DE69117982D1 - Übergangsmetall-amidoverbindung und katalysatorsystem zur herstellung von isotaktischem propylen - Google Patents

Übergangsmetall-amidoverbindung und katalysatorsystem zur herstellung von isotaktischem propylen

Info

Publication number
DE69117982D1
DE69117982D1 DE69117982T DE69117982T DE69117982D1 DE 69117982 D1 DE69117982 D1 DE 69117982D1 DE 69117982 T DE69117982 T DE 69117982T DE 69117982 T DE69117982 T DE 69117982T DE 69117982 D1 DE69117982 D1 DE 69117982D1
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DE
Germany
Prior art keywords
transition metal
catalyst system
isotactic propylene
amido compound
producing isotactic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69117982T
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English (en)
Other versions
DE69117982T2 (de
Inventor
Jo Canich
Howard Turner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of DE69117982D1 publication Critical patent/DE69117982D1/de
Publication of DE69117982T2 publication Critical patent/DE69117982T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/10Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE69117982T 1990-12-27 1991-12-26 Übergangsmetall-amidoverbindung und katalysatorsystem zur herstellung von isotaktischem propylen Expired - Lifetime DE69117982T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US63498790A 1990-12-27 1990-12-27
PCT/US1991/009676 WO1992012162A1 (en) 1990-12-27 1991-12-26 An amido transition metal compound and a catalyst system for the production of isotactic polypropylene

Publications (2)

Publication Number Publication Date
DE69117982D1 true DE69117982D1 (de) 1996-04-18
DE69117982T2 DE69117982T2 (de) 1996-08-08

Family

ID=24545953

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69117982T Expired - Lifetime DE69117982T2 (de) 1990-12-27 1991-12-26 Übergangsmetall-amidoverbindung und katalysatorsystem zur herstellung von isotaktischem propylen

Country Status (8)

Country Link
US (1) US5318935A (de)
EP (1) EP0569388B1 (de)
JP (1) JP3255173B2 (de)
AT (1) ATE135358T1 (de)
AU (1) AU9136391A (de)
DE (1) DE69117982T2 (de)
ES (1) ES2085000T3 (de)
WO (1) WO1992012162A1 (de)

Families Citing this family (181)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6265338B1 (en) * 1989-09-13 2001-07-24 Exxon Chemical Patents, Inc. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin copolymer production catalysts
CA2124187C (en) * 1991-11-25 2001-08-07 Howard William Turner Polyonic transition metal catalyst composition
JP3332051B2 (ja) * 1992-12-18 2002-10-07 出光興産株式会社 重合用触媒及び該触媒系を用いる重合体の製造方法
BE1006453A3 (nl) * 1992-12-21 1994-08-30 Dsm Nv Katalysator en werkwijze voor een ziegler polymerisatie.
DE4324685A1 (de) * 1993-07-22 1995-01-26 Wacker Chemie Gmbh Organosiloxangebundene Übergangsmetallkomplexe
US5486585A (en) * 1993-08-26 1996-01-23 Exxon Chemical Patents Inc. Amidosilyldiyl bridged catalysts and method of polymerization using said catalysts.
AU2579895A (en) * 1994-06-07 1996-01-04 Specs And Biospecs B.V. Novel organo-metallic compounds, methods for preparing same, and a method for the polymerization of unsaturated hydrocarbons using said organo-metallic compounds as catalysts, as well as novel semi-products and catalyst preparations
NL9400919A (nl) * 1994-06-07 1996-01-02 Specs B V Nieuwe organometaalverbindingen en werkwijze voor het polymeriseren van alkenen onder toepassing van deze organonetaalverbindingen als katalysatoren.
NL9401515A (nl) * 1994-09-19 1996-05-01 Specs And Biospecs Bv Nieuwe organometaalverbindingen en werkwijze voor het polymeriseren van alkenen onder toepassing van deze organometaalverbindingen als katalysatoren.
US5707913A (en) * 1994-06-15 1998-01-13 Basf Aktiengesellschaft Amidinato catalyst systems for the polymerization of olefins
KR0151873B1 (ko) * 1994-10-13 1998-10-15 김영욱 메탈로센 화합물, 이의 제조방법 및 이를 촉매로 이용한 고분자의 제조방법
US5985356A (en) 1994-10-18 1999-11-16 The Regents Of The University Of California Combinatorial synthesis of novel materials
US6440745B1 (en) 1994-10-18 2002-08-27 Symyx Technologies Combinatorial synthesis and screening of organometallic compounds and catalysts
US6419881B1 (en) 1994-10-18 2002-07-16 Symyx Technologies, Inc. Combinatorial arrays of organometallic compounds and catalysts
US6030917A (en) 1996-07-23 2000-02-29 Symyx Technologies, Inc. Combinatorial synthesis and analysis of organometallic compounds and catalysts
KR100418168B1 (ko) * 1995-01-24 2004-02-14 이.아이,듀우판드네모아앤드캄파니 중합 방법
US5880241A (en) * 1995-01-24 1999-03-09 E. I. Du Pont De Nemours And Company Olefin polymers
US6897272B1 (en) 1995-01-24 2005-05-24 E.I. Du Pont De Nemours And Company α-olefins and olefin polymers and processes therefor
US5939347A (en) * 1995-01-25 1999-08-17 W.R. Grace & Co. -Conn. Supported catalytic activator
JPH11503063A (ja) * 1995-03-08 1999-03-23 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒組成物における架橋ビスアミド第4族金属化合物
US5527752A (en) * 1995-03-29 1996-06-18 Union Carbide Chemicals & Plastics Technology Corporation Catalysts for the production of polyolefins
US6143682A (en) * 1995-06-07 2000-11-07 Exxon Chemical Patents Inc. Bimetallocyclic transition metal catalyst systems
US6063633A (en) 1996-02-28 2000-05-16 The University Of Houston Catalyst testing process and apparatus
JP2000513399A (ja) 1996-06-17 2000-10-10 エクソン・ケミカル・パテンツ・インク オレフィン重合用の混合遷移金属触媒系
KR100361088B1 (ko) * 1996-06-27 2003-02-17 삼성종합화학주식회사 올레핀중합용킬레이트촉매및그제조방법
US6720186B1 (en) 1998-04-03 2004-04-13 Symyx Technologies, Inc. Method of research for creating and testing novel catalysts, reactions and polymers
KR100320331B1 (ko) * 1997-02-07 2002-06-20 나까니시 히로유끼 올레핀중합촉매및올레핀중합체제조방법
WO1998034970A1 (en) 1997-02-07 1998-08-13 Exxon Chemical Patents Inc. Thermoplastic elastomer compositions from branched olefin copolymers
US5851945A (en) 1997-02-07 1998-12-22 Exxon Chemical Patents Inc. Olefin polymerization catalyst compositions comprising group 5 transition metal compounds stabilized in their highest metal oxidation state
US6100354A (en) * 1997-02-24 2000-08-08 Exxon Chemical Patents Inc. Olefin copolymers from bridged bis(arylamido) Group 4 catalyst compounds
US5777120A (en) * 1997-03-14 1998-07-07 University Of Iowa Research Foundation Cationic aluminum alkyl complexes incorporating amidinate ligands as polymerization catalysts
US6228794B1 (en) 1997-03-14 2001-05-08 University Of Iowa Research Foundation Cationic group 13 complexes incorporating bidentate ligands as polymerization catalysts
AU6953898A (en) * 1997-04-04 1998-10-30 Damon R. Click Polymerization catalysts containing electron-withdrawing amide ligands
US5889128A (en) * 1997-04-11 1999-03-30 Massachusetts Institute Of Technology Living olefin polymerization processes
US6030918A (en) * 1997-06-25 2000-02-29 The Regents Of The University Of California Gallium based low-interaction anions
US6268447B1 (en) 1998-12-18 2001-07-31 Univation Technologies, L.L.C. Olefin polymerization catalyst
US6136748A (en) * 1997-07-02 2000-10-24 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the polymerization of olefins
US6096676A (en) * 1997-07-02 2000-08-01 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6103657A (en) * 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
IL122115A (en) 1997-07-27 2007-06-17 Technion Res & Dev Foundation Alpha polymerization method - olefins and polymers, copolymers and elastomers prepared by this method
US6197910B1 (en) 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
US6184327B1 (en) 1997-12-10 2001-02-06 Exxon Chemical Patents, Inc. Elastomeric propylene polymers
WO1999052631A1 (en) * 1998-04-15 1999-10-21 Shell Internationale Research Maatschappij B.V. CATALYST SYSTEM FOR α-OLEFIN OLIGOMERIZATION
KR100342541B1 (ko) * 1998-04-16 2002-06-28 나까니시 히로유끼 올레핀 중합촉매 및 중합방법
TW562810B (en) * 1998-04-16 2003-11-21 Mitsui Chemicals Inc Catalyst for olefinic polymerization and method for polymerizing olefine
EP1084152B1 (de) 1998-05-01 2002-12-11 ExxonMobil Chemical Patents Inc. Dreiwertige ligand-enthaltende metallcomplexkatalysatoren für die olefinpolymerisation
CN1167718C (zh) 1998-08-26 2004-09-22 埃克森美孚化学专利公司 支化聚丙烯组合物
CA2248463A1 (en) 1998-09-28 2000-03-28 Scott Collins Iminophosphonamide complexes for olefin polymerization
US6403773B1 (en) * 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
US6303719B1 (en) 1998-12-18 2001-10-16 Univation Technologies Olefin polymerization catalyst system
US6271325B1 (en) 1999-05-17 2001-08-07 Univation Technologies, Llc Method of polymerization
US6300438B1 (en) 1999-10-22 2001-10-09 Univation Technolgies, Llc Hafnium transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6300439B1 (en) 1999-11-08 2001-10-09 Univation Technologies, Llc Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6380328B1 (en) 1999-12-10 2002-04-30 Univation Technologies, Llc Catalyst systems and their use in a polymerization process
US6624107B2 (en) 1999-10-22 2003-09-23 Univation Technologies, Llc Transition metal catalyst compounds having deuterium substituted ligand and catalyst systems thereof
US6417304B1 (en) 1999-11-18 2002-07-09 Univation Technologies, Llc Method of polymerization and polymer produced therefrom
US6265505B1 (en) 1999-11-18 2001-07-24 Univation Technologies, Llc Catalyst system and its use in a polymerization process
US6476164B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Carbenium cationic complexes suitable for polymerization catalysts
US6475946B1 (en) * 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
KR100567304B1 (ko) * 1999-10-22 2006-04-04 유니베이션 테크놀로지즈, 엘엘씨 촉매 시스템 및 그의 중합 방법에서의 용도
US6271323B1 (en) 1999-10-28 2001-08-07 Univation Technologies, Llc Mixed catalyst compounds, catalyst systems and their use in a polymerization process
WO2001030858A1 (en) * 1999-10-28 2001-05-03 University Of Maryland, College Park Stereospecific living polymerization of olefins by a novel ziegler-natta catalyst composition
US6822057B2 (en) * 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
US6281306B1 (en) * 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
JP2003518169A (ja) 1999-12-20 2003-06-03 エクソンモービル・ケミカル・パテンツ・インク 担持イオン性触媒を使用するポリオレフィン樹脂の製造方法
US7067603B1 (en) 1999-12-22 2006-06-27 Exxonmobil Chemical Patents Inc. Adhesive alpha-olefin inter-polymers
CA2395532A1 (en) 1999-12-22 2001-06-28 A. G. Karandinos Polypropylene-based adhesive compositions
AU2001228778A1 (en) * 2000-01-27 2001-08-07 Technion Research And Development Foundation Ltd. Process for the production of stereoregular polymers and elastomers of alpha-olefins and certain novel catalysts therefor
US6710006B2 (en) 2000-02-09 2004-03-23 Shell Oil Company Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins
KR20010082913A (ko) * 2000-02-22 2001-08-31 박찬구 아미도계 iv족 금속 착화합물을 이용한 폴리이소부텐의제조방법
US6809209B2 (en) 2000-04-07 2004-10-26 Exxonmobil Chemical Patents Inc. Nitrogen-containing group-13 anionic compounds for olefin polymerization
US7078164B1 (en) 2000-06-19 2006-07-18 Symyx Technologies, Inc. High throughput screen for identifying polymerization catalysts from potential catalysts
DE60135502D1 (de) * 2000-09-25 2008-10-02 Basell Polyolefine Gmbh Verfahren zur herstellung von ethylenpolymeren mit einer bis-amid-titanverbindung
US7037988B2 (en) 2000-10-03 2006-05-02 Shell Oil Company Process for the co-oligomerisation of ethylene and alpha olefins
CA2424370A1 (en) * 2000-10-19 2002-04-25 Exxonmobil Chemical Patents Inc. Cationic group-3 catalyst system
JP2004518780A (ja) 2000-10-25 2004-06-24 エクソンモービル・ケミカル・パテンツ・インク カチオン触媒系
US6828397B2 (en) 2000-11-07 2004-12-07 Symyx Technologies, Inc. Methods of copolymerizing ethylene and isobutylene and polymers made thereby
WO2003000740A2 (en) 2001-06-20 2003-01-03 Exxonmobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
WO2003011876A1 (en) * 2001-08-01 2003-02-13 Shell Internationale Research Maatschappij B.V. Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins
US7196148B2 (en) * 2001-10-25 2007-03-27 Exxon Mobil Chemical Patents Inc. Cationic catalyst system
US6831187B2 (en) 2001-12-18 2004-12-14 Univation Technologies, Llc Multimetallic catalyst compositions for the polymerization of olefins
US6864205B2 (en) 2001-12-18 2005-03-08 Univation Technologies, Llc Heterocyclic-amide catalyst compositions for the polymerization of olefins
US7001863B2 (en) 2001-12-18 2006-02-21 Univation Technologies, Llc Monoamide based catalyst compositions for the polymerization of olefins
US6919467B2 (en) 2001-12-18 2005-07-19 Univation Technologies, Llc Imino-amide catalyst compositions for the polymerization of olefins
US7199255B2 (en) 2001-12-18 2007-04-03 Univation Technologies, Llc Imino-amide catalysts for olefin polymerization
US6992131B2 (en) * 2002-03-22 2006-01-31 Exxonmobil Chemical Patents Inc. Adhesives
US7060848B2 (en) * 2002-04-24 2006-06-13 Symyx Technologies, Inc. Bridged bi-aromatic catalysts, complexes, and methods of using the same
US7091292B2 (en) 2002-04-24 2006-08-15 Symyx Technologies, Inc. Bridged bi-aromatic catalysts, complexes, and methods of using the same
JP4371305B2 (ja) * 2002-04-24 2009-11-25 シミックス・ソルーションズ・インコーポレーテッド 架橋ビス芳香族リガンド、錯体、触媒、または、重合方法およびそれにより得られるポリマー
WO2004000894A1 (en) 2002-06-21 2003-12-31 Exxonmobil Chemical Patents Inc. Yttrium-based ethylene polymerization catalysts with bulky amidinate ancillary ligands
US7033560B2 (en) * 2002-08-30 2006-04-25 Air Products And Chemicals, Inc. Single source mixtures of metal siloxides
ES2260678T3 (es) 2002-09-25 2006-11-01 Shell Internationale Research Maatschappij B.V. Sistema cataliticos para la oligomerizacion de etileno a alfa-olefinas lineales.
US7294681B2 (en) 2002-10-15 2007-11-13 Exxonmobil Chemical Patents Inc. Mutliple catalyst system for olefin polymerization and polymers produced therefrom
US7041759B2 (en) * 2002-11-20 2006-05-09 The University Of Maryland, College Park Method for the preparation of well-defined metal acetamidinate-based catalysts on solid supports
US7183364B2 (en) * 2002-12-20 2007-02-27 University Of Maryland, College Park Process for preparation of polyolefins via degenerative transfer polymerization
US7541412B2 (en) * 2002-12-20 2009-06-02 University Of Maryland, College Park Process for preparation of polyolefins via degenerative transfer polymerization
US7037989B2 (en) * 2003-05-27 2006-05-02 Exxonmobil Chemical Patents Inc. Copolymers of ethylene and/or α-olefins and vicinally disubstituted olefins
US20050014983A1 (en) * 2003-07-07 2005-01-20 De Boer Eric Johannes Maria Process for producing linear alpha olefins
US6967184B2 (en) * 2004-02-17 2005-11-22 Univation Technologies, Llc Fluoroalcohol leaving group for non-metallocene olefin polymerization catalysts
EP1740598B1 (de) 2004-03-24 2008-03-05 Shell Internationale Researchmaatschappij B.V. Übergangsmetallkomplexe
GB0411742D0 (en) 2004-05-26 2004-06-30 Exxonmobil Chem Patents Inc Transition metal compounds for olefin polymerization and oligomerization
AR049714A1 (es) * 2004-07-13 2006-08-30 Shell Int Research Proceso de preparacion de alfa olefinas lineales
US7193017B2 (en) * 2004-08-13 2007-03-20 Univation Technologies, Llc High strength biomodal polyethylene compositions
US7256296B2 (en) * 2004-09-22 2007-08-14 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts
WO2006036748A2 (en) * 2004-09-22 2006-04-06 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts, and methods of making and using the same
US7399874B2 (en) * 2004-10-29 2008-07-15 Exxonmobil Chemical Patents Inc. Catalyst compound containing divalent tridentate ligand
WO2006066126A2 (en) * 2004-12-16 2006-06-22 Symyx Technologies, Inc. Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts
US6987152B1 (en) 2005-01-11 2006-01-17 Univation Technologies, Llc Feed purification at ambient temperature
US7312279B2 (en) * 2005-02-07 2007-12-25 Univation Technologies, Llc Polyethylene blend compositions
US7868088B2 (en) * 2005-03-17 2011-01-11 University Of Maryland, College Park Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby
WO2006102106A1 (en) * 2005-03-17 2006-09-28 University Of Maryland, College Park Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby
US7947797B2 (en) 2005-09-14 2011-05-24 Univation Technologies, Llc Method for operating a gas-phase reactor at or near maximum production rates while controlling polymer stickiness
US20070109911A1 (en) * 2005-11-16 2007-05-17 Neubauer Anthony C High speed and direct driven rotating equipment for polyolefin manufacturing
EP1963347B1 (de) 2005-12-14 2011-10-19 ExxonMobil Chemical Patents Inc. Halogensubstituierte metallocenverbindungen für die olefinpolymerisation
US7956207B2 (en) * 2006-09-28 2011-06-07 Praxair Technology, Inc. Heteroleptic organometallic compounds
EP2081966B1 (de) 2006-10-03 2019-02-20 Univation Technologies, LLC Verfahren zur verhinderung von katalysatoragglomerierung auf der basis von produktratenänderungen
WO2008042078A1 (en) * 2006-10-03 2008-04-10 Univation Technologies, Llc Effervescent nozzle for catalyst injection
US8281332B2 (en) * 2007-05-02 2012-10-02 Google Inc. Animated video overlays
EP2112175A1 (de) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Aktivator für Metallocene, der einen oder mehrere halogensubstituierte heterocyklische Liganden enthält, die an ein Alumoxan koordiniert sind
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
TW200936564A (en) * 2007-11-15 2009-09-01 Univation Tech Llc Methods for the removal of impurities from polymerization feed streams
US7910760B2 (en) 2008-04-15 2011-03-22 Exxonmobil Chemical Patents Inc. Semi-rigid linked diamines, precursors therefor, and transition metal diamido complexes as catalysts for olefin polymerization processes
US20090286944A1 (en) * 2008-05-15 2009-11-19 Symyx Technologies, Inc. Select phenol-heterocycle ligands, metal complexes formed therefrom, and their uses as catalysts
US7973116B2 (en) * 2008-07-25 2011-07-05 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
US8394902B2 (en) 2008-07-25 2013-03-12 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
US8710163B2 (en) 2008-07-25 2014-04-29 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
US8674040B2 (en) * 2008-07-25 2014-03-18 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
SG195587A1 (en) 2008-08-01 2013-12-30 Exxonmobil Chem Patents Inc Catalyst system and process for olefin polymerization
US8580902B2 (en) 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
ES2408589T3 (es) 2008-12-18 2013-06-21 Univation Technologies, Llc Método para tratamiento de un lecho de siembra para una reacción de polimerización
US20120028866A1 (en) 2010-07-28 2012-02-02 Sudhin Datta Viscosity Modifiers Comprising Blends of Ethylene-Based Copolymers
US8378042B2 (en) * 2009-04-28 2013-02-19 Exxonmobil Chemical Patents Inc. Finishing process for amorphous polymers
WO2011090861A1 (en) 2010-01-22 2011-07-28 Exxonmobil Chemical Patents Inc. Lubricating oil compositions and method for making them
US8598283B2 (en) 2010-02-18 2013-12-03 Univation Technologies, Llc Methods for operating a polymerization reactor
ES2693720T3 (es) 2010-02-22 2018-12-13 Univation Technologies, Llc Sistemas catalíticos y métodos para usar los mismos para producir productos poliolefínicos
US8058461B2 (en) 2010-03-01 2011-11-15 Exxonmobil Chemical Patents Inc. Mono-indenyl transition metal compounds and polymerization therewith
EP2558531B1 (de) 2010-04-13 2017-02-15 Univation Technologies, LLC Polymermischungen und filme
EP2593217B1 (de) 2010-07-16 2014-07-02 Univation Technologies, LLC Systeme und verfahren zur messung der partikelakkumulation auf reaktorflächen
WO2012009215A1 (en) 2010-07-16 2012-01-19 Univation Technologies, Llc Systems and methods for measuring static charge on particulates
WO2012015898A1 (en) 2010-07-28 2012-02-02 Univation Technologies, Llc Systems and methods for measuring velocity of a particle/fluid mixture
WO2012074709A1 (en) 2010-11-30 2012-06-07 Univation Technologies, Llc Processes for the polymerization of olefins with extracted metal carboxylate salts
JP5859561B2 (ja) 2010-11-30 2016-02-10 ユニベーション・テクノロジーズ・エルエルシー 改善された流動特性を有する触媒組成物並びにその製造方法及び使用方法
CN103298842B (zh) 2010-12-17 2016-08-31 尤尼威蒂恩技术有限责任公司 从聚烯烃吹扫气体产物回收烃的***以及方法
US9643900B2 (en) 2011-03-25 2017-05-09 Dow Global Technologies Llc Hyperbranched ethylene-based oils and greases
WO2012158260A1 (en) 2011-05-13 2012-11-22 Univation Technologies, Llc Spray-dried catalyst compositions and polymerization processes employing the same
CN102807580B (zh) * 2011-06-03 2015-06-17 中国石油化工股份有限公司 一种含有二齿配体的过渡金属化合物及其在烯烃聚合中的应用
WO2013028283A1 (en) 2011-08-19 2013-02-28 Univation Technologies, Llc Catalyst systems and methods for using same to produce polyolefin products
EP2776476B1 (de) 2011-11-08 2019-03-13 Univation Technologies, LLC Verfahren zur herstellung von polyolefinen mit katalysatorsystemen
US9234060B2 (en) 2011-11-08 2016-01-12 Univation Technologies, Llc Methods of preparing a catalyst system
US20130281340A1 (en) 2012-04-19 2013-10-24 Exxonmobil Chemical Patents Inc. Lubricant Compositions Comprising Ethylene Propylene Copolymers and Methods for Making Them
EP2938434B1 (de) 2012-12-28 2022-05-04 Univation Technologies, LLC Geträgerter katalysator mit verbesserten fliesseigeschaften
US9650453B2 (en) 2012-12-28 2017-05-16 Univation Technologies, Llc Methods of integrating aluminoxane production into catalyst production
EP2945737B1 (de) 2013-01-14 2019-03-13 Univation Technologies, LLC Verfahren zur herstellung von katalysatorsystemen mit erhöhter produktivität
KR102143409B1 (ko) 2013-01-30 2020-08-14 유니베이션 테크놀로지즈, 엘엘씨 개선된 유동을 갖는 촉매 조성물의 제조 방법
KR102113899B1 (ko) 2013-02-07 2020-05-21 유니베이션 테크놀로지즈, 엘엘씨 폴리올레핀의 제조
WO2014149361A1 (en) 2013-03-15 2014-09-25 Univation Technologies, Llc Ligands for catalysts
EP2970524B1 (de) 2013-03-15 2018-03-07 Univation Technologies, LLC Dreizahnige stickstoffliganden für olefinpolymerisationskatalysatoren
US9604893B2 (en) 2013-06-05 2017-03-28 Univation Technologies, Llc Protecting phenol groups
US10196336B2 (en) 2013-06-28 2019-02-05 Dow Global Technologies Llc Process for the preparation of lightly-branched hydrophobes and the corresponding surfactants and applications thereof
BR112015031326B1 (pt) 2013-06-28 2021-05-25 Dow Global Technologies Llc processo para preparar uma composição de fluido de utilidade
ES2660464T3 (es) 2013-06-28 2018-03-22 Dow Global Technologies Llc Proceso para la preparación de poliolefinas ramificadas para aplicaciones lubricantes
US9315526B2 (en) 2014-03-03 2016-04-19 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
BR112016022780B1 (pt) 2014-04-02 2021-08-17 Univation Technologies, Llc Composição de continuidade
BR112017019133B1 (pt) 2015-03-10 2021-11-23 Univation Technologies, Llc Método para produzir uma composição de catalisador suportado para polimerização de olefina
SG11201708340QA (en) 2015-04-17 2017-11-29 Univation Tech Llc Methods and systems for olefin polymerization
EP3286228B1 (de) 2015-04-24 2020-03-18 Univation Technologies, LLC Verfahren zum betrieb eines polymerisierungsreaktors
US10519256B2 (en) 2015-04-27 2019-12-31 Univation Technologies, Llc Supported catalyst compositions having improved flow properties and preparation thereof
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
WO2018048472A1 (en) 2016-09-09 2018-03-15 Exxonmobil Chemical Patents Inc. Pilot plant scale semi-condensing operation
US11186654B2 (en) 2016-12-20 2021-11-30 Exxonmobil Chemical Patents Inc. Methods for controlling start up conditions in polymerization processes
US11459408B2 (en) 2018-05-02 2022-10-04 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
CN112055719B (zh) 2018-05-02 2022-11-25 埃克森美孚化学专利公司 从中试装置放大到较大生产设施的方法
JP2022505111A (ja) 2018-11-06 2022-01-14 ダウ グローバル テクノロジーズ エルエルシー アルカン可溶性非メタロセンプレ触媒を使用してオレフィンを重合する方法
US11891464B2 (en) 2018-11-06 2024-02-06 Dow Global Technologies Llc Alkane-soluble non-metallocene precatalysts
EP3877392B1 (de) 2018-11-06 2023-11-15 Dow Global Technologies LLC Alkanlösliche nichtmetallocen-vorkatalysatoren
CA3235407A1 (en) 2021-10-21 2023-04-27 Univation Technologies, Llc Bimodal poly(ethylene-co-1-alkene) copolymer and blow-molded intermediate bulk containers made therefrom
WO2024081272A1 (en) 2022-10-11 2024-04-18 Dow Global Technologies Llc Bimodal hdpe and polyethylene blend containing virgin and recycled hdpe materials
WO2024081271A1 (en) 2022-10-11 2024-04-18 Dow Global Technologies Llc Polyethylene blends containing virgin and recycled hdpe materials
WO2024129637A1 (en) 2022-12-12 2024-06-20 Univation Technologies, Llc Decreasing triboelectric charging of, and/or reactor fouling by, polyolefin particles

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3392160A (en) * 1964-02-07 1968-07-09 Cabot Corp Cocatalyst compositions
BE737574A (de) * 1968-09-05 1970-02-02
NL163523C (nl) * 1970-07-31 1983-11-16 Montedison Spa Werkwijze om een polymerisatiekatalysator te bereiden.
IT1080687B (it) * 1977-06-30 1985-05-16 Snam Progetti Composizioni chimiche a base di titanio trialogenuro,procedimento per la loro preparazione e loro impieghi
US4552982A (en) * 1983-08-01 1985-11-12 Eli Lilly And Company Synthesis of 9-carbamoyl-9-(3-aminopropyl)fluorenes
US4892914A (en) * 1983-08-25 1990-01-09 The Dow Chemical Company Catalysts prepared from tetrakis(dialkylamide or diarylamide) derivatives of titanium and polymerization of olefins therewith
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US4794096A (en) * 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US4774301A (en) * 1987-06-08 1988-09-27 The Dow Chemical Company Zirconium containing catalysts and method of use
US4956323A (en) * 1987-11-30 1990-09-11 The Dow Chemical Company Catalysts prepared from tetrakis(dialkylamide or diarylamide) derivatives of titanium and polymerization of olefins therewith
US5039766A (en) * 1988-06-28 1991-08-13 Sumitomo Chemical Company, Limited Liquid catalyst component, catalyst system containing said component and process for producing ethylene-alpha-olefin copolymer using said catalyst system

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DE69117982T2 (de) 1996-08-08
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AU9136391A (en) 1992-08-17
EP0569388A1 (de) 1993-11-18
ES2085000T3 (es) 1996-05-16
JP3255173B2 (ja) 2002-02-12
ATE135358T1 (de) 1996-03-15
US5318935A (en) 1994-06-07
WO1992012162A1 (en) 1992-07-23

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