CN1389524A - 亲水性改性剂,亲水性改性方法和借此改性亲水性的铝材料或铝合金材料 - Google Patents
亲水性改性剂,亲水性改性方法和借此改性亲水性的铝材料或铝合金材料 Download PDFInfo
- Publication number
- CN1389524A CN1389524A CN02108070A CN02108070A CN1389524A CN 1389524 A CN1389524 A CN 1389524A CN 02108070 A CN02108070 A CN 02108070A CN 02108070 A CN02108070 A CN 02108070A CN 1389524 A CN1389524 A CN 1389524A
- Authority
- CN
- China
- Prior art keywords
- mentioned
- hydrophilic modifier
- hydrophilic
- free radical
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003607 modifier Substances 0.000 title claims abstract description 72
- 239000000463 material Substances 0.000 title claims abstract description 38
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 21
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 12
- 238000000034 method Methods 0.000 title claims description 27
- 239000000956 alloy Substances 0.000 title abstract description 6
- 239000004411 aluminium Substances 0.000 title description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims description 52
- 150000003254 radicals Chemical class 0.000 claims description 49
- 150000005846 sugar alcohols Polymers 0.000 claims description 49
- 238000009736 wetting Methods 0.000 claims description 47
- -1 phosphorus compound salt Chemical class 0.000 claims description 42
- 238000000576 coating method Methods 0.000 claims description 31
- 239000011248 coating agent Substances 0.000 claims description 29
- 239000002245 particle Substances 0.000 claims description 27
- 150000002894 organic compounds Chemical class 0.000 claims description 21
- 239000000758 substrate Substances 0.000 claims description 19
- 239000007787 solid Substances 0.000 claims description 17
- 229910052698 phosphorus Inorganic materials 0.000 claims description 16
- 239000011574 phosphorus Substances 0.000 claims description 15
- 239000011347 resin Substances 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 15
- 238000012545 processing Methods 0.000 claims description 12
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 11
- 239000007822 coupling agent Substances 0.000 claims description 11
- 239000003431 cross linking reagent Substances 0.000 claims description 11
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 11
- 238000007127 saponification reaction Methods 0.000 claims description 10
- 238000005253 cladding Methods 0.000 claims description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 125000003368 amide group Chemical group 0.000 claims description 2
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical group NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 claims description 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 2
- 239000003205 fragrance Substances 0.000 abstract description 14
- 229920000642 polymer Polymers 0.000 abstract description 11
- 238000002715 modification method Methods 0.000 abstract 2
- 239000002253 acid Substances 0.000 description 22
- 239000001506 calcium phosphate Substances 0.000 description 22
- 229910000389 calcium phosphate Inorganic materials 0.000 description 22
- 235000011010 calcium phosphates Nutrition 0.000 description 22
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 239000000126 substance Substances 0.000 description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- 230000004048 modification Effects 0.000 description 13
- 238000012986 modification Methods 0.000 description 13
- 239000006185 dispersion Substances 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000000428 dust Substances 0.000 description 10
- 125000000524 functional group Chemical group 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- 239000003139 biocide Substances 0.000 description 8
- 239000011651 chromium Substances 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 8
- 239000000178 monomer Substances 0.000 description 8
- 230000003115 biocidal effect Effects 0.000 description 7
- 229910052804 chromium Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000000377 silicon dioxide Substances 0.000 description 7
- 229920000178 Acrylic resin Polymers 0.000 description 6
- 239000004925 Acrylic resin Substances 0.000 description 6
- 229920001519 homopolymer Polymers 0.000 description 6
- 229920002401 polyacrylamide Polymers 0.000 description 6
- 239000008399 tap water Substances 0.000 description 6
- 235000020679 tap water Nutrition 0.000 description 6
- 239000006200 vaporizer Substances 0.000 description 6
- 229920002125 Sokalan® Polymers 0.000 description 5
- 241001062472 Stokellia anisodon Species 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000007598 dipping method Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000004584 polyacrylic acid Substances 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- 229960001866 silicon dioxide Drugs 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 238000004532 chromating Methods 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 229910000765 intermetallic Inorganic materials 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000006210 lotion Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 235000011007 phosphoric acid Nutrition 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- XEVRDFDBXJMZFG-UHFFFAOYSA-N carbonyl dihydrazine Chemical compound NNC(=O)NN XEVRDFDBXJMZFG-UHFFFAOYSA-N 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000003016 phosphoric acids Chemical class 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000010526 radical polymerization reaction Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 235000013599 spices Nutrition 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 2
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 150000001718 carbodiimides Chemical class 0.000 description 2
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 2
- 230000004087 circulation Effects 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 125000002883 imidazolyl group Chemical group 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000012778 molding material Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 150000002924 oxiranes Chemical group 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 229920003987 resole Polymers 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- OMSYGYSPFZQFFP-UHFFFAOYSA-J zinc pyrophosphate Chemical compound [Zn+2].[Zn+2].[O-]P([O-])(=O)OP([O-])([O-])=O OMSYGYSPFZQFFP-UHFFFAOYSA-J 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- CSNIZNHTOVFARY-UHFFFAOYSA-N 1,2-benzothiazole Chemical compound C1=CC=C2C=NSC2=C1 CSNIZNHTOVFARY-UHFFFAOYSA-N 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-N 1H-imidazole Chemical compound C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 1
- RXGSAYBOEDPICZ-UHFFFAOYSA-N 2-[6-[[amino-(diaminomethylideneamino)methylidene]amino]hexyl]-1-(diaminomethylidene)guanidine Chemical compound NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)N RXGSAYBOEDPICZ-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229940123208 Biguanide Drugs 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- HZVIGSHUIQEAAI-UHFFFAOYSA-N C(CCCCCCCCC)[P] Chemical compound C(CCCCCCCCC)[P] HZVIGSHUIQEAAI-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 108010020346 Polyglutamic Acid Proteins 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- VYRDHRYMAZWQJH-UHFFFAOYSA-N [P].P Chemical compound [P].P VYRDHRYMAZWQJH-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001409 amidines Chemical class 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical compound [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 description 1
- 150000004283 biguanides Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001638 boron Chemical class 0.000 description 1
- TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- LAIOKZCTQAIQDM-UHFFFAOYSA-H chromium(3+);diphosphate;heptahydrate Chemical compound O.O.O.O.O.O.O.[Cr+3].[Cr+3].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LAIOKZCTQAIQDM-UHFFFAOYSA-H 0.000 description 1
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007739 conversion coating Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- CASPZMCSNJZQMV-UHFFFAOYSA-N ethane;2-methyloxirane Chemical compound CC.CC1CO1 CASPZMCSNJZQMV-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 125000003010 ionic group Chemical group 0.000 description 1
- 229910000398 iron phosphate Inorganic materials 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical group [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005341 metaphosphate group Chemical group 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- ZTFZSHLWORMEHO-UHFFFAOYSA-A pentaaluminum;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ZTFZSHLWORMEHO-UHFFFAOYSA-A 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002643 polyglutamic acid Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 150000003376 silicon Chemical class 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- NFMWFGXCDDYTEG-UHFFFAOYSA-N trimagnesium;diborate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]B([O-])[O-].[O-]B([O-])[O-] NFMWFGXCDDYTEG-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- WQEVDHBJGNOKKO-UHFFFAOYSA-K vanadic acid Chemical compound O[V](O)(O)=O WQEVDHBJGNOKKO-UHFFFAOYSA-K 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000004846 water-soluble epoxy resin Substances 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/02—Homopolymers or copolymers of unsaturated alcohols
- C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D17/00—Regenerative heat-exchange apparatus in which a stationary intermediate heat-transfer medium or body is contacted successively by each heat-exchange medium, e.g. using granular particles
- F28D17/005—Regenerative heat-exchange apparatus in which a stationary intermediate heat-transfer medium or body is contacted successively by each heat-exchange medium, e.g. using granular particles using granular particles
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F13/00—Arrangements for modifying heat-transfer, e.g. increasing, decreasing
- F28F13/18—Arrangements for modifying heat-transfer, e.g. increasing, decreasing by applying coatings, e.g. radiation-absorbing, radiation-reflecting; by surface treatment, e.g. polishing
- F28F13/182—Arrangements for modifying heat-transfer, e.g. increasing, decreasing by applying coatings, e.g. radiation-absorbing, radiation-reflecting; by surface treatment, e.g. polishing especially adapted for evaporator or condenser surfaces
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/05—Polymer mixtures characterised by other features containing polymer components which can react with one another
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2245/00—Coatings; Surface treatments
- F28F2245/02—Coatings; Surface treatments hydrophilic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemical Treatment Of Metals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
亲水性改性剂(在亲水性改性剂中浓度,以质量%计) | 亲水性 | 气味 | |||||||
PVA | 金属化合物 | 交联剂 | 添加剂 | 1 | 2 | 粉尘气味1 | 附着气味1 | 附着气味2 | |
实施例1 | (2.0) | 磷酸钙(0.5) | - | - | 30 | 38 | 1.5 | 1.8 | 1.8 |
实施例2 | (2.0) | 磷酸铁(0.5) | - | - | 30 | 38 | 1.5 | 1.8 | 2 |
实施例3 | (2.0) | 三聚磷酸铝 | - | - | 30 | 38 | 1.5 | 1.8 | 1.8 |
实施例4 | (2.0) | 硼酸镁 | - | - | 30 | 37 | 1.5 | 1.8 | 1.8 |
实施例5 | (2.0) | 焦磷酸锌 | - | - | 30 | 38 | 1.5 | 1.8 | 1.8 |
实施例6 | (2.0) | 磷酸钙(0.5)分散剂(0.2) | - | - | 28 | 35 | 1.5 | 1.8 | 1.8 |
实施例7 | (2.0) | 磷酸钙(0.5) | 交联酚(0.2) | - | 30 | 38 | 1 | 1.8 | 1.8 |
实施例8 | 羧酸改性的(2.0) | 磷酸钙(0.5) | 硅烷偶联剂(0.2) | - | 25 | 35 | 1.5 | 2 | 2 |
实施例9 | 羰基改性的(2.0) | 磷酸钙(0.5) | 卡巴肼(0.2) | - | 28 | 35 | 1.5 | 1.8 | 2 |
实施例10 | (2.0) | - | 氟化锆锑(0.2) | - | 30 | 38 | 1.5 | 2 | 2 |
实施例11 | (2.0) | 磷酸钙(0.5) | 聚异氰酸酯(0.2) | - | 30 | 38 | 1 | 1.8 | 1.8 |
实施例12 | (2.0) | 磷酸钙(0.5) | - | 丙烯酸类树脂(0.5) | 25 | 35 | 1 | 1.8 | 1.8 |
实施例13 | (2.0) | - | - | 丙烯酸类树脂(0.5) | 25 | 35 | 1 | 2 | 2 |
实施例14 | (2.0) | 磷酸钙(0.5) | - | PEO(0.5) | 28 | 38 | 1.5 | 1.8 | 2 |
实施例15 | (2.0) | 磷酸钙(0.5) | - | 聚丙烯酰胺(0.5) | 25 | 35 | 1.5 | 2 | 2 |
实施例16 | (2.0) | 磷酸钙(0.5) | - | 聚乙烯基磺酸钠(0.5) | 25 | 35 | 1.5 | 2 | 2 |
实施例17 | (2.0) | 磷酸钙(0.5) | - | 树脂粒子(0.5) | 28 | 35 | 1.5 | 1.8 | 2 |
实施例18 | (2.0) | 磷酸钙(0.5) | - | 抗微生物剂(0.2) | 30 | 38 | 1.5 | 1.8 | 1.8 |
亲水性改性剂(在亲水性改性剂中浓度,以质量%计) | 亲水性 | 气味 | ||||
1 | 2 | 粉尘气味1 | 附着气味1 | 附着气味2 | ||
对比例1 | 聚丙烯酸(1.0)胶体二氧化硅(2.0) | 20 | 35 | 3 | 3 | 3 |
对比例2 | 羧甲基纤维素(1.0)聚丙烯酸(1.0)氟化锆锑(0.2) | 25 | 50 | 2 | 3 | 2.5 |
对比例3 | 聚乙烯基磺酸(1.0)聚丙烯酰胺(1.0)氟化锆锑(0.2) | 20 | 35 | 1.5 | 3 | 2.5 |
对比例4 | 聚乙烯吡咯烷酮(1.0)PEO(1.0)聚丙烯酸(1.0)磷酸钙(0.2) | 25 | 40 | 1.5 | 2.5 | 3 |
亲水性改性剂(在亲水性改性剂中浓度,以质量%计) | 亲水性 | 气味 | |||||||
PVA | 金属化合物 | 交联剂 | 添加剂 | 1 | 2 | 粉尘气味1 | 附着气味1 | 附着气味2 | |
实施例19 | (2.0) | 磷酸钙(0.5) | - | - | 25 | 35 | 1.5 | 1.8 | 1.8 |
实施例20 | (2.0) | 卡巴肼 | - | - | 25 | 35 | 1.5 | 1.8 | 1.8 |
实施例21 | (2.0) | 焦磷酸锌 | - | - | 28 | 35 | 1.5 | 1.8 | 1.8 |
实施例22 | (2.0) | 磷酸钙(0.5)分散剂(0.2) | - | - | 25 | 35 | 1.5 | 1.8 | 1.8 |
实施例23 | (2.0) | 磷酸钙(0.5) | 交联酚(0.2) | - | 28 | 38 | 1 | 1.8 | 1.8 |
实施例24 | 羰基改性的(2.0) | 磷酸钙(0.5) | 卡巴肼(0.2) | - | 22 | 35 | 1.5 | 2 | 1.8 |
实施例25 | (2.0) | - | 氟化锆锑(0.2) | - | 25 | 35 | 1.5 | 2 | 2 |
实施例26 | (2.0) | 磷酸钙(0.5) | - | 丙烯酸类树脂(0.5) | 20 | 33 | 1 | 1.8 | 1.8 |
实施例27 | (2.0) | - | - | 丙烯酸类树脂(0.5) | 23 | 33 | 1 | 2 | 2 |
实施例28 | (2.0) | 磷酸钙(0.5) | - | PE0(0.5) | 23 | 35 | 1.5 | 2 | 1.8 |
实施例29 | (2.0) | 磷酸钙(0.5) | - | 聚丙烯酰胺(0.5) | 20 | 33 | 1.5 | 2 | 2 |
实施例30 | (2.0) | 磷酸钙(0.5) | - | 聚乙烯基磺酸钠(0.5) | 20 | 33 | 1.5 | 2 | 2 |
实施例31 | (2.0) | 磷酸钙(0.5) | - | 树脂粒子(0.5) | 20 | 30 | 1.5 | 2 | 1.8 |
Claims (9)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001091048A JP4942251B2 (ja) | 2001-03-27 | 2001-03-27 | 親水化処理剤、親水化処理方法及び親水化処理されたアルミニウム材又はアルミニウム合金材 |
JP91049/01 | 2001-03-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1389524A true CN1389524A (zh) | 2003-01-08 |
CN1229446C CN1229446C (zh) | 2005-11-30 |
Family
ID=18945745
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB021080631A Expired - Fee Related CN1232597C (zh) | 2001-03-27 | 2002-03-27 | 亲水性改性剂,亲水性改性方法和由此得到的亲水性改性了的铝或铝合金材料 |
CNB021080704A Expired - Fee Related CN1229446C (zh) | 2001-03-27 | 2002-03-27 | 亲水性改性剂,亲水性改性方法和借此改性亲水性的铝材料或铝合金材料 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB021080631A Expired - Fee Related CN1232597C (zh) | 2001-03-27 | 2002-03-27 | 亲水性改性剂,亲水性改性方法和由此得到的亲水性改性了的铝或铝合金材料 |
Country Status (5)
Country | Link |
---|---|
US (1) | US7371272B2 (zh) |
EP (1) | EP1245654A1 (zh) |
JP (1) | JP4942251B2 (zh) |
CN (2) | CN1232597C (zh) |
AU (1) | AU782294B2 (zh) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102368031A (zh) * | 2011-06-28 | 2012-03-07 | 苏州方暨圆节能科技有限公司 | 具有薄膜的铝换热器板 |
CN102877052A (zh) * | 2011-07-15 | 2013-01-16 | 日本帕卡濑精株式会社 | 水系金属表面处理剂及利用该处理剂处理而得到的金属材料 |
CN103360894A (zh) * | 2012-03-27 | 2013-10-23 | 比亚迪股份有限公司 | 一种水性中涂漆及其制备方法 |
CN103789716A (zh) * | 2014-01-19 | 2014-05-14 | 大连理工大学 | 一种大气压冷等离子体射流对金属材料表面改性的方法 |
CN112245975A (zh) * | 2020-08-24 | 2021-01-22 | 浙江陌上科技有限公司 | 一种高分子改性剂及油水吸附材料 |
CN115917042A (zh) * | 2020-06-10 | 2023-04-04 | 诺维尔里斯公司 | 用于表面改性的利用含磷有机酸的铝合金预处理 |
CN117164902A (zh) * | 2023-11-02 | 2023-12-05 | 凯莱英生命科学技术(天津)有限公司 | 亲水性聚苯乙烯微球和其制备方法 |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10310972A1 (de) * | 2003-03-13 | 2004-09-23 | Basf Ag | Stickstoffhaltige Polymere für die Metalloberflächenbehandlung |
JP2007225174A (ja) * | 2006-02-22 | 2007-09-06 | Fujifilm Corp | 熱交換器 |
JP5129464B2 (ja) * | 2006-07-06 | 2013-01-30 | 住友軽金属工業株式会社 | 冷蔵庫用熱交換器及びその製造方法 |
JP2008224204A (ja) * | 2007-02-16 | 2008-09-25 | Kobe Steel Ltd | 熱交換器用アルミニウムフィン材 |
JP5086040B2 (ja) * | 2007-11-19 | 2012-11-28 | 関西ペイント株式会社 | 金属表面処理組成物 |
JP5529372B2 (ja) * | 2007-11-20 | 2014-06-25 | 関西ペイント株式会社 | 金属表面処理組成物 |
JP5319952B2 (ja) * | 2008-04-18 | 2013-10-16 | 株式会社神戸製鋼所 | 樹脂被覆アルミニウム製フィン材 |
JP2011153343A (ja) * | 2010-01-26 | 2011-08-11 | Nippon Paint Co Ltd | 熱交換器の表面処理方法、親水化処理剤、及びアルミニウム製熱交換器 |
JP5663174B2 (ja) * | 2010-02-15 | 2015-02-04 | 日本パーカライジング株式会社 | 表面処理皮膜を有するアルミニウム又はアルミニウム合金材料及びその表面処理方法 |
JP5865619B2 (ja) * | 2011-07-15 | 2016-02-17 | 日本パーカライジング株式会社 | 水系金属表面処理剤及びその処理剤で処理してなる金属材料 |
JPWO2013122106A1 (ja) * | 2012-02-13 | 2015-05-18 | 日本カーバイド工業株式会社 | ビニルエーテル共重合体及びこれを含有するコーティング組成物 |
JP6041717B2 (ja) * | 2012-12-25 | 2016-12-14 | 日本合成化学工業株式会社 | 親水化処理剤、及び該親水化処理剤で表面処理されたアルミニウム材 |
IN2015DN00095A (zh) * | 2013-03-21 | 2015-05-29 | Nihon Parkerizing | |
DE102014210278A1 (de) | 2014-05-30 | 2015-12-03 | Henkel Ag & Co. Kgaa | Hydrophile Beschichtung für Wärmetauscher |
JP6064088B1 (ja) * | 2015-04-24 | 2017-01-18 | 日本パーカライジング株式会社 | 水系表面処理剤、皮膜の製造方法及び表面処理材 |
CN107754017B (zh) * | 2016-08-22 | 2021-06-04 | 上海微创医疗器械(集团)有限公司 | 医疗器械表面用涂料及应用 |
JP6857996B2 (ja) * | 2016-10-25 | 2021-04-14 | 日本パーカライジング株式会社 | 表面処理剤、皮膜及び表面処理方法 |
JP6732644B2 (ja) * | 2016-12-02 | 2020-07-29 | 日本ペイント・サーフケミカルズ株式会社 | 熱交換器、及び熱交換器の親水化処理方法 |
CN106634389B (zh) * | 2016-12-30 | 2019-12-27 | 广州慧谷化学有限公司 | 一种用于制备润滑性亲水涂层的涂料及其应用 |
JP6941465B2 (ja) * | 2017-04-07 | 2021-09-29 | 日本ペイント・サーフケミカルズ株式会社 | 親水化処理剤及び親水性皮膜の形成方法 |
WO2019017647A1 (ko) * | 2017-07-19 | 2019-01-24 | 엘지전자 주식회사 | 열교환기 |
JP6928660B2 (ja) * | 2017-08-24 | 2021-09-01 | 花王株式会社 | インクジェット用液体組成物 |
JP7503449B2 (ja) * | 2020-08-13 | 2024-06-20 | 株式会社Uacj | プレコートフィン材 |
CN112827368B (zh) * | 2021-01-07 | 2023-08-11 | 中化(宁波)润沃膜科技有限公司 | 抗污染反渗透膜及其制备方法 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3052652A (en) * | 1958-02-26 | 1962-09-04 | Borden Co | Alkoxylated polyvinyl alcohol |
JPS59155408A (ja) * | 1983-02-22 | 1984-09-04 | Nippon Synthetic Chem Ind Co Ltd:The | 変性ポリビニルアルコ−ルの製造方法 |
JP2997066B2 (ja) | 1990-12-27 | 2000-01-11 | 大日本塗料株式会社 | 塗料組成物及び被覆アルミニウム材 |
JP2574197B2 (ja) * | 1992-04-24 | 1997-01-22 | 日本ペイント株式会社 | アルミニウム製熱交換器用親水化表面処理剤、及び親水化表面処理方法 |
JP2649297B2 (ja) | 1991-09-18 | 1997-09-03 | 三菱アルミニウム株式会社 | 塗料組成物及び塗装フィン材並びにフィン材の製造方法 |
JPH05202313A (ja) | 1992-01-24 | 1993-08-10 | Kansai Paint Co Ltd | 親水化処理剤 |
JPH06221786A (ja) * | 1992-09-14 | 1994-08-12 | Kobe Steel Ltd | 熱交換器用表面処理フィン |
US5478884A (en) * | 1992-10-27 | 1995-12-26 | Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha | Oxyalkylene group-containing polyvinyl alcohol resin composition and process for the production of shaped articles from said composition |
US5538078A (en) * | 1994-04-08 | 1996-07-23 | Nippondenso Co., Ltd. | Aluminum-containing metal composite material and process for producing same |
JP3102838B2 (ja) | 1994-04-08 | 2000-10-23 | 株式会社デンソー | アルミニウム含有金属複合材料およびその製造方法 |
JP3717205B2 (ja) | 1995-06-29 | 2005-11-16 | 株式会社デンソー | アルミニウム含有金属製熱交換器および製造方法 |
JP3819956B2 (ja) | 1995-09-22 | 2006-09-13 | 関西ペイント株式会社 | 親水化処理用組成物及び親水化処理方法 |
JPH1030069A (ja) | 1996-03-28 | 1998-02-03 | Nippon Light Metal Co Ltd | 水性親水性付与剤及びその付与剤を使用する熱交換器用プレコートフィン材の製造方法 |
JPH1036757A (ja) * | 1996-07-23 | 1998-02-10 | Dai Ichi Kogyo Seiyaku Co Ltd | 熱交換器フィン用親水性表面処理剤 |
WO1998044044A1 (fr) * | 1997-04-01 | 1998-10-08 | Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha | Solution aqueuse tres stable de resine ester vinylique partiellement saponifiee |
JPH11131254A (ja) | 1997-10-24 | 1999-05-18 | Nippon Parkerizing Co Ltd | アルミニウム含有金属材料の表面処理方法 |
JP4063375B2 (ja) * | 1997-11-28 | 2008-03-19 | 関西ペイント株式会社 | 親水化処理用組成物及び親水化処理方法 |
JP2000262968A (ja) * | 1999-03-15 | 2000-09-26 | Kobe Steel Ltd | 表面処理フィン材 |
JP4495270B2 (ja) * | 1999-05-18 | 2010-06-30 | 関西ペイント株式会社 | 親水化処理用組成物及び親水化処理方法 |
-
2001
- 2001-03-27 JP JP2001091048A patent/JP4942251B2/ja not_active Expired - Fee Related
-
2002
- 2002-03-26 AU AU27693/02A patent/AU782294B2/en not_active Ceased
- 2002-03-26 US US10/105,159 patent/US7371272B2/en not_active Expired - Lifetime
- 2002-03-27 CN CNB021080631A patent/CN1232597C/zh not_active Expired - Fee Related
- 2002-03-27 CN CNB021080704A patent/CN1229446C/zh not_active Expired - Fee Related
- 2002-03-27 EP EP20020290771 patent/EP1245654A1/en not_active Withdrawn
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102368031A (zh) * | 2011-06-28 | 2012-03-07 | 苏州方暨圆节能科技有限公司 | 具有薄膜的铝换热器板 |
CN102877052A (zh) * | 2011-07-15 | 2013-01-16 | 日本帕卡濑精株式会社 | 水系金属表面处理剂及利用该处理剂处理而得到的金属材料 |
CN102877052B (zh) * | 2011-07-15 | 2016-08-03 | 日本帕卡濑精株式会社 | 水系金属表面处理剂及利用该处理剂处理而得到的金属材料 |
CN103360894A (zh) * | 2012-03-27 | 2013-10-23 | 比亚迪股份有限公司 | 一种水性中涂漆及其制备方法 |
CN103789716A (zh) * | 2014-01-19 | 2014-05-14 | 大连理工大学 | 一种大气压冷等离子体射流对金属材料表面改性的方法 |
CN103789716B (zh) * | 2014-01-19 | 2015-10-28 | 大连理工大学 | 一种大气压冷等离子体射流对金属材料表面改性的方法 |
CN115917042A (zh) * | 2020-06-10 | 2023-04-04 | 诺维尔里斯公司 | 用于表面改性的利用含磷有机酸的铝合金预处理 |
CN112245975A (zh) * | 2020-08-24 | 2021-01-22 | 浙江陌上科技有限公司 | 一种高分子改性剂及油水吸附材料 |
CN117164902A (zh) * | 2023-11-02 | 2023-12-05 | 凯莱英生命科学技术(天津)有限公司 | 亲水性聚苯乙烯微球和其制备方法 |
CN117164902B (zh) * | 2023-11-02 | 2024-01-26 | 凯莱英生命科学技术(天津)有限公司 | 亲水性聚苯乙烯微球和其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
AU2769302A (en) | 2002-10-03 |
CN1377928A (zh) | 2002-11-06 |
CN1232597C (zh) | 2005-12-21 |
JP4942251B2 (ja) | 2012-05-30 |
US20030039849A1 (en) | 2003-02-27 |
US7371272B2 (en) | 2008-05-13 |
CN1229446C (zh) | 2005-11-30 |
JP2002285139A (ja) | 2002-10-03 |
EP1245654A1 (en) | 2002-10-02 |
AU782294B2 (en) | 2005-07-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1229446C (zh) | 亲水性改性剂,亲水性改性方法和借此改性亲水性的铝材料或铝合金材料 | |
CN1269579C (zh) | 亲水改性方法和用其处理过的热交换器 | |
EP1154042B1 (en) | Treatment method for making heat exchanger hydrophilic and heat exchanger treated to be hydrophilic | |
JP5570127B2 (ja) | 親水化処理剤、アルミニウム含有金属材及びアルミニウム合金製熱交換器 | |
WO2016195098A1 (ja) | 水性樹脂分散体、水性樹脂分散体の製造方法、親水化処理剤、親水化処理方法、金属材料及び熱交換器 | |
AU773821B2 (en) | Treatment agent for hydrophilicity and method for preparing thereof | |
JP5503556B2 (ja) | アルミニウム含有金属材用親水化処理剤、親水化処理方法及び親水化処理されたアルミニウム含有金属材 | |
US8815022B2 (en) | Method for surface treating a heat exchanger, surface treatment agent, and aluminum heat exchanger | |
CN1133709C (zh) | 亲水化处理剂、亲水化处理液及亲水化处理方法 | |
JP4464076B2 (ja) | 架橋性微粒子、親水処理剤、親水皮膜被覆方法及び親水皮膜 | |
CN1353296A (zh) | 制造铝散热片材料的方法和由该方法制得的铝散热片材料 | |
US20030039850A1 (en) | Modifier for hydrophilicity, hydrophilic modification method and aluminum material or aluminum alloy material modified hydrophilic thereby | |
JP2000328038A (ja) | 親水化処理用組成物及び親水化処理方法 | |
JP3836742B2 (ja) | 親水化処理方法及び親水化処理された熱交換器 | |
JP2005008975A (ja) | 金属表面処理方法、表面処理アルミニウム系金属、及び、親水処理の前処理方法 | |
JP4176026B2 (ja) | 防錆剤 | |
JP2009179811A (ja) | 架橋性微粒子、親水処理剤、親水皮膜被覆方法及び親水皮膜 | |
JPS62129366A (ja) | アルミニウムフイン用粧料 | |
JP2000248225A (ja) | 親水化処理用組成物及び親水化処理方法 | |
JPH09292197A (ja) | 熱交換器用親水化処理剤、処理方法及び処理アルミニウム材 | |
CN1128547A (zh) | 表面涂装方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C41 | Transfer of patent application or patent right or utility model | ||
C56 | Change in the name or address of the patentee | ||
CP01 | Change in the name or title of a patent holder |
Address after: Osaka Japan Patentee after: NIPPON PAINT HOLDINGS CO.,LTD. Address before: Osaka Japan Patentee before: NIPPON PAINT Co.,Ltd. |
|
TR01 | Transfer of patent right |
Effective date of registration: 20160114 Address after: Tokyo, Japan Patentee after: NIPPON PAINT SURF CHEMICALS CO.,LTD. Address before: Osaka Japan Patentee before: NIPPON PAINT HOLDINGS CO.,LTD. |
|
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20051130 Termination date: 20210327 |