CO6602153A2 - Produccion de propileno por deshidratacion e isomerizacion del esqueleto simultaneas de isobutanol sobre catalizadores acidos seguidos de metatesis - Google Patents
Produccion de propileno por deshidratacion e isomerizacion del esqueleto simultaneas de isobutanol sobre catalizadores acidos seguidos de metatesisInfo
- Publication number
- CO6602153A2 CO6602153A2 CO12158673A CO12158673A CO6602153A2 CO 6602153 A2 CO6602153 A2 CO 6602153A2 CO 12158673 A CO12158673 A CO 12158673A CO 12158673 A CO12158673 A CO 12158673A CO 6602153 A2 CO6602153 A2 CO 6602153A2
- Authority
- CO
- Colombia
- Prior art keywords
- reactor
- metathesis
- butenes
- isobutanol
- optionally
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
- C07C5/25—Migration of carbon-to-carbon double bonds
- C07C5/2506—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
- C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/14858—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with inorganic compounds not provided for before
- C07C7/14866—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with inorganic compounds not provided for before water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/14875—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with organic compounds
- C07C7/14891—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with organic compounds alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/177—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by selective oligomerisation or polymerisation of at least one compound of the mixture
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/28—Molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/30—Tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/32—Manganese, technetium or rhenium
- C07C2523/36—Rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Procedimiento para la producción de propileno en el que, en una primera etapa, el isobutanol se somete a una deshidratación e isomerización del esqueleto simultáneas para producir olefinas sustancialmente correspondientes, que tienen el mismo número de carbonos y que consisten esencialmente en una mezcla de n-butenos e ¡so-buteno y, en una segunda etapa, los n-butenos se someten a metátesis, comprendiendo dicho procedimiento: a) introducir en un reactor una comente (A) que comprende isobutanol, opcionalmente agua, opcionalmente un componente inerte, b) poner en contacto dicha corriente con un catalizador en dicho reactor en condiciones eficaces para deshidratar e isomerizar el esqueleto de al menos una porción del isobutanol para crear una mezcla de nbutenos e iso-buteno, c) recuperar de dicho reactor una comente (B), retirar el agua, el componente inerte silo hubiera y el isobutanol no convertido silo hubiera y conseguir una mezcla de n-butenos e ¡so-buteno, d) fraccionar dicha mezcla para obtener una comente de n-butenos (N) y retirar la parte esencial de isobuteno opcionalmente reciclado con la (A) al reactor de deshidratación lisomenzación de la etapa b), e) enviar la corriente (N) a un reactor de metátesis y poner en contacto la corriente (N) con un catalizador en dicho reactor de metátesis, opcionalmente en presencia de etileno, en condiciones eficaces para producir propileno, f) recuperar de dicho reactor de metátesis una comente (P) que comprende esencialmente propileno, n-butenos no reaccionados, productos pesados, opcionalmente etileno no reaccionado, g) fraccionar la corriente (P) para recuperar propileno y opcionalmente reciclar los n-butenos no reaccionados y el etileno no reaccionado al reactor de metátesis.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10156537A EP2366682A1 (en) | 2010-03-15 | 2010-03-15 | Simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts |
EP10159461A EP2374780A1 (en) | 2010-04-09 | 2010-04-09 | Production of propylene via simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts followed by metathesis |
EP10159463A EP2374781A1 (en) | 2010-04-09 | 2010-04-09 | Simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts |
EP10160840 | 2010-04-23 | ||
EP10161125 | 2010-04-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
CO6602153A2 true CO6602153A2 (es) | 2013-01-18 |
Family
ID=44242821
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CO12158673A CO6602153A2 (es) | 2010-03-15 | 2012-09-14 | Produccion de propileno por deshidratacion e isomerizacion del esqueleto simultaneas de isobutanol sobre catalizadores acidos seguidos de metatesis |
Country Status (16)
Country | Link |
---|---|
US (1) | US9260355B2 (es) |
EP (1) | EP2547639B1 (es) |
JP (2) | JP5784647B2 (es) |
KR (1) | KR101572714B1 (es) |
CN (1) | CN102906053B (es) |
AR (1) | AR080682A1 (es) |
BR (1) | BR112012023261B1 (es) |
CA (1) | CA2791219C (es) |
CO (1) | CO6602153A2 (es) |
DK (1) | DK2547639T3 (es) |
EA (1) | EA025706B1 (es) |
ES (1) | ES2604134T3 (es) |
MY (1) | MY161426A (es) |
PE (1) | PE20130760A1 (es) |
PL (1) | PL2547639T3 (es) |
WO (1) | WO2011113836A1 (es) |
Families Citing this family (43)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120016172A1 (en) * | 2009-04-01 | 2012-01-19 | Mitsui Chemicals, Inc. | Method for manufacturing olefin |
MY161426A (en) * | 2010-03-15 | 2017-04-14 | Total Res & Technology Feluy | Production of propylene via simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts followed by metathesis |
US20130150643A1 (en) * | 2011-12-08 | 2013-06-13 | Saudi Basic Industries Corporation | Mixed-phase operation of butenes metathesis process for maximizing propylene production |
FR2988717B1 (fr) * | 2012-03-29 | 2014-04-11 | IFP Energies Nouvelles | Procede de deshydratation et d'isomerisation d'alcools utilisant un catalyseur a base d'un materiau mesostructure comprenant du silicium |
US9688591B2 (en) | 2013-01-10 | 2017-06-27 | Equistar Chemicals, Lp | Ethylene separation process |
US10392315B2 (en) * | 2013-11-08 | 2019-08-27 | Braskem S.A. | Propene production method |
EP3071538B1 (en) * | 2013-11-20 | 2021-02-17 | Lummus Technology LLC | Olefin double bond isomerization catalyst with high poison resistance |
FR3015514B1 (fr) | 2013-12-23 | 2016-10-28 | Total Marketing Services | Procede ameliore de desaromatisation de coupes petrolieres |
KR101747501B1 (ko) * | 2014-12-05 | 2017-06-14 | 주식회사 엘지화학 | 부타디엔 제조용 복합산화물 촉매 및 이의 제조방법 |
KR101966773B1 (ko) | 2015-05-13 | 2019-04-08 | 주식회사 엘지화학 | 이성질화 반응을 이용한 노말부텐의 분리방법 및 노말부텐을 분리하기 위한 공정시스템 |
KR102178406B1 (ko) | 2015-07-02 | 2020-11-16 | 사우디 아라비안 오일 컴퍼니 | 프로필렌 제조용의 이중 촉매 시스템 |
US20170022125A1 (en) * | 2015-07-21 | 2017-01-26 | Uop Llc | Processes for producing polymer grade light olefins from mixed alcohols |
CN106467450B (zh) * | 2015-08-19 | 2020-05-12 | 中国石油化工股份有限公司 | 一种制备异丁烯的方法 |
CN110325493B (zh) * | 2016-10-14 | 2022-12-20 | 吉沃公司 | 由生物基醇以高产率将c2-c8烯烃混合物转化为喷气油燃料和/或柴油燃料 |
FR3058413A1 (fr) * | 2016-11-08 | 2018-05-11 | IFP Energies Nouvelles | Procede de deshydratation isomerisante d'une charge d'un monoalcool primaire non lineaire sur un catalyseur comprenant une zeolithe de type fer et un alcalin |
US10329225B2 (en) | 2017-01-20 | 2019-06-25 | Saudi Arabian Oil Company | Dual catalyst processes and systems for propylene production |
US10934231B2 (en) | 2017-01-20 | 2021-03-02 | Saudi Arabian Oil Company | Multiple-stage catalyst systems and processes for propene production |
CN107118069A (zh) * | 2017-06-17 | 2017-09-01 | 安徽海德石油化工有限公司 | 一种利用异丁醇脱水制备异丁烯的方法 |
WO2019016710A1 (en) | 2017-07-19 | 2019-01-24 | Sabic Global Technologies B.V. | USE OF MTBE REFINED IN PROPYLENE PRODUCTION |
FR3074803B1 (fr) * | 2017-12-13 | 2019-11-29 | IFP Energies Nouvelles | Procede d’elimination simultanee d’isobutanal et d’ethanol de charges olefiniques par adsorption sur un materiau a base d’oxyde refractaire poreux |
FR3074802B1 (fr) | 2017-12-13 | 2019-12-06 | IFP Energies Nouvelles | Procede d'elimination simultanee d'isobutanal et d'acetone de charges olefiniques par adsorption sur un materiau zeolithique |
FR3077818B1 (fr) | 2018-02-09 | 2020-02-28 | IFP Energies Nouvelles | Procede de separation d'olefines non lineaires d'une charge olefinique par distillation reactive |
US11242299B2 (en) * | 2018-10-10 | 2022-02-08 | Saudi Arabian Oil Company | Catalyst systems that include metal oxide co-catalysts for the production of propylene |
CN111013639A (zh) * | 2018-10-10 | 2020-04-17 | 中国石油化工股份有限公司 | 丁烯双键异构化催化剂及其用途 |
US10961171B2 (en) | 2018-10-10 | 2021-03-30 | Saudi Arabian Oil Company | Catalysts systems that include metal co-catalysts for the production of propylene |
CN111116282B (zh) * | 2018-10-30 | 2022-07-08 | 中国石油化工股份有限公司 | 叔丁醇制烯烃的方法 |
US11192090B2 (en) * | 2019-03-25 | 2021-12-07 | Korea Institute Of Energy Research | Alcohol dehydration catalyst, preparation method the same and method for preparing alpha-olefins using the same |
KR20210126101A (ko) * | 2019-03-29 | 2021-10-19 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 방향족 탄화수소 전환용 mel형 제올라이트, 상기 제올라이트의 제조 방법, 및 상기 제올라이트를 포함하는 촉매 조성물 |
CN112209791B (zh) * | 2019-07-12 | 2023-08-04 | 中国石油化工股份有限公司 | 一种叔丁醇转化生产丙烯的方法 |
CN112209790B (zh) * | 2019-07-12 | 2023-08-29 | 中国石油化工股份有限公司 | 叔丁醇直接转化生产丙烯的方法 |
MX2022003604A (es) * | 2019-09-30 | 2022-05-30 | Gevo Inc | Deshidratacion, dimerizacion y metatesis simultaneas de alcoholes c2-c5. |
CN112679295B (zh) * | 2019-10-18 | 2022-11-04 | 中国石油化工股份有限公司 | 叔丁醇转化生产丙烯的方法 |
WO2021099534A1 (en) | 2019-11-22 | 2021-05-27 | Total Se | Alkyl halides conversion into c3-c5 alpha olefins |
WO2021099551A1 (en) | 2019-11-22 | 2021-05-27 | Total Se | Process for converting one or more methyl halides into c3-c5 alpha olefins |
US11185850B2 (en) | 2019-12-02 | 2021-11-30 | Saudi Arabian Oil Company | Dual functional composite catalyst for olefin metathesis and cracking |
US11339332B2 (en) | 2020-01-29 | 2022-05-24 | Saudi Arabian Oil Company | Systems and processes integrating fluidized catalytic cracking with metathesis for producing olefins |
US11572516B2 (en) | 2020-03-26 | 2023-02-07 | Saudi Arabian Oil Company | Systems and processes integrating steam cracking with dual catalyst metathesis for producing olefins |
EP4129963A4 (en) * | 2020-03-31 | 2023-09-27 | Mitsubishi Chemical Corporation | CATALYST, METHOD FOR PRODUCING ISOBUTYLENE, METHOD FOR PRODUCING METHACRYLIC ACID AND METHOD FOR PRODUCING METHYL METHACRYLATE |
WO2021198479A1 (en) | 2020-04-03 | 2021-10-07 | Total Se | Production of light olefins via oxychlorination |
US11845705B2 (en) | 2021-08-17 | 2023-12-19 | Saudi Arabian Oil Company | Processes integrating hydrocarbon cracking with metathesis for producing propene |
US11827589B2 (en) | 2021-10-04 | 2023-11-28 | Lyondell Chemical Technology, L.P. | Methods for isobutylene conversion to C5+ compounds |
CN114849679B (zh) * | 2022-04-01 | 2024-02-02 | 万华化学集团股份有限公司 | 一种固体超强酸负载催化剂以及β-苯乙醇的制备方法 |
CN115141086A (zh) * | 2022-06-30 | 2022-10-04 | 浙江美福石油化工有限责任公司 | 一种甲基叔丁基醚回炼工艺 |
Family Cites Families (43)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US488760A (en) | 1892-12-27 | Philetus warren gates | ||
US615933A (en) | 1898-12-13 | Gutter-former | ||
DE890953C (de) * | 1938-08-21 | 1953-10-29 | Basf Ag | Verfahren zur Herstellung von Butylen-Isobutylen-Gemischen |
GB1064829A (en) | 1964-11-19 | 1967-04-12 | British Petroleum Co | Olefin preparation |
FR91345E (es) | 1965-11-22 | 1968-09-09 | ||
US3658927A (en) | 1969-09-02 | 1972-04-25 | Phillips Petroleum Co | Olefin conversion and catalysts therefor |
US4469911A (en) | 1980-10-23 | 1984-09-04 | Petro Tex Chemical Corporation | Isobutene removal from C4 streams |
US4568788A (en) | 1980-11-17 | 1986-02-04 | Phillips Petroleum Company | Olefin disproportionation and catalyst therefor |
EP0304515B1 (en) | 1983-03-10 | 1991-12-04 | The Dow Chemical Company | A process for the disproportionation of alkenes |
US4575575A (en) | 1984-04-05 | 1986-03-11 | Phillips Petroleum Company | Catalysts and process for olefin conversion |
US4754098A (en) | 1986-02-24 | 1988-06-28 | Phillips Petroleum Company | Catalyst compositions useful for olefin isomerization and disproportionation |
US4684760A (en) | 1986-02-24 | 1987-08-04 | Phillips Petroleum Company | Catalyst compositions useful for olefin isomerization and disproportionation |
FR2606669B1 (fr) | 1986-11-18 | 1989-02-17 | Inst Francais Du Petrole | Procede de preparation d'un catalyseur renfermant du rhenium, catalyseur obtenu et utilisation de ce catalyseur pour la production d'olefines par metathese |
FR2608595B1 (fr) | 1986-12-17 | 1989-04-28 | Inst Francais Du Petrole | Procede de metathese d'olefines |
US6495732B1 (en) | 1992-02-10 | 2002-12-17 | Catalytic Distillation Technologies | Olefin isomerization process |
FR2709125B1 (fr) | 1993-08-20 | 1995-10-06 | Inst Francais Du Petrole | Procédé de métathèse des oléfines mettant en Óoeuvre un catalyseur au rhénium amélioré. |
US6159433A (en) | 1995-05-11 | 2000-12-12 | Institut Francais Du Petrole | Plant for the conversion of olefinic C4 and C5 cuts to an ether and to propylene |
FR2733986B1 (fr) * | 1995-05-11 | 1997-06-13 | Inst Francais Du Petrole | Procede et installation pour la conversion de coupes c4 olefiniques en polyisobutenes et en propylene |
ZA966107B (en) * | 1995-07-21 | 1997-02-03 | Shell Int Research | Dehydration of primary alcohols. |
FR2740056B1 (fr) | 1995-10-20 | 1997-12-05 | Inst Francais Du Petrole | Catalyseur supporte contenant du rhenium et de l'aluminium, procede de preparation et application a la metathese des olefines |
US5895830A (en) | 1995-12-15 | 1999-04-20 | Uop Llc | Process for oligomer production and saturation |
US5877372A (en) | 1997-11-21 | 1999-03-02 | Arco Chemical Technology, L.P. | Isobutylene oligomerization using isooctane diluent |
FR2802921B1 (fr) | 1999-12-24 | 2002-08-23 | Inst Francais Du Petrole | Production d'isobutene de haute purete et de propylene a partir de coupes d'hydrocarbures a quatre atomes de carbone |
US6616910B2 (en) * | 2000-05-05 | 2003-09-09 | Institut Francais Du Petrole | Process for preparation of an EUO-structural-type zeolite, the zeolite that is obtained and its use as catalyst for isomerization of C8-aromatic compounds |
US6689927B1 (en) | 2001-05-07 | 2004-02-10 | Uop Lcc | Process for oligomer production and saturation |
US20050124839A1 (en) | 2001-06-13 | 2005-06-09 | Gartside Robert J. | Catalyst and process for the metathesis of ethylene and butene to produce propylene |
US6768035B2 (en) * | 2002-01-31 | 2004-07-27 | Chevron U.S.A. Inc. | Manufacture of high octane alkylate |
US6777582B2 (en) * | 2002-03-07 | 2004-08-17 | Abb Lummus Global Inc. | Process for producing propylene and hexene from C4 olefin streams |
DE10302457B3 (de) | 2003-01-23 | 2004-10-07 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Butenoligomeren und tert.-Butylethern aus Isobuten-haltigen C4-Strömen |
US6977318B2 (en) * | 2004-05-04 | 2005-12-20 | Equistar Chemicals, Lp | Propylene production |
US7220886B2 (en) | 2004-10-27 | 2007-05-22 | Catalytic Distillation Technologies | Olefin metathesis |
CN101133007B (zh) * | 2005-03-03 | 2012-08-29 | 三井化学株式会社 | 烯烃类的制造方法 |
US20080132741A1 (en) | 2006-06-16 | 2008-06-05 | D Amore Michael B | Process for making butenes from dry isobutanol |
US20080154077A1 (en) * | 2006-12-21 | 2008-06-26 | Bozzano Andrea G | Oxygenate conversion to olefins with metathesis |
MX2009011192A (es) | 2007-04-18 | 2009-10-30 | Du Pont | Produccion fermentativa de isobutanol con el uso de enzimas reductoisomerasas con alta actividad acida y cetolica. |
KR101127676B1 (ko) * | 2007-04-27 | 2012-03-22 | 미쓰이 가가쿠 가부시키가이샤 | 올레핀의 제조 방법 |
US8178737B2 (en) * | 2007-06-14 | 2012-05-15 | Lyondell Chemical Technology, L.P. | Propylene production |
EP2225351A4 (en) | 2007-12-03 | 2016-11-09 | Gevo Inc | RENEWABLE COMPOSITIONS |
EP2090561A1 (en) | 2008-02-07 | 2009-08-19 | Total Petrochemicals Research Feluy | Dehydration of alcohols on crystalline silicates |
JP2011511037A (ja) * | 2008-02-07 | 2011-04-07 | トータル・ペトロケミカルズ・リサーチ・フエリユイ | 不活性成分の存在下でのアルコールの脱水 |
CN104761427A (zh) | 2008-02-07 | 2015-07-08 | 道达尔研究技术弗吕公司 | 醇在结晶硅酸盐上的脱水 |
EP2108634A1 (en) * | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Dehydration of alcohols on crystalline silicates |
MY161426A (en) * | 2010-03-15 | 2017-04-14 | Total Res & Technology Feluy | Production of propylene via simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts followed by metathesis |
-
2011
- 2011-03-15 MY MYPI2012003839A patent/MY161426A/en unknown
- 2011-03-15 PL PL11708460T patent/PL2547639T3/pl unknown
- 2011-03-15 ES ES11708460.8T patent/ES2604134T3/es active Active
- 2011-03-15 PE PE2012001549A patent/PE20130760A1/es not_active Application Discontinuation
- 2011-03-15 CA CA2791219A patent/CA2791219C/en not_active Expired - Fee Related
- 2011-03-15 AR ARP110100833A patent/AR080682A1/es not_active Application Discontinuation
- 2011-03-15 WO PCT/EP2011/053905 patent/WO2011113836A1/en active Application Filing
- 2011-03-15 EP EP11708460.8A patent/EP2547639B1/en active Active
- 2011-03-15 BR BR112012023261A patent/BR112012023261B1/pt not_active IP Right Cessation
- 2011-03-15 JP JP2012557530A patent/JP5784647B2/ja not_active Expired - Fee Related
- 2011-03-15 CN CN201180024167.6A patent/CN102906053B/zh not_active Expired - Fee Related
- 2011-03-15 KR KR1020127024106A patent/KR101572714B1/ko active IP Right Grant
- 2011-03-15 DK DK11708460.8T patent/DK2547639T3/en active
- 2011-03-15 EA EA201270740A patent/EA025706B1/ru not_active IP Right Cessation
- 2011-03-15 US US13/583,990 patent/US9260355B2/en active Active
-
2012
- 2012-09-14 CO CO12158673A patent/CO6602153A2/es not_active Application Discontinuation
-
2014
- 2014-11-19 JP JP2014234243A patent/JP2015042677A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
CA2791219A1 (en) | 2011-09-22 |
PL2547639T3 (pl) | 2017-02-28 |
PE20130760A1 (es) | 2013-06-21 |
KR101572714B1 (ko) | 2015-11-27 |
KR20120135905A (ko) | 2012-12-17 |
CN102906053A (zh) | 2013-01-30 |
US20130245348A1 (en) | 2013-09-19 |
EP2547639B1 (en) | 2016-08-24 |
MY161426A (en) | 2017-04-14 |
EP2547639A1 (en) | 2013-01-23 |
JP5784647B2 (ja) | 2015-09-24 |
JP2013522271A (ja) | 2013-06-13 |
DK2547639T3 (en) | 2016-12-19 |
CN102906053B (zh) | 2015-06-03 |
US9260355B2 (en) | 2016-02-16 |
EA025706B1 (ru) | 2017-01-30 |
BR112012023261B1 (pt) | 2018-09-18 |
AR080682A1 (es) | 2012-05-02 |
WO2011113836A1 (en) | 2011-09-22 |
CA2791219C (en) | 2015-11-24 |
JP2015042677A (ja) | 2015-03-05 |
EA201270740A1 (ru) | 2013-02-28 |
ES2604134T3 (es) | 2017-03-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CO6602153A2 (es) | Produccion de propileno por deshidratacion e isomerizacion del esqueleto simultaneas de isobutanol sobre catalizadores acidos seguidos de metatesis | |
BR112015000387A8 (pt) | método para oligomerização de etileno | |
PH12015500512A1 (en) | Propylene via metathesis with low or no ethylene | |
AR080756A1 (es) | Deshidratacion e isomerizacion esqueletica simultaneas de isobutanol en catalizadores acidos | |
EA200900860A1 (ru) | Превращение кислородсодержащих соединений в олефины с димеризацией и диспропорционированием | |
ATE516256T1 (de) | Propylenherstellung | |
CL2009001815A1 (es) | Proceso para la produccion de propileno que comprende contactar etileno y una corriente de 1-buteno y 2-buteno con un catalizador bifuncional para isomerizacion y metatesis; catalizador bifuncional; y proceso de preparacion. | |
CO6731070A2 (es) | Producción de alquenos mediante conversión enzimática combinada de ácidos 3-hidroxialcanoicos | |
BR112018009885A2 (pt) | produção de derivados de olefina graxos através de metátese de olefina | |
CO6571890A2 (es) | Procedimiento de fabricación de un catalizadro que comprende una zeolita modificada con fosforo para uso en un procedimiento de deshidrtación de alcoholes | |
MY149709A (en) | Process for manufacturing acrolein or acrylic acid from glycerin | |
BR112013011269A2 (pt) | produção de aditivos para combustível através da desidratação e isomerização estrutural simultâneas de isobutanol sobre catalisadores ácidos seguido pela eterificação | |
WO2014053535A3 (en) | Process for the hydrogenation of esters of aromatic carboxylic acids to yield saturated homologues thereof | |
SG195091A1 (en) | Method for producing diisobutylene using mixed c4 fraction as raw material | |
TW200732275A (en) | Oxygenate conversion to olefins with metathesis | |
ES2443539B1 (es) | Proceso de oligomerización de alquenos utilizando la zeolita ITQ-39 | |
WO2011062988A3 (en) | A method of making a synthetic alkylaryl sulfonate | |
WO2018057125A3 (en) | Use of light gas by-products in the production of paraxylene by the methylation of toluene and/or benzene | |
EP3778023A4 (en) | REGENERATION PROCESS FOR ACID SOLID BENZENE ALKYLATION CATALYST | |
AR111124A1 (es) | Métodos para fabricar olefinas ligeras a partir de corrientes de alimentación diferentes | |
WO2006115648A3 (en) | Diisobutylene process | |
FR2959736A1 (fr) | Procede de production d'alkylbenzenes a partir d'une charge produite par oligomerisation catalysee par voie homogene. | |
MX2015005019A (es) | Proceso de produccion de propileno con reciclaje de productos pesados. | |
WO2018008982A3 (ko) | 아세토페논이 포함된 혼합물로부터 선택적 산화반응을 통한 벤조산의 제조방법 | |
EA201791244A1 (ru) | Применение катализатора для корректировки распределения продуктов в процессе мто |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FC | Application refused |