B1 (en) * 1998-09-01 2001-07-03 E. I. Du Pont De Nemours And Company Polymerization of olefins
US6180735B1 (en) 1998-12-17 2001-01-30 Univation Technologies Catalyst composition and methods for its preparation and use in a polymerization process
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6828268B1 (en) * 1999-11-05 2004-12-07 Phillips Petroleum Company Polymerization catalyst systems and processes using alkyl lithium compounds as a cocatalyst
US6713573B2 (en) 2000-11-30 2004-03-30 Univation Technologies, Llc Catalyst modifiers and their use in the polymerization of olefin(s)
WO2002060957A2 (en) * 2001-01-16 2002-08-08 Exxonmobil Chemical Patents Inc. Catalysts with at least two transition metal compounds and polymerization processes using them
FR2833191B1 (fr) * 2001-12-10 2004-08-20 Inst Francais Du Petrole Composition catalytique et procede ameliores pour l'oligomerisation de l'ethylene, en particulier en hexene-1
AU2003277808A1 (en) * 2002-06-21 2004-01-06 Exxonmobil Chemical Patents Inc. Yttrium-based ethylene polymerization catalysts with bulky amidinate ancillary ligands
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
EP1620479B1 (de) 2002-10-15 2013-07-24 ExxonMobil Chemical Patents Inc. Polyolefinklebstoffzusammensetzungen und daraus hergestellte gegenstände
EP1611169B1 (de) * 2003-03-21 2010-06-02 Dow Global Technologies Inc. Verfahren zur herstellung von polyolefinen mit kontrollierter morphologie
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
US20050148742A1 (en) * 2004-01-02 2005-07-07 Hagerty Robert O. Method for controlling sheeting in gas phase reactors
US7163906B2 (en) * 2004-11-04 2007-01-16 Chevron Phillips Chemical Company, Llp Organochromium/metallocene combination catalysts for producing bimodal resins
BRPI0419176B8 (pt) * 2004-11-04 2016-09-13 Chevron Phillips Chemical Co composição de catalisadores de organocromo/metaloceno combinados para produzir resinas bimodais, método de fazer uma composição de catalisador e método de polimerizar olefinas
EP1948701A1 (de) * 2005-11-17 2008-07-30 ExxonMobil Chemical Patents Inc. Katalysatorsystem für die olefinpolymerisation und daraus hergestellte polymere
EP1803747A1 (de) 2005-12-30 2007-07-04 Borealis Technology Oy Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt
WO2008140875A1 (en) * 2007-05-16 2008-11-20 Exxonmobil Chemical Patents Inc. Catalyst system for olefin polymerization and polymers produced therefrom
CA2605077C (en) * 2007-10-01 2014-07-08 Nova Chemicals Corporation A co-supported catalyst system
CA2605044C (en) * 2007-10-01 2014-12-02 Nova Chemicals Corporation Polymerization process using a mixed catalyst system
TW200932762A (en) 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
BRPI0922454A2 (pt) 2008-12-18 2018-05-22 Univation Tech Llc método para tratamento de leito de semente para uma reação de polimerização
CA2713042C (en) * 2010-08-11 2017-10-24 Nova Chemicals Corporation Method of controlling polymer architecture
CA2783494C (en) 2012-07-23 2019-07-30 Nova Chemicals Corporation Adjusting polymer composition
ES2823768T3 (es) 2012-12-28 2021-05-10 Univation Tech Llc Métodos para integrar la producción de aluminoxano en la producción de catalizador
US10246528B2 (en) 2014-01-09 2019-04-02 Chevron Phillips Chemical Company Lp Chromium (III) catalyst systems with activator-supports
EP3747913B1 (de) 2014-04-02 2024-04-17 Univation Technologies, LLC Kontinuitätszusammensetzungen und verwendung davon in olefinpolymerisationsverfahren
EP3268399B1 (de) 2015-03-10 2021-01-20 Univation Technologies, LLC Sprühgetrocknete katalysatorzusammensetzungen, verfahren zur herstellung und verwendung in olefinpolymerisierungsverfahren
CA2983736C (en) 2015-04-27 2023-09-12 Univation Technologies, Llc Supported catalyst compositions having improved flow properties and preparation thereof
US9505856B1 (en) 2016-01-13 2016-11-29 Chevron Phillips Chemical Company Lp Methods for making fluorided chromium (VI) catalysts, and polymerization processes using the same

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US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
DE68913226T2 (de) * 1988-04-26 1994-09-29 Showa Denko Kk Verfahren zur Herstellung von Ethylenpolymeren.
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US5593931A (en) * 1995-03-03 1997-01-14 Chevron Chemical Company Cyclopentadienyl group 6b metal alpha-olefin polymerization catalysts and process for polymerizing alpha-olefins

Also Published As

Publication number Publication date
US5723399A (en) 1998-03-03
EP0763550B1 (de) 1999-05-06
EP0763550A1 (de) 1997-03-19
DE69602329D1 (de) 1999-06-10

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