DE69722902D1 - Katalysator für Alpha-Olefinpolymerisation - Google Patents

Katalysator für Alpha-Olefinpolymerisation

Info

Publication number
DE69722902D1
DE69722902D1 DE69722902T DE69722902T DE69722902D1 DE 69722902 D1 DE69722902 D1 DE 69722902D1 DE 69722902 T DE69722902 T DE 69722902T DE 69722902 T DE69722902 T DE 69722902T DE 69722902 D1 DE69722902 D1 DE 69722902D1
Authority
DE
Germany
Prior art keywords
polymerization catalyst
olefin polymerization
alpha olefin
alpha
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69722902T
Other languages
English (en)
Other versions
DE69722902T2 (de
Inventor
Toshihiko Sugano
Toru Suzuki
Hisashi Shoda
Takayuki Aoshima
Eiji Isobe
Yasuo Maruyama
Masami Kashimoto
Sugio Nishimura
Naoshi Iwama
Satoshi Hayakawa
Taku Kato
Stefan Sieber
Yoshinori Suga
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Publication of DE69722902D1 publication Critical patent/DE69722902D1/de
Application granted granted Critical
Publication of DE69722902T2 publication Critical patent/DE69722902T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69722902T 1996-12-09 1997-12-09 Katalysator für Alpha-Olefinpolymerisation Expired - Lifetime DE69722902T2 (de)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP32835296 1996-12-09
JP32835296 1996-12-09
JP10821097 1997-04-10
JP10821097 1997-04-10
JP21418697 1997-07-24
JP21418697 1997-07-24

Publications (2)

Publication Number Publication Date
DE69722902D1 true DE69722902D1 (de) 2003-07-24
DE69722902T2 DE69722902T2 (de) 2004-05-19

Family

ID=27311173

Family Applications (2)

Application Number Title Priority Date Filing Date
DE69722902T Expired - Lifetime DE69722902T2 (de) 1996-12-09 1997-12-09 Katalysator für Alpha-Olefinpolymerisation
DE69738304T Expired - Lifetime DE69738304T2 (de) 1996-12-09 1997-12-09 Katalysator zur Alpha-Olefinpolymerisation

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE69738304T Expired - Lifetime DE69738304T2 (de) 1996-12-09 1997-12-09 Katalysator zur Alpha-Olefinpolymerisation

Country Status (3)

Country Link
US (5) US6340652B1 (de)
EP (2) EP1312619B1 (de)
DE (2) DE69722902T2 (de)

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KR970015606A (ko) * 1995-09-01 1997-04-28 윤덕용 폴리올레핀 중합용 메탈로센 담지촉매의 제조방법
DE69722902T2 (de) * 1996-12-09 2004-05-19 Mitsubishi Chemical Corp. Katalysator für Alpha-Olefinpolymerisation
EP0936229B1 (de) 1998-02-12 2004-04-28 Eastman Chemical Resins, Inc. Verfahren zur Herstellung aromatisch modifizierter alifatischer Kohlenwasserstoffharze mit hervorragendem Ausgleich zwischen Klebrigkeit und Scherfestigkeit
JP4116148B2 (ja) * 1998-06-08 2008-07-09 三菱化学株式会社 新規な遷移金属化合物、オレフィン重合用触媒成分およびα−オレフィン重合体の製造方法

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US6344530B2 (en) 2002-02-05
US6590045B2 (en) 2003-07-08
US20030166459A1 (en) 2003-09-04
US20010034425A1 (en) 2001-10-25
EP1312619A3 (de) 2004-12-22
EP0846696B1 (de) 2003-06-18
DE69738304D1 (de) 2007-12-27
DE69722902T2 (de) 2004-05-19
US6252097B1 (en) 2001-06-26
DE69738304T2 (de) 2008-09-18
EP1312619A2 (de) 2003-05-21
US6340652B1 (en) 2002-01-22
EP1312619B1 (de) 2007-11-14
EP0846696A1 (de) 1998-06-10

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