CN1613901A - 含淀粉的全生物降解的吹塑成型树脂组合物及其制备方法 - Google Patents
含淀粉的全生物降解的吹塑成型树脂组合物及其制备方法 Download PDFInfo
- Publication number
- CN1613901A CN1613901A CN 200310113303 CN200310113303A CN1613901A CN 1613901 A CN1613901 A CN 1613901A CN 200310113303 CN200310113303 CN 200310113303 CN 200310113303 A CN200310113303 A CN 200310113303A CN 1613901 A CN1613901 A CN 1613901A
- Authority
- CN
- China
- Prior art keywords
- starch
- weight
- composition
- aliphatic polyester
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002472 Starch Polymers 0.000 title claims abstract description 46
- 238000000071 blow moulding Methods 0.000 title claims abstract description 20
- 239000008107 starch Substances 0.000 title claims description 44
- 235000019698 starch Nutrition 0.000 title claims description 44
- 239000011342 resin composition Substances 0.000 title claims description 6
- 238000002360 preparation method Methods 0.000 title abstract description 18
- 229920005989 resin Polymers 0.000 claims abstract description 53
- 239000011347 resin Substances 0.000 claims abstract description 53
- 239000000203 mixture Substances 0.000 claims abstract description 45
- 229920003232 aliphatic polyester Polymers 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 25
- -1 poly ethylene Polymers 0.000 claims abstract description 14
- 229920000573 polyethylene Polymers 0.000 claims abstract description 13
- 239000004698 Polyethylene Substances 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 11
- 230000000996 additive effect Effects 0.000 claims description 11
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 9
- 239000000600 sorbitol Substances 0.000 claims description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 8
- 239000012752 auxiliary agent Substances 0.000 claims description 8
- 229920006228 ethylene acrylate copolymer Polymers 0.000 claims description 8
- 235000011187 glycerol Nutrition 0.000 claims description 8
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000008116 calcium stearate Substances 0.000 claims description 5
- 235000013539 calcium stearate Nutrition 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 235000010216 calcium carbonate Nutrition 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000008188 pellet Substances 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 238000009775 high-speed stirring Methods 0.000 claims description 3
- 229940059574 pentaerithrityl Drugs 0.000 claims description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 244000017020 Ipomoea batatas Species 0.000 claims description 2
- 235000002678 Ipomoea batatas Nutrition 0.000 claims description 2
- 240000003183 Manihot esculenta Species 0.000 claims description 2
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 2
- 241000276489 Merlangius merlangus Species 0.000 claims description 2
- 229920000331 Polyhydroxybutyrate Polymers 0.000 claims description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 2
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 claims description 2
- 229910000020 calcium bicarbonate Inorganic materials 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000007822 coupling agent Substances 0.000 claims description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 2
- 235000013312 flour Nutrition 0.000 claims description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 239000005015 poly(hydroxybutyrate) Substances 0.000 claims description 2
- 229920001592 potato starch Polymers 0.000 claims description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims 2
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims 1
- 235000019359 magnesium stearate Nutrition 0.000 claims 1
- 238000006731 degradation reaction Methods 0.000 abstract description 13
- 239000002253 acid Substances 0.000 abstract description 9
- 230000015556 catabolic process Effects 0.000 abstract description 8
- 150000002148 esters Chemical class 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 2
- 238000000465 moulding Methods 0.000 abstract description 2
- 235000019890 Amylum Nutrition 0.000 abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 1
- 238000007664 blowing Methods 0.000 abstract 1
- IIPKBWQWKYOKRA-UHFFFAOYSA-N ethane;prop-1-ene Chemical compound CC.CC=C IIPKBWQWKYOKRA-UHFFFAOYSA-N 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 18
- 229920003023 plastic Polymers 0.000 description 14
- 239000004033 plastic Substances 0.000 description 14
- 238000012856 packing Methods 0.000 description 12
- 102000004190 Enzymes Human genes 0.000 description 7
- 108090000790 Enzymes Proteins 0.000 description 7
- 235000013305 food Nutrition 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 229940095686 granule product Drugs 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 4
- 239000005642 Oleic acid Substances 0.000 description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 4
- 229920006167 biodegradable resin Polymers 0.000 description 4
- 238000000635 electron micrograph Methods 0.000 description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- 235000012424 soybean oil Nutrition 0.000 description 4
- 239000003549 soybean oil Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000007515 enzymatic degradation Effects 0.000 description 3
- 230000002255 enzymatic effect Effects 0.000 description 3
- 125000004185 ester group Chemical group 0.000 description 3
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 2
- IUPHTVOTTBREAV-UHFFFAOYSA-N 3-hydroxybutanoic acid;3-hydroxypentanoic acid Chemical class CC(O)CC(O)=O.CCC(O)CC(O)=O IUPHTVOTTBREAV-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- 102000004882 Lipase Human genes 0.000 description 2
- 108090001060 Lipase Proteins 0.000 description 2
- 239000004367 Lipase Substances 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 229940061720 alpha hydroxy acid Drugs 0.000 description 2
- 150000001280 alpha hydroxy acids Chemical class 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000003413 degradative effect Effects 0.000 description 2
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 235000019421 lipase Nutrition 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 description 2
- 229920000070 poly-3-hydroxybutyrate Polymers 0.000 description 2
- 229920001281 polyalkylene Polymers 0.000 description 2
- 229920000903 polyhydroxyalkanoate Polymers 0.000 description 2
- 229920005672 polyolefin resin Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000010189 synthetic method Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- VYMPLPIFKRHAAC-UHFFFAOYSA-N 1,2-ethanedithiol Chemical compound SCCS VYMPLPIFKRHAAC-UHFFFAOYSA-N 0.000 description 1
- CEFDWZDNAJAKGO-UHFFFAOYSA-N 2-hydroxy-2-sulfoacetic acid Chemical compound OC(=O)C(O)S(O)(=O)=O CEFDWZDNAJAKGO-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 229920001273 Polyhydroxy acid Polymers 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000006701 autoxidation reaction Methods 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 229920000704 biodegradable plastic Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 1
- FANFFPDSASGEBD-UHFFFAOYSA-N ethylidenetin Chemical compound CC=[Sn] FANFFPDSASGEBD-UHFFFAOYSA-N 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 102000034238 globular proteins Human genes 0.000 description 1
- 108091005896 globular proteins Proteins 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000002035 hexane extract Substances 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 235000021374 legumes Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 239000002362 mulch Substances 0.000 description 1
- KWUZCAVKPCRJPO-UHFFFAOYSA-N n-ethyl-4-(6-methyl-1,3-benzothiazol-2-yl)aniline Chemical compound C1=CC(NCC)=CC=C1C1=NC2=CC=C(C)C=C2S1 KWUZCAVKPCRJPO-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 1
Images
Landscapes
- Biological Depolymerization Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
原材料名称 | 实施例2 | 实施例3 |
淀粉 | 40 | 45 |
山梨糖醇 | 5.5 | 6 |
硬脂酸锌 | 0.2 | 0.2 |
硬脂酸钙 | 0.2 | 0.2 |
油酸 | 0.5 | - |
1010 | - | 0.2 |
RWS-784 | - | 0.2 |
甘油 | 3.5 | 3 |
环氧大豆油 | 0.7 | 1.5 |
UV-531 | - | 0.2 |
超细碳黑 | 0.8 | 0.5 |
乙烯丙烯酸共聚物 | 10 | 12 |
双酚A | - | 0.5 |
京锡-8831 | - | 1.5 |
脂肪族聚酯 | 38.6 | 29 |
总量 | 100 | 100 |
序号 | 测试项目 | 结果 | |
01 | 外观 | 浅黄色颗料,无异味,异嗅,异物 | |
02 | 淀粉含量 % | 25(实施例2) | 35(实施例3) |
03 | 易降解组份含量 % | 100 | 100 |
04 | 水份含量 % | 0.82 | 0.88 |
05 | 熔体流动速率 g/10min | 3.9 | 3.1 |
06 | 密度 g/cm3 | 1.01 | 1.04 |
07 | 拉伸强度(纵、横) Mpa | 33,20 | 26,19 |
08 | 断裂伸长率(纵、横) % | 374,534 | 352,460 |
09 | 直解撕裂强度(纵、横)N/mm | 141,105 | 91,75 |
10 | 生物降解率 %/14天 | 70 | 80 |
11 | 霉菌降解级 21天 | 4级 | 4级 |
原料 | 实施例4 | 实施例5 | 实施例6 | 实施例7 | 实施例8 | 实施例9 |
淀粉 | 20 | 30 | 40 | 50 | 60 | 70 |
山梨糖醇 | 7 | 6 | 5 | 5 | 4 | 4 |
硬脂酸锌 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
硬脂酸钙 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
油酸 | 1 | 1 | 1 | 1 | - | 1 |
硬脂酸 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | - |
马来酸酐 | 2 | 2.5 | 2 | 2 | - | 1 |
甘油 | 5 | 4 | 3 | 5 | 2 | 1 |
环氧大豆油 | 2 | 1.5 | 2 | 2 | 1 | 2 |
硼酸 | 1 | 1.5 | 1 | 1 | - | 0.5 |
PE | 10 | - | - | - | - | - |
HDPE | 8 | - | - | - | - | - |
乙烯丙烯酸共聚物 | 8 | 7 | - | 5 | - | 5 |
脂肪族聚酯 | 35 | 45.5 | 45 | 28 | 32 | 15 |
总量 | 100 | 100 | 100 | 100 | 100 | 100 |
序号 | 测试项目 | 测试结果 |
01 | 外观 | 成黄色颗料,无异味,异嗅,异物 |
02 | 淀粉含量 % | 40 |
03 | 易降解组份含量 % | 100 |
04 | 水份含量 % | 0.86 |
05 | 熔体流动速率 g/10min | 3.75 |
06 | 密度 g/cm3 | 1.02 |
07 | 拉伸强度(纵、横) Mpa | 26,18 |
08 | 断裂伸长率(纵、横) % | 379,417 |
09 | 直解撕裂强度(纵、横)N/mm | 71,98 |
10 | 微生物降解率 %/14天 | 31 |
11 | 霉菌降解级 21天 | 4级 |
12 | 灼烧残渣 % | 0.3 |
13 | 正己烷提取物 % | 3.5 |
14 | 高锰酸钾消耗量 mg/L | 6 |
原料名称 | 实施例10 | 实施例11 | 实施例12 | 实施例13 | 实施例14 | 实施例15 |
淀粉 | 20 | 30 | 40 | 50 | 60 | 70 |
山梨糖醇 | 5 | 5 | 5.5 | 6 | 6.5 | 6 |
硬脂酸锌 | 0.2 | 0.2 | 0.2 | 0.15 | 0.2 | 0.2 |
硬脂酸钙 | 0.3 | 0.3 | 0.3 | 0.15 | 0.3 | 0.3 |
油酸 | 1 | 1 | 0.5 | 0.2 | - | 0.5 |
硬脂酸 | 1 | 1.5 | 1 | - | - | 1 |
二月桂酸二凌辛基锡 | 1.5 | 2 | 1 | - | - | - |
京鍚-8831 | - | - | - | - | - | - |
RWS-784 | - | - | - | - | - | - |
甘油 | 3 | 3 | 3 | 3 | 3.5 | 3 |
环氧大豆油 | 0.5 | 1 | 0.5 | 0.5 | 0.5 | 1 |
再生PE利用 | 17.5 | - | - | - | - | - |
乙烯丙烯酸共聚物 | 4 | - | 5 | 8 | - | 8 |
脂肪族聚酯 | 46 | 56 | 43 | 32 | 29 | 10 |
总量 | 100 | 100 | 100 | 100 | 100 | 100 |
序号 | 测试项目 | 测试结果 | ||||
01 | 密封试验 | ***漏 | ||||
02 | 跌落试验 | 不破损,不蹦盖,撞地击时允许桶口部分有少量液体,之后不得渗漏 | ||||
03 | 悬挂试验 | 公称容量,L | -5 | 10-15 | 20-40 | 50-200 |
残留变形量mm | 2 | ≤3 | ≤4 | 不裂 | ||
04 | 堆码试验 | 不倒堆 | ||||
05 | 应力开裂试验 | 开裂的试样数<50% | ||||
06 | 液压开裂试验 | 无破损,***漏 | ||||
07 | 微生物降率14天,% | >77 | ||||
08 | 霉菌降解级21天,级 | ≥4级 |
Claims (12)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2003101133036A CN1307246C (zh) | 2003-11-07 | 2003-11-07 | 含淀粉的全生物降解的吹塑成型树脂组合物及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2003101133036A CN1307246C (zh) | 2003-11-07 | 2003-11-07 | 含淀粉的全生物降解的吹塑成型树脂组合物及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1613901A true CN1613901A (zh) | 2005-05-11 |
CN1307246C CN1307246C (zh) | 2007-03-28 |
Family
ID=34759885
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2003101133036A Expired - Fee Related CN1307246C (zh) | 2003-11-07 | 2003-11-07 | 含淀粉的全生物降解的吹塑成型树脂组合物及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1307246C (zh) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100572433C (zh) * | 2006-05-16 | 2009-12-23 | 广东上九生物降解塑料有限公司 | 一种可完全生物降解塑料树脂及其薄膜类制品的生产方法 |
CN101910283A (zh) * | 2007-12-17 | 2010-12-08 | 丰田自动车株式会社 | 树脂组合物及使用其的成型品 |
CN1931908B (zh) * | 2005-09-16 | 2011-07-06 | 李小鲁 | 可生物降解组合物及其制备方法以及注射类成型制品 |
CN1931906B (zh) * | 2005-09-16 | 2011-07-27 | 李小鲁 | 可生物降解组合物及其制备方法以及膜制品 |
CN1935886B (zh) * | 2005-09-21 | 2011-09-28 | 李小鲁 | 水溶性可生物降解材料及其制备方法以及注射类成型制品 |
CN102257066A (zh) * | 2008-12-26 | 2011-11-23 | 三菱化学株式会社 | 树脂组合物、膜、袋制品、和树脂组合物的制造方法 |
CN1931907B (zh) * | 2005-09-16 | 2013-06-05 | 北京泓桦生物材料有限公司 | 可生物降解组合物及其制备方法以及片材类成型制品 |
CN109757257A (zh) * | 2018-12-20 | 2019-05-17 | 上海昶法新材料有限公司 | 一种可降解育苗块及其制备方法 |
CN113321903A (zh) * | 2021-05-25 | 2021-08-31 | 广州睿安材料科技有限公司 | 一种生物质材料的制备工艺及其应用 |
WO2021193219A1 (ja) * | 2020-03-27 | 2021-09-30 | 株式会社カネカ | 熱可塑性樹脂組成物の製造方法、成形体の製造方法、及びフィルム |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1039648C (zh) * | 1991-08-01 | 1998-09-02 | 诺瓦蒙特股份公司 | 可得自含变构淀粉和热塑性聚合物的熔体的聚合物组合物 |
IT1272871B (it) * | 1995-01-10 | 1997-07-01 | Novamont Spa | Composizioni termoplastiche compredenti amido ed altre componenti di origine naturale |
CN1114653C (zh) * | 2000-01-12 | 2003-07-16 | 李小鲁 | 可生物降解的树脂组合物及其制备方法和应用 |
CN1320656A (zh) * | 2000-04-25 | 2001-11-07 | 深圳市红达实业发展有限公司 | 生物降解淀粉树脂组合物 |
CN1357563A (zh) * | 2001-12-29 | 2002-07-10 | 中国科学院长春应用化学研究所 | 淀粉-聚乙烯醇-聚酯类三元体系生物降解膜的制备方法 |
CN1169869C (zh) * | 2002-12-10 | 2004-10-06 | 中国科学院长春应用化学研究所 | 淀粉型全降解塑料的制备方法 |
-
2003
- 2003-11-07 CN CNB2003101133036A patent/CN1307246C/zh not_active Expired - Fee Related
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1931908B (zh) * | 2005-09-16 | 2011-07-06 | 李小鲁 | 可生物降解组合物及其制备方法以及注射类成型制品 |
CN1931906B (zh) * | 2005-09-16 | 2011-07-27 | 李小鲁 | 可生物降解组合物及其制备方法以及膜制品 |
CN1931907B (zh) * | 2005-09-16 | 2013-06-05 | 北京泓桦生物材料有限公司 | 可生物降解组合物及其制备方法以及片材类成型制品 |
CN1935886B (zh) * | 2005-09-21 | 2011-09-28 | 李小鲁 | 水溶性可生物降解材料及其制备方法以及注射类成型制品 |
CN100572433C (zh) * | 2006-05-16 | 2009-12-23 | 广东上九生物降解塑料有限公司 | 一种可完全生物降解塑料树脂及其薄膜类制品的生产方法 |
CN101910283A (zh) * | 2007-12-17 | 2010-12-08 | 丰田自动车株式会社 | 树脂组合物及使用其的成型品 |
CN102257066A (zh) * | 2008-12-26 | 2011-11-23 | 三菱化学株式会社 | 树脂组合物、膜、袋制品、和树脂组合物的制造方法 |
US8974881B2 (en) | 2008-12-26 | 2015-03-10 | Mitsubishi Chemical Corporation | Resin composition, film, bag product and production process of resin composition |
US9206306B2 (en) | 2008-12-26 | 2015-12-08 | Mitsubishi Chemical Corporation | Resin composition, film, bag product and production process of resin composition |
CN109757257A (zh) * | 2018-12-20 | 2019-05-17 | 上海昶法新材料有限公司 | 一种可降解育苗块及其制备方法 |
WO2021193219A1 (ja) * | 2020-03-27 | 2021-09-30 | 株式会社カネカ | 熱可塑性樹脂組成物の製造方法、成形体の製造方法、及びフィルム |
CN113321903A (zh) * | 2021-05-25 | 2021-08-31 | 广州睿安材料科技有限公司 | 一种生物质材料的制备工艺及其应用 |
Also Published As
Publication number | Publication date |
---|---|
CN1307246C (zh) | 2007-03-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN110791069B (zh) | 一种软包装用全降解高阻隔复合材料 | |
US8389614B2 (en) | Biodegradable nanopolymer compositions and biodegradable articles made thereof | |
CN1233717C (zh) | 用于光和生物降解塑料制品的多元组合物及用途 | |
CN113801350A (zh) | 一种碳酸钙填充pbat/pla生物降解塑料薄膜及其制备方法 | |
JP2021169608A (ja) | 高濃度の生物学的実体を含むマスターバッチ組成物 | |
US20080153940A1 (en) | Biodegradable compositions and biodegradable articles made thereof | |
CN1037515C (zh) | 一种可生物降解的含淀粉的高分子组合物及其制备方法 | |
CN102167890A (zh) | 适用于制备可生物降解的聚合物组合物的母料及其制备方法 | |
JPH06500819A (ja) | ポリヒドロキシ酸と相溶化剤を含有するフィルム | |
CN110698822A (zh) | 一种餐饮具用全生物降解复合材料及其制备方法与应用 | |
KR20130068620A (ko) | 식물체 바이오매스를 이용한 친환경 사출 성형품 및 그 제조방법 | |
CN1114653C (zh) | 可生物降解的树脂组合物及其制备方法和应用 | |
CN101717537A (zh) | 一种聚烯烃薄膜及其制造方法 | |
CN101045801A (zh) | 一种全生物降解塑料及其生产方法 | |
CN1613901A (zh) | 含淀粉的全生物降解的吹塑成型树脂组合物及其制备方法 | |
EP3162841B1 (en) | A biodegradable biocompostable biodigestible plastic | |
KR20090008110A (ko) | 전분을 이용한 자연 분해성 시트 및 그 제조방법 | |
KR20150073593A (ko) | 소맥피를 이용한 탄소중립형 고강도 바이오 플라스틱 필름 및 그 제조 방법 | |
JPWO2016139946A1 (ja) | ポリエステル樹脂組成物及び成形体の製造方法、並びにポリエステル樹脂組成物及び成形体 | |
KR101322600B1 (ko) | 생분해성 플라스틱 조성물 | |
KR102058394B1 (ko) | 친환경 바이오 필름 봉투의 제조방법 및 이로부터 수득된 필름 봉투 | |
CN1298777C (zh) | 用于塑料的热氧化促降解母料及其制备方法 | |
KR102579310B1 (ko) | 폴리비닐알코올을 포함하는 생분해성 수지 조성물 및 그 제조방법 | |
KR100955024B1 (ko) | 개선된 공정에 의한 자연 분해성 시트 및 그 제조방법 | |
KR20090008099A (ko) | 물성이 개선된 생분해성 수지 조성물 및 그의 제조 방법 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: BEIJING DYNASTY INTERNATIONAL BIODEGRADABLE MATERIAL TECHNOLOGY CO., LTD. Assignor: Li Xiaolu Contract record no.: 2011990000290 Denomination of invention: Biological degradable blow-moulding resin composition containing starch and its preparation Granted publication date: 20070328 License type: Exclusive License Open date: 20050511 Record date: 20110421 |
|
ASS | Succession or assignment of patent right |
Owner name: MA GUANG Free format text: FORMER OWNER: LI XIAOLU Effective date: 20121226 |
|
C41 | Transfer of patent application or patent right or utility model | ||
COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 100036 HAIDIAN, BEIJING TO: 100026 CHAOYANG, BEIJING |
|
TR01 | Transfer of patent right |
Effective date of registration: 20121226 Address after: 100026, 5-3-501, Tuanjiehu Middle Road, Beijing, Chaoyang District Patentee after: Ma Guang Address before: 100036, room 410, Executive Hotel, 24 Fuxing Road, Beijing, Haidian District Patentee before: Li Xiaolu |
|
ASS | Succession or assignment of patent right |
Owner name: DYNASTY- BSR (BEIJING) BIOTECH R + D CO., LTD. Free format text: FORMER OWNER: MA GUANG Effective date: 20130312 |
|
C41 | Transfer of patent application or patent right or utility model | ||
COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 100026 CHAOYANG, BEIJING TO: 100101 CHAOYANG, BEIJING |
|
TR01 | Transfer of patent right |
Effective date of registration: 20130312 Address after: 100101 Beijing city Chaoyang District Asian Sports Village Huibin building block B room 1716 Patentee after: BEIJING DYNASTY INTERNATIONAL BIODEGRADABLE MATERIAL TECHNOLOGY CO., LTD. Address before: 100026, 5-3-501, Tuanjiehu Middle Road, Beijing, Chaoyang District Patentee before: Ma Guang |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070328 Termination date: 20181107 |
|
CF01 | Termination of patent right due to non-payment of annual fee |