DE602007008852D1 - Kopplungsmittel für mit natürlichen fasern gefüllten polyolefinen und zusammensetzungen daraus - Google Patents
Kopplungsmittel für mit natürlichen fasern gefüllten polyolefinen und zusammensetzungen darausInfo
- Publication number
- DE602007008852D1 DE602007008852D1 DE602007008852T DE602007008852T DE602007008852D1 DE 602007008852 D1 DE602007008852 D1 DE 602007008852D1 DE 602007008852 T DE602007008852 T DE 602007008852T DE 602007008852 T DE602007008852 T DE 602007008852T DE 602007008852 D1 DE602007008852 D1 DE 602007008852D1
- Authority
- DE
- Germany
- Prior art keywords
- coupling agent
- compositions
- natural fibers
- maleic anhydride
- polyolefins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/045—Reinforcing macromolecular compounds with loose or coherent fibrous material with vegetable or animal fibrous material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Reinforced Plastic Materials (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US77939606P | 2006-03-03 | 2006-03-03 | |
US11/713,134 US20070208110A1 (en) | 2006-03-03 | 2007-03-01 | Coupling agents for natural fiber-filled polyolefins |
PCT/US2007/005554 WO2007130201A1 (en) | 2006-03-03 | 2007-03-02 | Coupling agents for natural fiber-filled polyolefins and compositions thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
DE602007008852D1 true DE602007008852D1 (de) | 2010-10-14 |
Family
ID=38472226
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE602007008852T Active DE602007008852D1 (de) | 2006-03-03 | 2007-03-02 | Kopplungsmittel für mit natürlichen fasern gefüllten polyolefinen und zusammensetzungen daraus |
Country Status (7)
Country | Link |
---|---|
US (1) | US20070208110A1 (de) |
EP (1) | EP1994064B1 (de) |
AT (1) | ATE479717T1 (de) |
CA (1) | CA2643440A1 (de) |
DE (1) | DE602007008852D1 (de) |
RU (1) | RU2437894C2 (de) |
WO (1) | WO2007130201A1 (de) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102006006656A1 (de) * | 2005-08-26 | 2007-03-01 | Degussa Ag | Silan enthaltendes Bindemittel für Verbundwerkstoffe |
US7659330B2 (en) * | 2005-09-16 | 2010-02-09 | University Of Maine System Board Of Trustees | Thermoplastic composites containing lignocellulosic materials and methods of making same |
DE102006046358B3 (de) * | 2006-09-28 | 2007-11-29 | Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. | Verfahren zur Herstellung von funktionellen cellulosischen Formkörpern |
CA2686755A1 (en) * | 2007-05-16 | 2008-11-27 | Nova Chemicals, Inc. | Plastic-cellulosic composite articles |
US7994241B2 (en) * | 2008-01-15 | 2011-08-09 | Innovative Plastics and Molding RNE Tech | Wood composite alloy composition having a compatibilizer that improves the ability to process and compress cellulosic fiber |
US9238731B2 (en) * | 2008-02-29 | 2016-01-19 | Saco Polymers, Inc. | Reinforcing additives for composite materials |
US20110060077A1 (en) * | 2009-09-10 | 2011-03-10 | Yeng-Fong Shih | Process for Manufacturing High-Performance Natural Fiber Reinforced Composites |
CN102153801A (zh) * | 2011-02-28 | 2011-08-17 | 殷正福 | 一种秸秆塑料及其生产方法 |
CN102321378A (zh) * | 2011-09-22 | 2012-01-18 | 黄山华塑新材料科技有限公司 | 一种耐低温型木塑地板及其制备工艺 |
DE102011117833B4 (de) * | 2011-11-08 | 2015-12-31 | Technische Universität Chemnitz | Führungs- und Stützelemente für Zug- und Tragmittel in der Fördertechnik und Verfahren zu ihrer Herstellung |
US20130206035A1 (en) * | 2012-02-14 | 2013-08-15 | Weyerhaeuser Nr Company | Composite Polymer |
CN103602091B (zh) * | 2013-11-07 | 2015-09-09 | 任慧 | 秸秆/热固性树脂复合物及其制备方法 |
CN103602090B (zh) * | 2013-11-07 | 2015-09-09 | 任慧 | 一种秸杆与热固性树脂复合物的制备方法 |
EP2871210A1 (de) * | 2013-11-08 | 2015-05-13 | Rotho Kunststoff AG | Zusammensetzung für einen Verbundwerkstoff, Verbundwerkstoff, Kunststoff-Formkörper und Verfahren zum Herstellen eines solchen |
WO2016172207A1 (en) | 2015-04-20 | 2016-10-27 | Blake Teipel | Natural fiber composite and method of production |
EP3397665B2 (de) | 2015-12-29 | 2023-11-08 | Dow Global Technologies LLC | Hochgepropfte polymere auf ethylenbasis, hochgepropfte polymerzusammensetzungen auf ethylenbasis und verfahren zur formung davon |
WO2018098796A1 (en) | 2016-12-02 | 2018-06-07 | Dow Global Technologies Llc | Process to form a composition containing functionalized and un-functionalized ethylene-based polymers |
DK3441425T3 (da) | 2016-12-05 | 2021-05-31 | Furukawa Electric Co Ltd | Cellulose-aluminium-dispergeret polyethylenharpikskomposit, pellet og formet element ved anvendelse af samme og fremgangsmåde til fremstilling af samme |
WO2019039569A1 (ja) | 2017-08-23 | 2019-02-28 | 古河電気工業株式会社 | セルロース繊維分散ポリオレフィン樹脂複合材、これを用いたペレット及び成形体、並びにセルロース繊維分散ポリオレフィン樹脂複合材の製造方法 |
CN111132806A (zh) | 2017-08-23 | 2020-05-08 | 古河电气工业株式会社 | 分散有纤维素纤维的聚乙烯树脂复合材料、使用了该复合材料的成型体和粒料、它们的制造方法、以及附着有纤维素纤维的聚乙烯薄膜片的再循环方法 |
KR20200043998A (ko) * | 2017-08-23 | 2020-04-28 | 후루카와 덴키 고교 가부시키가이샤 | 셀룰로오스 섬유 분산 폴리에틸렌 수지 복합재, 이를 이용한 성형체 및 펠릿, 이들의 제조 방법, 그리고 셀룰로오스 섬유 부착 폴리에틸렌 박막편의 리사이클 방법 |
EP3674360A4 (de) | 2017-08-23 | 2021-05-12 | Furukawa Electric Co., Ltd. | Polyolefinharzverbundstoff mit dispergierten cellulosefasern |
WO2019066069A1 (ja) | 2017-09-29 | 2019-04-04 | 古河電気工業株式会社 | 成形品 |
WO2019066070A1 (ja) * | 2017-09-29 | 2019-04-04 | 古河電気工業株式会社 | 成形品 |
EP3689973A4 (de) * | 2017-09-29 | 2021-06-09 | Furukawa Electric Co., Ltd. | Formkörper |
WO2019088140A1 (ja) | 2017-10-31 | 2019-05-09 | 古河電気工業株式会社 | 成形品 |
US20220235186A1 (en) * | 2019-06-18 | 2022-07-28 | Upm-Kymmene Corporation | Natural fiber plastic composite precursor material for compounding, method for preparing thereof and method for preparing natural fiber plastic composite product |
WO2021005260A1 (en) * | 2019-07-05 | 2021-01-14 | Upm-Kymmene Corporation | Natural fiber plastic composite precursor material for compounding, method for preparing thereof and method for preparing natural fiber plastic composite product |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
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US3414551A (en) * | 1965-06-24 | 1968-12-03 | Hercules Inc | Modification of crystalline propylene polymers |
JPS599576B2 (ja) * | 1981-01-06 | 1984-03-03 | チッソ株式会社 | ポリオレフイン樹脂組成物 |
US4762890A (en) | 1986-09-05 | 1988-08-09 | The Dow Chemical Company | Method of grafting maleic anhydride to polymers |
US4717742A (en) * | 1985-05-29 | 1988-01-05 | Beshay Alphons D | Reinforced polymer composites with wood fibers grafted with silanes - grafting of celluloses or lignocelluloses with silanes to reinforce the polymer composites |
US4820749A (en) * | 1985-05-29 | 1989-04-11 | Beshay Alphons D | Reinforced polymer composites with wood fibers grafted with silanes |
US4857600A (en) * | 1988-05-23 | 1989-08-15 | Union Carbide Corporation | Process for grafting diacid anhydrides |
US5079302A (en) * | 1990-01-19 | 1992-01-07 | University Of Akron | Polymerization process and the polymers thereof |
US5273671A (en) * | 1990-03-08 | 1993-12-28 | Exxon Chemical Patents Inc. | Multifunctional viscosity index improver-dispersant antioxidant |
JP3714675B2 (ja) * | 1991-12-13 | 2005-11-09 | エクソンモービル・ケミカル・パテンツ・インク | 溶融加工装置における複数反応方法 |
US5346963A (en) * | 1993-04-28 | 1994-09-13 | The Dow Chemical Company | Graft-modified, substantially linear ethylene polymers and methods for their use |
CA2197791C (en) * | 1994-08-25 | 2001-06-19 | Thomas David Roberts | Maleated high acid number high molecular weight polypropylene of low color |
US7408007B2 (en) * | 1994-08-25 | 2008-08-05 | Eastman Chemical Company | Maleated high acid number high molecular weight polypropylene of low color |
DE69620440T3 (de) * | 1995-11-24 | 2010-05-20 | Chisso Corp. | Propylenzusammensetzung, verfahren zu deren herstellung, polypropylenzusammensetzung und geformte gegenstände |
US6218476B1 (en) * | 1999-03-03 | 2001-04-17 | Eastman Chemical Company | Functionalized polypropylenes and process for production |
US6265037B1 (en) * | 1999-04-16 | 2001-07-24 | Andersen Corporation | Polyolefin wood fiber composite |
WO2002018463A1 (en) * | 2000-08-29 | 2002-03-07 | Dupont Canada Inc. | High melt flow, highly-grafted polypropylene |
US6380320B1 (en) * | 2000-10-19 | 2002-04-30 | Dupont Canada Inc. | Process for preparing anhydride-grafted polymers with improved color |
EP1408077A1 (de) * | 2002-10-09 | 2004-04-14 | Borealis Technology Oy | Polymerzusammensetzung mit Füllstoffen im Nanometerbereich |
US6939903B2 (en) * | 2002-10-09 | 2005-09-06 | Crompton Corporation | Natural fiber-filled polyolefin composites |
US7781500B2 (en) * | 2003-04-14 | 2010-08-24 | Crompton Corporation | Coupling agents for natural fiber-filled polyolefins |
US7041716B2 (en) * | 2003-07-11 | 2006-05-09 | National Research Council Of Canada | Cellulose filled thermoplastic composites |
US8455574B2 (en) * | 2004-02-19 | 2013-06-04 | E I Du Pont De Nemours And Company | Composite compositions comprising cellulose and polymeric components |
IL161473A0 (en) * | 2004-04-18 | 2004-09-27 | Polyram Ram On Ind Lp | Star-like polyolefin having high propylene content and polar derivatives thereof and method for its production |
JP2006002052A (ja) * | 2004-06-18 | 2006-01-05 | Mitsubishi Chemicals Corp | 複合樹脂組成物およびその成形体 |
US20060069188A1 (en) * | 2004-09-29 | 2006-03-30 | Klosiewicz Daniel W | Processes for producing functionalized polyolefin emulsions |
KR20080031734A (ko) * | 2005-06-24 | 2008-04-10 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 작용화된 프로필렌 공중합체 접착제 조성물 |
-
2007
- 2007-03-01 US US11/713,134 patent/US20070208110A1/en not_active Abandoned
- 2007-03-02 RU RU2008139293/04A patent/RU2437894C2/ru not_active IP Right Cessation
- 2007-03-02 EP EP07752268A patent/EP1994064B1/de not_active Not-in-force
- 2007-03-02 CA CA002643440A patent/CA2643440A1/en not_active Abandoned
- 2007-03-02 DE DE602007008852T patent/DE602007008852D1/de active Active
- 2007-03-02 AT AT07752268T patent/ATE479717T1/de active
- 2007-03-02 WO PCT/US2007/005554 patent/WO2007130201A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
EP1994064B1 (de) | 2010-09-01 |
ATE479717T1 (de) | 2010-09-15 |
CA2643440A1 (en) | 2007-11-15 |
RU2008139293A (ru) | 2010-04-10 |
US20070208110A1 (en) | 2007-09-06 |
RU2437894C2 (ru) | 2011-12-27 |
WO2007130201A1 (en) | 2007-11-15 |
EP1994064A1 (de) | 2008-11-26 |
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