CN1420910A - 基于抗冲击性改进的聚对苯二甲酸乙二醇酯/聚碳酸酯共混物的组合物 - Google Patents
基于抗冲击性改进的聚对苯二甲酸乙二醇酯/聚碳酸酯共混物的组合物 Download PDFInfo
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- CN1420910A CN1420910A CN00818190.XA CN00818190A CN1420910A CN 1420910 A CN1420910 A CN 1420910A CN 00818190 A CN00818190 A CN 00818190A CN 1420910 A CN1420910 A CN 1420910A
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- 239000002243 precursor Substances 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 150000003336 secondary aromatic amines Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 229940071182 stannate Drugs 0.000 description 1
- 125000005402 stannate group Chemical group 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Description
实施例 | 1 | 2 | 3 | |
聚碳酸酯 | [%] | 40 | 40 | 40 |
聚对苯二甲酸乙二醇酯,类型2 | [%] | 29.2 | 24.2 | 19.2 |
接枝橡胶 | [%] | 10 | 15 | 20 |
滑石,类型1 | [%] | 20 | 20 | 20 |
添加剂 | [%] | 0.8 | 0.8 | 0.8 |
Vicat B | [℃] | 143 | 140 | 134 |
HDT A | [℃] | 111 | 111 | 109 |
伊佐德冲击韧性23℃ | [kJ/m2] | 77 | 116 | 119 |
伊佐德冲击韧性-10℃ | [kJ/m2] | 80 | 67 | 123 |
伊佐德冲击韧性-20℃ | [kJ/m2] | 70 | 69 | 92 |
拉伸模量 | [MPa] | 4500 | 3940 | 3560 |
断裂伸长率 | [%] | 8 | 14 | 13 |
线性热膨胀系数(l/tr) | [10-6/K] | 54/84 | 44/76 | 41/66 |
MVR(280℃/2.16kg) | [cm3/10min] | 9 | 4 | 2 |
表面质量 | ++ | ++ | ++ |
实施例 | 4 | 5 | 6 | 7 | |
聚碳酸酯 | [%] | 50 | 50 | 50 | 50 |
聚对苯二甲酸乙二醇酯,类型1 | [%] | 27.1 | 22.1 | 17.1 | 12.1 |
接枝橡胶 | [%] | 12 | 12 | 12 | 12 |
滑石,类型1 | [%] | 10 | 15 | 20 | 25 |
添加剂 | [%] | 0.9 | 0.9 | 0.9 | 0.9 |
Vicat B | [℃ ] | 140 | 142 | 140 | 138 |
HDT A | [℃] | 101 | 106 | 118 | 120 |
伊佐德冲击韧性23℃ | [kJ/m2] | n.b. | 49 | 62 | 81 |
伊佐德冲击韧性-10℃ | [kJ/m2] | - | 59 | 59 | 87 |
伊佐德冲击韧性-20℃ | [kJ/m2] | n.b. | 53 | 62 | 55 |
拉伸模量 | [MPa] | 3000 | 3630 | 4040 | 4190 |
断裂伸长率 | [%] | 47 | 6 | 8 | 7 |
线性热膨胀系数(l/tr) | [10-6/K] | 59/85 | 54/76 | 48/81 | 47/72 |
MVR(280℃/2.16kg) | [cm3/10min] | 12 | 15 | 5 | 3 |
表面质量 | ++ | ++ | ++ | ++ |
实施例 | 8 | 9 | 10 | |
聚碳酸酯 | [%] | 40 | 40 | 40 |
聚对苯二甲酸乙二醇酯,类型1 | [%] | 37.1 | 32.1 | 27.1 |
接枝橡胶 | [%] | 12 | 12 | 12 |
滑石,类型1 | [%] | 10 | 15 | 20 |
添加剂 | [%] | 0.9 | 0.9 | 0.9 |
Vicat B | [℃] | 140 | 141 | 140 |
HDT A | [℃] | 98 | 103 | 111 |
伊佐德冲击韧性23℃ | [kJ/m2] | n.b. | 174 | 58 |
伊佐德冲击韧性-10℃ | [kJ/m2] | 167 | 87 | 56 |
伊佐德冲击韧性-20℃ | [kJ/m2] | 156 | 93 | 62 |
拉伸模量 | [MPa] | 3090 | 3610 | 4140 |
断裂伸长率 | [%] | 22 | 20 | 8 |
线性热膨胀系数(l/tr) | [10-6/K] | 73/81 | 69/78 | 50/71 |
MVR(280℃/2.16kg) | [cm3/10min] | 16 | 12 | 9 |
表面质量 | ++ | ++ | ++ |
实施例 | 11 | 12 | 13 | |
聚碳酸酯 | [%] | 30 | 30 | 30 |
聚对苯二甲酸乙二醇酯,类型1 | [%] | 47.1 | 42.1 | 37.1 |
接枝橡胶 | [%] | 12 | 12 | 12 |
滑石,类型1 | [%] | 10 | 15 | 20 |
添加剂 | [%] | 0.9 | 0.9 | 0.9 |
Vicat B | [℃] | 142 | 142 | 141 |
HDT A | [℃] | 90 | 93 | 106 |
伊佐德冲击韧性23℃ | [kJ/m2] | 73 | 67 | 24 |
伊佐德冲击韧性-10℃ | [kJ/m2] | 66 | 63 | 32 |
伊佐德冲击韧性-20℃ | [kJ/m2] | 63 | 57 | 33 |
拉伸模量 | [MPa] | 3140 | 3680 | 4300 |
断裂伸长率 | [%] | 8 | 5 | 3 |
线性热膨胀系数(l/tr) | [10-6/K] | 66/90 | 62/60 | 48/72 |
MVR(280℃/2.16kg) | [cm3/10min] | 22 | 17 | 12 |
表面质量 | ++ | ++ | ++ |
实施例 | 14 | 15 | 16 | 17 | 18 | 19 | |
聚碳酸酯 | [%] | 50 | 50 | 50 | 50 | 50 | 50 |
聚对苯二甲酸乙二醇酯,类型1 | [%] | 27.2 | 27.2 | 27.2 | -- | -- | -- |
聚对苯二甲酸乙二醇酯,类型2 | [%] | -- | -- | -- | 27.2 | 27.2 | 27.2 |
接枝橡胶 | [%] | 12 | 12 | 12 | 12 | 12 | 12 |
滑石,类型1 | [%] | 10 | -- | -- | 10 | -- | -- |
滑石,类型2 | [%] | -- | 10 | -- | -- | 10 | -- |
滑石,类型3 | [%] | -- | -- | 10 | -- | -- | 10 |
添加剂 | [%] | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 |
Vicat B | [℃] | 140 | 140 | 138 | 139 | 139 | 138 |
HDT A | [℃] | 107 | -- | -- | 105 | -- | -- |
伊佐德冲击韧性23℃ | [kJ/m2] | n.b. | n.b. | 166 | n.b. | n.b. | n.b. |
伊佐德冲击韧性-10℃ | [kJ/m2] | -- | 286 | -- | -- | -- | -- |
伊佐德冲击韧性-20℃ | [kJ/m2] | n.b. | 198 | 122 | n.b. | n.b. | 127 |
拉伸模量 | [MPa] | 3020 | 3040 | 3040 | 3020 | 2990 | 2990 |
断裂伸长率 | [%] | 43 | 33 | 15 | 38 | 44 | 19 |
MVR(280℃/2.16kg) | [cm3/10min] | 11 | 10 | 11 | 7 | 8 | 8 |
表面质量 | ++ | ++ | ++ | ++ | ++ | ++ |
实施例 | 20 | 21 | 22 | 23 | 24 | |
聚碳酸酯 | [%] | 47 | 47 | 50 | 50 | 43 |
聚对苯二甲酸乙二醇酯,类型2 | [%] | 34.2 | 34.2 | 27.2 | 26.9 | 21.3 |
嵌段共聚物,类型1 | [%] | 12 | 0 | 12 | 0 | 15 |
嵌段共聚物,类型2 | [%] | 0 | 12 | 0 | 12 | 0 |
滑石,类型1 | [%] | 3 | 3 | 10 | 10 | 20 |
添加剂 | [%] | 0.8 | 0.8 | 0.8 | 1.1 | 0.7 |
Vicat B | [℃] | 136 | 133 | 140 | 138 | 140 |
HDT A | [℃] | 90 | 95 | 107 | 108 | 112 |
伊佐德冲击韧性23℃ | [kJ/m2] | n.b. | n.b. | n.b. | n.b. | 92 |
伊佐德冲击韧性-10℃ | [kJ/m2] | n.b. | n.b. | n.b. | n.b. | 79 |
伊佐德冲击韧性-20℃ | [kJ/m2] | n.b. | n.b. | n.b. | n.b. | 76 |
拉伸模量 | [MPa] | 2200 | 2190 | 2900 | 2900 | 3940 |
断裂伸长率 | [%] | 110 | 120 | 50 | 54 | 9 |
线性热膨胀系数(l/tr) | [10-6/K] | - | - | 71/82 | - | 53/65 |
MVR(280℃/2.16kg) | [cm3/10min] | 24 | 27 | 21 | 24 | 11 |
表面质量 | ++ | ++ | ++ | ++ | ++ |
Claims (18)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19953545.0 | 1999-11-08 | ||
DE19953545 | 1999-11-08 | ||
DE10016190.1 | 2000-03-31 | ||
DE10016190A DE10016190A1 (de) | 1999-11-08 | 2000-03-31 | Zusammensetzungen auf Basis schlagzähmodifizierten Polyethylenterephthalat/Polycarbonat Blends |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1420910A true CN1420910A (zh) | 2003-05-28 |
CN100467537C CN100467537C (zh) | 2009-03-11 |
Family
ID=26005134
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB00818190XA Expired - Fee Related CN100467537C (zh) | 1999-11-08 | 2000-10-26 | 基于抗冲击性改进的聚对苯二甲酸乙二醇酯/聚碳酸酯共混物的组合物 |
Country Status (14)
Country | Link |
---|---|
EP (1) | EP1232216B1 (zh) |
JP (1) | JP2003514094A (zh) |
CN (1) | CN100467537C (zh) |
AR (1) | AR026297A1 (zh) |
AT (1) | ATE346119T1 (zh) |
AU (1) | AU779213B2 (zh) |
BR (1) | BR0015378B1 (zh) |
CA (1) | CA2390124A1 (zh) |
CZ (1) | CZ20021583A3 (zh) |
DE (1) | DE50013789D1 (zh) |
ES (1) | ES2275559T3 (zh) |
HU (1) | HUP0203481A2 (zh) |
PL (1) | PL355755A1 (zh) |
WO (1) | WO2001034703A1 (zh) |
Cited By (6)
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CN1882656B (zh) * | 2003-11-18 | 2011-01-26 | 拜尔材料科学股份公司 | 基于冲击改性聚对苯二甲酸亚烷二醇酯/聚碳酸酯共混物的均匀模塑色和耐天候稳定组合物 |
CN101142277B (zh) * | 2005-03-16 | 2011-04-13 | 帝人化成株式会社 | 树脂组合物 |
CN101861657B (zh) * | 2007-11-16 | 2012-07-11 | 大仓工业株式会社 | 太阳能电池组件用背面保护片以及用它保护的太阳能电池组件 |
CN103772934A (zh) * | 2012-10-22 | 2014-05-07 | 黑龙江鑫达企业集团有限公司 | 一种高抗冲、高耐热pc/pbt合金材料及其制备工艺 |
CN105838051A (zh) * | 2015-01-16 | 2016-08-10 | 苏州汉扬精密电子有限公司 | Pc/pet复合材料及其产品 |
CN109135204A (zh) * | 2018-08-13 | 2019-01-04 | 四川大学 | 一种自增强透明pet/pc合金及其制备方法 |
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US6500890B2 (en) | 2000-12-15 | 2002-12-31 | Wellman, Inc. | Polyester bottle resins having reduced frictional properties and methods for making the same |
USH2132H1 (en) | 2001-06-29 | 2005-11-01 | Eastman Chemical Company | Polyester containers having a reduced coefficient of friction |
CN1312200C (zh) † | 2003-05-12 | 2007-04-25 | 帝人化成株式会社 | 片状窗构件以及窗结构体 |
US7718733B2 (en) * | 2004-12-20 | 2010-05-18 | Sabic Innovative Plastics Ip B.V. | Optically clear polycarbonate polyester compositions |
US20060270767A1 (en) * | 2005-05-26 | 2006-11-30 | Van Gisbergen Josephus Gerardu | Mineral filled polyester polycarbonate composition |
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KR20230125822A (ko) | 2021-01-04 | 2023-08-29 | 사빅 글로벌 테크놀러지스 비.브이. | 내열성 방향족 폴리카르보네이트-폴리에스테르 조성물 |
CN114292499B (zh) * | 2021-11-30 | 2023-09-08 | 广东基烁新材料股份有限公司 | 一种petg导电母粒及其制备方法和应用 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3337295A1 (de) * | 1983-07-28 | 1985-02-07 | Bayer Ag, 5090 Leverkusen | Thermoplastische formmassen |
JPS6248760A (ja) * | 1985-08-27 | 1987-03-03 | Nissan Motor Co Ltd | 成形用熱可塑性組成物 |
JPH06271754A (ja) * | 1993-03-17 | 1994-09-27 | Mitsubishi Kasei Corp | 難燃性ポリカーボネート樹脂組成物 |
JP3278082B2 (ja) * | 1993-04-08 | 2002-04-30 | 電気化学工業株式会社 | 熱可塑性樹脂組成物およびその製造方法 |
JP3002394B2 (ja) * | 1994-10-31 | 2000-01-24 | 出光石油化学株式会社 | ポリカーボネート樹脂組成物及びそれを用いた自動車外装部材 |
-
2000
- 2000-10-26 ES ES00975924T patent/ES2275559T3/es not_active Expired - Lifetime
- 2000-10-26 AU AU13879/01A patent/AU779213B2/en not_active Ceased
- 2000-10-26 JP JP2001537408A patent/JP2003514094A/ja active Pending
- 2000-10-26 WO PCT/EP2000/010549 patent/WO2001034703A1/de active IP Right Grant
- 2000-10-26 CA CA002390124A patent/CA2390124A1/en not_active Abandoned
- 2000-10-26 PL PL00355755A patent/PL355755A1/xx not_active Application Discontinuation
- 2000-10-26 CZ CZ20021583A patent/CZ20021583A3/cs unknown
- 2000-10-26 BR BRPI0015378-8A patent/BR0015378B1/pt not_active IP Right Cessation
- 2000-10-26 CN CNB00818190XA patent/CN100467537C/zh not_active Expired - Fee Related
- 2000-10-26 AT AT00975924T patent/ATE346119T1/de not_active IP Right Cessation
- 2000-10-26 HU HU0203481A patent/HUP0203481A2/hu unknown
- 2000-10-26 EP EP00975924A patent/EP1232216B1/de not_active Expired - Lifetime
- 2000-10-26 DE DE50013789T patent/DE50013789D1/de not_active Expired - Lifetime
- 2000-10-30 AR ARP000105720A patent/AR026297A1/es unknown
Cited By (8)
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CN1882656B (zh) * | 2003-11-18 | 2011-01-26 | 拜尔材料科学股份公司 | 基于冲击改性聚对苯二甲酸亚烷二醇酯/聚碳酸酯共混物的均匀模塑色和耐天候稳定组合物 |
TWI404762B (zh) * | 2003-11-18 | 2013-08-11 | Bayer Materialscience Ag | 可耐候之均勻著色的模塑組成物 |
CN101142277B (zh) * | 2005-03-16 | 2011-04-13 | 帝人化成株式会社 | 树脂组合物 |
CN101861657B (zh) * | 2007-11-16 | 2012-07-11 | 大仓工业株式会社 | 太阳能电池组件用背面保护片以及用它保护的太阳能电池组件 |
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Also Published As
Publication number | Publication date |
---|---|
AU1387901A (en) | 2001-06-06 |
DE50013789D1 (de) | 2007-01-04 |
CA2390124A1 (en) | 2001-05-17 |
AU779213B2 (en) | 2005-01-13 |
CN100467537C (zh) | 2009-03-11 |
CZ20021583A3 (cs) | 2002-08-14 |
EP1232216B1 (de) | 2006-11-22 |
ATE346119T1 (de) | 2006-12-15 |
AR026297A1 (es) | 2003-02-05 |
WO2001034703A1 (de) | 2001-05-17 |
EP1232216A1 (de) | 2002-08-21 |
JP2003514094A (ja) | 2003-04-15 |
BR0015378A (pt) | 2002-07-09 |
BR0015378B1 (pt) | 2011-05-17 |
ES2275559T3 (es) | 2007-06-16 |
HUP0203481A2 (en) | 2003-01-28 |
PL355755A1 (en) | 2004-05-17 |
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