CN1869093A - 表皮一体化层压材料的车内制品、制造不发泡聚氨酯树脂的方法及其用途 - Google Patents
表皮一体化层压材料的车内制品、制造不发泡聚氨酯树脂的方法及其用途 Download PDFInfo
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- CN1869093A CN1869093A CNA2006100794317A CN200610079431A CN1869093A CN 1869093 A CN1869093 A CN 1869093A CN A2006100794317 A CNA2006100794317 A CN A2006100794317A CN 200610079431 A CN200610079431 A CN 200610079431A CN 1869093 A CN1869093 A CN 1869093A
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- polyurethane resin
- foaming polyurethane
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- mould
- epidermis
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- QHTUMQYGZQYEOZ-UHFFFAOYSA-N 2-(4-methylpiperazin-1-yl)ethanol Chemical compound CN1CCN(CCO)CC1 QHTUMQYGZQYEOZ-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 1
- OPIPDUFGXKXYLW-UHFFFAOYSA-N 4-methyl-2-oxopentanal Chemical compound CC(C)CC(=O)C=O OPIPDUFGXKXYLW-UHFFFAOYSA-N 0.000 description 1
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- 241000196324 Embryophyta Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- BNZDZXXKNVOCJK-UHFFFAOYSA-N O1C=COC=C1.C=CCCCC Chemical compound O1C=COC=C1.C=CCCCC BNZDZXXKNVOCJK-UHFFFAOYSA-N 0.000 description 1
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- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
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- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
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- TXXWBTOATXBWDR-UHFFFAOYSA-N n,n,n',n'-tetramethylhexane-1,6-diamine Chemical compound CN(C)CCCCCCN(C)C TXXWBTOATXBWDR-UHFFFAOYSA-N 0.000 description 1
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- DYFXGORUJGZJCA-UHFFFAOYSA-N phenylmethanediamine Chemical compound NC(N)C1=CC=CC=C1 DYFXGORUJGZJCA-UHFFFAOYSA-N 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
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- 235000011056 potassium acetate Nutrition 0.000 description 1
- PHZLMBHDXVLRIX-UHFFFAOYSA-M potassium lactate Chemical compound [K+].CC(O)C([O-])=O PHZLMBHDXVLRIX-UHFFFAOYSA-M 0.000 description 1
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- 235000011085 potassium lactate Nutrition 0.000 description 1
- 229960001304 potassium lactate Drugs 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/82—Post-polymerisation treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6685—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2120/00—Compositions for reaction injection moulding processes
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
Description
多元醇混合物(I) |
聚醚多元醇(1)启动分子:丙二醇平均官能度:约2.0,聚醚多元醇的羟基值:45mg KOH/g |
增链剂(2)增链剂(2-1)二乙基二氨基甲苯增链剂(2-2)乙二醇 |
催化剂(3)催化剂(3-1)33%三亚乙基二胺在丙二醇中的溶液催化剂(3-2)二月桂酸二丁基锡 |
多异氰酸酯化合物(II)多异氰酸酯化合物(II-1):碳化二亚胺-uretoimine改性的二苯甲烷二异氰酸酯NCO%:29.0%,粘度:40mPa.s/25℃多异氰酸酯化合物(II-2):氨基甲酸酯改性的异氰酸酯预聚物,基于二苯甲烷二异氰酸酯(NCO%:17.0%,粘度:1000mPa.s/25℃)和多元醇(平均官能度:3,平均分子量:6,000)多异氰酸酯化合物(II-3):多亚甲基多苯基多异氰酸酯NCO%:31.5%,粘度:180mPa.s/25℃ |
实例 | 对比例 | ||||||
1 | 2 | 3 | 4 | 1 | 2 | 3 | |
多元醇混合物(I)聚醚多元醇(1)(重量份数)增链剂(2-1)(重量份数)增链剂(2-2)(重量份数)催化剂(3-1)(重量份数)催化剂(3-2)(重量份数)防老化剂合计羟基值(mg KOH/g) | 93.9550.60.050.410077.1 | 93.5551.00.050.410079.2 | 96.7520.80.050.410060.6 | 93.9550.60.050.410077.1 | 96.851.51.20.050.410077.4 | 95.3531.20.050.4100103.8 | 88.95100.60.050.4100106.4 |
多异氰酸酯化合物(II) | |||||||
多异氰酸酯化合物(II-1) | x | ||||||
多异氰酸酯化合物(II-2) | x | ||||||
多异氰酸酯化合物(II-3) | x | x | x | x | x | ||
NC0指数 | 105 | 105 | 105 | 105 | 105 | 105 | 105 |
混合比(重量分数)多元醇混合物(I)/多异氰酸酯化合物(II) | 100/20.9 | 100/36.6 | 100/15.1 | 100/19.3 | 100/19.3 | 100/25.9 | 100/26.6 |
实例 | 对比例 | ||||||
1 | 2 | 3 | 4 | 1 | 2 | 3 | |
原料温度(℃) | 30 | 30 | 30 | 30 | 30 | 30 | 30 |
倾倒数量(g/s) | 200 | 200 | 200 | 200 | 200 | 200 | 200 |
反应性能胶凝时间(s) | 8 | 14 | 11 | 9 | 6 | 5 | 3 |
厚度(mm) | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 |
固化时间(s) | 60 | 70 | 60 | 60 | 150 | 120 | 60 |
混合性能 | 好 | 好 | 好 | 好 | 坏 | 好 | 好 |
流动性 | 好 | 好 | 好 | 好 | 好 | 好 | 坏 |
物理性质密度(g/cm3)Asker A表面硬度 | 1.0560 | 1.0249 | 1.0553 | 1.0560 | 1.0560 | 1.0575 | n.d.77 |
抗张强度(MPa) | 4.6 | 3.4 | 4.0 | 3.7 | n.d. | 4.1 | n.d. |
断裂伸长(%) | 440 | 415 | 420 | 165 | n.d. | 80 | n.d. |
撕裂强度(N/cm) | 240 | 195 | 200 | 142 | n.d. | 135 | n.d. |
实施例5 | |
原料温度(℃) | 30 |
倾倒数量(g/s) | 200 |
厚度(mm) | 1 |
固化时间(s) | 60 |
混合性能 | 好 |
流动性 | 好 |
粘合性能 | 好 |
物理性质 | |
密度(g/cm3) | 1.05 |
Asker A表面硬度 | 53 |
Claims (6)
Applications Claiming Priority (3)
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JP2005132466 | 2005-04-28 | ||
JP2005-132466 | 2005-04-28 | ||
JP2005132466A JP4418398B2 (ja) | 2005-04-28 | 2005-04-28 | 表皮付き積層体である車両内装部品、並びに非発泡ポリウレタン樹脂及びそれを用いた表皮付き積層体の製造方法 |
Publications (2)
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CN1869093A true CN1869093A (zh) | 2006-11-29 |
CN1869093B CN1869093B (zh) | 2011-04-06 |
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CN2006100794317A Expired - Fee Related CN1869093B (zh) | 2005-04-28 | 2006-04-28 | 表皮一体化层压材料的车内制品、制造不发泡聚氨酯树脂的方法及其用途 |
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US (2) | US7572404B2 (zh) |
EP (1) | EP1717256B1 (zh) |
JP (1) | JP4418398B2 (zh) |
KR (1) | KR101304013B1 (zh) |
CN (1) | CN1869093B (zh) |
AT (1) | ATE444978T1 (zh) |
BR (1) | BRPI0601608A (zh) |
CA (1) | CA2545044A1 (zh) |
DE (1) | DE602006009576D1 (zh) |
ES (1) | ES2332810T3 (zh) |
MX (1) | MXPA06004604A (zh) |
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RU (1) | RU2006114343A (zh) |
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CN101440207B (zh) * | 2007-09-19 | 2012-08-08 | 住化拜耳氨酯株式会社 | 表皮整体成形品、表皮整体成形品以及带表皮的层叠体的制造方法 |
WO2014108067A1 (en) * | 2013-01-08 | 2014-07-17 | Basf Se | Insulation component and molding process for the same |
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Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3609107A (en) * | 1969-05-23 | 1971-09-28 | Borg Warner | Self-extinguishing polyurethane foams |
DE2622951B2 (de) * | 1976-05-21 | 1979-09-06 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von elastischen Fonnkörpern |
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US6294248B1 (en) | 1994-09-27 | 2001-09-25 | Bayer Corporation | Soft molded composites and a process for their production |
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JP4418398B2 (ja) * | 2005-04-28 | 2010-02-17 | 住化バイエルウレタン株式会社 | 表皮付き積層体である車両内装部品、並びに非発泡ポリウレタン樹脂及びそれを用いた表皮付き積層体の製造方法 |
-
2005
- 2005-04-28 JP JP2005132466A patent/JP4418398B2/ja not_active Expired - Fee Related
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2006
- 2006-04-20 EP EP06008156A patent/EP1717256B1/en not_active Not-in-force
- 2006-04-20 ES ES06008156T patent/ES2332810T3/es active Active
- 2006-04-20 US US11/408,197 patent/US7572404B2/en active Active
- 2006-04-20 PL PL06008156T patent/PL1717256T3/pl unknown
- 2006-04-20 DE DE602006009576T patent/DE602006009576D1/de active Active
- 2006-04-20 AT AT06008156T patent/ATE444978T1/de not_active IP Right Cessation
- 2006-04-25 CA CA002545044A patent/CA2545044A1/en not_active Abandoned
- 2006-04-25 MX MXPA06004604A patent/MXPA06004604A/es unknown
- 2006-04-27 RU RU2006114343/04A patent/RU2006114343A/ru not_active Application Discontinuation
- 2006-04-27 KR KR1020060038075A patent/KR101304013B1/ko active IP Right Grant
- 2006-04-28 CN CN2006100794317A patent/CN1869093B/zh not_active Expired - Fee Related
- 2006-04-28 BR BRPI0601608-1A patent/BRPI0601608A/pt not_active IP Right Cessation
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CN101440207B (zh) * | 2007-09-19 | 2012-08-08 | 住化拜耳氨酯株式会社 | 表皮整体成形品、表皮整体成形品以及带表皮的层叠体的制造方法 |
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Also Published As
Publication number | Publication date |
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KR20060113492A (ko) | 2006-11-02 |
US20090267254A1 (en) | 2009-10-29 |
US20060264522A1 (en) | 2006-11-23 |
KR101304013B1 (ko) | 2013-09-04 |
EP1717256B1 (en) | 2009-10-07 |
JP4418398B2 (ja) | 2010-02-17 |
CA2545044A1 (en) | 2006-10-28 |
PL1717256T3 (pl) | 2010-03-31 |
US8057727B2 (en) | 2011-11-15 |
DE602006009576D1 (de) | 2009-11-19 |
RU2006114343A (ru) | 2007-11-20 |
CN1869093B (zh) | 2011-04-06 |
ATE444978T1 (de) | 2009-10-15 |
MXPA06004604A (es) | 2007-02-08 |
BRPI0601608A (pt) | 2006-12-26 |
ES2332810T3 (es) | 2010-02-12 |
JP2006305916A (ja) | 2006-11-09 |
US7572404B2 (en) | 2009-08-11 |
EP1717256A1 (en) | 2006-11-02 |
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