DE2754762C2 - Verfahren zur katalytischen Verbrennung von Schwefelwasserstoff enthaltendem Abgas und zur Durchführung des Verfahrens geeigneter Katalysator - Google Patents

Verfahren zur katalytischen Verbrennung von Schwefelwasserstoff enthaltendem Abgas und zur Durchführung des Verfahrens geeigneter Katalysator

Info

Publication number: DE2754762C2
Authority: DE; Germany
Prior art keywords: catalyst; weight; bismuth; percent; copper
Prior art date: 1977-01-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

DE2754762A

Other languages

German (de)

English (en)

Other versions

DE2754762A1 (de

Inventor

David Michael Houston Tex. Singleton

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Shell Internationale Research Maatschappij BV

Original Assignee

Shell Internationale Research Maatschappij BV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-01-07

Filing date

1977-12-08

Publication date

1987-02-05

1977-12-08 Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV

1978-07-13 Publication of DE2754762A1 publication Critical patent/DE2754762A1/de

1987-02-05 Application granted granted Critical

1987-02-05 Publication of DE2754762C2 publication Critical patent/DE2754762C2/de

Status Expired legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims description 73
239000007789 gas Substances 0.000 title claims description 54
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims description 42
238000000034 method Methods 0.000 title claims description 42
238000007084 catalytic combustion reaction Methods 0.000 title claims description 7
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 36
229910052802 copper Inorganic materials 0.000 claims description 36
239000010949 copper Substances 0.000 claims description 36
229910052797 bismuth Inorganic materials 0.000 claims description 32
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 32
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 24
229910052760 oxygen Inorganic materials 0.000 claims description 24
239000001301 oxygen Substances 0.000 claims description 24
PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
239000012876 carrier material Substances 0.000 claims description 5
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
239000000203 mixture Substances 0.000 claims description 3
239000000463 material Substances 0.000 description 17
238000006243 chemical reaction Methods 0.000 description 15
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 10
239000002245 particle Substances 0.000 description 10
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
238000002485 combustion reaction Methods 0.000 description 6
229910000037 hydrogen sulfide Inorganic materials 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
235000010269 sulphur dioxide Nutrition 0.000 description 5
239000005864 Sulphur Substances 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
239000002904 solvent Substances 0.000 description 4
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 4
230000003197 catalytic effect Effects 0.000 description 3
230000000694 effects Effects 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000000243 solution Substances 0.000 description 3
239000004291 sulphur dioxide Substances 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
230000003213 activating effect Effects 0.000 description 2
239000000654 additive Substances 0.000 description 2
238000003915 air pollution Methods 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
150000004679 hydroxides Chemical class 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
150000002823 nitrates Chemical class 0.000 description 2
229910010271 silicon carbide Inorganic materials 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
239000002912 waste gas Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
239000005909 Kieselgur Substances 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
239000011149 active material Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000003125 aqueous solvent Substances 0.000 description 1
239000010425 asbestos Substances 0.000 description 1
239000003637 basic solution Substances 0.000 description 1
150000001622 bismuth compounds Chemical class 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
150000001860 citric acid derivatives Chemical class 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
230000007423 decrease Effects 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000010790 dilution Methods 0.000 description 1
238000011049 filling Methods 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
230000001788 irregular Effects 0.000 description 1
239000007788 liquid Substances 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
229910052752 metalloid Inorganic materials 0.000 description 1
150000002738 metalloids Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
150000002826 nitrites Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000008262 pumice Substances 0.000 description 1
238000004064 recycling Methods 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229910052895 riebeckite Inorganic materials 0.000 description 1
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
239000011343 solid material Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000004763 sulfides Chemical class 0.000 description 1
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000010457 zeolite Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/843—Arsenic, antimony or bismuth
- B01J23/8437—Bismuth
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Biomedical Technology (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Materials Engineering (AREA)
Environmental & Geological Engineering (AREA)
Analytical Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Catalysts (AREA)
Exhaust Gas Treatment By Means Of Catalyst (AREA)
Incineration Of Waste (AREA)

DE2754762A 1977-01-07 1977-12-08 Verfahren zur katalytischen Verbrennung von Schwefelwasserstoff enthaltendem Abgas und zur Durchführung des Verfahrens geeigneter Katalysator Expired DE2754762C2 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US75753177A	1977-01-07	1977-01-07

Publications (2)

Publication Number	Publication Date
DE2754762A1 DE2754762A1 (de)	1978-07-13
DE2754762C2 true DE2754762C2 (de)	1987-02-05

Family

ID=25048172

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE2754762A Expired DE2754762C2 (de)	1977-01-07	1977-12-08	Verfahren zur katalytischen Verbrennung von Schwefelwasserstoff enthaltendem Abgas und zur Durchführung des Verfahrens geeigneter Katalysator

Country Status (13)

Country	Link
JP (1)	JPS5377873A (pt)
AR (1)	AR212728A1 (pt)
AU (1)	AU510872B2 (pt)
BE (1)	BE862443A (pt)
BR (1)	BR7800064A (pt)
CA (1)	CA1125731A (pt)
DE (1)	DE2754762C2 (pt)
FR (1)	FR2376686A1 (pt)
GB (1)	GB1558656A (pt)
MY (1)	MY8100349A (pt)
NL (1)	NL190357C (pt)
RO (1)	RO76367A (pt)
ZA (1)	ZA7850B (pt)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4576814A (en) *	1979-04-04	1986-03-18	Union Oil Company Of California	Catalyst and process for oxidizing hydrogen sulfide
EP0085213B1 (en) *	1982-02-02	1990-02-07	Union Oil Company Of California	Catalyst and process for oxidizing hydrogen sulfide
FR2631854A1 (fr) *	1988-05-26	1989-12-01	Norsolor Sa	Procede de purification catalytique d'un effluent aqueux
CA2261585A1 (en) *	1996-07-26	1998-02-05	Shell Internationale Research Maatschappij B.V.	Catalyst composition, its preparation, and its use in catalytic incineration
JP2000515806A (ja) *	1996-07-26	2000-11-28	シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ	接触灰化法及び前記方法に有用な触媒組成物
JP3847712B2 (ja)	2000-10-18	2006-11-22	日揮株式会社	硫化水素、メルカプタン、炭酸ガス、芳香族炭化水素を含むガス中の硫黄化合物の除去方法およびその装置
IT1403545B1 (it) *	2011-02-02	2013-10-31	Eonsudenergia Srl	Catalizzatore per la termolisi di rifiuti
EP3799854A1 (en)	2019-10-01	2021-04-07	Stefan Johannes Fellner	Extract of organic humified materials
CN113117517B (zh) *	2019-12-31	2022-10-11	中国石油化工股份有限公司	一种高浓度含硫有机废气的处理方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US1900751A (en) *	1928-02-27	1933-03-07	Ig Farbenindustrie Ag	Purification of gases
GB319396A (en) *	1928-06-20	1929-09-20	Ig Farbenindustrie Ag	Improvements relating to the purification of gas containing sulphuretted hydrogen
FR1070681A (fr) *	1953-02-06	1954-08-05	Bataafsche Petroleum	Procédé de préparation du soufre à partir de l'hydrogène sulfuré

1977
- 1977-12-08 DE DE2754762A patent/DE2754762C2/de not_active Expired
- 1977-12-29 BE BE1008616A patent/BE862443A/xx not_active IP Right Cessation
1978
- 1978-01-05 ZA ZA00780050A patent/ZA7850B/xx unknown
- 1978-01-05 BR BR7800064A patent/BR7800064A/pt unknown
- 1978-01-05 FR FR7800205A patent/FR2376686A1/fr active Granted
- 1978-01-05 AU AU32198/78A patent/AU510872B2/en not_active Expired
- 1978-01-05 GB GB368/78A patent/GB1558656A/en not_active Expired
- 1978-01-05 AR AR270636A patent/AR212728A1/es active
- 1978-01-05 NL NLAANVRAGE7800126,A patent/NL190357C/xx not_active IP Right Cessation
- 1978-01-05 JP JP5678A patent/JPS5377873A/ja active Granted
- 1978-01-05 RO RO7892830A patent/RO76367A/ro unknown
- 1978-01-06 CA CA294,517A patent/CA1125731A/en not_active Expired
1981
- 1981-12-30 MY MY349/81A patent/MY8100349A/xx unknown

Also Published As

Publication number	Publication date
RO76367A (ro)	1981-11-04
MY8100349A (en)	1981-12-31
JPS6120342B2 (pt)	1986-05-21
BR7800064A (pt)	1979-01-02
CA1125731A (en)	1982-06-15
NL7800126A (nl)	1978-07-11
FR2376686B1 (pt)	1982-05-07
DE2754762A1 (de)	1978-07-13
BE862443A (nl)	1978-06-29
NL190357C (nl)	1994-02-01
ZA7850B (en)	1978-12-27
NL190357B (nl)	1993-09-01
FR2376686A1 (fr)	1978-08-04
AU510872B2 (en)	1980-07-17
GB1558656A (en)	1980-01-09
JPS5377873A (en)	1978-07-10
AU3219878A (en)	1979-07-12
AR212728A1 (es)	1978-09-15

Legal Events

Date	Code	Title	Description
1983-10-06	8128	New person/name/address of the agent	Representative=s name: JUNG, E., DIPL.-CHEM. DR.PHIL. SCHIRDEWAHN, J., DI
1985-01-24	8110	Request for examination paragraph 44
1985-02-14	8125	Change of the main classification	Ipc: B01D 53/36
1987-02-05	D2	Grant after examination
1987-07-30	8364	No opposition during term of opposition

Publication	Publication Date	Title
DE2414333C3 (de)	1981-09-10	Verfahren zur selektiven Abtrennung von Stickstoffoxiden aus Abgasen
DE2838231C2 (de)	1983-04-21	Verfahren zur Entschwefelung eines Kohlenwasserstofföls
DE2441199A1 (de)	1975-03-27	Katalysatoren fuer die behandlung von schwefelverbindungen enthaltenden abgasen
DE2341650A1 (de)	1974-03-07	Verfahren zum entfernen von cyanwasserstoff aus gasen
DE2135522C2 (de)	1983-01-13	Verfahren zur Verringerung des Gesamtschwefelgehaltes von Schwefeldioxid enthaltenden Abgasen, die aus einer Claus-Anlage stammen
DE2754762C2 (de)	1987-02-05	Verfahren zur katalytischen Verbrennung von Schwefelwasserstoff enthaltendem Abgas und zur Durchführung des Verfahrens geeigneter Katalysator
DE69913098T2 (de)	2004-09-09	Verfahren zur direkten, katalytischen oxidation des geringen h2s-gehaltes eines gases zu schwefel
DD151878A5 (de)	1981-11-11	Traegerkatalysator aus silber
EP0140045A2 (de)	1985-05-08	Verfahren zur Entschwefelung von H 2 S-haltigen Gasen
DE2101901A1 (de)	1972-04-06	Verfahren zur Verringerung des Gesamtschwefelgehaltes von Claus Abgasen
DE2433076A1 (de)	1975-02-06	Verfahren zur entfernung von stickstoffoxyden aus abgasen
DE2442986C3 (de)	1979-01-18	Verfahren zur Entfernung von Stickstoffoxyden aus Gasen
DE2232027A1 (de)	1973-01-11	Oxydation von schwefel und schwefelverbindungen zu schwefeldioxid
DE3535815A1 (de)	1987-04-09	Verfahren zum reinigen von schwefelwasserstoff und schwefeldioxid enthaltendem abgas
DE1241429B (de)	1967-06-01	Verfahren zur Herstellung von Methanol
EP0215317B1 (de)	1989-06-07	Verfahren zum Entfernen von Schwefelwasserstoff aus Abgasen
DE3429394A1 (de)	1986-02-13	Verfahren und katalysator zur selektiven katalytischen hydrolyse von anorganischen schwefelverbindungen
DE2646627C2 (pt)	1992-02-06
DE1667768B2 (de)	1975-09-11	Verfahren zur Herstellung von Schwefel aus einer Sulfidlösung
DE2454515A1 (de)	1975-05-22	Verfahren zur reduktion von stickstoffoxyden
DE2054942C3 (de)	1978-12-14	Verfahren zur mehrstufigen Umwandlung von Kohlenoxid und Wasserdampf zu Wasserstoff und Kohlendioxid
DE2456113A1 (de)	1975-06-05	Verfahren zur herstellung von methylacrylat oder gemischen hiervon mit akrylsaeure
DE3036605C2 (de)	1987-04-16	Verfahren zur Herstellung einer wäßrigen Lösung von Calciumnitrit
DE69014628T2 (de)	1997-01-30	Katalysator für die heterogene katalyse, der aus einer legierung von übergangsmetallen besteht.
DE2706182B2 (de)	1981-06-25	Katalysatorbett für die Verwendung bei der Oxidation von Ammoniakgas