CN1709960A - 一种纳米碳酸钙补强三元乙丙橡胶的制备方法 - Google Patents
一种纳米碳酸钙补强三元乙丙橡胶的制备方法 Download PDFInfo
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- CN1709960A CN1709960A CN 200510027344 CN200510027344A CN1709960A CN 1709960 A CN1709960 A CN 1709960A CN 200510027344 CN200510027344 CN 200510027344 CN 200510027344 A CN200510027344 A CN 200510027344A CN 1709960 A CN1709960 A CN 1709960A
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- calcium carbonate
- nano
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- rubber
- propylene rubber
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 title claims abstract description 83
- 229910000019 calcium carbonate Inorganic materials 0.000 title claims abstract description 57
- 229920000181 Ethylene propylene rubber Polymers 0.000 title claims description 15
- 238000002360 preparation method Methods 0.000 title claims description 15
- 229920001971 elastomer Polymers 0.000 claims abstract description 55
- 239000005060 rubber Substances 0.000 claims abstract description 55
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 5
- 229920001897 terpolymer Polymers 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 20
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 6
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical group C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 5
- KHAVLLBUVKBTBG-UHFFFAOYSA-N caproleic acid Natural products OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 229960002703 undecylenic acid Drugs 0.000 claims description 5
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 4
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical group C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 238000005987 sulfurization reaction Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 6
- 229920002943 EPDM rubber Polymers 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- 230000004048 modification Effects 0.000 abstract description 4
- 238000012986 modification Methods 0.000 abstract description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 description 17
- 235000019241 carbon black Nutrition 0.000 description 17
- 239000000945 filler Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 230000002787 reinforcement Effects 0.000 description 7
- 238000005728 strengthening Methods 0.000 description 6
- 239000000470 constituent Substances 0.000 description 4
- 230000003014 reinforcing effect Effects 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 229920013649 Paracril Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- -1 glycidyl methacrylate modified carbon Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
实施例1 | 对比例1 | |
三元乙丙橡胶(ND 4770)纳米碳酸钙丙烯酸过氧化二异丙苯 | 100601.23 | 1006003 |
实施例1 | 对比例1 | |
100%定伸强度,MPa拉伸强度,MPa扯断伸长率,%撕裂强度,kN/m | 6.416.917434.5 | 3.712.431634.5 |
实施例2 | 对比例2 | |
三元乙丙橡胶(ND 4770)纳米碳酸钙甲基丙烯酸过氧化二异丙苯 | 1006064 | 1006004 |
实施例2 | 对比例2 | |
100%定伸强度,MPa拉伸强度,MPa扯断伸长率,%撕裂强度,kN/m | 5.019.727332.7 | 3.86.820828.6 |
实施例3 | 对比例3 | |
三元乙丙橡胶(ND 4770)纳米碳酸钙十一烯酸过氧化二异丙苯 | 100601.23 | 1006003 |
实施例3 | 对比例3 | |
100%定伸强度,MPa拉伸强度,MPa扯断伸长率,%撕裂强度,kN/m | 5.115.421735.3 | 3.712.431634.5 |
实施例4 | 对比例4 | |
三元乙丙橡胶(DSM 4703)纳米碳酸钙甲基丙烯酸2,5-二甲基-2,5(二叔丁基过氧)己烷 | 100601.22 | 1006002 |
实施例4 | 对比例4 | |
100%定伸强度,MPa拉伸强度,MPa扯断伸长率,%撕裂强度,kN/m | 3.011.223724.8 | 2.86.119820.7 |
Claims (6)
Priority Applications (1)
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CNB2005100273442A CN1309778C (zh) | 2005-06-30 | 2005-06-30 | 一种纳米碳酸钙补强三元乙丙橡胶的制备方法 |
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CNB2005100273442A CN1309778C (zh) | 2005-06-30 | 2005-06-30 | 一种纳米碳酸钙补强三元乙丙橡胶的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN1709960A true CN1709960A (zh) | 2005-12-21 |
CN1309778C CN1309778C (zh) | 2007-04-11 |
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CNB2005100273442A Expired - Fee Related CN1309778C (zh) | 2005-06-30 | 2005-06-30 | 一种纳米碳酸钙补强三元乙丙橡胶的制备方法 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101698730B (zh) * | 2009-04-30 | 2011-08-24 | 张万鹏 | 一种橡胶颗粒及其制备方法 |
CN102344610A (zh) * | 2010-07-28 | 2012-02-08 | 中国科学院合肥物质科学研究院 | 纳米复合乙丙橡胶电缆材料及其制备方法 |
CN103509207A (zh) * | 2013-09-11 | 2014-01-15 | 淮北市蒋疃民和新型建材有限责任公司 | 一种用于橡胶填充料的改性石灰石粉 |
CN107641176A (zh) * | 2017-08-31 | 2018-01-30 | 航天材料及工艺研究所 | 一种橡胶组合物及橡胶材料制备方法 |
US11059962B2 (en) * | 2015-10-14 | 2021-07-13 | Imertech Sas | Polymer blends |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56163134A (en) * | 1980-05-20 | 1981-12-15 | Aichi Kogyo Daigaku | Rubber compound |
JPS575735A (en) * | 1980-06-16 | 1982-01-12 | Karupu Kogyo Kk | Resin composition for vacuum molding |
CN1023705C (zh) * | 1986-10-29 | 1994-02-09 | 三井石油化学工业株式会社 | 热塑性弹性体组合物的制备方法 |
KR20040021417A (ko) * | 2002-09-04 | 2004-03-10 | 동일고무벨트주식회사 | 표면 모폴로지가 향상된 열가소성 탄성체 조성물 |
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2005
- 2005-06-30 CN CNB2005100273442A patent/CN1309778C/zh not_active Expired - Fee Related
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101698730B (zh) * | 2009-04-30 | 2011-08-24 | 张万鹏 | 一种橡胶颗粒及其制备方法 |
CN102344610A (zh) * | 2010-07-28 | 2012-02-08 | 中国科学院合肥物质科学研究院 | 纳米复合乙丙橡胶电缆材料及其制备方法 |
CN102344610B (zh) * | 2010-07-28 | 2013-10-30 | 中国科学院合肥物质科学研究院 | 纳米复合乙丙橡胶电缆材料及其制备方法 |
CN103509207A (zh) * | 2013-09-11 | 2014-01-15 | 淮北市蒋疃民和新型建材有限责任公司 | 一种用于橡胶填充料的改性石灰石粉 |
US11059962B2 (en) * | 2015-10-14 | 2021-07-13 | Imertech Sas | Polymer blends |
CN107641176A (zh) * | 2017-08-31 | 2018-01-30 | 航天材料及工艺研究所 | 一种橡胶组合物及橡胶材料制备方法 |
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Publication number | Publication date |
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CN1309778C (zh) | 2007-04-11 |
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Owner name: ZHEJIANG TIANCHEN RUBBER CO., LTD. Free format text: FORMER OWNER: PUJIANG TIANJIE RUBBER INDUSTRY CO., LTD. Effective date: 20130527 |
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Effective date of registration: 20130527 Address after: Pujiang County, Zhejiang province 322000 Jinhua city Jiawu town Anping Road No. 199 Patentee after: ZHEJIANG TIANCHEN RUBBER INDUSTRY CO., LTD. Address before: 322000 Zhejiang County of Pujiang province Jiawu Zheng Zhen An Ping Road No. 199 Patentee before: Pujiang County Jie Jie glue industry Co., Ltd. |
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