CN1114653C - 可生物降解的树脂组合物及其制备方法和应用 - Google Patents
可生物降解的树脂组合物及其制备方法和应用 Download PDFInfo
- Publication number
- CN1114653C CN1114653C CN00100127A CN00100127A CN1114653C CN 1114653 C CN1114653 C CN 1114653C CN 00100127 A CN00100127 A CN 00100127A CN 00100127 A CN00100127 A CN 00100127A CN 1114653 C CN1114653 C CN 1114653C
- Authority
- CN
- China
- Prior art keywords
- starch
- metallocene
- weight
- composition
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000011342 resin composition Substances 0.000 title abstract description 5
- 229920002472 Starch Polymers 0.000 claims abstract description 105
- 239000008107 starch Substances 0.000 claims abstract description 105
- 235000019698 starch Nutrition 0.000 claims abstract description 105
- 239000000203 mixture Substances 0.000 claims abstract description 37
- 238000000034 method Methods 0.000 claims abstract description 15
- 229920000098 polyolefin Polymers 0.000 claims abstract description 12
- 239000000654 additive Substances 0.000 claims abstract description 11
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 10
- 238000005187 foaming Methods 0.000 claims abstract description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 88
- 239000000843 powder Substances 0.000 claims description 73
- 229920005989 resin Polymers 0.000 claims description 58
- 239000011347 resin Substances 0.000 claims description 58
- 229920001526 metallocene linear low density polyethylene Polymers 0.000 claims description 52
- 229920006228 ethylene acrylate copolymer Polymers 0.000 claims description 47
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 46
- 239000000600 sorbitol Substances 0.000 claims description 46
- 235000011187 glycerol Nutrition 0.000 claims description 44
- 229920005672 polyolefin resin Polymers 0.000 claims description 26
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 24
- 239000008116 calcium stearate Substances 0.000 claims description 22
- 235000013539 calcium stearate Nutrition 0.000 claims description 22
- -1 Zinic stearas Chemical compound 0.000 claims description 13
- 239000004743 Polypropylene Substances 0.000 claims description 11
- 229920001155 polypropylene Polymers 0.000 claims description 11
- 230000000996 additive effect Effects 0.000 claims description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000002023 wood Substances 0.000 claims description 9
- 239000003112 inhibitor Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 241000196324 Embryophyta Species 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000008188 pellet Substances 0.000 claims description 5
- 235000010216 calcium carbonate Nutrition 0.000 claims description 4
- 239000012968 metallocene catalyst Substances 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 238000005453 pelletization Methods 0.000 claims description 4
- 241000276489 Merlangius merlangus Species 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 229940059574 pentaerithrityl Drugs 0.000 claims description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 244000017020 Ipomoea batatas Species 0.000 claims description 2
- 235000002678 Ipomoea batatas Nutrition 0.000 claims description 2
- 240000003183 Manihot esculenta Species 0.000 claims description 2
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 2
- 240000008790 Musa x paradisiaca Species 0.000 claims description 2
- 235000018290 Musa x paradisiaca Nutrition 0.000 claims description 2
- 229920000331 Polyhydroxybutyrate Polymers 0.000 claims description 2
- 238000013019 agitation Methods 0.000 claims description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 2
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 claims description 2
- 229910000020 calcium bicarbonate Inorganic materials 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000007822 coupling agent Substances 0.000 claims description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 2
- 239000003063 flame retardant Substances 0.000 claims description 2
- 235000013312 flour Nutrition 0.000 claims description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 239000005015 poly(hydroxybutyrate) Substances 0.000 claims description 2
- 229920001592 potato starch Polymers 0.000 claims description 2
- 230000003068 static effect Effects 0.000 claims description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims 2
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims 1
- 229920001684 low density polyethylene Polymers 0.000 claims 1
- 239000004702 low-density polyethylene Substances 0.000 claims 1
- 235000019359 magnesium stearate Nutrition 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 229920001897 terpolymer Polymers 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 10
- 238000000071 blow moulding Methods 0.000 abstract description 6
- 239000002245 particle Substances 0.000 abstract description 5
- 238000006065 biodegradation reaction Methods 0.000 abstract description 3
- 238000002347 injection Methods 0.000 abstract description 3
- 239000007924 injection Substances 0.000 abstract description 3
- 235000012438 extruded product Nutrition 0.000 abstract description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 43
- 239000004593 Epoxy Substances 0.000 description 42
- 235000012424 soybean oil Nutrition 0.000 description 41
- 239000003549 soybean oil Substances 0.000 description 41
- 239000010408 film Substances 0.000 description 28
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 27
- 235000021355 Stearic acid Nutrition 0.000 description 25
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 25
- 239000008117 stearic acid Substances 0.000 description 25
- FRVCGRDGKAINSV-UHFFFAOYSA-L iron(2+);octadecanoate Chemical compound [Fe+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O FRVCGRDGKAINSV-UHFFFAOYSA-L 0.000 description 21
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 20
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 20
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 20
- 239000005642 Oleic acid Substances 0.000 description 20
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 20
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 20
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 20
- 239000002362 mulch Substances 0.000 description 13
- 239000004793 Polystyrene Substances 0.000 description 12
- 239000004698 Polyethylene Substances 0.000 description 11
- 229920002223 polystyrene Polymers 0.000 description 11
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 10
- 229920003023 plastic Polymers 0.000 description 10
- 239000004033 plastic Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- BWDDKSQGVQKNAM-UHFFFAOYSA-L calcium octadecanoate octadecanoic acid Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O BWDDKSQGVQKNAM-UHFFFAOYSA-L 0.000 description 8
- 230000015556 catabolic process Effects 0.000 description 8
- BTVVNGIPFPKDHO-UHFFFAOYSA-K cerium(3+);octadecanoate Chemical compound [Ce+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O BTVVNGIPFPKDHO-UHFFFAOYSA-K 0.000 description 8
- 238000006731 degradation reaction Methods 0.000 description 8
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 8
- 229920001903 high density polyethylene Polymers 0.000 description 8
- 239000004700 high-density polyethylene Substances 0.000 description 8
- 229920000573 polyethylene Polymers 0.000 description 8
- 238000012545 processing Methods 0.000 description 7
- 238000007789 sealing Methods 0.000 description 7
- 239000006229 carbon black Substances 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 6
- 239000004594 Masterbatch (MB) Substances 0.000 description 5
- 238000005336 cracking Methods 0.000 description 5
- 239000002035 hexane extract Substances 0.000 description 5
- 229920000092 linear low density polyethylene Polymers 0.000 description 5
- 239000004707 linear low-density polyethylene Substances 0.000 description 5
- 239000005639 Lauric acid Substances 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 230000002906 microbiologic effect Effects 0.000 description 4
- 230000008929 regeneration Effects 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 229920006167 biodegradable resin Polymers 0.000 description 3
- FPILTBXTDIEHAT-UHFFFAOYSA-N boric acid;furan-2,5-dione Chemical compound OB(O)O.O=C1OC(=O)C=C1 FPILTBXTDIEHAT-UHFFFAOYSA-N 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000004185 ester group Chemical group 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 230000001939 inductive effect Effects 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000012271 agricultural production Methods 0.000 description 2
- 235000013361 beverage Nutrition 0.000 description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 2
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000003413 degradative effect Effects 0.000 description 2
- 238000006253 efflorescence Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000006353 environmental stress Effects 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000004811 fluoropolymer Substances 0.000 description 2
- 229920002313 fluoropolymer Polymers 0.000 description 2
- 239000006261 foam material Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000013467 fragmentation Methods 0.000 description 2
- 238000006062 fragmentation reaction Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 230000001976 improved effect Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 239000011344 liquid material Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920000070 poly-3-hydroxybutyrate Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 206010037844 rash Diseases 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- VYMPLPIFKRHAAC-UHFFFAOYSA-N 1,2-ethanedithiol Chemical compound SCCS VYMPLPIFKRHAAC-UHFFFAOYSA-N 0.000 description 1
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 1
- CEFDWZDNAJAKGO-UHFFFAOYSA-N 2-hydroxy-2-sulfoacetic acid Chemical compound OC(=O)C(O)S(O)(=O)=O CEFDWZDNAJAKGO-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- OAIHGOPYZKYSJI-UHFFFAOYSA-L C(CCCCCCCC=C/CCCCCCCC)(=O)O.C(CCCCCCCCCCCCCCCCC)(=O)[O-].[Ca+2].C(CCCCCCCCCCCCCCCCC)(=O)[O-] Chemical compound C(CCCCCCCC=C/CCCCCCCC)(=O)O.C(CCCCCCCCCCCCCCCCC)(=O)[O-].[Ca+2].C(CCCCCCCCCCCCCCCCC)(=O)[O-] OAIHGOPYZKYSJI-UHFFFAOYSA-L 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 1
- 230000005526 G1 to G0 transition Effects 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000006701 autoxidation reaction Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- FANFFPDSASGEBD-UHFFFAOYSA-N ethylidenetin Chemical compound CC=[Sn] FANFFPDSASGEBD-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 229940095686 granule product Drugs 0.000 description 1
- 150000005826 halohydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 235000021374 legumes Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- KWUZCAVKPCRJPO-UHFFFAOYSA-N n-ethyl-4-(6-methyl-1,3-benzothiazol-2-yl)aniline Chemical compound C1=CC(NCC)=CC=C1C1=NC2=CC=C(C)C=C2S1 KWUZCAVKPCRJPO-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 230000002277 temperature effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 1
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Landscapes
- Biological Depolymerization Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
35 | 6 | 4 | 0.8 | 0.1 | 0.3 | 0.3 |
1010 | UV-531 | EAA | 茂金属聚乙烯 | DSTP | 超细炭黑 | - |
0.5 | 0.6 | 10.0 | 41 | 0.8 | 1 | - |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
25 | 7 | 5 | 0.7 | 0.1 | 0.2 | 0.2 |
硬脂酸 | 普通PE | EAA | 茂金属PE | 马来酸酐 | 硼酸 | - |
1.8 | 20 | 12 | 25 | 2 | 1 | - |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸钙 |
45 | 3 | 2 | 0.5 | 0.2 | 0.5 |
硬脂酸钙 | 硬脂酸锌 | 马来酸酐 | 硼酸 | EAA | 茂金属PE |
0.2 | 0.2 | 0.2 | 0.2 | 15 | 33 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
25 | 7 | 5 | 0.7 | 0.1 | 0.2 | 0.2 |
1010 | RWS-784 | EAA | 茂金属聚乙烯 | - | UV-531 | 超细炭黑 |
0.4 | 1 | 14 | 45.4 | - | 0.2 | 0.8 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
35 | 5.5 | 3.5 | 1.5 | - | 0.2 | 0.2 |
硬脂酸 | 京锡-8831 | EAA | 茂金属聚乙烯 | - | 双酚A | 超细炭黑 |
- | 1.4 | 18 | 33.7 | - | 0.5 | 0.5 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
20 | 7 | 5 | 2 | 1 | 0.25 | 0.25 |
硬脂酸 | EAA | 茂金属聚乙烯 | - | 马来酸酐 | 硼酸 | |
0.5 | 8 | 53 | - | 2 | 1 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
30 | 6 | 4 | 1.5 | 1 | 0.25 | 0.25 |
硬脂酸 | EAA | 茂金属聚乙烯 | - | 马来酸酐 | 硼酸 | |
0.5 | 12 | 40.5 | - | 2.5 | 1.5 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
40 | 5 | 3 | 2 | 1 | 0.25 | 0.25 |
硬脂酸 | EAA | 茂金属聚乙烯 | - | 马来酸酐 | 硼酸 | |
0.5 | - | 17 | 28 | - | 2 | 1 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
20 | 7 | 5 | 2 | 1 | 0.25 | 0.25 |
硬脂酸 | 垃圾袋加再生PE | EAA | 茂金属聚乙烯 | - | 马来酸酐 | 硼酸 |
0.5 | 10 | 8 | 43 | - | 2 | 1 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
30 | 6 | 4 | 1.5 | 1 | 0.25 | 0.25 |
硬脂酸 | HDPE | EAA | 茂金属聚乙烯 | - | 马来酸酐 | 硼酸 |
0.5 | 10.5 | 12 | 30 | - | 2.5 | 1.5 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
40 | 5 | 3 | 2 | 1 | 0.25 | 0.25 |
硬脂酸 | HDPE | EAA | 茂金属聚乙烯 | - | 马来酸酐 | 硼酸 |
0.5 | 5 | 17 | 24.5 | - | 1 | 0.5 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
20 | 7 | 5 | 2 | 1 | 0.25 | 0.25 |
硬脂酸 | 金属铝粉≥300目 | EAA | 茂金属聚乙烯 | HDPE | 马来酸酐 | 硼酸 |
0.5 | 10 | 8 | 41 | 2 | 2 | 1 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
30 | 6 | 4 | 1.5 | 1 | 0.25 | 0.25 |
硬脂酸 | 金属铝粉≥300 | EAA | 茂金属聚乙烯 | - | 马来酸酐 | 硼酸 |
0.5 | 5 | 12 | 37.5 | - | 1 | 1 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
40 | 4 | 2 | 2 | 1 | 0.25 | 0.25 |
硬脂酸 | 金属铝粉≥300目 | EAA | 茂金属聚乙烯 | - | 马来酸酐 | 硼酸 |
0.5 | 5 | 17 | 26.5 | - | 1 | 0.5 |
项目 | 要求 | 实测数据 |
外观 | 浅黄色颗粒、无异味、异嗅、异物 | |
淀粉含量 % | ≥25 | |
水份含量 % | ≤1.2 | 0.48~1.10 |
熔体流动速率 g/10min | 2.0±0.5 | |
拉伸强度(纵/横) Mpa | ≥14 | 15~32 |
断裂伸长率(纵/横) % | >250 | 300~720 |
直角撕裂强度(纵/横) % | >60 | 70~160 |
微生物降解率14天 % | >16 |
霉菌降解级 21天 级 | ≥2 |
灼烧残渣 % | ≤0.2 |
正己烷提取物 % | ≤4.0 |
高锰酸钾消耗量 mg/L | ≤35.0 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
25 | 5 | 3 | 0.5 | 1 | 0.2 | 0.3 |
硬脂酸 | 二月桂酸二辛基锡 | EAA | 茂金属聚乙烯 | 再生PE | - | - |
1 | 1.5 | 8 | 40 | 14.5 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
40 | 7 | 5 | 1.5 | 1 | 0.2 | 0.3 |
硬脂酸 | 二月桂酸二辛基锡 | EAA | 茂金属聚乙烯 | 再生PE | - | - |
1.5 | 2 | 15 | 22 | 3.5 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
55 | 6 | 3 | 0.5 | 0.5 | 0.2 | 0.3 |
硬脂酸 | 二月桂酸二辛基锡 | EAA | 茂金属聚乙烯 | - | - | - |
1 | 1 | 15 | 17.5 | - | - | - |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
30 | 6 | 4 | 1.8 | 2 | 0.3 | 0.4 |
硬脂酸 | 京锡-8831 | EAA | 茂金属聚乙烯 | - | - | - |
1 | 1.5 | 10 | 43 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
40 | 7 | 5 | 2.5 | 1.5 | 0.2 | 0.3 |
硬脂酸 | 二月桂酸二辛基锡 | EAA | 茂金属聚乙烯 | - | - | - |
1.5 | 2 | 15 | 25 | - |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 油酸 | 硬脂酸锌 | 硬脂酸钙 |
50 | 5 | 3 | 1 | 0.5 | 0.2 | 0.3 |
硬脂酸 | 酯基錫RWS-784 | EAA | 茂金属聚乙烯 | - | - | - |
1 | 1 | 18 | 20 | - | - | - |
项目 | |||||
密封试验 | ***漏 | ||||
跌落试验 | 无破损、不蹦盖、撞击时允许桶口部有少量液体,之后不得渗漏 | ||||
悬挂试验 | 公称容量,L | 1~5 | 10~15 | 20~40 | 50~200 |
残留变形量,mm | ≤2 | ≤3 | ≤4 | 不裂 | |
堆码试验 | 不倒堆 | ||||
应力开裂试验 | 开裂的试样数(桶体、盖)<投入试验试样数50% | ||||
液压试验 | 无破损、***漏 | ||||
微生物降解率14天, % | >10 | ||||
霉菌降解级21天,级 | ≥2级 | ||||
灼烧残渣 % | ≤0.2 | ||||
正己烷提取物 % | ≤4.0 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | TNPP | 硬脂酸铁 |
50 | 5 | 2 | 1 | 0.2 | 0.2 |
EAA | 茂金属聚乙烯 | PP | 二茂铁 | ||
15 | 20 | 6 | 0.6 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | TNPP | 硬脂酸铁 |
40 | 5 | 2.5 | 0.5 | 0.3 | 0.3 |
EAA | 茂金属聚乙烯 | PP | 硬脂酸铁 | ||
12 | 30 | 9 | 0.4 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | TNPP | 硬脂酸铁 |
30 | 6 | 3 | 1 | 0.5 | 0.5 |
EAA | 茂金属聚乙烯 | PP | 二茂铁 | ||
8 | 35.5 | 15 | 0.5 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | TNPP | 硬脂酸铁 |
60 | 5 | 3 | 1 | 0.5 | 0.5 |
EAA | 茂金属聚乙烯 | PP | 二硫代氨基甲酸铁 | ||
12 | 12.5 | 5 | 0.5 |
项目 | 要求 | 实测数据 |
外观 | 浅黄色颗粒、无异味、异嗅、异物 | |
淀粉含量 % | ≥30 | |
水份含量 % | ≤1.2 | 0.2~0.6 |
熔体流动速率 g/10min | 3.2~5.2 | |
简支梁冲击强度 KJ/M2 | ≥25 | |
洛氏硬度(R标尺) | ≥28 | |
拉伸屈服强度(纵/横)Mpa | ≥16 | 18~37 |
维卡软化点 ℃ | ≥100 | |
微生物降解率14天 % | ≥10 | |
霉菌降解级 21天 级 | ≥2级 | |
灼烧残渣 % | ≤0.2 | |
正己烷提取物 % | ≤4.0 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | TNPP | 硬脂酸铁 |
35 | 3 | 6 | 1 | 0.5 | 0.5 |
EAA | 茂金属聚乙烯 | PS | 二茂铁 | 硬脂酸 | 滑石粉 |
10 | 15 | 25.5 | 0.5 | 1 | 3 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | TNPP | 硬脂酸铁 |
30 | 3 | 6 | 1 | 0.5 | 0.5 |
EAA | 茂金属聚乙烯 | PS | 二茂铁 | 硬脂酸 | 滑石粉 |
8 | 20 | 33 | 0.5 | 0.5 | 2.5 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | TNPP | 硬脂酸铁 |
45 | 7 | 3 | 2 | 0.5 | 0.5 |
EAA | 茂金属聚乙烯 | PS | 二茂铁 | 硬脂酸 | 滑石粉 |
12 | 28.5 | - | 0.5 | 0.5 | 0.5 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | TNPP | 硬脂酸铁 |
65 | 5 | 2 | 2 | 0.5 | 0.5 |
EAA | 茂金属聚乙烯 | PS | 二茂铁 | 硬脂酸 | 滑石粉 |
12 | 11.5 | - | 0.5 | 0.5 | 0.5 |
项目 | 要求 | 实测数据 |
外观 | 浅黄色颗粒、无异味、异嗅、异物 | |
淀粉含量 % | ≥25 | |
水份含量 % | ≤1.0 | 0.2~0.8 |
熔体流动速率 g/10min | 2.3~3.8 | |
简支梁冲击强度 KJ/M2 | ≥6.0 | |
屈服强度(纵/横) Mpa | ≥35 | 35~58 |
维卡软化点 ℃ | ≥90 | |
降解质量损失率28天% | ≥35 | |
霉菌降解级 21天 级 | ≥2级 | |
挥发物 % | ≤1.8 | |
干燥失重 % | ≤0.5 | |
正己烷提取物 % | ≤1.5 |
淀粉 | 木粉 | 山梨糖醇 | 油 | 环氧大豆油 | TNPP | 硬脂酸铁 | ||
20 | 10 | 5 | 2 | 2 | 1 | 1 | ||
EAA | 茂金属聚乙烯 | PS | 二茂铁 | SBS | 硬脂酸 | 玻璃纤维 | 滑石粉 | |
8 | 25 | 6 | 0.5 | 5 | 0.5 | 4 | 10 |
淀粉 | 木粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | TNPP | 硬脂酸铁 | ||
30 | 10 | 6 | 2 | 1 | 3.5 | 0.5 | ||
EAA | 茂金属聚乙烯 | PS | 二茂铁 | SBS | 硬脂酸 | 玻璃纤维 | 滑石粉 | |
10 | 15 | 3 | 0.5 | 2 | 0.5 | 1 | 8 |
淀粉 | 贝壳粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | TNPP | 硬脂酸铁 | ||
30 | 30 | 7 | 2 | 1 | 0.5 | 0.5 | ||
EAA | 茂金属聚乙烯 | PS | 二茂铁 | SBS | 硬脂酸 | 玻璃纤维 | 滑石粉 | |
10 | 13 | 2 | 0.5 | - | 0.5 | 1 | 2 |
淀粉 | 木粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | TNPP | 硬脂酸铁 | ||
60 | 10 | 3 | 1 | 6 | 3.5 | 0.5 | ||
EAA | 茂金属聚乙烯 | PS | 二茂铁 | SBS | 硬脂酸 | 玻璃纤维 | 滑石粉 | |
9 | 8 | - | 0.5 | - | 0.5 | - | 1 |
项目 | 要求 | 实测数据 |
外观 | 浅黄色颗粒、无异味、异嗅、异物 | |
淀粉含量 % | ≥45 | |
水份含量 % | ≤3.0 | 0.9~2.8 |
熔体流动速率 g/10min | 0.3~3.0 | |
微生物降解率 14天 % | ≥40 | |
霉菌降解级 21天 级 | ≥3级 | |
灼烧残渣 % | ≤1.5 | |
正己烷提取物 % | ≤4.0 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 硬脂酸 | 硬脂酸钙 |
60 | 6 | 2 | 1 | 0.5 | 0.5 |
硬脂酸铁 | RWS-784 | 硬脂酸铈 | EAA | 茂金属聚乙烯 | - |
0.5 | 0.5 | 1 | 12 | 15 | - |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 硬脂酸 | 硬脂酸钙 |
50 | 7 | 2 | 1 | 0.5 | 0.5 |
硬脂酸铁 | RWS-784 | 硬脂酸铈 | EAA | 茂金属聚乙烯 | - |
0.5 | 0.5 | 1 | 12 | 25 | - |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 硬脂酸 | 硬脂酸钙 |
60 | 6 | 2 | 1 | 0.5 | 0.5 |
硬脂酸铁 | RWS-784 | 硬脂酸铈 | EAA | 茂金属聚乙烯 | PP |
0.5 | 0.5 | 1 | 10 | 12 | 6 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 硬脂酸 | 硬脂酸钙 |
50 | 6 | 2 | 1 | 0.5 | 0.5 |
硬脂酸铁 | RWS-784 | 硬脂酸铈 | EAA | 茂金属聚乙烯 | PP |
0.5 | 0.5 | 1 | 12 | 15 | 11 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 硬脂酸 | 硬脂酸钙 |
50 | 7 | 2 | 1 | 0.5 | 0.5 |
硬脂酸铁 | RWS-784 | 硬脂酸铈 | EAA | 茂金属聚乙烯 | PS |
0.5 | 0.5 | 1 | 13 | 15 | 10 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 硬脂酸 | 硬脂酸钙 |
40 | 5 | 2 | 1 | 0.5 | 0.5 |
硬脂酸铁 | RWS-784 | 硬脂酸铈 | EAA | 茂金属聚乙烯 | PS |
0.5 | 0.5 | 1 | 12 | 17 | 19 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 硬脂酸 | 硬脂酸钙 |
70 | 6 | 2 | 1 | 0.5 | 0.5 |
硬脂酸铁 | RWS-784 | 硬脂酸铈 | EAA | 茂金属聚乙烯 | 木粉 |
0.5 | 0.5 | 1 | 10 | 5 | 3 |
淀粉 | 山梨糖醇 | 甘油 | 环氧大豆油 | 硬脂酸 | 硬脂酸钙 |
60 | 6 | 2 | 1 | 0.5 | 0.5 |
硬脂酸铁 | RWS-784 | 硬脂酸铈 | EAA | 茂金属聚乙烯 | 木粉 |
0.5 | 0.5 | 1 | 10 | 10 | 8 |
Claims (11)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN00100127A CN1114653C (zh) | 2000-01-12 | 2000-01-12 | 可生物降解的树脂组合物及其制备方法和应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN00100127A CN1114653C (zh) | 2000-01-12 | 2000-01-12 | 可生物降解的树脂组合物及其制备方法和应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1267680A CN1267680A (zh) | 2000-09-27 |
CN1114653C true CN1114653C (zh) | 2003-07-16 |
Family
ID=4575258
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN00100127A Expired - Fee Related CN1114653C (zh) | 2000-01-12 | 2000-01-12 | 可生物降解的树脂组合物及其制备方法和应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1114653C (zh) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1307246C (zh) * | 2003-11-07 | 2007-03-28 | 李小鲁 | 含淀粉的全生物降解的吹塑成型树脂组合物及其制备方法 |
CN102115549B (zh) * | 2010-12-13 | 2012-09-05 | 北京新华联生物材料有限公司 | 可生物降解的含淀粉的高分子组合物及其制备 |
CN102134333B (zh) * | 2010-12-13 | 2013-04-17 | 北京宜科博泰生态科技有限公司 | 高强度生物降解热塑性淀粉树脂及其制备方法和应用 |
CN104098920B (zh) * | 2014-05-16 | 2016-11-16 | 苏州格瑞惠农膜材料科技有限公司 | 一种草粉基可降解农用地膜及其制备方法 |
CN103980548B (zh) * | 2014-05-16 | 2016-06-15 | 江苏省农业科学院 | 一种淀粉基可降解农用地膜及其制备方法 |
CN104031313A (zh) * | 2014-06-27 | 2014-09-10 | 柳州市汉森机械制造有限公司 | 塑料地膜 |
CN104277335A (zh) * | 2014-09-24 | 2015-01-14 | 苏州博利迈新材料科技有限公司 | 一种耐高温耐老化降解可控pp膜及其制备方法 |
CN104672504A (zh) * | 2015-02-02 | 2015-06-03 | 安徽玉堂雨具有限公司 | 一种防静电生物降解塑料及其制备方法 |
CN104672505A (zh) * | 2015-02-02 | 2015-06-03 | 安徽玉堂雨具有限公司 | 一种含废瓷粉的生物降解塑料及其制备方法 |
CN104650388A (zh) * | 2015-02-02 | 2015-05-27 | 安徽玉堂雨具有限公司 | 一种阻燃生物降解塑料及其制备方法 |
CN104725672A (zh) * | 2015-04-14 | 2015-06-24 | 苏州靖羽新材料有限公司 | 具有抗氧化功能的食品用环保包装材料及其制备方法 |
CN104893073A (zh) * | 2015-06-17 | 2015-09-09 | 道真自治县黔福现代农业开发有限责任公司 | 用于洛党参的地膜及其生产工艺 |
CN106307760A (zh) * | 2016-08-17 | 2017-01-11 | 安徽兴源塑料包装有限公司 | 一种塑料花卉 |
CN107266791A (zh) * | 2017-08-01 | 2017-10-20 | 界首市宏利塑料有限公司 | 一种老人使用的塑料勺子 |
CN110804216A (zh) * | 2019-11-29 | 2020-02-18 | 湖南工业大学 | 一种薄膜级淀粉基复合材料及其制备方法 |
CN114106418B (zh) * | 2020-08-27 | 2023-05-30 | 上海昶法新材料有限公司 | 塑化淀粉、生物基塑料及其原料组合物、制备方法和应用 |
CN112795081A (zh) * | 2021-02-04 | 2021-05-14 | 潍坊众合安美包装科技有限公司 | 降解手指隔离膜 |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1988006609A1 (en) * | 1987-02-27 | 1988-09-07 | Amrotex Ag | Degradable synthetic compositions |
EP0408502A2 (en) * | 1989-07-11 | 1991-01-16 | Warner-Lambert Company | Polymer base blend compositions containing destructurized starch |
EP0444880A2 (en) * | 1990-02-28 | 1991-09-04 | Director-General Of The Agency Of Industrial Science And Technology | Biodecomposable or biodisintegrable moldable material |
WO1991015542A1 (en) * | 1990-04-06 | 1991-10-17 | Agri-Tech Industries, Inc. | Starch-based degradable plastic containing polypropylene glycol |
CN1122815A (zh) * | 1995-08-28 | 1996-05-22 | 叶永成 | 光和生物双降解母料 |
CN1138598A (zh) * | 1995-06-15 | 1996-12-25 | 徐朝臣 | 一种生物和光可控双降解pe膜的配方及其生产工艺 |
EP0781087A1 (de) * | 1994-09-14 | 1997-07-02 | SAME S.p.A. | Selbstfahrende erntemaschine |
JPH1112379A (ja) * | 1997-06-25 | 1999-01-19 | Toyo Purasuto:Kk | 生分解樹脂発泡体 |
US5861461A (en) * | 1995-12-06 | 1999-01-19 | Yukong Limited | Biodegradable plastic composition, method for preparing thereof and product prepared therefrom |
CN1239725A (zh) * | 1999-06-22 | 1999-12-29 | 沈阳南阳经贸集团有限公司 | 多元降解树脂组合物及其制备方法 |
-
2000
- 2000-01-12 CN CN00100127A patent/CN1114653C/zh not_active Expired - Fee Related
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1988006609A1 (en) * | 1987-02-27 | 1988-09-07 | Amrotex Ag | Degradable synthetic compositions |
EP0408502A2 (en) * | 1989-07-11 | 1991-01-16 | Warner-Lambert Company | Polymer base blend compositions containing destructurized starch |
EP0444880A2 (en) * | 1990-02-28 | 1991-09-04 | Director-General Of The Agency Of Industrial Science And Technology | Biodecomposable or biodisintegrable moldable material |
WO1991015542A1 (en) * | 1990-04-06 | 1991-10-17 | Agri-Tech Industries, Inc. | Starch-based degradable plastic containing polypropylene glycol |
EP0781087A1 (de) * | 1994-09-14 | 1997-07-02 | SAME S.p.A. | Selbstfahrende erntemaschine |
CN1138598A (zh) * | 1995-06-15 | 1996-12-25 | 徐朝臣 | 一种生物和光可控双降解pe膜的配方及其生产工艺 |
CN1122815A (zh) * | 1995-08-28 | 1996-05-22 | 叶永成 | 光和生物双降解母料 |
US5861461A (en) * | 1995-12-06 | 1999-01-19 | Yukong Limited | Biodegradable plastic composition, method for preparing thereof and product prepared therefrom |
JPH1112379A (ja) * | 1997-06-25 | 1999-01-19 | Toyo Purasuto:Kk | 生分解樹脂発泡体 |
CN1239725A (zh) * | 1999-06-22 | 1999-12-29 | 沈阳南阳经贸集团有限公司 | 多元降解树脂组合物及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN1267680A (zh) | 2000-09-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1114653C (zh) | 可生物降解的树脂组合物及其制备方法和应用 | |
CN1058736C (zh) | 生物降解组合物及其制备方法和应用 | |
CN101805499B (zh) | 一种全降解热塑复合材料及其片材 | |
CN1296432C (zh) | 乳酸基树脂组合物 | |
CN100338132C (zh) | 全生物分解组合物及其制备方法和用途 | |
CN1074435C (zh) | 多元降解树脂组合物及其制备方法 | |
EP4379000A1 (en) | Biodegradable resin composition, and biodegradable film and biodegradable mulching film each using same | |
KR101436916B1 (ko) | 식물체 바이오매스를 이용한 친환경 사출 성형품 및 그 제조방법 | |
CN101993558A (zh) | 用淀粉纤维废塑料生产薄膜 | |
CN1946807A (zh) | 生物降解性树脂组合物 | |
KR102509689B1 (ko) | 개선된 인성을 갖는 열가소성 조성물, 이로부터의 물품 및 이의 방법 | |
US20090149606A1 (en) | Degradable plastic composition and methods | |
CN1665882A (zh) | 聚酯共混物组合物和由其生产的生物可降解薄膜 | |
CN101717537A (zh) | 一种聚烯烃薄膜及其制造方法 | |
CN113583405A (zh) | 一种高性能全降解复合材料及其制备方法 | |
CN101942114B (zh) | 一种注塑用生物降解淀粉树脂及其制备方法和制品 | |
KR102058394B1 (ko) | 친환경 바이오 필름 봉투의 제조방법 및 이로부터 수득된 필름 봉투 | |
CN109988400A (zh) | 一种环保型可降解包装复合膜及其制备方法 | |
RU2418014C1 (ru) | Биологически разрушаемая термопластичная композиция с использованием природного наполнителя | |
CN1613901A (zh) | 含淀粉的全生物降解的吹塑成型树脂组合物及其制备方法 | |
TWI598389B (zh) | 新型低碳排可降解片材及其製品 | |
CN108129807A (zh) | 一种可生物降解功能母料组合物及其制备方法 | |
CN1916062A (zh) | 可生物降解的含淀粉树脂组合物和制品及制备方法 | |
CN1272304A (zh) | 一种新型双料农用地膜及其制备方法 | |
CN107266760A (zh) | 一种可降解秸秆聚乙烯膜及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C06 | Publication | ||
PB01 | Publication | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: BEIJING HUABO ANSHI DEGRADATION MATERIAL CO., LTD Free format text: FORMER OWNER: LI XIAOLU Effective date: 20060623 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20060623 Address after: 100071 316/318 room (Park), No. 80 West Fourth Ring Road, Beijing, Fengtai District Co-patentee after: Li Xiaolu Patentee after: Beijing Hua Shi Bo degradation material Co. Ltd. Address before: 100039 box 83, box 132, Beijing, Haidian District Patentee before: Li Xiaolu |
|
C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20030716 Termination date: 20110112 |