DE3889721D1 - Verfahren zur Herstellung von Polymeren auf der Basis von Styrol und Katalysator zur Verwendung bei diesem Verfahren. - Google Patents

Verfahren zur Herstellung von Polymeren auf der Basis von Styrol und Katalysator zur Verwendung bei diesem Verfahren.

Info

Publication number
DE3889721D1
DE3889721D1 DE3889721T DE3889721T DE3889721D1 DE 3889721 D1 DE3889721 D1 DE 3889721D1 DE 3889721 T DE3889721 T DE 3889721T DE 3889721 T DE3889721 T DE 3889721T DE 3889721 D1 DE3889721 D1 DE 3889721D1
Authority
DE
Germany
Prior art keywords
styrene
catalyst
based polymers
preparation
contact product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE3889721T
Other languages
English (en)
Other versions
DE3889721T2 (de
Inventor
Hiroshi Maezawa
Norio Tomotsu
Masahiko Kuramoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Kosan Co Ltd
Original Assignee
Idemitsu Kosan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP32539187A external-priority patent/JPH0791326B2/ja
Priority claimed from JP746588A external-priority patent/JPH0757767B2/ja
Priority claimed from JP63007466A external-priority patent/JP2698085B2/ja
Priority claimed from JP63030048A external-priority patent/JPH0819175B2/ja
Priority claimed from JP63066910A external-priority patent/JPH0813853B2/ja
Priority claimed from JP63066908A external-priority patent/JPH0813851B2/ja
Application filed by Idemitsu Kosan Co Ltd filed Critical Idemitsu Kosan Co Ltd
Application granted granted Critical
Publication of DE3889721D1 publication Critical patent/DE3889721D1/de
Publication of DE3889721T2 publication Critical patent/DE3889721T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
DE3889721T 1987-12-24 1988-12-15 Verfahren zur Herstellung von Polymeren auf der Basis von Styrol und Katalysator zur Verwendung bei diesem Verfahren. Expired - Fee Related DE3889721T2 (de)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP32539187A JPH0791326B2 (ja) 1987-12-24 1987-12-24 スチレン系重合体の製造方法
JP746588A JPH0757767B2 (ja) 1988-01-19 1988-01-19 スチレン系重合体の製造方法及び触媒
JP63007466A JP2698085B2 (ja) 1988-01-19 1988-01-19 スチレン系重合体の製造方法とその触媒
JP63030048A JPH0819175B2 (ja) 1988-02-13 1988-02-13 スチレン系重合体の製造方法及びその触媒
JP63066910A JPH0813853B2 (ja) 1988-03-19 1988-03-19 スチレン系重合体の製造方法とその触媒
JP63066908A JPH0813851B2 (ja) 1988-03-19 1988-03-19 スチレン系重合体の製造方法とその触媒

Publications (2)

Publication Number Publication Date
DE3889721D1 true DE3889721D1 (de) 1994-06-30
DE3889721T2 DE3889721T2 (de) 1994-09-22

Family

ID=27548059

Family Applications (1)

Application Number Title Priority Date Filing Date
DE3889721T Expired - Fee Related DE3889721T2 (de) 1987-12-24 1988-12-15 Verfahren zur Herstellung von Polymeren auf der Basis von Styrol und Katalysator zur Verwendung bei diesem Verfahren.

Country Status (11)

Country Link
US (2) US4978730A (de)
EP (1) EP0322663B1 (de)
KR (1) KR930010923B1 (de)
AT (1) ATE106090T1 (de)
AU (1) AU607827B2 (de)
CA (1) CA1325005C (de)
DE (1) DE3889721T2 (de)
ES (1) ES2056886T3 (de)
FI (1) FI93845C (de)
MY (1) MY104071A (de)
RU (1) RU2086563C1 (de)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01501487A (ja) * 1987-06-17 1989-05-25 ザ　ダウ　ケミカル　カンパニー シンジオタクチックポリスチレンの製造のための触媒および方法
US5286762A (en) * 1988-07-23 1994-02-15 Idemitsu Kosan Company Limited Styrene-based polymer moldings and process for production thereof
JPH02252706A (ja) * 1989-03-28 1990-10-11 Idemitsu Kosan Co Ltd スチレン系重合体の製造方法
EP0422239B1 (de) * 1989-03-31 1995-12-06 Idemitsu Kosan Company Limited Styren-kopolymer und verfahren zur herstellung
US5321122A (en) * 1989-07-28 1994-06-14 Idemitsu Kosan Co., Ltd. Process for purification of styrene polymer
JP2936172B2 (ja) * 1990-03-07 1999-08-23 東ソー株式会社 シンジオタクチック芳香族ビニル化合物重合体製造用触媒およびシンジオタクチック芳香族ビニル化合物重合体の製造方法
WO1991013917A1 (en) * 1990-03-16 1991-09-19 Tonen Corporation Olefin polymerization catalyst
JP3048653B2 (ja) * 1991-02-07 2000-06-05 三菱化学株式会社 α‐オレフィン重合体の製造
US5391603A (en) * 1992-03-09 1995-02-21 The Dow Chemical Company Impact modified syndiotactic vinyl aromatic polymers
US5446117A (en) * 1993-08-19 1995-08-29 Queen's University At Kingston Process for producing amorphous syndiotactic polystyrene
JP3369294B2 (ja) * 1994-03-11 2003-01-20 出光興産株式会社 遷移金属化合物、それを用いた重合用触媒及び該重合用触媒を用いたスチレン系重合体の製造方法
TW454020B (en) * 1994-08-09 2001-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst
ATE185141T1 (de) 1995-07-12 1999-10-15 Witco Gmbh Verfahren zur herstellung von cyclopentadienyltitantrialkoxy-derivaten
US5962714A (en) * 1995-10-02 1999-10-05 Mccullough; Laughlin Gerard Monocyclopentadienyl transition metal catalyst and olefin polymerization process
DE69612214T2 (de) * 1995-12-12 2001-06-28 Idemitsu Kosan Co. Ltd., Tokio/Tokyo Polymerisationskatalysator und verfahren zur herstellung von polymeren
IT1277677B1 (it) 1995-12-21 1997-11-11 Enichem Spa Procedimento per la preparazione di polimeri vinilaromatici cristallini a struttura predominantemente sindiotattica
US6034024A (en) * 1996-05-10 2000-03-07 Albemarle Corporation Heat treated alumoxanes
US6271322B1 (en) 1996-10-02 2001-08-07 Mccullough Laughlin Gerard Monocyclopentadienyl transition metal catalyst and olefin polymerization process
IT1286031B1 (it) * 1996-10-24 1998-07-07 Enichem Spa Procedimento per la produzione di polimeri vinilaromatici ad elevato grado di sindiotassia
EP0861853A1 (de) * 1997-02-27 1998-09-02 ENICHEM S.p.A. Katalysator und Verfahren für die syndiotaktische Polymerisation von vinylaromatischen Verbindungen
US5990035A (en) * 1997-10-21 1999-11-23 Koeppl; Alexander Polymerization catalyst systems, their preparation, and use
US6677265B1 (en) 1997-12-08 2004-01-13 Albemarle Corporation Process of producing self-supported catalysts
WO1999029738A1 (en) 1997-12-08 1999-06-17 Albemarle Corporation Catalyst compositions of enhanced productivity
US6551955B1 (en) 1997-12-08 2003-04-22 Albemarle Corporation Particulate group 4 metallocene-aluminoxane catalyst compositions devoid of preformed support, and their preparation and their use
US6100414A (en) * 1998-04-02 2000-08-08 Eastman Chemical Company Cyclopentadienyl transition metal compounds useful as polymerization catalysts
JP4195138B2 (ja) 1998-12-10 2008-12-10 出光興産株式会社 アルミニウムオキシ化合物、オレフィン重合用触媒成分及びポリオレフィンの製造方法
KR100656001B1 (ko) 1999-01-29 2006-12-08 이데미쓰 고산 가부시키가이샤 스티렌 중합용 촉매 및 스티렌계 중합체의 제조방법
JP2000248015A (ja) * 1999-02-26 2000-09-12 Idemitsu Petrochem Co Ltd オレフィン−スチレン類共重合用触媒及びオレフィン−スチレン系共重合体の製造方法
US6921734B2 (en) * 2002-04-10 2005-07-26 China Petroleum & Chemical Corporation Titanocene complexes and its catalyst for preparing syndiotactic polystyrene
US6982306B2 (en) * 2003-11-26 2006-01-03 Chevron Phillips Chemical Company, L.P. Stannoxy-substituted metallocene catalysts for olefin and acetylene polymerization
WO2023059515A1 (en) * 2021-10-08 2023-04-13 Entegris, Inc. Process for preparing organo-titanium compounds

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3534006A (en) * 1966-03-25 1970-10-13 Toray Industries Methods of polymerizing alpha-olefins with a transition metal and a bis(dialkylaluminumoxy)alkane compound
CA1276748C (en) * 1985-07-29 1990-11-20 Michitake Uoi Styrene polymers
JPS62187708A (ja) * 1985-11-11 1987-08-17 Idemitsu Kosan Co Ltd スチレン系重合体の製造法

Also Published As

Publication number Publication date
US4978730A (en) 1990-12-18
KR930010923B1 (ko) 1993-11-17
AU607827B2 (en) 1991-03-14
KR890009992A (ko) 1989-08-05
MY104071A (en) 1993-11-30
FI93845B (fi) 1995-02-28
US5023222A (en) 1991-06-11
DE3889721T2 (de) 1994-09-22
FI885974A (fi) 1989-06-25
FI93845C (fi) 1995-06-12
EP0322663B1 (de) 1994-05-25
EP0322663A3 (en) 1989-12-13
ES2056886T3 (es) 1994-10-16
CA1325005C (en) 1993-12-07
RU2086563C1 (ru) 1997-08-10
AU2640388A (en) 1989-06-29
ATE106090T1 (de) 1994-06-15
EP0322663A2 (de) 1989-07-05

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee